Physical Sciences and Mathematics Commons^™

Hydrophobic Surfactant Proteins Strongly Induce Negative Curvature, Mariya Chavarha, Ryan W. Loney, Shankar B. Rananavare, Stephen B. Hall

Chemistry Faculty Publications and Presentations

The hydrophobic surfactant proteins SP-B and SP-C greatly accelerate the adsorption of vesicles containing the surfactant lipids to form a film that lowers the surface tension of the air/water interface in the lungs. Pulmonary surfactant enters the interface by a process analogous to the fusion of two vesicles. As with fusion, several factors affect adsorption according to how they alter the curvature of lipid leaflets, suggesting that adsorption proceeds via a rate-limiting structure with negative curvature, in which the hydrophilic face of the phospholipid leaflets is concave. In the studies reported here, we tested whether the surfactant proteins might promote …

Attribute-Based Encryption With Efficient Verifiable Outsourced Decryption, Baodong Qin, Robert H. Deng, Shengli Liu, Siqi Ma

Research Collection School Of Computing and Information Systems

Attribute-based encryption (ABE) with outsourced decryption not only enables fine-grained sharing of encrypted data, but also overcomes the efficiency drawback (in terms of ciphertext size and decryption cost) of the standard ABE schemes. In particular, an ABE scheme with outsourced decryption allows a third party (e.g., a cloud server) to transform an ABE ciphertext into a (short) El Gamal-type ciphertext using a public transformation key provided by a user so that the latter can be decrypted much more efficiently than the former by the user. However, a shortcoming of the original outsourced ABE scheme is that the correctness of the …

A Convolution Kernel Approach To Identifying Comparisons In Text, Maksim Tkachenko, Hady W. Lauw

Research Collection School Of Computing and Information Systems

Comparisons in text, such as in online reviews, serve as useful decision aids. In this paper, we focus on the task of identifying whether a comparison exists between a specific pair of entity mentions in a sentence. This formulation is transformative, as previous work only seeks to determine whether a sentence is comparative, which is presumptuous in the event the sentence mentions multiple entities and is comparing only some, not all, of them. Our approach leverages not only lexical features such as salient words, but also structural features expressing the relationships among words and entity mentions. To model these features …

Online Learning To Rank For Content-Based Image Retrieval, Ji Wan, Pengcheng Wu, Steven C. H. Hoi, Peilin Zhao, Xingyu Gao, Dayong Wang, Yongdong. Zhang, Jintao Li

Research Collection School Of Computing and Information Systems

A major challenge in Content-Based Image Retrieval (CBIR) is to bridge the semantic gap between low-level image contents and high-level semantic concepts. Although researchers have investigated a variety of retrieval techniques using different types of features and distance functions, no single best retrieval solution can fully tackle this challenge. In a real-world CBIR task, it is often highly desired to combine multiple types of different feature representations and diverse distance measures in order to close the semantic gap. In this paper, we investigate a new framework of learning to rank for CBIR, which aims to seek the optimal combination of …

Probabilistic Inference Based Message-Passing For Resource Constrained Dcops, Supriyo Ghosh, Akshat Kumar, Pradeep Varakantham

Research Collection School Of Computing and Information Systems

Distributed constraint optimization (DCOP) is an important framework for coordinated multiagent decision making. We address a practically useful variant of DCOP, called resource-constrained DCOP (RC-DCOP), which takes into account agents’ consumption of shared limited resources. We present a promising new class of algorithm for RC-DCOPs by translating the underlying co- ordination problem to probabilistic inference. Using inference techniques such as expectation- maximization and convex optimization machinery, we develop a novel convergent message-passing algorithm for RC-DCOPs. Experiments on standard benchmarks show that our approach provides better quality than previous best DCOP algorithms and has much lower failure rate. Comparisons against an …

Active Semi-Supervised Approach For Checking App Behavior Against Its Description, Ma Siqi, Shaowei Wang, David Lo, Deng, Robert H., Cong Sun

