Physical Sciences and Mathematics Commons^™

An Analytical Method For Detecting Toxic Metal Cations Using Cyclotriveratrylene Derivative Capped Gold Nanoparticles, Zachary R. Osner, Richard C. Holz, Daniel P. Becker Ph.D.

Chemistry: Faculty Publications and Other Works

Cyclotriveratrylene-oxime (CTV-oxime) derivatives that terminate with a dithiolate linker were synthesized enabling the supramolecular scaffold to adhere to gold nanoparticles (AuNPs) with the bowl-shaped cavity of the CTV scaffold exposed for utilization in host–guest chemistry. Exposure of these CTV functionalized AuNPs to varying concentrations of di- and trivalent metal cations resulted in the formation of large CTV-AuNP polymeric clusters and an accompanying a shift in the plasmon resonance. These interactions between the CTV-AuNPs and the metal cations in solution provides proof-of-concept that supramolecular functionalized AuNPs can be used as a simple and straightforward, on-site detection system for toxic metal cations …

Propagation Of Tidal Waves Up In Yangtze Estuary During The Dry Season, Sheng Lu, Chaofeng Tong, Dong-Young Lee, Jinhai Zheng, Jian Shen, Wei Zhang, Yixin Yan

VIMS Articles

Tide is one of the most important hydrodynamic driving forces and has unique features in the Yangtze Estuary (YE) due to the complex geometry of third-order bifurcations and four outlets. This paper characterizes the tidal oscillations, tidal dampening, tidal asymmetry, and tidal wave propagation, which provides insights into the response of the estuary to tides during the dry season. The structural components of tidal oscillations are initially attained by tidal analysis. The increasingly richer spectrum inside the estuary shows an energy transfer corresponding to the generation and development of nonlinear overtides and compound tides. A 2-D numerical model is further …

Evidence For Unnatural-Parity Contributions To Electron-Impact Ionization Of Laser-Aligned Atoms, G. S. J. Armstrong, J. Colgan, M. S. Pindzola, S. Amami, Don H. Madison, J. Pursehouse, K. L. Nixon, A. J. Murray

Physics Faculty Research & Creative Works

Recent measurements have examined the electron-impact ionization of excited-state laser-aligned Mg atoms. In this work we show that the ionization cross section arising from the geometry where the aligned atom is perpendicular to the scattering plane directly probes the unnatural parity contributions to the ionization amplitude. The contributions from natural parity partial waves cancel exactly in this geometry. Our calculations resolve the discrepancy between the nonzero measured cross sections in this plane and the zero cross section predicted by distorted-wave approaches. We demonstrate that this is a general feature of ionization from p-state targets by additional studies of ionization from …

Coplanar Asymmetric Angles And Symmetric Energy Sharing Triple Differential Cross Sections For 200 Ev Electron-Impact Ionization Of Ar (3p), Zehra Nur Ozer, Sadek M. Amami, Onur Varol, Murat Yavuz, Mevlut Dogan, Don H. Madison

Physics Faculty Research & Creative Works

We have measured triple differential cross sections (TDCSs) for electron-impact ionization of the 3p shell of Ar at 200 eV incident electron energy. The experiments have been performed in coplanar asymmetric energy sharing geometry. The experimental results are compared with the theoretical models of three body distorted wave (3DW) and distorted wave Born approximation (DWBA).

Polyatomic Molecular Structure Retrieval Using Laser-Induced Electron Diffraction, Michael G. Pullen, Benjamin Wolter, Anh-Thu Le, Matthias Baudisch, Michael Hemmer, Arne Senftleben, M. Sclafani, Claus Dieter Schroeter, Joachim Ullrich, Robert Moshammer, C. D. Lin, Jens Biegert

Physics Faculty Research & Creative Works

Laser-induced electron diffraction is a developing dynamical imaging technique that is already able to probe molecular dynamics at few-femtosecond temporal resolutions and has the potential to reach the sub-femtosecond level. Here we provide the recipe for the extension of the technique to polyatomic molecules and we demonstrate the method by extracting the structure of aligned and anti-aligned acetylene (C₂H₂). We show that multiple bond lengths can be simultaneously imaged at high accuracy including elusive hydrogen containing bonds. Our results open the door to the investigation of larger complex molecules and the realization of a true molecular movie.

