Physical Sciences and Mathematics Commons^™

Greenhouse Gas Emission Reduction Plan, Lauren Bruhl, Guinter Vogg, Gabe Hamburg, Shanu Sankara, Rohan Kansagra, Colin Page, Colette Vynerib

Sustainability Exchange

Our team aimed to compile a greenhouse gas inventory for the St. Louis region. Partnered with OneSTL, Ameren, and the USGBC, we determined that St. Louis has a goal to reduce emissions 50% by 2030 from 2005 levels, and become carbon neutral in 2050. After analyzing the Ameren’s Integrated Resource Plan and factors such as the cost and scope of emissions, we researched funding sources to improve energy efficiency and increase renewables in the region. Our top funding sources are the Inflation Reduction Act (IRA) and the Bipartisan Infrastructure Law (BIL). From the IRA, we found the following credits most …

Wustl Campus Zero-Waste Strategy Washu Waste System Assessment & Zero Waste Planning, Carol Ge, Bella Kennebrae, Thalia Phillips, Avi Shah, Charles Wilson

Sustainability Exchange

WUSTL Campus Zero-Waste Strategy WashU Waste System Assessment & Zero Waste Planning for Sustainability Exchange, Washington University in St. Louis, Spring 2023

Change Point Detection For A Process Having Several Regimes, Oliver Gerd Meister

Theses and Dissertations

In this dissertation, possible methods for multiple change point detection on Markovchain processes are studied. Related works for oine and online change point detection are discussed and their applicability on sequential multiple change point detection for several regimes is evaluated. We develop a method for a multiple change point detection for a process having three regimes. Its eciency is then evaluated on simulated Markov chain data by looking into dierent scenarios such as processes that signicantly dier between each other or probability distributions that are slightly similar. This approach is then applied on Covid- 19 hospital data. Therefore, the data …

Analyzing And Computing Complete Solution For Dots And Boxes Game, Carl Mcaninch

Graduate Dissertations and Theses

This thesis improves a process that analyzes all the states of a game of Dots and Boxes. We use retrograde analysis and simulations to create a solution that provides significant performance improvements over our previous best solution. Expanding upon a previous 4x4 solution using rotations, reflections, better optimization, and cloud computing to limit the processing time and gather more data efficiently. We compute a file and the number of states associated with each file and process every state starting with a completely filled board. We optimized the data for cloud computing by running simulations to find the most efficient number …

Internet Programming, Kwame A. Baffour

Open Educational Resources

CSC 31800 – Internet Programming

The design and implementation of websites from a Human-Computer Interaction point of view. Covers client-side technologies such as HTML, CSS and JavaScript and server-side technologies including Node.js and relational databases. Responsiveness, inclusion and accessibility by persons with mobility and vision impairment is necessary and must be addressed in the final project.

Fair Enough: Standardizing Evaluation And Model Selection For Fairness Research In Nlp, Xudong Han, Timothy Baldwin, Trevor Cohn

Natural Language Processing Faculty Publications

Modern NLP systems exhibit a range of biases, which a growing literature on model debiasing attempts to correct. However, current progress is hampered by a plurality of definitions of bias, means of quantification, and oftentimes vague relation between debiasing algorithms and theoretical measures of bias. This paper seeks to clarify the current situation and plot a course for meaningful progress in fair learning, with two key contributions: (1) making clear inter-relations among the current gamut of methods, and their relation to fairness theory; and (2) addressing the practical problem of model selection, which involves a trade-off between fairness and accuracy …

Development Of Three Novel Edna Assays For Detecting Coastal Sharks, Kristina Dawn Flanigan

