Physical Sciences and Mathematics Commons^™

Fourier Inequalities In Lorentz And Lebesgue Spaces, Javad Rastegari Koopaei

Electronic Thesis and Dissertation Repository

Mapping properties of the Fourier transform between weighted Lebesgue and Lorentz spaces are studied. These are generalizations to Hausdorff-Young and Pitt’s inequalities. The boundedness of the Fourier transform on $R^n$ as a map between Lorentz spaces leads to weighted Lebesgue inequalities for the Fourier transform on $R^n$ .

A major part of the work is on Fourier coefficients. Several different sufficient conditions and necessary conditions for the boundedness of Fourier transform on unit circle, viewed as a map between Lorentz $\Lambda$ and $\Gamma$ spaces are established. For a large range of Lorentz indices, necessary and sufficient conditions for boundedness are …

Identification Of Ancient Maya Agriculture In The Periphery Of Motul De San José, Alexandra E. Smofsky

Electronic Thesis and Dissertation Repository

Agricultural systems were investigated in the Motul de San José periphery, an ancient Maya polity in Guatemala, using soil geochemical techniques. The δ¹³C values of soil organic matter delineated areas of ancient maize agriculture at the satellite center of Kante’t’u’ul. A new method to locate areas of former cacao cultivation or processing was developed using HPLC to detect theobromine, an alkaloid of the cacao plant, preserved in soils. Extraction of spiked soils revealed that theobromine adsorption is inversely correlated with organic matter content of soils. Detection of naturally occurring theobromine was successful, demonstrating its utility as a tracer. …

Stimuli-Responsive Polymersomes And Surface Functionalized Dendrimersomes: Platforms For Biomedical Applications, J Trevor Mcintosh

Electronic Thesis and Dissertation Repository

Amphiphilic block copolymers (BCPs) and dendrimers are known to self-assemble in aqueous solution to form a number of aggregate morphologies. These different architectures are largely a function of the hydrophilic volume or weight fractions of the different components of the polymer system. One possible morphology is a vesicle, also referred to as a polymersome or dendrimersome when BCPs or dendrimers, respectively, are used. Vesicles are multi-functional, supramolecular, bilayer assemblies, whose potential for stimuli-responsiveness and surface functionalization make them promising materials for a variety of biomedical applications. This thesis demonstrates the use of UV-sensitive block copolymers forming photodegradable vesicles, as well …

Mechanistic Studies Of Donor-Acceptor Cyclopropanes, Tristan Chidley

Electronic Thesis and Dissertation Repository

Cyclopropane 1,1-diesters have been investigated as a source of donor-acceptor cyclopropanes, providing an understanding of the mechanism of reaction between these cyclopropanes and nitrosoarenes, as well as azo dicarboxylates. Cross-over experiments have been utilized to provide key pieces of experimental evidence that help generate a theoretical model of the reactions. By understanding these reactions with precision, the avenue to expand the reaction scope and develop other useful reactions is opened up. This allows the chemistry to be better utilized, providing easier access to important molecules when needed, and contributes to advancing the field of synthetic organic chemistry.

In addition, cyclobutane …

Fourier Transform Infrared And Ultraviolet-Visible Spectroscopic Characterization Of Ammonium Acetate And Ammonium Chloride: An Impact Of Biofield Treatment, Mahendra Kumar Trivedi, Alice Branton, Dahryn Trivedi, Gopal Nayak, Khemraj Bairwa, Snehasis Jana

Mahendra Kumar Trivedi

A Coordinated X-Ray And Optical Campaign Of The Nearest Massive Eclipsing Binary, Δ Orionis Aa: Ii. X-Ray Variability., J. Nichols, D. P. Huenemoerder, M. F. Corcoran, W. Waldron, Y. Nazé, A. M. T. Pollock, A. F. J. Moffat, J. Lauer, T. Shenar, C. M. P. Russell, N. D. Richardson, H. Pablo, N. R. Evans, K. Hamaguchi, T. Gull, W.-R. Hamann, L. Oskinova, R. Ignace, Jennifer L. Hoffman, K. T. Hole, J. R. Lomax