Research Collection School Of Computing and Information Systems

Mobile applications are popular in recent years. They are often allowed to access and modify users' sensitive data. However, many mobile applications are malwares that inappropriately use these sensitive data. To detect these malwares, Gorla et al. Propose CHABADA which compares app behaviors against its descriptions. Data about known malwares are not used in their work, which limits its effectiveness. In this work, we extend the work by Gorla et al. By proposing an active and semi-supervised approach for detecting malwares. Different from CHABADA, our approach will make use of both known benign and malicious apps to predict other malicious …

Novel Azole-Based Rearrangements, Kolawole Folayele Ayinuola

Graduate Theses and Dissertations

This work describes efforts targeted at the development of novel reactivity modes for the Breslow intermediate, which was proposed by Breslow to explain the mechanism of action of thiamine-dependent enzymes. By employing this intermediate as a hydroxy-substituted N,S-ketene acetal, we successfully captured it via Claisen rearrangement towards the preparation of diaryl tertiary alcohol products that are isomers of the hitherto elusive intermediate. This strategy also constitutes an unusual disconnection for a Claisen rearrangement precursor.

We have also uncovered an unprecedented radical C-N bond scission of a Breslow intermediate when a fluorenyl group is installed on the azolium nitrogen atom. This …

Construction And Destruction Of Mont Pelée Volcano: Volumes And Rates Constrained From A Geomorphological Model Of Evolution, Aurélie Germa, Pierre Lahitte, Xavier Quidelleur

School of Geosciences Faculty and Staff Publications

This study presents long‐term volumes and construction rates for the Mont Conil‐Mont Pelée volcano and rate estimates at which volcanic activity creates relief. An algorithm, ShapeVolc, is used to numerically model topographic surfaces. Volcano morphology is analyzed using current digital elevation model in combination with mapped geology to produce 10 paleotopographies at the end of four constructional stages and three destructional events. Volumes of each constructional stage were estimated at about 35.2 km³, 26.2 km³, 8.3 km³, and 2.5 km³ for a total cumulative erupted volume of 72.2 km³. We estimate …

How Many Explosive Eruptions Are Missing From The Geologic Record? Analysis Of The Quaternary Record Of Large Magnitude Explosive Eruptions In Japan, Koji Kiyosugi, Charles B. Connor, Robert S. J. Sparks, Helen S. Crosweller, Sarah K. Brown, Lee Siebert, Ting Wang, Shinji Takarada

School of Geosciences Faculty and Staff Publications

Large magnitude explosive eruptions in Japan were compiled for the Large Magnitude Explosive Volcanic Eruptions (LaMEVE) database. Here we use this dataset to investigate the under-recording of Japanese explosive eruptions. We identify under-recording of Volcanic Explosivity Index (VEI) 4–5 eruptions on two timescales. Model fitting and Akaike’s information criterion (AIC and AICc) model selection suggest that these trends can be represented with the double exponential decay model, reflecting geologic processes. The time series of the recording rate of larger eruptions (VEI 6 and 7) show a slowly decreasing trend in comparison to smaller eruptions. These time series can be represented …

Long-Term Effects Of Alternative Residue Management Practices On Near-Surface Soil Properties And Soybean Production In A Wheat-Soybean, Double-Crop System In Eastern Arkansas, Christopher Ryan Norman

Graduate Theses and Dissertations

Adoption of management practices that maintain or increase soil organic matter (SOM), which contains 58% carbon (C) on average, may help to mitigate climate change by sequestering atmospheric C. Therefore, the main objective of this study was to determine the long-term trends in SOM, soil C and nitrogen (N), bulk density, various soil chemical properties (i.e., pH, electrical conductivity [EC], and Mehlich-3-extractable nutrients) in the top 10 cm, and soybean yield as affected by residue burning (burning and non-burning), tillage (conventional and no-tillage), irrigation (irrigated and non-irrigated), and N-fertilization/residue level (high and low) in a wheat (Triticum aestivum L.)-soybean [Glycine …

Lithologic Controls On Bedrock Channel Morphology In The Buffalo River Basin, Evan A. Thaler