Electronic Theses and Dissertations

Environmental DNA (eDNA) analysis is an emerging, non-invasive community monitoring tool. This study aimed to determine if eDNA methods can be reliably used in a large brackish, partially mixed estuary by developing and testing three novel eDNA primers, for Sandbar Sharks (Carcharhinus plumbeus), Blacknose Sharks (Carcharhinus acronotus), and Bonnetheads (Sphyrna tiburo). These primers were designed to target 109, 156, and 120 base pair (bp) fragments, respectively, of the highly conserved NAD2 gene in the mitochondrial genome of each species. Primer function was validated through testing against 102 known genomic source samples and 25 filtered water samples from aquaria in which …

Dissolved Copper Distributions In The Western Mississippi Sound: Characterizing An Unrecognized Endmember, Megan Hansen

Honors Theses

This study examined the distribution of dissolved copper (Cu) in the western Mississippi Sound, as the element can be beneficial or harmful to organisms depending on its concentration and its chemical form. A mixing experiment eliminated flocculation as a control on Cu distributions during estuarine mixing in both dissolved and colloidal fractions. Field sampling of the western Mississippi Sound occurred during a low river discharge period, and distributions of Cu indicated conservative mixing between fresh ([Cu] ≈ 17 nM) and saline ([Cu] ≈ 2 nM) sources in mid-to-high salinities. Storm outfalls were sampled after rain events to evaluate the impact …

Spot1328 Meira Spit, Robert C. Mahon, Elizabeth J. Trower, Benjamin P. Smith, Tyler A. Lincoln, Juliana Olsen-Valdez, John S. Magyar, Cedric J. Hagen

2D Wave Spectral Data, South Arm, Great Salt Lake, Utah

Data in this folder are produced by a SoFarOcean Spotter wave buoy deployed along the south arm of the Great Salt Lake, near Antelope Island State Park from the period of July 13, 2021 through June 28, 2022, in relatively shallow water, approximately 1.6m.

IMPORTANT NOTE: Water depths for #1328 (Miera Spit) started at ~1.7 m, but dropped rapidly to 0.9 m on July 15, 2021 and dropped further to ~0.4 m on August 17, 2021. The timing of these rapid water depth changes matches the timing of buoy location changes when the anchor was dragged inshore by waves. When …

Spot1356 Black Rock Derived Data, Robert C. Mahon, Elizabeth J. Trower, Benjamin P. Smith, Tyler A. Lincoln, Juliana Olsen-Valdez, John S. Magyar, Cedric J. Hagen

2D Wave Spectral Data, South Arm, Great Salt Lake, Utah

Data in this folder are produced by a SoFarOcean Spotter wave buoy deployed along the south arm of the Great Salt Lake, near Antelope Island State Park from the period of July 13, 2021 through June 28, 2022, in relatively shallow water, approximately 1.6m.

Investigating The Effect Of Greediness On The Coordinate Exchange Algorithm For Generating Optimal Experimental Designs, William Thomas Gullion

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Design of Experiments (DoE) is the field of statistics concerned with helping researchers maximize the amount of information they gain from their experiments. Recently, researchers have been turning to optimal experimental designs instead of classical/catalog experimental designs. One of the most popular algorithms used today to generate optimal designs is the Coordinate Exchange (CEXCH) Algorithm. CEXCH is known to be a greedy algorithm, which means it tends to favor immediate, locally best designs instead of globally optimal designs. Previous research demonstrated that this tradeoff was efficacious in that it reduced the cost of a single run of CEXCH and allowed …

Theoretical And Computational Aspects Of Robust Cluster Analysis For Multivariate And High-Dimensional Datasets, Andrews Tawiah Anum

Open Access Theses & Dissertations

Multivariate and high-dimensional datasets typically contain subgroups that may not be immediately apparent. To reveal these groups, cluster analysis is performed. Cluster analysis is an unsupervised machine learning technique commonly employed to partition a dataset into distinct categories referred to as clusters. The k-means algorithm is a prominent distance-based clustering method. Despite overwhelming popularity, the algorithm is not invariant under non-singular affine transformations and is not robust, i.e., can be unduly influenced by outliers. To address these deficiencies, we propose an alternative model-based clustering procedure by minimizing a “trimmed” variant of the negative log-likelihood function. We develop a “concentration step”, …