Richard Ignace

We present time-resolved and phase-resolved variability studies of an extensive X-ray high-resolution spectral data set of the δ Ori Aa binary system. The four observations, obtained with Chandra ACIS HETGS, have a total exposure time of ≈ 479 ks and provide nearly complete binary phase coverage. Variability of the total X-ray flux in the range of 5–25 Å is confirmed, with a maximum amplitude of about ±15% within a single ≈ 125 ks observation. Periods of 4.76 and 2.04 days are found in the total X-ray flux, as well as an apparent overall increase in the flux level throughout the …

A Coordinated X-Ray And Optical Campaign Of The Nearest Massive Eclipsing Binary, Δ Ori Aa: I. Overview Of The X-Ray Spectrum., M. F. Corcoran, J. S. Nichols, H. Pablo, T. Shenar, A. M. T. Pollock, W. L. Waldron, A. F. J. Moffat, N. D. Richardson, C. M. P. Russell, K. Hamaguchi, D. P. Huenemoerder, L. Oskinova, W.-R. Hamann, Y. Nazé, R. Ignace, N. R. Evans, J. R. Lomax, J. L. Hoffman, K. Gayley, S. P. Owocki, M. Leutenegger, T. R. Gull, K. T. Hole, J. Lauer, R. C. Iping

Richard Ignace

A Coordinated X-Ray And Optical Campaign Of The Nearest Massive Eclipsing Binary, Δ Orionis Aa. Iii. Analysis Of Optical Photometric (Most) And Spectroscopic (Ground Based) Variations., Herbert Pablo, Noel D. Richardson, Anthony F. J. Moffat, Michael Corcoran, Tomer Shenar, Omar Benvenuto, Jim Fuller, Yaël Nazé, Jennifer L. Hoffman, Anatoly Miroshnichenko, Jesús Maíz Apellániz, Nancy Evans, Thomas Eversberg, Ken Gayley, Ted Gull, Kenji Hamaguchi, Wolf-Rainer Hamann, Huib Henrichs, Tabetha Hole, Richard Ignace, Rosina Iping, Jennifer Lauer, Maurice Leutenegger, Jamie Lomax, Joy Nichols, Lida Oskinova, Stan Owocki, Andy Pollock, Christopher M. P. Russell, Wayne Waldron, Christian Buil, Thierry Garrel, Keith Graham, Bernard Heathcote, Thierry Lemoult, Dong Li, Benjamin Mauclaire, Mike Potter, Jose Ribeiro, Jaymie Matthews, Chris Cameron, David Guenther, Rainer Kuschnig, Jason Rowe, Slavek Rucinski, Dimitar Sasselov, Werner Weiss

Richard Ignace

The Unusual 3d Interplay Of Basement Fault Reactivation And Fault-Propagation-Fold Development: A Case Study Of The Laramide-Age Stillwell Anticline, West Texas (Usa), Benjamin Surpless, Nicola Hill, Cara Beasley

Benjamin E Surpless

Subsurface fault geometries have a systematic influence on folds formed above those faults. We use the extraordinarily well-exposed fold geometries of the Laramide-age Stillwell anticline in west Texas (USA) to develop a strain-predictive model of fault-propagation fold formation. The anticline is a 10-km long, NW-trending, NE-vergent, asymmetric fold system with an axis that displays a map-view left-stepping, en echelon pattern. We integrated field observations, geologic and structural data, cross-sections, and 2D kinematic modeling to establish an unusual 3D two-stage model of contractional fold formation, including: 1) reverse reactivation of a pre-existing, NW-striking, SW-dipping, left-stepping, en echelon normal fault system in …

Holocene Earthquakes And Late Pleistocene Slip-Rate Estimates On The Wassuk Range Fault Zone, Nevada, Jayne Bormann, Benjamin Surpless, Marc Caffee, Steven Wesnousky

Benjamin E Surpless

The Wassuk Range fault zone is an 80‐km‐long, east‐dipping, high‐angle normal fault that flanks the eastern margin of the Wassuk Range in central Nevada. Observations from two alluvial fan systems truncated by the fault yield information on the vertical slip rate and Holocene earthquake history along the range front. At the apex of the Rose Creek alluvial fan, radiocarbon dating of offset stratigraphy exposed in two fault trenches shows that multiple earthquakes resulted in 7.0 m of vertical offset along the fault since ∼9400 cal B.P. These data yield a Holocene vertical slip rate of 0.7±0.1  mm/yr. The south trench …