Graduate Theses and Dissertations

The longevity of high relief terrains in passive margin systems remains an explained phenomenon in geomorphology. Current landscape evolution models assume an equilibrium state between rock uplift rates and erosion rates. However, analysis of chi gradients of bedrock channels across several lithologies in the Buffalo River Basin reveals disequilibrium in the basin controlled by the presence of a thick interval of Pennsylvanian sandstone that caps many of the plateaus in the basin. Headwater channels beneath the caprock tend to have higher chi gradient values in all lithologies than headwater channels in basins where the sandstone caprock is absent. High chi …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

The Effects Of Strain And Vacancies On The Electric And Vibrational Properties Of Ferroelectric Batio3 From First-Principles, Aldo Serge Michael Raeliarijaona

Graduate Theses and Dissertations

The studies of ferroelectricity (FE) are of technological significance because of the multitude of applicable properties that ferroelectric materials exhibit. The mastery, and control of these properties necessitate the knowledge of the fundamental physics governing these insulating materials.

In this dissertation I present the results of first-principles investigations of the behavior of the fundamental ferroelectric properties under strain, and in the presence of vacancies. In the first part I introduce the important FE properties, their common behavior, and their numerous valuable applications. Following this background on FEs, a review of theoretical methods is presented with topics such as: Density Functional …

Surface Modification Of Noble Metal Nanostructures Toward Biomedical Applications, Samir V. Jenkins

Graduate Theses and Dissertations

Noble metal nanostructures have seen a steady increase in biomedical application over the last several decades; new diagnostic and therapeutic modalities are under intense investigation. Many of these applications are possible because of post-synthetic modifications to the particle surface. These modifications take a variety of forms and can significantly affect the pharmacokinetics of these particles. In this work, various surface modifications were investigated. Particle agglomeration, which occurs when particle surfaces remain in contact, can significantly affect the toxicity and efficacy of a nanomedicine. Darkfield microscopy and single-particle ICP-MS were developed as complementary methods to detect agglomeration in blood, with the …

In Vitro Microdialysis Sampling Collection Of Volatile Organic Compounds (Voc's), Dodecafluoropentane (Ddfp) And Isoflurane, Valerie Shannon Mckinney

Graduate Theses and Dissertations

Death by stroke occurs every four minutes to human beings. Strokes cause necrosis within the tissue of the brain due to deprivation of oxygen. Perfluorocarbons have the ability to transport oxygen to tissue and in return decrease cell death. Dodecafluoropentane (DDFP) is a volatile fluorocarbon and collection in vivo can be a challenge since this compound evaporates at room temperature. There is currently not an efficient collection method in vivo for compounds that are volatile. Without a method to collect DDFP it is impossible to be approved for clinical use since exact concentrations of the drug within the body will …

Solubility And Detectability Of Hydrocarbons On The Surface Of Titan, Sandeep Singh

Graduate Theses and Dissertations

Titan’s thick atmosphere is enriched with organic compounds and its surface holds reservoirs of hydrocarbons. This makes Titan the only other candidate in our solar system (apart from Earth) to have stable liquid at the surface. The stability and characteristics of liquid and ices on the surface of Titan are of high importance in understanding its surface-atmosphere interactions. Titan’s hydrological cycle is similar to what we see on Earth, with the exception of methane (CH4) and ethane (C2H6) taking the place of water. The smoggy atmosphere veils the surface of Titan from the view of Cassini spacecraft, except at seven …

Asymmetric Synthesis And Transition Metal-Catalyzed Cross-Coupling Arylations Of Selected Organolithiums, Barry Kyle Sharp

Graduate Theses and Dissertations

My former boss, Dr. Gawley, always loved to say, “The world is chiral” (à la Pasteur). From DNA and proteins to hands and feet, it is obviously true. Also, a wide variety of chemical products exist as single enantiomers. Advances in chemical technology have greatly accelerated asymmetric synthesis in the past quarter century, and namely, organolithiums, have been shown to provide a versatile route to chiral natural products and biologically active molecules. Versatility arises from the array of methods that produce a chiral organolithium. Dynamic thermodynamic resolution (DTR) is considered one of the most practical methods, but among the others …

Reducing Nutrient Runoff From Poultry Production Facilities Using Locally-Sourced Iron And Aluminum Byproducts, Sheri Lynn Herron