Predictive Inference Using Latent Variables With Covariates, Lynne Steuerle Schofield, B. Junker, L. J. Taylor, D. A. Black

Mathematics & Statistics Faculty Works

Plausible values (PVs) are a standard multiple imputation tool for analysis of large education survey data, which measures latent proficiency variables. When latent proficiency is the dependent variable, we reconsider the standard institutionally generated PV methodology and find it applies with greater generality than shown previously. When latent proficiency is an independent variable, we show that the standard institutional PV methodology produces biased inference because the institutional conditioning model places restrictions on the form of the secondary analysts’ model. We offer an alternative approach that avoids these biases based on the mixed effects structural equations model of Schofield (Modeling measurement …

Problems In The Theory Of Extremal Graphs And Hypergraphs, Cory T. Palmer

University Grant Program Reports

Objective: Investigate the tree packing conjecture from graph theory and extremal numbers for hypergraphs.

Near-Duplicate Image Retrieval Based On Contextual Descriptor, Jinliang Yao, Bing Yang, Qiuming Zhu

Computer Science Faculty Publications

The state of the art of technology for near-duplicate image retrieval is mostly based on the Bag-of-Visual-Words model. However, visual words are easy to result in mismatches because of quantization errors of the local features the words represent. In order to improve the precision of visual words matching, contextual descriptors are designed to strengthen their discriminative power and measure the contextual similarity of visual words. This paper presents a new contextual descriptor that measures the contextual similarity of visual words to immediately discard the mismatches and reduce the count of candidate images. The new contextual descriptor encodes the relationships of …

Inelastic Neutron Scattering Cross Sections For 76Ge Relevant To Background In Neutrinoless Double-Β Decay Experiments, Benjamin P. Crider, Erin Elizabeth Peters, J. M. Allmond, Marcus T. Mcellistrem, Francisco M. Prados-Estévez, T. J. Ross, J. R. Vanhoy, Steven W. Yates

Physics and Astronomy Faculty Publications

The experimental signature in searches for the neutrinoless double-β decay of ⁷⁶Ge is a peak near 2039 keV in the spectrum. Given the low probability of the process, it is important that the background in this region be well understood. Inelastic scattering reactions with neutrons from muon-induced interactions and (α,n) reactions in the surrounding materials or in the detector can provide contributions to the background. We have measured the production cross sections for γ rays from the ⁷⁶Ge(n,n'γ ) reaction in the 2039-keV region at incident neutron energies up to …

Spatial And Temporal Trends In Information Technology Outsourcing, Arti Mann, David Folch, Robert J. Kauffman, Luc Anselin

Research Collection School Of Computing and Information Systems

Over the last two decades information technology (IT) outsourcing has grown dramatically, and has emerged as a strategic choice for firms searching for ways to control their costs and maintain a competitive edge. The mechanisms driving its growth are not fully understood though. In this research, we employ an approach that focuses on geographic, temporal, and industrial proximity in a mechanism that identifies the process underlying the diffusion of IT outsourcing across firms within the U.S from 2000 to 2010. We focus on the role that firm location plays in the diffusion process, and use space-time clustering techniques from the …

Candy Crush Combinatorics, Dana Rowland

Mathematics Faculty Publications

In the popular game Candy Crush, differently colored candies are arranged in a grid and a player swaps adjacent candies in order to crush them by lining up three or more of the same color. At the beginning of each game, the grid cannot have three consecutive candies of the same color in a row or column, but it must be possible to swap two adjacent candies in order to get at least three consecutive candies of the same color. How many starting configurations are there? We derive recurrence relations to answer this question for a single line of candy, …

Being Environmentally Responsible: Cosmopolitan Orientation Predicts Pro-Environmental Behaviors, Angela K. Y. Leung, Kelly Koh, Kim-Pong Tam

Research Collection School of Social Sciences

Much research has examined individuals' values and beliefs as antecedents or correlates of pro-environmental behaviors (PEB). We approach this question from the novel perspective of individuals' cosmopolitan orientation (CO). We define CO as made up of three essential qualities. First, cultural openness captures individuals' receptiveness to immerse in and learn from other cultures. Second, global prosociality denotes a sense of collective moral obligation to universally respect and promote basic human rights. Third, respect for cultural diversity concerns high tolerance of and appreciation for cultural differences. Across two studies, we validated the Cosmopolitan Orientation Scale (COS) with theoretically related criterion measures …

Nonstationary Internal Tides Observed Using Dual-Satellite Altimetry, Edward D. Zaron