Carbide-Derived Carbon By Electrochemical Etching Of Vanadium Carbides, Luis G.B. Camargo, Benjamin G. Palazzo, Greg Taylor, Zach A. Norris, Yash K. Patel, Jeffrey D. Hettinger, Lei Yu

College of Science & Mathematics Departmental Research

Carbide-derived Carbon (CDC) has been demonstrated to be an excellent electrode material for electrochemical devices including supercapacitors due to its chemical and electrochemical stability, large specific surface area and controllable pore size and morphology. Currently, CDC is prepared from metal carbides by chlorination in a chlorine gas atmosphere at temperatures of 350°C or higher. In this paper, conversion using electrochemical methods is reported, which can be achieved by oxidizing vanadium carbides (VC or V₂C) in aqueous solutions at room temperature and a mild electrode potential to prepare CDC thin film as electrode materials for “on-chip” supercapacitiors. It was …

Fluorinated Metallo Phthalocyanines For Chemical And Biological Catalysis, Hemantbhai H. Patel

Seton Hall University Dissertations and Theses (ETDs)

The rational design of robust oxidation catalysts based on organic molecules is hindered by the presence of labile C-H bonds. We have shown recently that replacing all C-H bonds by a combination of fluoro- and perfluoro-groups in a bioinspired Cytochrome P450 model based on a phthalocyanine, Pc, scaffold results in a stable yet reactive oxidation catalyst. The Pc cobalt complex catalyzes, for example, the aerobic oxidation of thiols to disulfides, a reaction of both biological significance and industrial importance.

The presence of robust C-F bonds, however, renders the catalyst unsuitable for attachment to solid-state supports, except via van der Waals …

Understanding The Backlog Problems Associated With Requests For Continued Examination Practice, Sean Tu

Duke Law & Technology Review

One of the greatest problems facing the current patent administration is a long patent pendency period. This study focuses on Request for Continued Examination (RCE) practice, and its effects on the current patent application backlog problem. RCEs are used to continue prosecution after a patent examiner has issued a final rejection. However, now that RCEs are placed on an examiner’s special docket, some examiners may pick up prosecution one to two years after the last action. Accordingly, there are great inefficiencies that may be created by this delay, such as relearning issues and questions from the previous action, diminished value …

Dendrochronological Analysis Of The Mann Homestead

Historic Structures

Dating historical structures using dendrochronology. The Historical Structures collection consists of reports that are the result of dendochronological analysis of timbers from structures in Pennsylvania and Ohio. Contributors: Wiesenberg, Nicholas

Coinage Metal Silylphosphido Complexes Stabilized By N-Heterocyclic Carbene Ligands, Bahareh Khalili Najafabadi

Electronic Thesis and Dissertation Repository

N-Heterocyclic carbenes (NHCs) are strong σ-donating ligands and thus, promising candidates for decorating and stabilizing metal-phosphide nanoclusters. While much research has been focused on the coordination of NHC ligands to different coinage metal centers in order to synthesize mononuclear organometallic complexes, their application in nanocluster chemistry has been relatively unexplored. The work described in this thesis involves employment of NHC ligands for stabilizing coinage metal t-butylthiolate and silylphosphido complexes. These complexes are promising molecular precursors for formation of larger NHC-stabilized nanoclusters.

In particular, the ligation of NHCs to [CuS^tBu] and [AgS^tBu] was developed as an …

Wildlife Of The Gold Coast Wetlands, Shelley Burgin, Daryl Mcphee

Daryl McPhee

Extract: Water in the landscape of the Gold Coast is dominated by marine and marine-influenced systems. The most obvious are the in-shore waters abutting the Gold Coast's world-famous beaches and estuaries. Little more than a glance at a map of the city also reveals the extensive canal estates built to take advantage of the marine waters, and indeed expand them. The waters of the rivers mix with the ocean's waters in the estuaries. These ecosystems are valuable nursery areas for marine wildlife, particularly, but not restricted to, fishes of commercial and recreational value.

