Physical Sciences and Mathematics Commons^™

Degradation Of Oligo[Poly(Ethylene Glycol) Fumarate] Hydrogels Through Stimulus-Mediated Pendent Group Cyclization, Andrew Chung, Burak Tavsanli, Elizabeth Gillies

Chemistry Publications

Hydrogels are of interest for a wide range of applications including drug delivery, regenerative medicine, agriculture, and personal care products. Among the water-soluble synthetic polymers that can be processed to form hydrogels, oligo[poly(ethylene glycol) fumarate] (OPF) has attracted significant attention. The degradation of OPF can be tuned to some extent based on the poly(ethylene glycol) chain length and amount of cross-linker incorporated, but the degradation is generally quite slow, occurring over several months. Here we introduce a new approach to tune and trigger the degradation of OPF. Fumarate alkenes were functionalized to introduce protected pendent amines, that after deprotection could …

Re: Comment Letter For The Butte Priority Soils Operable Unit (Bpsou) Draft Final Quarterly Operations And Maintenance Report Butte Treatment Lagoon System – Fourth Quarter 2022 (Dated March 30, 2023), Nikia Greene

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

High Resolution Intracavity Laser Absorption Spectroscopy Of Transition Metal-Containing Diatomic Molecules, Kristin Bales

Dissertations

Three transition metal-containing diatomic molecules have been studied using intracavity laser spectroscopy. Many of the transitions were recorded using a Fourier-transform spectrometer for detection, allowing collection at Doppler-limited resolution for the gas phase molecules. Several vibrational bands in two electronic transition systems of tantalum fluoride (TaF) have been analyzed, and new molecular constants provided. Transitions involving six electronic states of tungsten sulfide (WS) have been analyzed, with new and updated constants provided, including a deperturbation analysis of three vibrational bands in two of the states. Finally, a fresh perspective on two electronic states of tungsten oxide (WO) included a deperturbation …

Sustainability Of Permanent Grassland On A Low Moor Soil With Different N And K Nutrient Management, K. Orlovius, J. Pickert

IGC Proceedings (1993-2023)

After the reunification of Germany fertilisation with P and K was strongly reduced in the eastern states of Germany due to the poor financial situation of the farms. Particularly on sites with a low nutrient delivery capacity, such a nutrient management strategy implies the risk of decreasing soil fertility. On a low moor soil with permanent grassland a 4 - year trial with different N and K fertilisation was set up to study the development of dry matter production and K concentrations in the grass.

Topological Comparison Of Some Dimension Reduction Methods Using Persistent Homology On Eeg Data, Eddy Kwessi

Mathematics Faculty Research

In this paper, we explore how to use topological tools to compare dimension reduction methods. We first make a brief overview of some of the methods often used in dimension reduction such as isometric feature mapping, Laplacian Eigenmaps, fast independent component analysis, kernel ridge regression, and t-distributed stochastic neighbor embedding. We then give a brief overview of some of the topological notions used in topological data analysis, such as barcodes, persistent homology, and Wasserstein distance. Theoretically, when these methods are applied on a data set, they can be interpreted differently. From EEG data embedded into a manifold of high dimension, …

External Behavior Of A Logic Program And Verification Of Refactoring, Jorge Fandinno, Zachary Hansen, Yuliya Lierler, Vladimir Lifschitz, Nathan Temple

Computer Science Faculty Publications

Refactoring is modifying a program without changing its external behavior. In this paper, we make the concept of external behavior precise for a simple answer set programming language. Then we describe a proof assistant for the task of verifying that refactoring a program in that language is performed correctly.

