Physical Sciences and Mathematics Commons^™

The Effects Of Recreational Rock Climbing On Vascular And Nonvascular Plant Communities In Southeastern Tennessee, Caitlin A. Ruby

Honors Theses

Popularity for non-consumptive outdoor recreations has rapidly increased over the past decades. With many national and state park regulations failing to regulate rock climbing, scholars are concerned for the amount of ecological disturbance that may occur if left unmonitored. Visual assessments to disturbance disparities between remote climbing locales and contradictory scientific literature confirmed the need for further research on the effects of rock climbing on cliff ecology. Two climbing centers were focused in Southeastern Tennessee: Foster Falls in Sequatchie County and Leda in Hamilton County. Convenience sampling was used to collect 24 transects from intermediately graded routes and 24 transects …

Polymerization Of Blocked Isocyanate Functional Polymer Surfaces And Post-Polymerization Modification By Thiol-Isocyanate Reactions, Chase A. Tretbar

Honors Theses

Direct polymerization of isocyanate-functional monomers has been achieved with controlled radical polymerizations (CRP) for precisely engineered modification platforms with highly reactive side chains. However, despite the success of these strategies, the inherent reactivity of isocyanates still leads to adverse side reactions, such as hydrolysis, that are difficult to suppress. Phenol, lactam, and oxime-based blocking agents have been used to limit the reactivity of isocyanates in applications such as multicomponent urethane coating systems. The reactivity of these blocked isocyanates can be restored by thermal deprotection of the blocking agent to achieve the desired reactions. In this work, we use blocked isocyanate-functional …

Theoretical And Experimental Investigations Of The Electromagnetic Fields And Energetic Particles Associated With Thunderstorms And Lightning, Shahab Arabshahi

Theses and Dissertations

Despite more than 250 years after Benjamin Franklin’s kite experiment, lightning is still one of the mysteries of nature. We still do not understand how lightning works at the most basic level. Traditionally, lightning used to be studied using classical electrodynamics. However, in the last decade or so, the observation of many high energy phenomena associated with lightning and thunderclouds (e.g., X-rays from lightning leaders, TGFs, X-ray and gamma-ray glows from thunderstorms, etc.), started a new path in studying lightning and thunderstorms. It is suggested that energetic radiation in our atmosphere is the result of bremsstrahlung scattering of energetic electrons, …

Relativistic Runaway Electron Avalanches Inside The High Field Regions Of Thunderclouds, Eric Scott Cramer

Theses and Dissertations

In this dissertation, simplified equations describing the transport and energy spectrum of runaway electrons are derived from the basic kinematics of the continuity equations. These equations are useful in modeling the energy distribution of energetic electrons in strong electric fields, such as those found inside thunderstorms. Dwyer and Babich [2011] investigated the generation of low-energy electrons in relativistic runaway electron avalanches. The paper also developed simple analytical expressions to describe the detailed physics of Monte Carlo simulations of relativistic runaway electrons in air. In this work, the energy spectra of the runaway electron population are studied in detail. Dependence of …

Characterization Of Cataclysmic Variables And White Dwarfs In The Kepler Field, Trisha Doyle

Theses and Dissertations

We present long baseline Kepler photometry and ground-based Hale 20000 spectroscopy of five known white dwarfs, five newly identified white dwarfs, and a cataclysmic variable, V523 Lyr. Analysis of the photometric and spectroscopic data is used to characterize the white dwarfs and the cataclysmic variable, by determining preliminary fundamental parameters. We model the white dwarfs to determine their fundamental parameters, e↵ective temperature and surface gravity. If the e↵ective temperature of a white dwarf falls within a specific range, the white dwarf is expected to be a pulsator. We verified possible pulsation with complementary Kepler light curves when possible. The modeled …

Sprite Streamer Formation And Propagation: Theory And Observations, Burcu Kosar

Theses and Dissertations

Sprites are finely-structured, large scale electrical discharges typically initiated near the lower boundary of the ionosphere at 70-85 km altitudes [Pasko, 2010; Ebert et al., 2010; Pasko et al., 2011, 2013; Liu, 2014; Liu et al., 2015b]. Their lateral extent is ∼5-10 km and vertical extent is ∼50 km, and hence the atmospheric volume electrically and chemically affected by sprites is thousands of cubic kilometers [Sentman et al., 1995; Lyons, 2006]. Halos are relatively uniform, descending glows that may give rise to more structured features, from which sprites are initiated. A large amount of observational [e.g., Gerken et al., 2000; …