Marine Environments Of The Gold Coast: Out With The Old, In With The New, Daryl Mcphee

Daryl McPhee

Extract: The marine environments of the Gold Coast comprise one of the most highly modified and heavily utilised waterways in Australia. Chapters 2 and 3 discussed changes in the historic land use patterns. Just what has this meant to the marine environments of the Gold Coast? In this chapter the contemporary marine h abitats of the Gold Coast are described, along with the fauna that those habitats support. We talk about how the current status of the habitats compares with various historical points in time, and the role of novel habitats. Given the impor tance of recreational fishing to both …

In Conclusion, Something To Chew On: Native Plant Foods Of The Gold Coast, Simon Grigalius, Daryl Mcphee

Daryl McPhee

Extract: Ask most people what Gold Coast food is and you may hear answers like the ubiquitous prawn cocktail with avocado, a burger with ' fresh' pineapple available at the local surf club, or fish and chips (eaten on the beach to give it the seaside connection), with the fish often imported from New Zealand or Vietnam. None of this is the true food of the Gold Coast.

A Brief History Of Discovery, Settlement And Development, Tor Hundloe, Craig Page

Tor Hundloe

Extract: If we can rely on anecdotal data, the answers to what is truly Australian will start with mention of the koala, go to kangaroos and then include the rest of Australia's peculiar (to foreigners) fauna. The only exception might be that if we asked a male from the Asian subcontinent (India, Pakistan, Sri Lanka and Bangladesh) what he identified Australia with, he might answer 'Cricket'. Putting that aside, the Gold Coast is very likely to be in the mix of Australian icons. To capture the essence of the Gold Coast, we need to talk about its history in more …

The Impact On The Gold Coast's Terrestrial Environments, Tor Hundloe

Tor Hundloe

Extract: We tend to think of the Gold Coast as a water environment. As tourists know, it sits on the shore of the vast Pacific Ocean. That is why most come. They have seen the magnificent photographs. If not perched on flattened dunes looking east to the ocean, a significant part of the urban Gold Coast environment is located around natural and human-made water environments. Of these we will say little here, other than to note their extent. The focus of this chapter is the city's terrestrial environments, reporting on and ultimately, after describing the environments, discussing what proportion of …

The Gold Coast Before Cook Named Mount Warning, Tor Hundloe

Tor Hundloe

Extract: We could and should ask, where does the Gold Coast sit on a scale from 'good' to 'bad' in environmental terms? Sustainable or unsustainable? Is it progressing or regressing? It is far too early in the book to attempt to answer this. Maybe at the end of the book you will feel confident to make your own assessment. What we do in this chapter is to make obvious a small number of seemingly irreversible changes that have occurred since the first escaped convicts walked the Gold Coast beaches. We know that indigenous Australians have lived on the Gold Coast …

The Gold Coast: A Snapshot, Tor Hundloe

Tor Hundloe

Extract: We know the city's boundaries as they are today (they have changed dramatically over time) and that is all we need to answer the question: what is the size of the city? The city's boundaries today are shown in Plate 3. As noted previously, the Gold Coast was a lot smaller in a geographical sense a couple of generations ago. When it was known as the 'South Coast' (or simply 'the Coast'), its northern boundary was at Lands End, north of Labrador. Coolangatta to Lands End established the south- north limits. Beenleigh in Logan City was considered the half-way …

State Of The Environment, Tor Hundloe

Tor Hundloe

Extract: What have we done? What have we learned? In this chapter we turn our attention to the people of the Gold Coast and their environmental impacts, as experienced in the 21st century. The past is gone. The damage is done. Dramatic change in landforms and ecological relationships are inevitable in building cities. From this we can only learn and do things better in the future. This is why there will never be another Gold Coast like the one we describe in this book.

Reducing The Ecological Footprint: The Prospect For Green Energy, Sophie Telfar, Tor Hundloe

Tor Hundloe

Extract: In this chapter we ask the question: what scope is there for Gold Coast citizens, businesses and government agencies to play a proportionally appropriate role in replacing greenhouse gas-producing fossil fuels (in the generation of electricity and for transport) by environmentally friendly energy sources? We could expect that a sunny coastal city caressed by waves, subject to diurnal tidal flows and noted for its sea breezes would have more than average potential to play a leading role in this cause. This we will explore after putting the question into perspective.