Fault Aware Task Scheduling In Cloud Using Min-Min And Dbscan, S. M.F.D.Syed Mustapha, Punit Gupta

All Works

Cloud computing leverages computing resources by managing these resources globally in a more efficient manner as compared to individual resource services. It requires us to deliver the resources in a heterogeneous environment and also in a highly dynamic nature. Hence, there is always a risk of resource allocation failure that can maximize the delay in task execution. Such adverse impact in the cloud environment also raises questions on quality of service (QoS). Resource management for cloud application and service have bigger challenges and many researchers have proposed several solutions but there is room for improvement. Clustering the resources clustering and …

Evaluation Of Bio-Friendly Formulations From Siderophore-Producing Fluorescent Pseudomonas As Biocontrol Agents For The Management Of Soil-Borne Fungi, Fusarium Oxysporum And Rhizoctonia Solani, Gaber Attia Abo-Zaid, Ahmed Salah Abdullah, Nadia Abdel-Mohsen Soliman, Ebaa Ebrahim El-Sharouny, Abdulaziz A. Al-Askar, Yiming Su, Ahmed Abdelkhalek, Soraya Abdel-Fattah Sabry

Civil and Environmental Engineering Faculty Publications

Secretion of siderophores by Pseudomonas aeruginosa F2 and P. fluorescens JY3 was evaluated on chrome azurol S (CAS) agar plates and their inhibitory effect was inspected against Fusarium oxysporum and Rhizoctonia solani. Production of siderophores as biocontrol agents from F2 and JY3 was accomplished in two optimized media. Afterward, cell-free supernatants of the bacterial cultures containing siderophores were used for the preparation of two bio-friendly formulations for the management of F. oxysporum and R. solani under greenhouse conditions. The investigated bacterial isolates, F2 and JY3, showed antagonistic activity in vitro against F. oxysporum and R. solani and produced siderophores …

Rhodium-Catalyzed Asymmetric Synthesis Of P-P And P-C Bonds, Sarah T. Chachula

Dartmouth College Ph.D Dissertations

Chapter 1: Synthesis, Structure, Dynamics, and Enantioface-Selective η3-Benzyl Coordination in the Chiral Rhodium Complexes Rh(diphos*)(η3-CH2Ph) Abstract: The rhodium benzyl complexes Rh(diphos*)(η3-CH2Ph) (1-14, diphos* = chiral bis(phosphine)) were prepared either by treatment of Rh(COD)(η3-CH2Ph) (15, COD = 1,5-cyclooctadiene) with diphos*, or from the reaction of [Rh(diphos*)(Cl)]2 (16- 20) with PhCH2MgCl. For C2-symmetric diphos*, observation of one set of NMR signals for complexes 1-12 suggested that the two diastereomers in which different 3-benzyl enantiofaces were coordinated to rhodium interconverted rapidly on the NMR time scale via suprafacial shifts; observation of five inequivalent aryl 1H NMR signals showed that antarafacial shifts were slow …

How Technology May Be Used For Future Disease Predictions, Rich P. Manprisio

Journal of Applied Disciplines

Exasperated by the ongoing global pandemic, the healthcare system is grappling with the formidable challenges posed by proper and effective disease treatments. Nevertheless, amidst these growing difficulties, the healthcare field has witnessed significant technological advancements, offering promising avenues for disease prediction. Notably, a positive correlation exists between the utilization of technologies and their potential to serve as valuable tools for disease prediction. As our reliance on technological sophistication continues progressing, current research highlights numerous viable options to augment the healthcare sector. This review explores the current state of utilizing technologies and their potential to enhance healthcare, shedding light on their …

Influence Of Cutting Parameters On The Performance Of Plough During Hard Rock Cutting In Coal Mining, Sathish Kumar Palaniappan, Moganapriya Chinnasamy, Samir Kumar Pal, Rajasekar Rathanasamy

Journal of Sustainable Mining

Coal ploughs have proved very successful on many faces in various parts of the world. Recently, there has been a general tendency in longwall working to increase the speed at which the machine progresses along the coal face. An increase in production rate demands enhances either due to depth of penetration or cutting speed. This, in turn, results in increasing power demand and also the force acting on an individual pick. To get maximum efficiency from a cutting machine, a number of parameters need to be investigated. The first and foremost thing of interest is naturally the pick geometry. The …

Detecting Mental Distresses Using Social Behavior Analysis In The Context Of Covid-19: A Survey, Sahraoui Dhelim, Liming Chen, Sajal K. Das, Huansheng Ning, Chris Nugent, Gerard Leavey, Dirk Pesch, Eleanor Bantry-White, Devin Michael Burns