Graduate Theses and Dissertations

Phosphorus (P) inputs to fresh waters can accelerate the eutrophication process. Agricultural nutrient runoff has been shown to be a contributor of P and nitrogen (N). Broiler production areas were evaluated for their potential to contribute P and N to runoff. Broiler house dust (BHD) samples were analyzed and compared to broiler litter (BL), rainfall simulations were conducted on plots adjacent to broiler house fans to evaluate nutrient enrichment in runoff from deposited dust, and runoff was automatically sampled at two culverts draining the land around broiler houses. Following this, an on-farm byproduct containment and nutrient removal structure was designed …

Fret Study Of Ligand Binding And Exchange Kinetics On The Surface Of Cdse/Zns Quantum Dots, Randee Jean Mcbride

Graduate Theses and Dissertations

Quantum dots are a valuable tool in many research applications and commercial development. Their applications are far reaching and as such have become a topic of great interest. One of their greatest assets is the ability to utilize them as water soluble fluorescent labels. Rendering the nanocrystals water soluble can be accomplished in several ways, but one very popular method is by capping them with water-soluble multi-functional organic ligands. However, these ligands, when attached to the quantum dot surface, are labile and can be exchanged which can be problematic when using the quantum dots in research applications. This projects investigates …

Grass Finishing Systems For Lambs, Erin Leigh Smyth

Graduate Theses and Dissertations

There is strong interest in sustainably produced meat. Grass-fed lamb could fulfill this market by reducing off-farm inputs. The objective was to examine the effect of grass-finishing or minimal supplementation on performance of lambs in the southeastern US. Katahdin lambs born in October 2013 and 2014 and February 2014 were weaned in January 2014/2015 and May 2014, respectively. Lambs were blocked by gender (fall; winter included only ram lambs) and randomly assigned to receive no (NON) or grain co-product supplement (SUP; 15% CP) at 0.5% of BW/d. Lambs were rotationally grazed on predominantly grass. Body weight, fecal egg counts (FEC), …

Engineering The Ground State Of Complex Oxides, Derek Joseph Meyers

Graduate Theses and Dissertations

Transition metal oxides featuring strong electron-electron interactions have been at the forefront of condensed matter physics research in the past few decades due to the myriad of novel and exciting phases derived from their competing interactions. Beyond their numerous intriguing properties displayed in the bulk they have also shown to be quite susceptible to externally applied perturbation in various forms. The dominant theme of this work is the exploration of three emerging methods for engineering the ground states of these materials to access both their applicability and their deficiencies.

The first of the three methods involves a relatively new set …

An Empirical Water Quality And Best Management Practice Prioritization Model For Select Arkansas Watersheds, James Mccarty

Graduate Theses and Dissertations

The purpose of this study was to prioritize subwatersheds using water quality data and watershed characteristics. Water quality data was provided through studies by the Arkansas Natural Resources Commission, Beaver Water District, Arkansas Water Resources Center, and publicly available USGS gage data. A total of 114 sites across five HUC-8 watersheds were analyzed, including 12 USGS gages. Watershed characteristic data was retrieved from USGS and Arkansas GeoStore geodatabase repositories. A significant linear relationship between baseflow and stormflow nutrient concentrations was established allowing for the use of baseflow concentrations in the prioritization methodology. Pearson correlation, linear regression, classification and regression tree, …

Life Cycle Assessment Of Alternative Swine Management Practices, Prathamesh Avadhut Bandekar

Graduate Theses and Dissertations

Life Cycle Assessments (LCAs) are quantitative analyses of complex systems for evaluation of impacts and risk associated with management decisions. LCAs can be effective tools for determining comparative advantages of management strategies across specific impact concern. In this study, life cycle assessments of pork production management alternatives was performed. The alternative management practices included in this study were production of entire males (boars), use of pens for gestation housing, immunocastration, production without growth promoting antimicrobials, production without growth promoting and preventive antimicrobials, and production without ractopamine. These LCAs evaluated the impact of each management strategy on greenhouse gas emission (GHG), …

Is Chir Pine Displacing Banj Oak In The Central Himalaya? Socioeconomic Implications For Local People And The Conservation Of Oak Forest Biodiversity, Ankush Nautiyal

