Physical Sciences and Mathematics Commons^™

Prediction Of Nonradical Au (0)-Containing Precursors In Nanoparticle Growth Processes, Brian M. Barngrover, Timothy J. Manges, Christine M. Aikens

Faculty Publications

This density functional theory (DFT) investigation examines the formation of nonradical Au(0) species from the reduction of Au(I) species. The Au(I) complexes of interest are AuCl₂^–, AuBr₂^–, AuI₂^–, AuClPH₃, and AuCl(H)SCH₃⁽⁻⁾, which are precursors for gold nanoparticle and cluster formation. Reaction of two of the Au(I) species with a hydride results in ejection of two of the ligands and formation of Au₂ with two ligands still attached. AuX₂^– (where X = Cl, Br, or I) reactions eject two halides and form Au_{2 …}

Stretchable Conductive Composites For Use In Soft Devices, Joshua Aaron Lessing, Stephen A. Morin, George M. Whitesides

Chemistry Department: Faculty Publications

An elastically-deformable, conductive composite using elastomers and conductive fibers and simple fabrication procedures is provided. Conductive elastomeric composites offer low resistance to electrical current and are elastic over large (>25%) extensional strains. They can be easily interfaced/built into structures fabricated from elastomeric polymers.

The Implications Of Climate Change For Nebraska: Summary Report Of Sector-Based Roundtable Discussions (September-October 2015), Donald A. Wilhite, Kimberly Morrow

Drought Mitigation Center: Faculty Publications

Introduction ... iv

Roundtable Reports: Overview ... iv

Rural Nebraskans Poll: Summary of Key Outcomes on Climate Change ... vi

Summary of Roundtable Discussions ... 1

Addressing the Impacts of Climate Change on Ecosystems and Wildlife in Nebraska ... 1

Implications of Climate Change on Human Health in Nebraska ... 11

Implications of Climate Change on Nebraska’s Forests and Fire ... 21

Implications of Climate Change on Nebraska’s Agriculture, Food and Water ... 27

Implications of Climate Change on Energy Availability, Use and Management in Nebraska ... 31

Climate Change in Nebraska: What Does it Mean for our Faith Communities? …

From Too Much To Too Little: How The Central U.S. Drought Of 2012 Evolved Out Of One Of The Most Devastating Floods On Record In 2011, Brian Fuchs, Deborah Wood, Dee Ebbeka

Drought Mitigation Center: Faculty Publications

Introduction: Brian Fuchs, National Drought Mitigation Center

Regional Drought Perspective: Natalie A. Umphlett, High Plains Regional Climate Center, Michael S. Timlin, Midwest Regional Climate Center, Brian Fuchs, National Drought Mitigation Center

State Drought Perspectives — Colorado: Wendy Ryan and Nolan Doesken, Colorado Climate Center • Illinois: Jim Angel, Illinois State Water Survey • Indiana: Olivia Kellner, Indiana State Climate Office • Iowa: Harry J. Hillaker, Iowa Dept. of Agriculture & Land Stewardship • Kansas: Mary Knapp and Xiaomao Lin, Kansas State University • Kentucky: Stu Foster, Kentucky State Climate Office • Michigan: Jeff Andresen and Aaron Pollyea, Michigan State University …

U.S. Climate Resilience Toolkit Road Test: Bridging The Data-Practice Divide A Summary Report By Antioch University New England Center For Climate Resilience And Community Preparedness April 2015, Abigail Abrash Walton Phd, Michael Simpson Ms, Marilyn Castriotta Ms

Faculty Articles

Antioch University’s Center for Climate Preparedness and Community Resilience developed an online Facilitated Community of Practice model (FCoP) to convene 29 end-user decision-makers, working with 25 Eastern United States coastal communities, to “road test” the U.S. Climate Resilience Toolkit. FCoP participants (e.g., planners, emergency preparedness and municipal administration personnel, natural resource specialists) represented communities from Norfolk, VA, to Rockland, ME. The project was designed to provide constructive feedback to federal agencies to inform the usability of the toolkit for local decision makers and planners. The project also was intended to contribute to two broader outcomes: 1. building resilience in Eastern …