Civil and Environmental Engineering Faculty Publications and Presentations

Dual-satellite crossover data from the Jason-2 and Cryosat-2 altimeter missions are used in a novel approach to quantify stationary and nonstationary tides from time-lagged mean square sea surface height (SSH) differences, computed for lags from 1 to 1440 h (60 days). The approach is made feasible by removing independent estimates of the stationary tide and mesoscale SSH variance, which greatly reduces the sampling error of the SSH statistics. For the semidiurnal tidal band, the stationary tidal variance is approximately 0.73 cm(2), and the nonstationary variance is about 0.33 cm(2), or 30% of the total. The temporal correlation of the nonstationary …

Automatic Emotion Identification From Text, Wenbo Wang

Kno.e.sis Publications

Emotions are both prevalent in and essential to most aspects of our lives. They in- fluence our decision-making, affect our social relationships and shape our daily behavior. With the rapid growth of emotion-rich textual content, such as microblog posts, blog posts, and forum discussions, there is a growing need to develop algorithms and techniques for identifying people’s emotions expressed in text. It has valuable implications for the studies of suicide prevention, employee productivity, well-being of people, customer relationship management, etc. However, emotion identification is quite challenging partly due to the following reasons: i) It is a multi-class classification problem that …

Imaging Of Alignment And Structural Changes Of Carbon Disulfide Molecules Using Ultrafast Electron Diffraction, Jie Yang, Joshua Beck, Cornelis J. Uiterwaal, Martin Centurion

Martin Centurion Publications

Imaging the structure of molecules in transient-excited states remains a challenge due to the extreme requirements for spatial and temporal resolution. Ultrafast electron diffraction from aligned molecules provides atomic resolution and allows for the retrieval of structural information without the need to rely on theoretical models. Here we use ultrafast electron diffraction from aligned molecules and femtosecond laser mass spectrometry to investigate the dynamics in carbon disulfide following the interaction with an intense femtosecond laser pulse. We observe that the degree of alignment reaches an upper limit at laser intensities below the ionization threshold, and find evidence of structural deformation, …

Decadal Re-Evaluation Of Contaminant Exposure And Productivity Of Ospreys (Pandion Haliaetus) Nesting In Chesapeake Bay Regions Of Concern, Rs Lazarus, Ba Rattner, Pc Mcgowan, Robert Hale, Et Al

VIMS Articles

The last large-scale ecotoxicological study of ospreys (Pandion haliaetus) in Chesapeake Bay was conducted in 2000-2001 and focused on U.S. EPA-designated Regions of Concern (ROCs; Baltimore Harbor/Patapsco, Anacostia/middle Potomac, and Elizabeth Rivers). In 2011-2012, ROCs were re-evaluated to determine spatial and temporal trends in productivity and contaminants. Concentrations of p,p'-DDE were low in eggs and below the threshold associated with eggshell thinning. Eggs from the Anacostia/middle Potomac Rivers had lower total PCB concentrations in 2011 than in 2000; however, concentrations remained unchanged in Baltimore Harbor. Polybrominated diphenyl ether flame retardants declined by 40%, and five alternative brominated flame retardants were …

Wall Mechanical Properties And Hemodynamics Of Unruptured Intracranial Aneurysms, J. R. Cebral, X. Duan, Bong Jae Chung, C. Putman, Khaled Aziz, A. M. Robertson

Department of Applied Mathematics and Statistics Faculty Scholarship and Creative Works

BACKGROUND AND PURPOSE: Aneurysm progression and rupture is thought to be governed by progressive degradation and weakening of the wall in response to abnormal hemodynamics. Our goal was to investigate the relationship between the intra-aneurysmal hemodynamic conditions and wall mechanical properties in human aneurysms. MATERIALS AND METHODS: A total of 8 unruptured aneurysms were analyzed. Computational fluid dynamics models were constructed from preoperative 3D rotational angiography images. The aneurysms were clipped, and the domes were resected and mechanically tested to failure with a uniaxial testing system under multiphoton microscopy. Linear regression analysis was performed to explore possible correlations between hemodynamic …

Mobisurround: An Auditory User Interface For Geo-Service Delivery, Keith Gardiner, Charlie Cullen, James Carswell

