Physical Sciences and Mathematics Commons^™

Chiral Modification Of The Pd(111) Surface By Small Organic Molecules, Mausumi Mahapatra

Theses and Dissertations

Chiral modification of a metal surface is one of the most successful approaches of achieving enantioselective catalysis in heterogeneous phase. In this approach, an active metal surface is directly modified by adsorption of a chiral molecule (chiral modifier), the metal is responsible for catalytic activity while the adsorbed modifier controls the stereochemistry of adsorption and subsequent reactions through substrate interactions. So far, there are three types of widely recognized metal/modifier catalytic systems: tartaric acid modified Ni catalysts for the hydrogenation of β-ketoesters, cinchona modified Pt catalysts for hydrogenation of α-ketoesters and Pd catalysts modified with cinchona for selective activated alkene …

Virginia Game Fish Tagging Program Annual Report 2014, Susanna Musick, Lewis Gillingham

Reports

Through 2014, the Virginia Game Fish Tagging Program has maintained a 19-year database of records for tagged and recaptured fish. The program is a cooperative project of the Virginia Saltwater Fishing Tournament (under the Virginia Marine Resources Commission-VMRC) and the Virginia Institute of Marine Science (VIMS) of the College of William and Mary (under the VIMS Marine Advisory Program).

The Use Of Shape Memory Polymers As A Tool To Study Human Fibrosarcoma And Murine Mesenchymal Stem Cell Migration, Justin N. Elkhechen

Renée Crown University Honors Thesis Projects - All

Shape memory polymers (SMPs) are a class of “smart” materials that can transform between two distinct conformations through external stimuli, such as heat or electricity. Their usage in bioengineering has led to a promising field of research that lies at the interface of cell and mechanobiology, potentially providing insight into cancer therapies and tissue development—two processes that exist in dynamic environments in vivo. The present work involves creating new, shape changing, scaffolds for studies to analyze cell migration upon changes to the environmental topography. Specifically, this Capstone has been primarily focused on the development of a “half and half” fibrous …

Electrostatic Assembly Of Gold Nanoparticles Mediated By Polyoxomolybdates, Shannon M. Walter

Renée Crown University Honors Thesis Projects - All

The electrostatic assembly of cationic gold nanoparticles (AuNPs) with core diameters of approximately 1.5 nm and 4.5 nm and the anionic sphere and wheel polyoxomolybdates (Mo-132a), (Mo‑132b), and (Mo‑154) was investigated. The AuNPs were capped with a trimethylammonium terminated ligand. Zeta potential and UV-Vis studies supported the successful assembly of the oppositely charged species. The ratio at which the precipitation of aggregates from solution occurred was consistent with the point of electroneutrality observed in the zeta potential results. The UV-Vis studies showed the loss of the surface plasmon resonance (SPR) band as this point of electroneutrality was approached.

In a …

Geometry Of Hilbert Space Frames, Stephen Sorokanich Iii

Renée Crown University Honors Thesis Projects - All

In applied linear algebra, the term frame is used to refer to a redundant or linearly dependent coordinate system. The concept was introduced in the study of Fourier series and is pertinent in signal processing, where the reconstruction property for finite frames allows for redundant transmission of data to guard against losses due to noise. We give a brief introduction to the theory of finite frames in Section 1, including the major results that allow for the easy construction and description of frames. The subsequent sections relate to the theoretical importance of frames. As a natural extension of the definition …

Procedural Content Generation: Using A.I. To Generate Playable Content, Osler Kendall Moore Jr.

Honors Theses

This thesis is about using Artificial Intelligence in regards to Procedural Content Generation to help try and avoid a deadlock scenario in a hypothetical dungeon exploring game. The deadlock scenario is essentially having a key being placed in a room that’s inaccessible to the player. An example of such a scenario would be if the key to room A being in Room B, the key to room B was in room A, and the player was in room C. The program generates the dungeon world with a random number of rooms inside it, each room also having a random number …