Specific N-Glycans Of Hepatocellular Carcinoma Cell Surface And The Abnormal Increase Of Core-Α-1, 6-Fucosylated Triantennary Glycan Via N-Acetylglucosaminyltransferases-Iva Regulation, Huan Nie, Xia Liu, Yubao Zhang, Tingting Li, Chao Zhan, Wenjuan Huo, Anshun He, Yuanfei Yao, Yu Jin, Youpeng Qu, Xue-Long Sun, Yu Li

Chemistry Faculty Publications

Glycosylation alterations of cell surface proteins are often observed during the progression of malignancies. The specific cell surface N-glycans were profiled in hepatocellular carcinoma (HCC) with clinical tissues (88 tumor and adjacent normal tissues) and the corresponding serum samples of HCC patients. The level of core-α-1,6-fucosylated triantennary glycan (NA3Fb) increased both on the cell surface and in the serum samples of HCC patients (p < 0.01). Additionally, the change of NA3Fb was not influenced by Hepatitis B virus (HBV)and cirrhosis. Furthermore, the mRNA and protein expression of N-acetylglucosaminyltransferase IVa (GnT-IVa), which was related to the synthesis of the NA3Fb, was substantially increased in HCC tissues. Knockdown of GnT-IVa leads to a decreased level of NA3Fb and decreased ability of invasion and migration in HCC cells. NA3Fb can be regarded as a specific cell surface N-glycan of HCC. The high expression of GnT-IVa is the cause of the abnormal increase of NA3Fb on the HCC cell surface, which regulates cell migration. This study demonstrated the specific N-glycans of the cell surface and the mechanisms of altered glycoform related with HCC. These findings lead to better understanding of the function of glycan and glycosyltransferase in the tumorigenesis, progression and metastasis of HCC.

Towards Predicting Street-Level Inundation: Using Operational Forecast Modeling Techniques During 2011 Hurricane Irene, J. D. Loftis, H. V. Wang, D. R. Forrest

Presentations

Storm surge-induced coastal inundation poses numerous personal, commercial, industrial, and sociopolitical challenges for society. Flooding can be caused by the combination of storm surge and river-induced inland flooding in many locations throughout the coastal plain. The cross-disciplinary nature of the hydrodynamics involved (hydraulics, oceanography, and hydrology), coupled with the complexity of the atmospheric forcing, makes a numerical model the best approach for a comprehensive study of the dynamics of coastal inundation.

This study builds upon the lessons learned from forecast modeling experiences during 2011 Hurricane Irene in Tidewater Virginia, to ascertain the most effective way to approach predicting street-level inundation. …

Possible Tsunami Deposits On The Caribbean Coast Of The Yucatán Peninsula, Charles Shaw, Larry Benson

United States Geological Survey: Staff Publications

The western Caribbean Basin is notable for its tectonic stability. It has experienced no historical earthquakes or the tsunami that sometimes accompany them. This paper describes a single, wedge-shaped, boulder-covered, coastal berm on the Yucatán coast of México that stretches unbroken for 50 km across a coastal segment characterized by rocky headlands that alternate with crescent beaches. The remainder of the 350 km of Yucatán coast consists mostly of mangrove that extends 1 to 30 km inland, often behind long, sandy beaches. On the headlands, the surface of the berm is densely paved with boulders—large boulders on its seaward face …

Toxicity Reference Values For Chlorophacinone And Their Application For Assessing Anticoagulant Rodenticide Risk To Raptors, Barnett A. Rattner, Katherine E. Horak, Rebecca S. Lazarus, Sandra L. Schultz, Susan Knowles, Benjamin G. Abbo, Steven F. Volker