Conference papers

This paper describes original research carried out in the area of Location-Based Services (LBS) with an emphasis on Auditory User Interfaces (AUI) for content delivery. Previous work in this area has focused on accurately determining spatial interactions and informing the user mainly by means of the visual modality. mobiSurround is new research that builds upon these principles with a focus on multimodal content delivery and navigation and in particular the development of an AUI. This AUI enables the delivery of rich media content and natural directions using audio. This novel approach provides a hands free method for navigating a space …

Precalculus, Thomas Tradler, Holly Carley

Open Educational Resources

From the preface, "These are notes for a course in precalculus, as it is taught at New York City College of Technology - CUNY (where it is offered under the course number MAT 1375). Our approach is calculator based. For this, we will use the currently standard TI-84 calculator, and in particular, many of the examples will be explained and solved with it. However, we want to point out that there are also many other calculators that are suitable for the purpose of this course and many of these alternatives have similar functionalities as the calculator that we have chosen …

A Geospatial Tool For Wetland Prioritization At The Watershed Scale, Debra Sue Blackmore, Heejun Chang

Institute for Natural Resources Publications

There is an increasing demand for assessing ecosystem functions for freshwater wetlands, especially when comparing or prioritizing among wetlands at the watershed scale. We estimated the relative potential of selected ecosystem functions for freshwater wetlands within a watershed using widely available geospatial data. We developed four functions to estimate 1) flood storage, 2) late season flow, 3) sediment retention and 4) temperature control in four pilot watersheds in Oregon (Tualatin, Coquille, Upper Grande Ronde and Sprague). These watersheds are geographically separated from each other representing diverse ecoregion environments. Spatial analysis and geographic information system (GIS) were designed for maximum re-use, …

Molecular View Modeling Of Atmospheric Organic Particulate Matter: Incorporating Molecular Structure And Co-Condensation Of Water, James F. Pankow, Marguerite Colasurdo Marks, Kelley C. Barsanti, Abdullah Mahmud, William E. Asher, Jingyi Li, Qi Ying, Shantanu H. Jathar, Michael J. Kleeman

Chemistry Faculty Publications and Presentations

Most urban and regional models used to predict levels of organic particulate matter (OPM) are based on fundamental equations for gas/particle partitioning, but make the highly simplifying, anonymized-view (AV) assumptions that OPM levels are not affected by either: a) the molecular. characteristics of the condensing organic compounds (other than simple volatility); or b) co-condensation of water as driven by non-zero relative humidity (RH) values. The simplifying assumptions have allowed parameterized chamber results for formation of secondary organic aerosol (SOA) (e.g., “two-product” (2p) coefficients) to be incorporated in chemical transport models. However, a return towards a less simplistic (and more computationally …

Hydrological Partitioning In The Critical Zone: Recent Advances And Opportunities For Developing Transferable Understanding Of Water Cycle Dynamics, Paul D. Brooks, Jon Chorover, Ying Fan, Sarah E. Godsey, Reed M. Maxwell, James P. Mcnamara, Christina Tague

Geosciences Faculty Publications and Presentations

Hydrology is an integrative discipline linking the broad array of water-related research with physical, ecological, and social sciences. The increasing breadth of hydrological research, often where subdisciplines of hydrology partner with related sciences, reflects the central importance of water to environmental science, while highlighting the fractured nature of the discipline itself. This lack of coordination among hydrologic subdisciplines has hindered the development of hydrologic theory and integrated models capable of predicting hydrologic partitioning across time and space. The recent development of the concept of the critical zone (CZ), an open system extending from the top of the canopy to the …

Umphlett Qci Sept 2015, Natalie Umphlett

High Plains Regional Climate Center: Personnel Publications

Highlights for the Basin

Temperature and Precipitation Anomalie

Streamflow

Heavy Rains Continued

Positive and Negative Impacts to Agriculture

Persistent Smoke from Wildfires

3-Month Precipitation and Temperature Outlooks

Managing Precision Dairy Farming Technologies, Barbara Alice Wadsworth, Amanda Stone, Lauren M. Mayo, Nicky Tsai, Jeffrey M. Bewley

Agriculture and Natural Resources Publications

Precision dairy farming is the use of technologies to measure physiological, behavioral, and production indicators of individual animals to improve management strategies and farm performance. These systems have the potential to detect disease and estrus and to evaluate cow comfort by monitoring activity, feeding time, lying time, mounting activity, real-time location, reticulorumen pH, rumination time, and body temperature.