Towards A Usable-Security Engineering Framework For Enhancing Software Development, Yasser M. Hausawi

Theses and Dissertations

Computer systems are fundamental tools for almost every single process in life. People from all over the globe use computer systems for an unlimited number of purposes. Consequently, a close relationship between people and computer systems exists. Current research investigates how people and such systems to interact with each other in a proper manner. The research work on this matter is being conducted in different directions; one direction is investigating people’s behaviors toward computer systems, such as the cognitive and mental state of humans when interacting with computer systems; another direction studies the computer system’s behaviors toward people, such as …

Gaseous Particulate Interaction In A 3-Phase Granular Simulation, Kevin W. Munns

Theses and Dissertations

As computer generated special effects play an increasingly integral role in the development of films and other media, simulating granular material continues to be a challenging and resource intensive process. Solutions tend to be pieced together in order to address the complex and different behaviors of granular flow. As such, these solutions tend to be brittle, overly specific, and unnatural. With the introduction of a holistic 3-phase granular simulation, we can now create a reliable and adaptable granular simulation.Our solution improves upon this hybrid solution by addressing the issue of particle flow and correcting interpenetration amongst particles while maintaining the …

Feature Identification And Reduction For Improved Generalization Accuracy In Secondary-Structure Prediction Using Temporal Context Inputs In Machine-Learning Models, Matthew Benjamin Seeley

Theses and Dissertations

A protein's properties are influenced by both its amino-acid sequence and its three-dimensional conformation. Ascertaining a protein's sequence is relatively easy using modern techniques, but determining its conformation requires much more expensive and time-consuming techniques. Consequently, it would be useful to identify a method that can accurately predict a protein's secondary-structure conformation using only the protein's sequence data. This problem is not trivial, however, because identical amino-acid subsequences in different contexts sometimes have disparate secondary structures, while highly dissimilar amino-acid subsequences sometimes have identical secondary structures. We propose (1) to develop a set of metrics that facilitates better comparisons between …

Investigation Of The Chemical Protection Capacity Of Common Shoe Materials In Undergraduate Laboratories, Sarah E. Lawson

Undergraduate Honors Theses

The objective of this study was to evaluate the chemical resistance of common shoe materials regularly worn in undergraduate chemistry laboratories by subjecting the materials to hydrochloric acid and sodium hydroxide. The materials tested were leather, canvas cotton, and polyester. Due to the lack of restriction on undergraduate laboratory footwear, the research discussed in this thesis is important to undergraduate universities. Currently, many universities across the nation only require undergraduate students to wear close-toed, close-heeled shoes in chemistry laboratories, and often the resistance of the shoe material to acids and bases may not be taken into careful consideration. Overall, the …

Synthesis And Characterization Of Rhodium Acetate With Functionalized Benzonitriles, Jared M. Lowe

Undergraduate Honors Theses

Dirhodium complexes are effective catalysts in carbene transformations. These reactions involve chemistry between the catalyst and a carbene generated in situ. In order to better understand the rhodium-carbon bond, studies of rhodium acetate, Rh₂(OAc)₄, and a variety of functionalized benzonitriles were proposed. Diadducts of rhodium acetate with 4-nitrobenzonitrile, 4-aminobenzonitrile, 4-(dimethylamino)benzonitrile, and 3,5-dinitrobenzonitrile were successfully prepared and characterized by X-ray crystallography. IR and NMR spectroscopy were also employed for characterization purposes.