United States Geological Survey: Staff Publications

Despite widespread use and benefit, there are

growing concerns regarding hazards of second-generation

anticoagulant rodenticides to non-target wildlife which

may result in expanded use of first-generation compounds,

including chlorophacinone (CPN). The toxicity of CPN

over a 7-day exposure period was investigated in American

kestrels (Falco sparverius) fed either rat tissue mechanically-

amended with CPN, tissue from rats fed Rozol bait

(biologically-incorporated CPN), or control diets (tissue

from untreated rats or commercial bird of prey diet)

ad libitum. Nominal CPN concentrations in the formulated

diets were 0.15, 0.75 and 1.5 µg/g food wet weight, and

measured concentrations averaged 94 …

Global Change And Conservation Triage On National Wildlife Refuges, Fred Johnson, Mitchell J. Eaton, Gerard Mcmahon, Raye Nilius, Michael R. Bryant, Dave Case, Julien Martin, Nathan Wood, Laura Taylor

United States Geological Survey: Staff Publications

National Wildlife Refuges (NWRs) in the United States play an important role in the adaptation of social-ecological systems to climate change, land-use change, and other global-change processes. Coastal refuges are already experiencing threats from sea-level rise and other change processes that are largely beyond their ability to influence, while at the same time facing tighter budgets and reduced staff. We engaged in workshops with NWR managers along the U.S. Atlantic coast to understand the problems they face from global-change processes and began a multidisciplinary collaboration to use decision science to help address them. We are applying a values-focused approach to …

Nutrient Contributions From Alluvial Soils Associated With The Restoration Of Shallow Water Habitat In The Lower Missouri River, D C. Heimann, D M. Morris, T R. Gemeinhardt

United States Geological Survey: Staff Publications

The Missouri River has been extensively altered as the result of channelization, bank stabilization, and the construction of six main stem reservoirs. In response to the resultant habitat loss, the US Army Corps of Engineers was tasked with restoring approximately 8100 ha of shallow water habitat (SWH), in part, for the benefit of the endangered pallid sturgeon (Scaphirhynchus albus). Construction of off-channel habitats involves the removal and disposal of excavated alluvium either by direct discharge into the river or by secondary erosion, which raised concerns regarding the introduction of sediment and associated nutrients into the Missouri River. Soils from nine …

Drought Monitoring And Assessment: Remote Sensing And Modeling Approaches For The Famine Early Warning Systems Network, G B. Senay, N M. Velpuri, S Bohms, M Budde, C Young, J Rowland, J P. Verdin

United States Geological Survey: Staff Publications

Drought monitoring is an essential component of drought risk management. It is usually carried out using drought indices/indicators that are continuous functions of rainfall and other hydrometeorological variables. This chapter presents a few examples of how remote sensing and hydrologic modeling techniques are being used to generate a suite of drought monitoring indicators at dekadal (10-day), monthly, seasonal, and annual time scales for several selected regions around the world. Satellite-based rainfall estimates are being used to produce drought indicators such as standardized precipitation index, dryness indicators, and start of season analysis. The Normalized Difference Vegetation Index is being used to …

02. Animal Science, Northeastern State University

Oklahoma Research Day Abstracts

No abstract provided.

05. Chemistry, Northeastern State University

Oklahoma Research Day Abstracts

No abstract provided.

09. Environmental Science, Northeastern State University

Oklahoma Research Day Abstracts

No abstract provided.

12. Kinesiology, Northeastern State University

Oklahoma Research Day Abstracts

No abstract provided.

15. Pharmacy, Northeastern State University

Oklahoma Research Day Abstracts

No abstract provided.

19. Zoology, Northeastern State University

Oklahoma Research Day Abstracts

No abstract provided.

Towards Analytical Techniques For Optimizing Knowledge Acquisition, Processing, Propagation, And Use In Cyberinfrastructure, Leonardo Octavio Lerma

Open Access Theses & Dissertations

For many decades, there has been a continuous progress in science and engineering applications.

A large part of this progress comes from the new knowledge that researchers acquire, propagate, and use. This new knowledge has revolutionized many aspects of our life, from driving to communications to shopping.