Biomimetic Adhesive Thiol-Ene Films For Improved Adhesion, Laken L. Kendrick

Honors Theses

Current dental restoration materials fall short in adhesion and often pull away from the surface of the tooth upon curing. This project seeks to design polymers that can adhere to wet, heterogeneous surfaces as potential materials for dental restoration applications. The goal of this project is to mimic the structure and adhesive properties of natural adhesives containing 3,4-dihydroxyphenyl-L-alanine (DOPA). We will synthesize mono- and di-functional DOPA derivatives with catechol functionality and investigate their adhesion compared to their non-catechol-containing alternative through incorporation into a model thiol-ene photopolymerization. Functional group conversion, real time kinetics, and adhesion data will be used to analyze …

Developing A Bilingual, Computer-Tailored, Hpv Vaccination Promotion Intervention Targeting Latino Parents, Angela Chia-Chen Chen, Ashish Amresh

Publications

In this paper we present an innovative, computer-tailored application aimed at increasing Latino parents' intention to vaccinate their adolescent children against Human Papilloma Virus (HPV). HPV infection is the most common sexually transmitted infection in the United States. Latinas have the highest age-adjusted incidence rate for HPV-associated cervical cancer compared with their counterparts in other racial/ethnic groups. HPV vaccines offer hope against HPV-associated diseases. Because parental consent is required for children under age 18 to receive t h e HPV vaccination in most U. S. states, parents' attitudes and intention to have their children vaccinated are keys for promoting HPV …

Interactive Cause And Effect Comic-Book Storytelling For Improving Nutrition Outcomes In Children, Ashish Amresh, Madhumita Sinha, Rebecca Birr, Rahul Salla

Publications

Obesity among children and adolescents is increasingly becoming a major public health problem. Poverty and lower socio-economic status as well as lack of parental awareness regarding a balanced diet and adequate exercise all contribute towards childhood obesity. Unfortunately minority children have been especially vulnerable, among them inner-city Latino children continue to have the highest incidence rates of overweight and obesity; hence targeted intervention for this population group is of paramount importance. Access and affordability of smartphones and mobile internet devices provide an opportunity to create nutrition education interventions that can significantly impact and change attitude and knowledge regarding healthy diet …

Naturally-Occurring Metals Concentrations In Michigan Soils: A 2015 Survey, Zachary Lowell Spotts

Masters Theses

Closure of hazardous waste sites can be aided through the use of a soil background survey for metals. Data for these studies come from either field sampling or publicly available environmental files. Previous studies were conducted in Michigan, known as the Michigan Background Soil Survey (MBSS). The current update is a refinement and improvement of the 2005 update. New data was collected from publicly available environmental files and other sources. Both the current update and the 2005 update differentiated data by soil type and glacial lobe. GIS analysis was used to observe spatial distribution of the data and to determine …

Theoretical Results For Electroweak-Boson And Single-Top Production, Nikolaos Kidonakis

Faculty Articles

I present results from recent high-order calculations for the production of electroweak bosons and top quarks. In particular, I discuss W and Z boson production at large transverse momentum, single-top production, and FCNC top production. Theoretical predictions which include higherorder soft-gluon corrections are presented for total cross sections and differential distributions at the LHC.

A Comparison Of Habitat And Geomorphic Changes On East Ship Versus Sand Islands Mississippi, 2007-2014, Carlton Peter Anderson

Master's Theses

ABSTRACT

A COMPARISON OF HABITAT AND GEOMORPHIC CHANGES ON EAST SHIP VERSUS SAND ISLANDS MISSISSIPPI, 2007-2014

by Carlton Peter Anderson

May 2015

The islands of the Mississippi-Alabama (MS-AL) barrier island chain along the micro-tidal northern Gulf of Mexico are highly dynamic coastal features subject to rapid changes in habitat, geomorphology, and elevation by natural and anthropogenic disturbances, such as hurricanes, subsidence, sea-level rise, and dredging activities. The purpose of this study was to compare elevation, total volume, habitat-type coverage, and short-term change between “naturally” formed East Ship Island and “man-made” Sand Island (Disposal-Area 10). This study used a combination of …

Geographical Analysis Of Hub City Transit, Joshua Adam Watts

Master's Theses

This study assess Hub City Transit, the public bus system of Hattiesburg, MS. Statistical analysis is used to determine how well the transit system serves low income areas of the city. A 0.5 mile buffer was applied to the bus routes to determine the coverage of the transit system. Areas of disorder along the routes were also assessed to analyze the landscape routes pass through. Lastly, an analysis of ridership on each route was performed to determine the most heavily used areas, as well as to assess where riders are going on each route.