The Evolution Of Environmental Management As A Profession In Australia And New Zealand, E. Anderson, W. Haylock, Tor Hundloe, S. Molesworth, M. Morris, J. Roper-Lindsay, P. Skelton, J. Womersley

Tor Hundloe

Environmental management is a relatively new profession, having evolved since the rapid worldwide rise in environmental consciousness in the 1960s. This article, by past presidents of the Environment Institute of Australia and New Zealand, the inaugural editor of the Australasian Journal of Environmental Management, and collaborators, reflects on the establishment and development of environmental management as a profession, and the parallel development of the Institute as the focus for the profession. It concludes by considering future directions for the profession and Institute.

Lahar Infrasound Associated With Volcán Villarrica's 3 March 2015 Eruption, Jeffrey B. Johnson, Jose L. Palma

Geosciences Faculty Publications and Presentations

The paroxysmal 2015 eruption of Volcán Villarrica (Chile) produced a 2.5 h long lahar, which descended more than 20 km within the Rio Correntoso/Turbio drainage and destroyed two small bridges. A three-element infrasound array 10 km from the summit, and 4 km from the lahar’s closest approach, was used to study the flow’s progression. Array processing using cross-correlation lag times and semblance places constraints on the lahar’s dynamics, including detection of an initial flow pulse that traveled from 2 to 12 km at an average speed of 38m/s. Subsequently, the lahar signal evolved to a relatively stationary infrasonic tremor located …

Evaluation Of Regional Climate Models With Remotely Sensed Evapotranspiration Data, Doruk Ozturk

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Water is one of the most precious resources on Earth. Managing water resources is a complex discipline that requires accurate data, which in turn means that the management of water resources is limited by the availability and quality of these datasets. Evapotranspiration (ET) is one of these key datasets, but is also one that is lacking in large-scale spatial distribution with traditional methods such as weighing lysimeters or Bowen ratio. This is a quantity that needs to be evaluated in regional and global climate models since it is a substantial component of the land surface-atmosphere interaction. In order to overcome …

Sr2Ir1−XRhXO4(X<0.5): An Inhomogeneous JEff=1/2 Hubbard System, Shalinee Chikara, Daniel Haskel, Jae-Hoon Sim, Heung-Sik Kim, Cheng-Chien Chen, G. Fabbris, L. S. I. Veiga, N. M. Souza-Neto, Jsaminka Terzic, Kamal H. Butrouna, Gang Cao, Myung Joon Han, Michael Van Veenendaal

Physics and Astronomy Faculty Publications

In a combined experimental and theoretical study, we investigate the properties of Sr₂Ir_1−xRh_xO₄. From the branching ratios of the L-edge isotropic x-ray absorption spectra, we determine that the spin-orbit coupling is remarkably independent of x for both iridium and rhodium sites. DFT+U calculations show that the doping is close to isoelectronic and introduces impurity bands of predominantly rhodium character close to the lower Hubbard band. Overlap of these two bands leads to metallic behavior. Since the low-energy states for xj_eff=1/2 character, we suggest that the electronic …

Set It And Forget It: Approximating The Set Once Strip Cover Problem, Amotz Bar-Noy, Benjamin Baumer, Dror Rawitz

Mathematics Sciences: Faculty Publications

We consider the Set Once Strip Cover problem, in which n wireless sensors are deployed over a one-dimensional region. Each sensor has a fixed battery that drains in inverse proportion to a radius that can be set just once, but activated at any time. The problem is to find an assignment of radii and activation times that maximizes the length of time during which the entire region is covered. We show that this problem is NP-hard and that RoundRobin, the algorithm in which the sensors take turns covering the entire region, has a tight approximation guarantee of 3. Moreover, we …

Manipulating Electron Transfer Reactions From Micro- To Preparative Scale, Matthew Duane Graaf

Arts & Sciences Electronic Theses and Dissertations

The utilization of electron transfer reactions has allowed the transformation of a variety of substrates from polymer surfaces to highly functionalized organic molecules. The intricacies of these electron transfer reactions have been utilized to develop a new platform for building and studying addressable molecular libraries as they interact with biological targets. As a low cost, reusable alternative to other methods of these studying binding interactions, microelectrode arrays are beginning to gain traction with the scientific community as we continually push the limits of their potential. Additionally, the electron transfer techniques used to build the molecular libraries can be expanded to …