Somewhat surprisingly, there is one area of human activity which is the least impacted by the modern technological progress: the very processes of acquiring, processing, and propagating information. When we decide where to place sensors, which algorithm to use for processing the data – we rely mostly on our own intuition and on …

Does Low-Level Arsenic Exposure Predict Blood Pressure In Children?, Tania Angelica Mayorga

Open Access Theses & Dissertations

Background & Significance: Inorganic arsenic is a heavy metal naturally found in soil and human exposure to this heavy metal causes adverse effects. Exposure risks are particularly high in developing children. Arsenic is mainly found in bedrock. It is also a by-product of smelting, it is used in cement production, and historically is has been found in crop pesticides. Among other ill-effects, arsenic exposure in humans can cause respiratory diseases, peripheral neuropathy and liver fibrosis. In particular arsenic has been shown in many studies to be a contributing factor in the risk for hypertension in adults however no studies have …

Processing And Property Evaluation Of Tungsten-Based Mixed Oxides For Photovoltaics And Optoelectronics, Mirella Vargas

Open Access Theses & Dissertations

Tungsten Oxide (WO3) films and low-dimensional structures have proven to be promising candidates in the fields of photonics and electronics. WO3 is a well-established n-type semiconductor characterized by unique electrochromic behavior, an ideal optical band gap that permits transparency over a wide spectral range, and high chemical integrity. The plethora of diverse properties endow WO3 to be highly effective in applications related to electrochromism, gas sensing, and deriving economical energy. Compared to the bulk films, a materials system involving WO3 and a related species (elements or metal oxides) offer the opportunity to tailor the electrochromic response, and an overall enhancement …

Comparison Of Blood Lead Levels Between Children In An Urban Setting And Children In A Rural Setting, Juan Manuel Alvarez

Open Access Theses & Dissertations

Environmental heavy metal exposure is a public health problem that is of great concern because it is highly toxic for children. The urban setting in downtown El Paso is historically known to be contaminated through various sources of contamination of heavy metals. The goal of this study was to compare whether children in a historically contaminated urban downtown area had significantly increased levels of lead exposure as compared to children in a demographically similar rural area approximately 20 miles north of the urban center, while controlling for gender and age. Cadmium and mercury were also measured for comparison purposes. It …

Lithospheric Structure And Stress Field Orientations In The Northern Libya And East-Central Mediterranean Region, Abdusalam Ali Agail

Open Access Theses & Dissertations

This thesis is a combination of three studies including tomography using surface wave group velocities, stress orientations from focal mechanisms, and receiver functions. The study area covers northern Libya and the east central Mediterranean region. I utilized new data from the Libyan National Seismic Network to better understand the crustal thickness and stress orientation of northern Libya as well as the east central Mediterranean region. In the first study, I conducted surface wave group velocity tomography implementing the Gaussian beam method for obtaining 2-D velocity variations assuming an isotropic model. I constructed surface wave group velocity maps over a range …

Virtual Rapport With Extraverted Agents, Jacqueline Brixey

Open Access Theses & Dissertations

Studies from psychology conclude that "birds of a feather flock together"- or, in other words, people tend to seek companionship with those who have a similar personality to their own. Researchers in the fields of Linguistics and Psychology have found numerous markers that differentiate the dialogue of extroverts from that of introverts. Recent work in Human Computer Interaction has sought to understand the nature of creating and maintaining rapport between humans and Embodied Conversational Agents (ECAs).

Seeking an interdisciplinary approach that combines knowledge from HCI, Linguistics, and Psychology, I sought to establish whether introverted users report the highest level of …

Molecular Dynamics Study On Defect Reduction Strategies Towards The Fabrication Of High Performance Cd1-Xznxte/Cds Solar Cells, Jose Juan Chavez

Open Access Theses & Dissertations

Cadmium Telluride is a material widely used in terrestrial thin film photovoltaic applications due to its nearly ideal band gap (~1.5 eV) and high absorption coefficient. Due to its low manufacturing cost, this technology has the potential to become a significant energy resource if higher energy conversion efficiencies are achieved. However, the module efficiencies (~14%) are still far from the theoretical maximum (~30%) for this material in a single junction configuration. The reason behind this low performance is attributed to the high number of defects that are present within the device materials. The physics behind the formation mechanisms of these …