The findings show that Hub City …

Marine Snow Settling Velocities At An Oil Spill Site And A Control Site In The Northern Gulf Of Mexico, Clayton Hugh Dike

Master's Theses

After budgeting for response efforts and natural processes, over one million barrels of oil from the BP oil spill were unaccounted for. A hypothesis coined "The Dirty Blizzard" formed subsequent to observations of large and numerous oiled marine snow aggregates amidst the surface slick proposed that a large quantity of oil sank to depth via the aggregates. Having reached the seafloor, aggregates were subject to microbial degradation and to redistribution due to bottom currents. To assist in characterizing redistribution of particles near the seafloor, sediment traps, marine snow cameras, and acoustic Doppler current profilers (ADCPs) were deployed at two sites …

Framing Reality: Portrayals Of Climate Change In The "Las Vegas Review-Journal", 1997-2014, Jason Ryan Holley

UNLV Theses, Dissertations, Professional Papers, and Capstones

Discussions of human-caused climate change have become an increasingly salient artifact of various media in recent years. With regard to print media in particular, scholars have uncovered general increases in the frequencies with which climate change articles are published, tantamount to the annual reports from the Intergovernmental Panel on Climate Change (IPCC) advocating the detriments of human activities (particularly carbon dioxide emissions) on the natural environment. Among such reports—be they scientific or anecdotal—writers and journalists have had to interpret the ongoing discussions and evidence surrounding climate change, and develop schemas (or frames) in which to situate arguments. These arguments have …

Constraining The Progenitor And Central Engine Of Gamma-Ray Bursts With Observational Data, Lu Houjun

UNLV Theses, Dissertations, Professional Papers, and Capstones

Gamma-ray bursts (GRBs) are extremely energetic explosions at cosmological distances. We have made great progress in understanding the mysteries of these events since they were discovered more than forty years ago. However, some open questions still remain, e.g. how many classes of GRBs are there, what are the progenitors of these classes, and what is the central engine powering these huge explosions? Thanks to the NASA missions Swift and Fermi, which are used to detect the multi-wavelength emission from these transients, our understanding of GRBs has been greatly advanced. In this dissertation, I use multi-wavelength data to constrain the progenitor …

High Pressure Behavior Of Mullite-Type Oxides: Phase Transitions, Amorphization, Negative Linear Compressibility And Microstructural Implications, Patricia Kalita

UNLV Theses, Dissertations, Professional Papers, and Capstones

Even though mullite occurs rarely in nature, it is perhaps one of the most important phases in both traditional and advanced ceramics. Existing and emerging applications of mullite and mullite-type materials include: high-temperature composites, aerospace materials, ballistic shielding for military applications and even non-linear optical materials. There are many uncertainties regarding the basic physical properties of mullite-type materials, particularly in terms of their high-pressure structural stability and mechanical behavior that are important to address for emerging applications of mullites as engineering materials. This work is the first reported comprehensive investigation of the high –pressure structural behavior of several different mullites …

Modeling Background Radiation Using Geochemical Data, Kara Marsac

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys have many applications in geology and science in general, such as locating mining prospects, defining radioactive plumes, and detecting nuclear weapons. Unfortunately there is currently no simple way to separate the natural gamma radiation of soil and rocks from that of contaminants such as radioactive plumes. This project used geochemical data (uranium, potassium and thorium concentrations) collected from national databases, private companies, and the NURE (National Uranium Resource Evaluation) Survey, to create forward models of exposure rates measured by aerial gamma ray surveys. We developed these techniques using an area in north central Arizona known as …

Tracking And Monitoring Unmanned Aircraft Systems Activities With Crowd-Based Mobile Apps, Tejaswini Papireddy