Flexible Models For The Estimation Of Treatment Effect, Habeeb Abolaji Bashir

Open Access Theses & Dissertations

Estimation of treatment effect is an important problem which is well studied in the literature. While the regression models are one of the most commonly used techniques for the estimation of treatment effect, they are prone to model misspecification. To minimize the model misspecification bias, flexible nonparametric models are introduced for the estimation. Continuing this line of research, we propose two flexible nonparametric models that allow the treatment effect to vary across different levels of covariates. We provide estimation algorithms for both these models. Using simulations and data analysis, we illustrate the usefulness of the proposed methods.

Development Of Multi-Configuration Methods On Density Functional Theory Orbitals And Application On The Study Of Dimers, Jose Gustavo Bravo Flores

Open Access Theses & Dissertations

The configuration interaction (CI) methods is an exact method to solve the non relativistic Schrodinger equation, describing the wave function as a linear combination of Slater determinants. Because the computation time grows factorially as the number of electrons, CI is mostly used for relatively small systems. Density functional theory (DFT) rose as one of the most used methods for computational quantum chemistry in the last 30 years. DFT can describe a system's properties with the electron density, which only depends of of three coordinates. Due to its low computational costs it allows one to study bigger systems than CI, however …

Thermal Behavior Of Plain And Fiber-Reinforced Rigid Concrete Airfield Runways, Arash Karimi Pour

Open Access Theses & Dissertations

The environmental condition and temperature gradient are important factors resulting in concrete airfield runways cracking during the time. Rigid concrete airfield runways experience different thermal gradients during the day and night due to changes in air temperature. Curling and thermal expansion stresses are the main consequences resulting in various types of cracking over the surface and thickness of concrete airfield runways and increasing maintenance costs. The curvature of concrete slabs increases with an increase in the temperature gradient which is amplified when runways open to traffic. Additionally, the combination of the curling and shrinkage stresses, in rare circumstances, can be …

Geological Mapping Of Ferric And Ferrous Irons In The Apache Hills, New Mexico: Applying Landsat 8 (Oli), Spectrometry, And Geographic Information System (Gis) Methods, Sergio Gerardo Macias

Open Access Theses & Dissertations

Mineral discoveries are typically tangible on surface studies. Previous research describes mineral deposits of ferric and ferrous irons in the lithology, structures, and alluvial fans in the Apache Hills in southwest New Mexico. The research for this thesis combines and models four methods for validating and mapping the presence of Ferric and Ferrous Irons developed in weathered zones above mineral deposits. A beneficial steppingstone before exploration and discovery begins with extensive research. This study began with data acquisition and reviewing previous research and was essential for the project methods. The study combines four techniques: spectral geology (e.g., remote sensing and …

Microscopic And Spectroscopic Analysis Of Nordihydroguaiaretic Acid Effect On Astrocytes, Lizbeth Vanessa Martinez Lopez

Open Access Theses & Dissertations

Astrocytes, one of the most abundant cell components in the central nervous system (CNS), have been a research target in the last few years. Several studies have found that astrocytes are not only mere supporters of neurons but also of essential processes developed in the CNS. Their malfunction could induce neurodegenerative diseases and brain tumors. Thus, further understanding of astrocytes and their role is of high interest to develop possible new treatments and methods of disease diagnosis, especially in brain cancer. The plant Larrea tridentata (La Gobernadora in Mexico or Creosote bush in the United States) is known to have …

Linking Decomposition Reactions In Arctic Soils To Microbial Enzyme Production, Jane Karen Martinez

Open Access Theses & Dissertations

Microbial processes such as soil enzyme production are a major driver of decomposition and a current topic of interest in arctic soils due to the effects of climate warming. Despite the advances in understanding soil enzymes, there are still knowledge gaps regarding the role of enzymes in decomposition. In this dissertation, I addressed three of those gaps in the following chapters: (Ch.2) to explore the location of enzymes within the soil matrix, (Ch.3) to identify peptides matched to soil enzymes produced by microorganisms for organic matter decomposition, and (Ch.4) understand the longevity of enzymes in the soil after microbial production. …