Graduate Theses and Dissertations

Various studies have suggested that chir pine (Pinus roxburghii) is replacing banj oak (Quercus leucotrichophora) in the Central Himalaya. Five sites with three different types of forests (banj oak, chir pine and mixed oak-pine) were sampled to compare the diversity of their vegetation and to assess the impact of this ongoing conversion on biodiversity. Soil samples collected from oak and pine forests were analyzed and compared. In addition, dendrochronology was used to obtain age estimates of chir pine and to understand the growth response of this species to precipitation. Also, samples of ectomycorrhizal fungi were collected in the form of …

Odu-European Collaborations On Climate Change And Sea Level Rise Reserach, Tal Ezer

CCPO Publications

Less than five years ago, Old Dominion University started the Climate Change and Sea Level Rise Initiative (CCSLRI), which led to the recently established Mitigation and Adaptation Research Institute (MARI) and the Hampton Roads Sea Level Rise Preparedness & Resilience Intergovernmental Planning Pilot Project. This interdisciplinary area of research also has a long history in many European countries. Direct measurements of sea level started more than 200 years ago and flood mitigation measures have been in effect for a long time in London, the Netherlands and many other places. Today, reports on flooding in Norfolk, UK, by the BBC or …

Tools For Outreach Presentations, Ronald I. Greenberg, Dale Reed

Computer Science: Faculty Publications and Other Works

We present resources we have constructed and culled from the internet that can be used in computing outreach visits in K–12 classrooms, especially high schools. We have used such tools at about 100 schools, reaching several thousand students, and achieving positive attitudinal responses in surveys of several hundred of these students.

Local And Nonlocal Models In Thin-Plate And Bridge Dynamics, Jeremy Trageser

Department of Mathematics: Dissertations, Theses, and Student Research

This thesis explores several models in continuum mechanics from both local and nonlocal perspectives. The first portion settles a conjecture proposed by Filippo Gazzola and his collaborators on the finite-time blow-up for a class of fourth-order differential equations modeling suspension bridges. Under suitable assumptions on the nonlinearity and the initial data, a finite-time blowup is demonstrated as a result of rapid oscillations with geometrically growing amplitudes. The second section introduces a nonlocal peridynamic (integral) generalization of the biharmonic operator. Its action converges to that of the classical biharmonic as the radius of nonlocal interactions---the ``horizon"---tends to zero. For the corresponding …

Data And Analytics In Corporate Real Estate: Do You Have The Right Talent?, Clarence Goh

Research Collection School Of Accountancy

Is the lack of suitable data and analytics talent in your corporate real estate (CRE) team preventing you from contributing to the wider business strategy?

A Tent Pitching Scheme Motivated By Friedrichs Theory, Jay Gopalakrishnan, Peter Monk, Paulina Sepulveda

Mathematics and Statistics Faculty Publications and Presentations

Certain Friedrichs systems can be posed on Hilbert spaces normed with a graph norm. Functions in such spaces arising from advective problems are found to have traces with a weak continuity property at points where the inflow and outflow boundaries meet. Motivated by this continuity property, an explicit space-time finite element scheme of the tent pitching type, with spaces that conform to the continuity property, is designed. Numerical results for a model one-dimensional wave propagation problem are presented.

Sub-Planckian Black Holes And The Generalized Uncertainty Principle, Bernard Carr, Jonas R. Mureika, Piero Nicolini

Physics Faculty Works

The Black Hole Uncertainty Principle correspondence suggests that there could exist black holes with mass beneath the Planck scale but radius of order the Compton scale rather than Schwarzschild scale. We present a modified, self-dual Schwarzschild-like metric that reproduces desirable aspects of a variety of disparate models in the sub-Planckian limit, while remaining Schwarzschild in the large mass limit. The self-dual nature of this solution under M ↔ M⁻¹ naturally implies a Generalized Uncertainty Principle with the linear form Δx∼1/Δp+Δp. We also demonstrate a natural dimensional reduction feature, in that the gravitational radius and thermodynamics of sub-Planckian objects resemble …