UNLV Theses, Dissertations, Professional Papers, and Capstones

An Unmanned Aircraft System(UAS) is an aircraft without human pilot onboard. They can be controlled remotely from a ground control station (GCS) or can fly autonomously based on pre-programmed flight plans. Tracking and monitoring these UASs activities in the National Airspace System (NAS) is one of the major challenges related to UAS. This system tracks a set of UASs at a given point of time based on the user-submitted tracking information. This thesis presents the basic knowledge of UAS, types of UAS, advantages, and challenges with UASs. The implemented Android application allows the users to submit the observed UAS information …

Concurrent Lazy Splay Tree With Relativistic Programming Approach, Jaya Ram Sedai

UNLV Theses, Dissertations, Professional Papers, and Capstones

A splay tree is a self-adjusting binary search tree in which recently accessed elements are quick to access again. Splay operation causes the sequential bottleneck at the root of the tree in concurrent environment. The Lazy splaying is to rotate the tree at most one per access so that very frequently accessed item does full splaying. We present the RCU (Read-copy-update) based synchronization mechanism for splay tree operations which allows reads to occur concurrently with updates such as deletion and restructuring by splay rotation. This approach is generalized as relativistic programming. The relativistic programming is the programming technique for concurrent …

Modeling Studies And Numerical Analyses Of Coupled Pdes System In Electrohydrodynamics, Yuzhou Sun

UNLV Theses, Dissertations, Professional Papers, and Capstones

Electrohydrodynamics (EHD) is the term used for the hydrodynamics coupled with electrostatics, whose governing equations consist of the electrostatic potential (Poisson) equation, the ionic concentration (Nernst-Planck) equations, and Navier-Stokes equations for an incompressible, viscous dielectric liquid. In this dissertation, we focus on a specic application of EHD - fuel cell dynamics - in the eld of renewable and clean energy, study its traditional model and attempt to develop a new fuel cell model based on the traditional EHD model. Meanwhile, we develop a series of ecient and robust numerical methods for these models, and carry out their numerical analyses on …

Concurrent Non-Blocking Skip List Using Multi-Word Compare And Swap Operation, Anish Ratna Tuladhar

UNLV Theses, Dissertations, Professional Papers, and Capstones

We present a non-blocking lock-free implementation of skip list data structure using multi word compare and swap (CASN) operation. This operation is designed to work on arbitrary number of memory locations as a single atomic step. We discuss the implementation details of CASN operation which only utilizes the single word compare and swap atomic primitive found in most of the contemporary multiprocessor systems. Using this operation, we first design lock-free algorithms to implement various operations on linked list data structure, then extend it to design skip lists. Skip list is a probabilistic data structure composed of linked lists stacked together …

Patient No-Show For Outpatient Physical Therapy: A National Survey, James Bokinskie, Payton Johnson, Trevor Mahoney

UNLV Theses, Dissertations, Professional Papers, and Capstones

Introduction: Patients who fail to show for scheduled medical appointments (no-show) create a cascade of issues for the health care system, the provider, and themselves. No-show can affect clinical productivity, cost and quality of care, and treatment outcomes. There is an overwhelming lack of research on no-show as it relates to outpatient physical therapy in the United States. The purposes of this study were to report national no-show rates, describe the presence and characteristics of no-show policies, determine the relationship of these policies and other demographic information to no-show rates, and describe the most commonly perceived reasons for no-show.

Methods: …

Comparing Usability And Variance Of Low- And High Technology Approaches To Gait Analysis In Health Adults, John Mcconnell, Brian Silverman

UNLV Theses, Dissertations, Professional Papers, and Capstones

Purpose: The purpose of this study was to compare the usability, reliability, and objectivity of four tools that represented varying gait analysis technologies used in clinical practice and/or research. Low technology clinical tools included the Gait Abnormality Rating Scale (GARS-M) and the Rancho Los Amigos Observational Gait Analysis (Rancho OGA). High technology tools included the GAITRiteÒ computerized walkway, and the APDM Mobility LabÔ wearable sensor system.

Subjects: 74 healthy adults ages 18-41 years (mean = 24.82, SD = 4.39) 33 males and 40 females.