Three Essays On Panel Data Estimation, Alexander Houser

Dissertations

This work discusses various aspects of panel data estimation. In chapter one, an algorithm for semiparametric random effects estimation is proposed. The performance of bootstrap-based confidence intervals for the proposed estimators are examined and found reasonable. The algorithm is also applied to a set of U.S. state level medical expenditure data to estimate the medical Engel curve. In the second chapter, the predictive performance of various parametric and semiparametric panel data estimators is compared on the same dataset of U.S. state level medical expenditures as well as out of sample forecast performance and bootstrap bias-corrected mean square errors of the …

Phantom Maps, Decomposability, And Spaces Meeting Particular Finiteness Conditions, James Schwass

Dissertations

The purpose of this dissertation is to extend principles for detecting the existence of essential phantom maps into spaces meeting particular finiteness conditions. Zabrodsky shows that a space Y having the homotopy type of a finite CW complex is the target of essential phantom maps if and only if Y has a nontrivial rational homology group. We show this observation holds on the collection of finite generalized CW complexes. Similarly, Iriye shows a finite-type, simply connected suspension space is the target of essential phantom maps if and only if it has a nontrivial rational homology group. We show this observation …

A Comparative Study To Calculate Hydraulic Conductivity In Ultisols On An East Tennessee Hillslope, Sydney A. Lawson

Undergraduate Honors Theses

This study compares four different methods to measure hydraulic conductivity (K) at two sites on the East Tennessee State University Valleybrook Campus. It compares the K values to each other, to the different K values between the two sites, and to United States Department of Agriculture (USDA) K values. Two field methods, Well Bail Test and Auger Hole Test, and two lab methods, Constant Head Permeameter Test and Grain Size Distribution Test (GSD), were performed on the clay rich Ultisol soils on an East Tennessee hillslope in the Valley and Ridge Physiographic Province. One site was located close to a …

Improved Monitoring Of The Changjiang River Plume In The East China Sea During The Monsoon Season Using Satellite Borne L-Band Radiometers, Bumjun Kil

Dissertations

Measurement of sea surface salinity (SSS) from Satellite borne L-band (1.4 GHz, 21cm) radiometers (NASA Aquarius/SAC-D and ESA SMOS) in the East China Sea (ECS) is challenging due to the uncertainty of SSS caused by land thermal emissions in the antenna side lobes and because of strong radio frequency interference (RFI) due to illegally emitted man-made sources. RFI contamination in the ECS has gradually decreased because of the on-going international efforts to eliminate broadcasts in the protected L-band radio-astronomy frequency band. The present dissertation focuses on carefully eliminating the remaining RFI contamination in retrieved SSS, and masking out regions close …

Investigations Of The Photocatalytic Activity And Self-Cleaning Properties Of Polyhedral Oligomeric Silsesquioxane (Poss) Containing Titania Thiol-Ene Films, Lacrissia Unsonta Jefferson

Dissertations

In this document the film composition, self-cleaning aspect, photocatalytic efficiency, and methods employed to analyze a novel photocatalytic titania-containing thin film was evaluated. A primary objective of this research project was to assess the conditions required to achieve a stable titania dispersion for the photocatalytic coating and to determine the extent to which the presence of additives contributes to this process. Modified titania dispersions were prepared and characterized via dynamic light scattering (DLS), transmission electron microscopy (TEM), fourier transmission infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). Characterization details of the previous focus on the influence of polyhedral oligomeric silsesquioxane (POSS) …

Characterizing Silent Users In Social Media Communities, Wei Gong, Ee-Peng Lim, Feida Zhu

Research Collection School Of Computing and Information Systems

Silent users often constitute a significant proportion of an online user-generated content system. In the context of social media such as Twitter, users can opt to be silent all or most of the time. They are often called the invisible participants or lurkers. As lurkers contribute little to the online content, existing analysis often overlooks their presence and voices. However, we argue that understanding lurkers is important in many applications such as recommender systems, targeted advertising, and social sensing. This research therefore seeks to characterize lurkers in social media and propose methods to profile them. We examine 18 weeks of …

Matchmaking Game Players On Public Transport, Nairan Zhang, Youngki Lee, Rajesh Krishna Balan

Research Collection School Of Computing and Information Systems

This paper extends our recent work, called GameOn, which presented a system for allowing public transport commuters to engage in multiplayer games with fellow commuters traveling on the same bus or train. An important challenge for GameOn is to group players with reliable connections into the same game. In this case, the meaning of reliability has two dimensions. First, the network connectivity (TCP, UDP etc.) should be robust. Second, the players should be collocated with each other for a sufficiently long duration so that a game session will not be terminated by players leaving the public transport modality such as …

Advances In Knowledge Discovery And Data Mining: 19th Pacific-Asia Conference, Pakdd 2015, Ho Chi Minh City, Vietnam, May 19-22, 2015, Proceedings, Part I, Tru Cao, Ee-Peng Lim, Zhi-Hua Zhou, Tu-Bao Ho, David Wai-Lok Cheung, Hiroshi Motoda

Research Collection School Of Computing and Information Systems

No abstract provided.