Novel Endohedral Derivatives Of Sc3n@C2n (N = 34, 40) And Unique Tether Controlled Bis-Functionalization Of Fullerenes, Maira Raquel Ceron Hernandez

Open Access Theses & Dissertations

Since the discovery of fullerenes in 1985, their exohedral functionalization has been necessary to increase their solubility and explore their properties and potential applications in materials science and medicinal chemistry. This Thesis provides a short overview of the importance of electronic, size and shape complementarity in determining the structures of specific endohedral fullerene compounds. This is followed by a description of a new method for the separation of scandium nitride endohedral fullerenes Sc3N@C2n (n = 34, 39 and 40), and their monofunctionalization.

We also present the regioselective synThesis of easily isolable bis-derivatives of C60, C70, and M3N@Ih-C80 (M = Sc, …

Effect Of Plastic Deformation Anisotropies On Shock-Induced Phase Transitions In Metallic Single Crystals, Punam Ghimire

Open Access Theses & Dissertations

Most metals and alloys undergo plastic deformation at shear stresses and/or pressures in the Kbars regime. On the other hand, typical pressure-induced structural transitions, take place at much higher pressures, in the tens of GPa range. Surprisingly, there has not been to date, a systematic study on the role plastic deformation plays on the dynamics of defect-mediated phase transformations. The main purpose of this work was to investigate via atomistic simulations, the contribution of pre-existing defect densities on the kinetics of structural transformations under dynamic loading. We have carried out molecular dynamics simulations - including large-scale non-equilibrium molecular dynamics (NEMD), …

Exploratory Study Of Seasonal Indoor Bioaerosols And The Associated Health Outcomes In Low-Income Communities In El Paso, Texas, 2014, Eric Martinez

Open Access Theses & Dissertations

Introduction: Structural degradation, moisture levels, and building failures can influence poor indoor air quality and create a good environment for bioaerosols. People spend much of their time indoors and can potentially be exposed to these bioaerosols. Several studies have correlated exposures to high concentrations of bioaerosols to various health problems, severe allergies, asthma, or other respiratory illness. Objectives: The objectives of this study are to describe bioaerosol concentrations, meteorological factors, and health outcomes during the summer and fall seasons; characterize bioaerosols (bacteria and fungi) collected in low-income communities; compare bioaerosol concentrations by season; compare meteorological factors to bioaerosol concentrations by …

On The Path To Multi-Electron Redox Chemistry With Bimetallic Systems, Nathalie Metta

Open Access Theses & Dissertations

The following study is presented in two sections, in the first, a novel digold (II) complex with semi-bridging chlorides supported by two bulky formamidinates was synthesized for the purpose of studying late-transition metal multi-electron redox chemistry. Electrochemical analysis shows one non-reversible reduction. Although the electrochemistry of this complex is restricted, the compound shows interesting electronic properties. The crystal structure reveals a geometry distortion of the Au2ï?­-Cl2 core. The coupling of an unoccupied orbital and an occupied orbital through a vibrational mode, causes a distortion in the geometry of the molecule lowering the D2h symmetry to C2h. This is an example …

Prospective Secondary Science Teachers' Argumentation Skills And The Interaction Of These Skills With Their Conceptual Knowledge, Ömer Acar, Bruce R. Patton, Arthur L. White

Australian Journal of Teacher Education

This study investigated if prospective secondary science teachers enhance their argumentation skills and the interaction of the change in their argumentation skills with their conceptual knowledge during an argumentation-based guided inquiry course. 37 prospective secondary science teachers constituted the study sample. They were grouped according to whether or not they had a misconception about understanding of balanced forces at the beginning of the course. They performed oral and written argumentation tasks during the course. Their written argumentation tasks were assessed four times during the course for balanced forces and sinking and floating behaviour of objects. Results indicated that prospective secondary …