Methods: Subjects were instructed to walk at a self-selected speed for two minutes …

Four Weeks Of Minimalist Style Running Training Reduced Lumbar Paraspinal Muscle Activation During Shod Running, Stephanie Barton, David Brown, Talia Joyce

UNLV Theses, Dissertations, Professional Papers, and Capstones

Background and Purpose: Research has shown that the risk of low back dysfunctions in runners is related to the increased mileage of distance running. Repetitive shock loading of the spinal structures during running has been indicated as one of the important biomechanical mechanisms underlying such injury. Acute changes in foot strike pattern, like those seen during minimalist style running, have been shown to lead to modifications in lumbar range of motion. Minimalist style running could lead to changes in lumbar biomechanics and muscle activation, potentially reducing the loading on the musculoskeletal structures of the lower back. However, the long term …

Cockatoo Sands In The Victoria Highway And Carlton Hill Areas, East Kimberley: Land Capability Assessment For Developing Irrigated Agriculture, Henry Smolinski, Shahab Pathan, Paul Galloway, Kus Kuswardiyanto, Justin Laycock

Resource management technical reports

This report identifies areas of Cockatoo Sands adjacent to the Ord River Irrigation Area (ORIA), Kununurra, with high potential for developing irrigated agriculture. It builds on a reconnaissance soil survey conducted in 2009 which identified significant areas of sandy and loamy soils in the Kununurra area that could be suitable for agriculture.

Topics In Broadband Gravitational-Wave Astronomy, Sydney Joanne Chamberlin

Theses and Dissertations

The direct detection of gravitational waves promises to open a new observational window onto the universe, and a number of large scale efforts are underway worldwide to make such a detection a reality. In this work, we attack some of the current problems in gravitational-wave detection over a wide range of frequencies.

In the first part of this work, low frequency gravitational-wave detection is considered using pulsar timing arrays (PTAs). PTAs are a promising tool for probing the universe through gravitational radiation. Supermassive black hole binaries (SMBHBs), cosmic strings, relic gravitational waves from inflation, and first order phase transitions in …

Scattering Correction Methods Of Infrared Spectra Using Graphics Processing Units, Asher Imtiaz

Theses and Dissertations

Fourier transform infrared (FTIR) microspectroscopy has been used for many years as a technique that provides distinctive structure-specific infrared spectra for a wide range of materials (e.g., biological (tissues, cells, bacteria, viruses), polymers, energy related, composites, minerals). The mid-infrared radiation can strongly scatter from distinct particles, with diameters ranging between 2-20 micrometer. Transmission measurements of samples (approximately 100 micrometers x 100 micrometers x 10 micrometers) with distinct particles. will be dominated by this scattering (Mie scattering). The scattering distorts the measured spectra, and the absorption spectra appear different from pure absorbance spectra. This thesis presents development and implementation of two …

Improved Extraction Chromatographic Materials For The Separation And Preconcentration Of Metal Ions, Abdul Momen

Theses and Dissertations

Growing public health and safety concerns over the use of nuclear materials have increased the demand for improved methods for the separation and preconcentration of various metal ions from environmental and biological samples for subsequent determination. Historically, solvent extraction and ion-exchange have often been the methods of choice for these separations. Solvent extraction, however, is cumbersome and can generate substantial volumes of organic wastes. Ion-exchange, while less cumbersome, lacks adequate selectivity and requires careful control of pH for satisfactory separation. Moreover it is generally not compatible with acidic samples, such as are commonly encountered in the analysis of biological and …

Gravitational-Wave Science With The Laser Interferometer Gravitational-Wave Observatory, Madeline Wade

Theses and Dissertations

Gravitational-waves, as predicted by Einstein’s theory of general relativity, are oscillations of spacetime caused by the motion of masses. Although not yet directly detected, there is strong evidence for the existence of gravitational-waves. Detectable gravitational waves will come from dramatic astrophysical events, such as supernova explosions and collisions of black holes. The Laser Interferometer Gravitational-wave Observatory (LIGO) is a network of detectors designed to make the first direct detection of gravitational waves. The upgraded version of LIGO, Advanced LIGO (aLIGO), will offer a dramatic improvement in sensitivity that will virtually guarantee detections.

Gravitational-wave detections will not only illuminate mysterious astrophysical …