Predicting Bundles Of Spatial Locations From Learning Revealed Preference Data, Truc Viet Le, Siyuan Liu, Hoong Chuin Lau, Ramayya Krishnan

Research Collection School Of Computing and Information Systems

We propose the problem of predicting a bundle of goods, where the goods considered is a set of spatial locations that an agent wishes to visit. This typically arises in the tourism setting where attractions can often be bundled and sold as a package to visitors. While the problem of predicting future locations given the current and past trajectories is well-established, we take a radical approach by looking at it from an economic point of view. We view an agent's past trajectories as revealed preference (RP) data, where the choice of locations is a solution to an optimisation problem according …

Electronic Contract Signing Without Using Trusted Third Party, Zhiguo Wan, Robert H. Deng, David Kuo Chuen Lee

Research Collection School Of Computing and Information Systems

Electronic contract signing allows two potentially dis-trustful parties to digitally sign an electronic document “simultaneously” across a network. Existing solutions for electronic contract signing either require the involvement of a trusted third party (TTP), or are complex and expensive in communication and computation. In this paper we propose an electronic contract signing protocol between two parties with the following advantages over existing solutions: 1) it is practical and scalable due to its simplicity and high efficiency; 2) it does not require any trusted third party as the mediator; and 3) it guarantees fairness between the two signing parties. We achieve …

Ambient Rendezvous: Energy Efficient Neighbor Discovery Via Acoustic Sensing, Keyu Wang, Zheng Yang, Zimu Zhou, Yunhao Liu, Lionel M. Ni

Research Collection School Of Computing and Information Systems

The continual proliferation of mobile devices has stimulated the development of opportunistic encounter-based networking and has spurred a myriad of proximity-based mobile applications. A primary cornerstone of such applications is to discover neighboring devices effectively and efficiently. Despite extensive protocol optimization, current neighbor discovery modalities mainly rely on radio interfaces, whose energy and wake up delay required to initiate, configure and operate these protocols hamper practical applicability. Unlike conventional schemes that actively emit radio tones, we exploit ubiquitous audio events to discover neighbors passively. The rationale is that spatially adjacent neighbors tend to share similar ambient acoustic environments. We propose …

Raman Micro Spectroscopy For In Vitro Drug Screening: Subcellular Localisation And Interactions Of Doxorubicin, Zeineb Farhane, Franck Bonnier, Alan Casey, Hugh Byrne

Articles

Vibrational spectroscopy, including Raman spectroscopy, has been widely used over the last few years to explore potential biomedical applications. Indeed, Raman spectroscopy has been demonstrated to be a powerful non-invasive tool in cancer diagnosis and monitoring. In confocal microscopic mode, the technique is also a molecularly specific analytical tool with optical resolution which has potential applications in subcellular analysis of biochemical processes, and therefore as an in vitro screening tool of the efficacy and mode of action of, for example, chemotherapeutic agents.

In order to demonstrate and explore the potential in this field, established, model chemotherapeutic agents can be valuable. …

Investigating Students' Use Of Multiple Representations Of The Arrow-Pushing Formalism, Yu Shen

All Theses

Over decades, research in STEM education has been conducted to investigate how students translate from one representation to another. Based on dual coding theory, multiple external representations (MERs) can be effective when the verbal/linguistic representations are provided along with the corresponded diagrammatic/pictorial representations. However, little is known about the difficulties that undergraduate students encounter when translating between the verbal and diagrammatic representations in the context of the arrow-pushing formalism used in organic reaction descriptions. Chemists use the arrow-pushing formalism to represent the electron flow in organic mechanistic processes. Yet, far less is known about the meaning that undergraduate students attribute …