Computer Science Faculty Research & Creative Works

Online social media provides a channel for monitoring people's social behaviors from which to infer and detect their mental distresses. During the COVID-19 pandemic, online social networks were increasingly used to express opinions, views, and moods due to the restrictions on physical activities and in-person meetings, leading to a significant amount of diverse user-generated social media content. This offers a unique opportunity to examine how COVID-19 changed global behaviors regarding its ramifications on mental well-being. In this article, we surveyed the literature on social media analysis for the detection of mental distress, with a special emphasis on the studies published …

The Relationship Between Water Temperature And Proximity To Surface Urban Heat Islands Within The Lower Chesapeake Bay Watershed For The Summer Of 2019, Sarah Kerner

Student Research Submissions

Surface urban heat islands (SUHIs) are land surfaces with high concentrations of impervious surfaces like roofs, roads, sidewalks and other infrastructures that trap, absorb, and re-emit heat throughout the day/night and typically present higher temperatures than their surrounding rural areas. In this study, I evaluate how presence of and distance to SUHIs are associated with water temperature in the lower Chesapeake Bay watershed for the summer of 2019. When heavy precipitation events occur, flooding creates stormwater runoff, which is exposed to the hotter temperatures in urban areas. This introduces thermal pollution to nearby rivers and streams disrupting aquatic ecosystems. The …

Synthesis Of Small Molecule Modulators Of Non-Traditional Drug Targets, Jamie Nunziata

USF Tampa Graduate Theses and Dissertations

This work details the effort toward structure-activity-relationship (SAR) studies and synthesis of the small molecule modulators of two non-traditional drug targets. The first part of this manuscript (chapters 1–2) will discuss the collaborative work and synthesis of an inhibitor of Slingshot Homology 1 (SSH1) with the potential therapeutic application toward Alzheimer’s Disease (AD) treatment. The second part (chapters 3–6) will discuss the synthetic efforts toward modulation of a protein target known as STING, or stimulator of interferon genes, with the therapeutic application toward autoimmune disease or anti-tumor activity.

AD is a progressive and degenerative illness that holds the title of …

The Rayleigh–Bénard Problem For Water With Maximum Density Effects, Mahanthesh Basavarajappa, Dambaru Bhatta

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

Linear stability and weakly nonlinear stability analyses are developed for Rayleigh–Bénard convection in water near 3.98 °C subject to isothermal boundary conditions. The density–temperature relationship (equation of state) is approximated by a cubic polynomial, including linear, quadratic, and cubic terms. The continuity equation, the Navier–Stokes momentum equation, the equation of state, and the energy equation constitute the governing system. Linear stability analysis is used to investigate how the maximum density property of water affects the onset of convective instability and the choice of unstable wave number for four different types of boundary conditions. Then, a weakly nonlinear stability study is …

Assessing Ecological Relationships Among Late Triassic Vertebrates In Petrified Forest National Park, Alexandra Davis Apgar

Earth and Planetary Sciences ETDs

The complex vertebrate ecosystem of the Late Triassic has not yet been fully understood, largely due to oversimplification of hypothesized trophic hierarchies and limited preservation of direct evidence of faunal interaction. Paleocommunity reconstruction attempts can also fall victim to taphonomic biases, time-averaging inaccuracies, and non-analogue paleoecologies. Utilizing a combination of PAIRS analysis and NMDS ordination, we highlight vertebrate faunal relationships within the Adamanian and Revueltian faunachrons of Petrified Forest National Park, assess the likelihood that these patterns have ecological rather than preservational drivers, and examine how these potential interactions may have been impacted by the Adamanian-Revueltian turnover event. We are …

From Waste To Energy: The Electrochemical Reduction Of Co2 Using Recycled Nanostructured Catalysts, Ibrahim Badawy

Theses and Dissertations

The reduction of carbon dioxide (CO₂RR) using electrochemistry is a promising solution for the burgeoning global energy crisis. The overall vision of its implementation relies on renewable energy sources to power the reaction creating carbon neutral products and effectively closing the carbon cycle. Research in this field has come a long way since its inception in the mid-1900s. However, there remain significant hurdles and important considerations to overcome in order to reach full commercialization. Most electrocatalysts tested for CO₂RR have been designed solely for maximum performance while ignoring the environmental consequences if such a material were …