The data provided by a precision dairy farming device is only valuable if it records the data properly for the right cow and is used by the producer. This factsheet will describe problems that researchers at the University of Kentucky have experienced …

Transients Of Platoons With Asymmetric And Different Laplacians, Ivo Herman, Dan Martinec, J. J. P. Veerman

Mathematics and Statistics Faculty Publications and Presentations

We consider an asymmetric control of platoons of identical vehicles with nearest-neighbor interaction. Recent results show that if the vehicle uses different asymmetries for position and velocity errors, the platoon has a short transient and low overshoots. In this paper we investigate the properties of vehicles with friction. To achieve consensus, an integral part is added to the controller, making the vehicle a third-order system. We show that the parameters can be chosen so that the platoon behaves as a wave equation with different wave velocities. Simulations suggest that our system has a better performance than other nearest-neighbor scenarios. Moreover, …

Mining Biological Networks Towards Protein Complex Detection And Gene-Disease Association, Eileen Marie Hanna

Dissertations

Large amounts of biological data are continuously generated nowadays, thanks to the advancements of high-throughput experimental techniques. Mining valuable knowledge from such data still motivates the design of suitable computational methods, to complement the experimental work which is often bound by considerable time and cost requirements. Protein complexes or groups of interacting proteins, are key players in most cellular events. The identification of complexes not only allows to better understand normal biological processes but also to uncover Disease-triggering malfunctions. Ultimately, findings in this research branch can highly enhance the design of effective medical treatments. The aim of this research is …

Coastal Sediment Elevation Change Following Anthropogenic Mangrove Clearing, Heather Lyn Hayden, Elise F. Granek

Environmental Science and Management Faculty Publications and Presentations

Coastal mangrove forests along tropical shorelines serve as an important interface between land and sea. They provide a physical buffer protecting the coastline from erosion and act as sediment “traps” catching terrestrial sediment, thus preventing smothering of subtidal coral reefs. Coastal development that removes mangrove habitat may impact adjacent nearshore coral reefs through sedimentation and nutrient loading. We examined differences in sediment elevation change between patches of open-coast intact and anthropogenically cleared red mangroves (Rhizophora mangle) on the east side of Turneffe Atoll, Belize, to quantify changes following mangrove clearing. Samples were collected over a 24 month period at five …

Climate-Suitable Planting As A Strategy For Maintaining Forest Productivity And Functional Diversity, Matthew Joshua Duveneck, Robert M. Scheller

Environmental Science and Management Faculty Publications and Presentations

Within the time frame of the longevity of tree species, climate change will change faster than the ability of natural tree migration. Migration lags may result in reduced productivity and reduced diversity in forests under current management and climate change. We evaluated the efficacy of planting climate-suitable tree species (CSP), those tree species with current or historic distributions immediately south of a focal landscape, to maintain or increase aboveground biomass, productivity, and species and functional diversity. We modeled forest change with the LANDIS-II forest simulation model for 100 years (2000–2100) at a 2-ha cell resolution and five-year time steps within …

Towards An Automated Screening Tool For Pediatric Speech Delay, Roozbeh Sadeghian, Stephen A. Zahorian

Faculty Works

Speech delay is a childhood language problem that sometimes is resolved on its own but sometimes may cause more serious language difficulties later. This leads therapists to screen children for detection at early ages in order to eliminate future problems. Using the Goldman-Fristoe Test of Articulation (GFTA) method, therapists listen to a child's pronunciation of certain phonemes and phoneme pairs in specified words and judge the child's stage of speech development. The goal of this paper is to develop an Automatic Speech Recognition (ASR) tool and related speech processing methods which emulate the knowledge of speech therapists. In this paper …

Simulating A Multi-Phase Tephra Fall Event: Inversion Modelling For The 1707 Hoei Eruption Of Mount Fuji, Japan, Christina Magill, Kazutaka Mannen, Laura J. Connor, Costanza Bonadonna, Charles B. Connor

School of Geosciences Faculty and Staff Publications

Fuji Volcano last erupted in ad 1707 depositing approximately 40 mm of tephra in the area that is now central Tokyo. New high-resolution data describe 17 eruptive phases occurring over a period of 16 days (Miyaji et al., J Volcanol Geotherm Res 207(3–4):113–129, 2011). Inversion techniques were used in order to best replicate geological data and eyewitness accounts, and to estimate eruption source parameters. Inversion results based on data from individual eruptive phases suggest a total erupted mass of 2.09 × 1012 kg. Comparatively, results based on a single data set describing the entire eruption sequence suggest a total …