Mining Patterns Of Unsatisfiable Constraints To Detect Infeasible Paths, Sun Ding, Hee Beng Kuan Tan, Lwin Khin Shar

Research Collection School Of Computing and Information Systems

Detection of infeasible paths is required in many areas including test coverage analysis, test case generation, security vulnerability analysis, etc. Existing approaches typically use static analysis coupled with symbolic evaluation, heuristics, or path-pattern analysis. This paper is related to these approaches but with a different objective. It is to analyze code of real systems to build patterns of unsatisfiable constraints in infeasible paths. The resulting patterns can be used to detect infeasible paths without the use of constraint solver and evaluation of function calls involved, thus improving scalability. The patterns can be built gradually. Evaluation of the proposed approach shows …

Map: A Computational Model For Adaptive Persuasion, Yilin Kang, Ah-Hwee Tan

Research Collection School Of Computing and Information Systems

While a variety of persuasion agents have been created and applied in different domains such as marketing, military training and health industry, there is a lack of a model which provides a unified framework for different persuasion strategies. Specifically, persuasion is not adaptable to the individuals’ personal states in different situations. Grounded in the Elaboration Likelihood Model (ELM), this paper presents a computational model called Model for Adaptive Persuasion (MAP) for virtual agents. MAP is a semi-connected network model which enables an agent to adapt its persuasion strategies through feedback. We have implemented and evaluated a MAP-based virtual nurse agent …

Discovering The Rise And Fall Of Software Engineering Ideas From Scholarly Publication Data, Subhajit Datta, Santonu Sarkar, Sajeev A. S. M., Nishant Kumar

Research Collection School Of Computing and Information Systems

For researchers and practitioners of a relatively young discipline like software engineering, an enduring concern is to identify the acorns that will grow into oaks -- ideas remaining most current in the long run. Additionally, it is interesting to know how the ideas have risen in importance, and fallen, perhaps to rise again. We analyzed a corpus of 19,000+ papers written by 21,000+ authors across 16 software engineering publication venues from 1975 to 2010, to empirically determine the half-life of software engineering research topics. We adapted existing measures of half-life as well as defined a specific measure based on publication …

A Multi-Level Analysis Of Collaborations In Computer Science, Pramod Divakarmurthy

Theses and Dissertations

Working in collaboration is common in today’s highly connected scientific community. By collaborating, researchers can solve challenging multi-disciplinary problems, increase knowledge dissemination as well as productivity. These and other advantages motivate the study of the collaboration patterns of researchers. Such patterns can be observed directly in networks of manuscript co-authorship. In such a network, nodes represent authors and the links between them indicate that they have co-authored a paper. Several researchers constructed and studied large-scale networks representing collaborations in Mathematics, Biology, Physics, and Neuroscience. Most studies have performed bibliometric analysis of scientific publications, evaluated and ranked scholars on their research …

A Foundation For Cyber Experimentation, Evan Lawrence Stoner

Theses and Dissertations

Despite the variety of environments and tools available to computer scientists performing cyber experimentation, the community lacks a single cohesive platform that is capable of unifying these tools across environments and research domains. In pursuit of this unifying platform, we introduce a new framework that is agnostic to the underlying environment, tools, and domain. We show the effectiveness of this framework by (1) demonstrating how an example experiment can be described within the framework and what benefits this offers, (2) presenting a prototype implementation of the framework, and (3) offering a collection of approaches to automated experimentation that the framework …

Immediate Effects Of Cervical Spine Manipulation On Gait Parameters In Individuals With And Without Mechanical Neck Pain, Jordan Isom, Shaylyn Kennedy, Justin May, Samuel Moore

UNLV Theses, Dissertations, Professional Papers, and Capstones

Purpose: The purpose of this study was to determine 1) if there were any differences in gait parameters between participants with mechanical neck pain and those without and 2) if cervical spine manipulation has an immediate effect on these gait parameters.

Methods: Twenty participants with mechanical neck pain and twenty participants without neck pain were randomly assigned into either the sham or manipulation group. The two intervention groups participated in walking across a GAITRite Walkway that recorded gait parameters such as stride length, cadence and step width before and after cervical spine manipulation. The participants walked at their own cadence …