A Method For Calculating Lateral Surface Area Of Bistatic Radar Beam Overlap, James I. Murray, Fredrick A. Jenet

Physics and Astronomy Faculty Publications and Presentations

It has been shown that bistatic radars using radio telescopes as receivers can be used to increase the sensitivity of orbital debris measurements over traditional terrestrial monostatic radar. A method to calculate the lateral surface area of a bistatic radar is needed to evaluate the efficacy of a proposed bistatic radar configuration for orbital debris measurements. For over three decades, models of the orbital debris (OD) environment in low Earth orbit (LEO) have been developed to assess the risk posed by OD to spacecraft. While terrestrial radar measures debris 3 mm and larger and in situ measurements provide data for …

Using Machine Learning Techniques To Model Encoder/Decoder Pair For Non-Invasive Electroencephalographic Wireless Signal Transmission, Ernst Fanfan

Master of Science in Computer Science Theses

This study investigated the application and enhancement of Non-Invasive Brain-Computer Interfaces (NI-BCIs), focused on enhancing the efficiency and effectiveness of this technology for individuals with severe physical limitations. The core research goal was to improve current limitations associated with wires, noise, and invasive procedures often associated with BCI technology. The key discussed solution involves developing an optimized Encoder/Decoder (E/D) pair using machine learning techniques, particularly those borrowed from Generative Adversarial Networks (GAN) and other Deep Neural Networks, to minimize data transmission and ensure robustness against data degradation. The study highlighted the crucial role of machine learning in self-adjusting and isolating …

An Interactional Account Of Empathy In Human-Machine Communication, Shauna Concannon, Ian Roberts, Marcus Tomalin

Human-Machine Communication

Efforts to develop empathetic agents, or systems capable of responding appropriately to emotional content, have increased as the deployment of such systems in socially complex scenarios becomes more commonplace. In the context of human-machine communication (HMC), the ability to create the perception of empathy is achieved in large part through linguistic behavior. However, studies of how language is used to display and respond to emotion in ways deemed empathetic are limited. This article aims to address this gap, demonstrating how an interactional linguistics informed methodological approach can be applied to the study of empathy in HMC. We present an analysis …

Geophysical Imprint Of Mining-Induced Rock Mass Deformation In The Area Of Construction Disaster In Bytom (Poland), Andrzej Kotyrba, Łukasz Kortas

Journal of Sustainable Mining

The paper presents the analysis of the results of geophysical surveys conducted in the mining area located in Bytom – Karb (USCB, Poland) in the aspect of identifying the causes of significant damage to the complex of inhabited tenement houses which occurred in 2011. The surveys were carried out by microgravimetric and GPR methods. The construction disaster was caused by the exploitation of one of the hard coal seams at a depth of about 800 m along the mining longwall running underneath the settlement. The terrain deformation parameters exceeded the forecasted values, and in several places discontinuities took linear forms …

Photophysical Properties Of Synthetic Oligomeric Phenylene Ethynylene, Hugh F. Fritz Jr.

Chemistry and Chemical Biology ETDs

Oligomeric Phenylene Ethynylenes (OPEs) are a class of synthetically prepared compounds with the basic structure of phenylene rings connected by triple-bonded carbon atoms, also known as an ethyne link. This structure can be modified by incorporating functional groups onto one or more of the phenylene rings. The addition of functional groups, such as sulfoxide or imidazole, may alter the photophysical properties in detectable ways. The photophysical techniques used in this report include fluorescence, spectroscopy in the ultraviolet and visible light range (UVVIS), and photon-based excitation using a photo chamber.

One attractive function of OPEs is their antimicrobial property. Previously published …

Search For Medium Effects Using Jets From Bottom Quarks In Pbpb Collisions At √SNn=5.02tev, A. Tumasyan

Department of Physics and Astronomy: Faculty Publications

The first study of the shapes of jets arising from bottom (b) quarks in heavy ion collisions is presented. Jet shapes are studied using charged hadron constituents as a function of their radial distance from the jet axis. Lead-lead (PbPb) collision data at a nucleon-nucleon center-of-mass energy of √s_NN=5.02TeVwere recorded by the CMS detector at the LHC, with an integrated luminosity of 1.69nb⁻¹. Compared to proton-proton collisions, aredistribution of the energy inbjets to larger distances from the jet axis is observed in PbPb collisions. This medium-induced redistribution is found to be substantially larger forbjets than for …