Isotopic Insights Into Water Of Condensation, Cross-Formation Water Flow, And Natural Hydrocarbon Migration In Sedimentary Basins, Lisa J. Molofsky

Open Access Theses & Dissertations

This dissertation applies geochemical tools to track the movement, transformation, and behavior of water and gases in hydrocarbon-bearing sedimentary basins. During petroleum exploration and production, hydrocarbons are generated at the surface along with other fluids naturally present in the formation, such as formation water. In addition, where hydraulic fracturing is used to stimulate shale gas and oil production, a percentage of the injected fracturing fluid also returns to the surface. Understanding the origin and movement of these water sources, as well as targeted and non-targeted hydrocarbon gases is critical to evaluating reservoir performance and properly managing fluids at the surface. …

On The Predictability Of Appropriate Prosody Of Dialog Markers Directly From The Local Context, Anindita Nath

Open Access Theses & Dissertations

Today's state-of-the-art spoken dialog systems lack context-appropriate prosody in their responses, often making them sound unnatural. Better modeling of this contextual dependency would enable natural prosodic responsiveness. Accordingly, this dissertation explores the extent to which the prosody of a dialog marker can be predicted directly from the prosody of its local context. The prediction performance was evaluated in terms of the similarity between the predicted and the observed prosodic features as measured by the reduction of root mean square error from the baseline. This prediction task was accomplished for multiple combinations of various sets of context features and different machine …

Developing A Risk Assessment Instrument For Immigration Cases Under Federal Supervision, Mayra Eydie Pacheco

Open Access Theses & Dissertations

No abstract provided.

Developing And Applying Computational Methods On Biomolecules, Shengjie Sun

Open Access Theses & Dissertations

Computational biophysics is an interdisciplinary subject that uses numerical algorithms to study the physical principles underlying biological phenomena and processes. Electrostatic interactions play an important role in computational molecular biophysics and their potential impact on disease mechanisms. At distances larger than several Angstroms, electrostatic interactions dominate all other forces, while the alteration of short-range electrostatic pairwise interactions can also have significant effects. The dual nature of electrostatic interactions, being dominant at long-range and specific at short-range, underscores their profound implications for wild-type structure and function. Any disruption of the complex electrostatic network of interactions may abolish wild-type functionality and could …

A Framework To Build Secure Microservice Architecture, Wai Yan Elsa Tai Ramirez

Open Access Theses & Dissertations

Microservice architecture has become a popular architecture style in recent years. According to a series of surveys conducted by IBM Market Development & amp; Insights in 2021, microservices are heavily used in many industries worldwide. With an increase in the adoption of microservice architecture in the development of applications, such as Netflix, Amazon, Uber, Ebay, Twitter, DoorDash, Capital One, and Monzo, and the increase in security breaches in microservice based systems (e.g., the DoorDash data breaches in 2019 and 2022, Twitter data breach in 2022, and compromises to Netflixâ??s infrastructure), there is a need to examine and understand security issues …

Outlier Detection In Multivariate And High-Dimensional Datasets, Yuanhong Wu

Open Access Theses & Dissertations

Accurate detection of outliers is crucial in the field of statistical analysis. Using classical statisticalmodels without considering the presence of outliers in the data can lead to misleading outcomes. There exist a myriad of procedures to detect outliers in statistics. We concentrate on the statistical techniques that can robustly identify outliers in data sets. To this end, we pursue two aims. First, we give an extensive overview of robust statistical methods which are still popular in recent years for outlier detection. We provide the definitions, algorithms and also discuss some important properties of these methods. Second, two real examples are …