Dbscan Inspired Task Scheduling Algorithm For Cloud Infrastructure, S. M.F.D.Syed Mustapha, Punit Gupta

All Works

Cloud computing in today's computing environment plays a vital role, by providing efficient and scalable computation based on pay per use model. To make computing more reliable and efficient, it must be efficient, and high resources utilized. To improve resource utilization and efficiency in cloud, task scheduling and resource allocation plays a critical role. Many researchers have proposed algorithms to maximize the throughput and resource utilization taking into consideration heterogeneous cloud environments. This work proposes an algorithm using DBSCAN (Density-based spatial clustering) for task scheduling to achieve high efficiency. The proposed DBScan-based task scheduling algorithm aims to improve user task …

Draft Final 2023 Residential Metals Abatement Program (Rmap) Park Soil Sampling Field Sampling Plan (Fsp) Submittal #10 [Original Mine Yard], Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Draft Final Revised Residential Metals Abatement Program (Rmap) Quality Assurance Project Plan (Qapp) (Residential Parcels), Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Hyperspectral Point Cloud Projection For The Semantic Segmentation Of Multimodal Hyperspectral And Lidar Data With Point Convolution-Based Deep Fusion Neural Networks, Kevin T. Decker, Brett J. Borghetti

Faculty Publications

The fusion of dissimilar data modalities in neural networks presents a significant challenge, particularly in the case of multimodal hyperspectral and lidar data. Hyperspectral data, typically represented as images with potentially hundreds of bands, provide a wealth of spectral information, while lidar data, commonly represented as point clouds with millions of unordered points in 3D space, offer structural information. The complementary nature of these data types presents a unique challenge due to their fundamentally different representations requiring distinct processing methods. In this work, we introduce an alternative hyperspectral data representation in the form of a hyperspectral point cloud (HSPC), which …

Visualization Of Productivity Zones Based On Nitrogen Mass Balance Model In Narragansett Bay, Rhode Island, Jongsun Kim, Myung Hwangbo, Patricia S. Thibodeau, Georgia Rhodes, Emma Hogarth, Stewart Copeland

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Primary productivity in the coastal regions, linked to eutrophication and hypoxia, provides a critical understanding of ecosystem function. Although primary productivity largely depends on riverine nutrient inputs, estimation of the extent of riverine nutrient influences in the coastal regions is challenging. A nitrogen mass balance model is a practical tool to evaluate coastal ocean productivity to understand biological mechanisms beyond data observations. This study visualizes the biological production zones in Narragansett Bay, Rhode Island, USA, where hypoxia frequently occurs, by applying a nitrogen mass balance model. The Bay is divided into three zones - brown, green, and blue zones - …

What Is A Polygonal Impact Crater? A Proposed Framework Toward Quantifying Crater Shapes, Stuart J. Robbins, Jamie D. Riggs

College of Population Health Faculty Papers

Impact craters are used for a wide array of investigations of planetary surfaces. A crater form that is somewhat rare, forming only ∼10% of impact craters, is the polygonal impact crater (or PIC). These craters have been visually, manually identified as having at least two rim segments that are best represented as straight lines. Such straight lines or edges are most often used to infer details about the subsurface crust where faults control the structure of the crater cavity as it formed. The PIC literature is scant, but almost exclusively these craters are identified manually, and the potentially straight edges …

Decoy-Target Database Strategy And False Discovery Rate Analysis For Glycan Identification, Xiaoou Li

Electronic Thesis and Dissertation Repository

In recent years, the technology of glycopeptide sequencing through MS/MS mass spectrometry data has achieved remarkable progress. Various software tools have been developed and widely used for protein identification. Estimation of false discovery rate (FDR) has become an essential method for evaluating the performance of glycopeptide scoring algorithms. The target-decoy strategy, which involves constructing decoy databases, is currently the most popular utilized method for FDR calculation. In this study, we applied various decoy construction algorithms to generate decoy glycan databases and proposed a novel approach to calculate the FDR by using the EM algorithm and mixture model.