Spatially Adaptive Estimation Of Spectrum, Yi Xie

Open Access Theses & Dissertations

A time series may be analyzed either in the time or in the frequency domain. When working in the frequency domain, the main objective is to estimate the underlying spectrum. Various approaches have been proposed to this end, but most are based on smoothing the periodogram using a single smoothing parameter across all Fourier frequencies. Such a global smoothing parameter may result in a biased estimate. To improve the estimation, in this paper, we smooth the log periodogram by placing a dynamic shrinkage prior, such that varying degrees of smoothing may be applied to different regions of the Fourier frequencies, …

Structure Study Of Small Heat Shock Protein 27, Zhaobo Li

Open Access Theses & Dissertations

Molecular chaperones are a class of oligomeric proteins that play a critical role inpreventing the aggregation of non-native protein so that these proteins can later be refolded. Chaperones are ubiquitously expressed in all the kingdoms of life where their function is to counteract cellular stress and to maintain protein homeostasis. One subgroup of molecular chaperones is characterized by low molecular weight and are termed small heat shock proteins. The focus of the proposed research is the small heat shock protein 27 (Hsp27). Hsp27 is an ATP independent chaperone that is overexpressed in response to heat shock, radiation damage, oxidative damage, …

Enhancing Earthquake Detection Through Machine Learning- An Application To The 2017 Mw 8.2 Tehuantepec Earthquake In Mexico, Marc Adrian Garcia

Open Access Theses & Dissertations

The Tehuantepec seismic gap, located off the southern shore of Oaxaca and Chiapas, Mexico, was previously thought to be an aseismic zone due to no significant event in 100 years. The September 8, 2017 (M8.2) Tehuantepec earthquake disproved this idea and added many questions surrounding the Mexican subduction zone. Specifically, the earthquake did not occur at the subduction megathrust. It ruptured the subducting plate below the megathrust and appeared to stop at the megathrust. Following this event, as well as the September 19, 2017 (M7.1) Morelos-Puebla earthquake, researchers from the University of Texas at El Paso (UTEP), Universidad Autónoma Cuidad …

Separation Of Organic Acids Through Direct Catalysis From Sugars, Katelyn Robinson

Chemical Engineering Undergraduate Honors Theses

Society relies on plastic products, whether they are single use or durable. A downside of plastic is that the most common type is a product of oil and oil is not only a limited resource but also a climate-damaging resource. Polylactic acid (PLA) is a bio-based, biodegradable plastic. However, the process of converting biomass to polylactic acid polymer has the largest environmental impact of the PLA production process, so alternative methods of conversion are needed (Moretti et al., 2021). The polylactic acid polymer can be made with lactic acid, which can be converted from glucose.

The Novel Chlorination Of Zirconium Metal And Its Application To A Recycling Protocol For Zircaloy Cladding From Spent Nuclear Fuel Rods, Breanna K. Vestal

Doctoral Dissertations

A novel protocol has been developed for the chemical removal of zirconium alloy (Zircaloy) cladding from spent nuclear fuel rods and subsequent isolation and purification of nuclear-grade zirconium chloride derived therefrom. This protocol is based on the chemistry developed from two new scientific findings.

First, two new oxidative chlorination reactions have been discovered for zirconium metal. In both solvents, zirconium can be quantitatively chlorinated at temperatures less than 150°C, with the operative equations seen below. In sulfur monochloride, the reaction is completed in 2 – 4 hours via surface etching, exhibiting 0^th order kinetic behavior. The elemental sulfur byproduct …

Hydroclimate Effects On Great Salt Lake Decline Since 1980, Siiri Joy Bigalke

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

As a terminal basin lake, the Great Salt Lake (GSL) is known to act as a barometer for low frequency climate variability for the Western United States. As thus, there are naturally occurring large changes to GSL elevation levels that vary on time scales from years to decades. However, amongst these naturally occurring interannual changes there has been a significant declining trend in the elevation levels since a string of anomalous pluvial years in the early 1980s. In the summer of 2022, the Great Salt Lake reached its lowest levels in recorded history, which coincided with a two-decades long regional …