Physical Sciences and Mathematics Commons^™

Improving Processing By Adaption To Conditional Geostatistical Simulation Of Block Compositions, R. Tolosana-Delgado, Ute A. Mueller, K. G. Van Den Boogaart, C. Ward, J. Gutzmer

Research outputs 2014 to 2021

Exploitation of an ore deposit can be optimized by adapting the beneficiation processes to the properties of individual ore blocks. This can involve switching in and out certain treatment steps, or setting their controlling parameters. Optimizing this set of decisions requires the full conditional distribution of all relevant physical parameters and chemical attributes of the feed, including concentration of value elements and abundance of penalty elements. As a first step towards adaptive processing, the mapping of adaptive decisions is explored based on the composition, in value and penalty elements, of the selective mining units. Conditional distributions at block support are …

The Use Of Ontologies In Forensic Analysis Of Smartphone Content, Mohammed Alzaabi, Thomas Anthony Martin, Kamal Taha, Andy Jones

Research outputs 2014 to 2021

Digital forensics investigators face a constant challenge in keeping track with evolving technologies such as smartphones. Analyzing the contents of these devices to infer useful information is becoming more time consuming as the volume and complexity of data are increasing. Typically, such analysis is undertaken by a human, which makes it dependent on the experience of the investigator. To overcome such impediments, an automated technique can be utilized in order to aid the investigator to quickly and efficiently analyze the data. In this paper, we propose F-DOS; a set of ontologies that models the smartphone content for the purpose of …

Current Land Bird Distribution And Trends In Population Abundance Between 1982 And 2012 On Rota, Mariana Islands, Richard J. Camp, Kevin W. Brink, P. Marcos Gorreson, Fred A. Amidon, Paul Radley, S. Paul Berkowitz, Paul C. Banko

Research outputs 2014 to 2021

The western Pacific island of Rota is the fourth largest human-inhabited island in the Mariana archipelago and designated an Endemic Bird Area. Between 1982 and 2012, 12 point-transect distance-sampling surveys were conducted to assess bird population status. Surveys did not consistently sample the entire island; thus, we used a ratio estimator to estimate bird abundances in strata not sampled during every survey. Trends in population size were reliably estimated for 11 of 13 bird species, and 7 species declined over the 30-y time series, including the island collared-dove Streptopelia bitorquata, white-throated ground-dove Gallicolumba xanthonura, Mariana fruit-dove Ptilinopus roseicapilla, collared kingfisher …

Alcts Crs Holdings Information Forum, 3-4 P.M. January 31, 2015, Connie Foster

Connie Foster

Cecilia Genereux (data management & access/metadata & intellectual access, University of Minnesota Libraries) introduced the session by confessing to a pun intended for her presentation: Alma: To Have and to Hold. The levity quickly shifted into some very detailed analysis of the way the Ex Libris Alma system handled specific types of serials during a migration from Aleph. The University of Minnesota started with Aleph (Ex Libris) in 2002 and moved to Alma on December 26, 2013. Frances McNamara (director, Integrated Library Systems and Administrative and Desktop Systems at University of Chicago), discussed migrating serials data from Horizon to Kulai …

Properly Colored Notions Of Connectivity - A Dynamic Survey, Xueliang Li, Colton Magnant

Theory and Applications of Graphs

A path in an edge-colored graph is properly colored if no two consecutive edges receive the same color. In this survey, we gather results concerning notions of graph connectivity involving properly colored paths.

Second Hamiltonian Cycles In Claw-Free Graphs, Hossein Esfandiari, Colton Magnant, Pouria Salehi Nowbandegani, Shirdareh Haghighi

Theory and Applications of Graphs

Sheehan conjectured in 1975 that every Hamiltonian regular simple graph of even degree at least four contains a second Hamiltonian cycle. We prove that most claw-free Hamiltonian graphs with minimum degree at least 3 have a second Hamiltonian cycle and describe the structure of those graphs not covered by our result. By this result, we show that Sheehan’s conjecture holds for claw-free graphs whose order is not divisible by 6. In addition, we believe that the structure that we introduce can be useful for further studies on claw-free graphs.

Connection And Separation In Hypergraphs, Mohammad A. Bahmanian, Mateja Sajna

Theory and Applications of Graphs

In this paper we study various fundamental connectivity properties of hypergraphs from a graph-theoretic perspective, with the emphasis on cut edges, cut vertices, and blocks. We prove a number of new results involving these concepts. In particular, we describe the exact relationship between the block decomposition of a hypergraph and the block decomposition of its incidence graph.

Advancing Feedback-Driven Optimization For Modern Computing., Mingzhou Zhou

Dissertations, Theses, and Masters Projects

No abstract provided.

Sea-Air Co2 Exchange In The Western Arctic Coastal Ocean, Wiley Evans, Jeremy T. Mathis, Jessica N. Cross, Nicholas R. Bates, Karen E. Frey, Brent G.T. Else, Tim N. Papkyriakou, Mike D. Degrandpre, Fakhrul Islam, Wei Jun Cai, Baoshan Chen, Michiyo Yamamoto-Kawai, Eddy Carmack, William J. Williams, Taro Takahashi

Geography

The biogeochemical seascape of the western Arctic coastal ocean is in rapid transition. Changes in sea ice cover will be accompanied by alterations in sea-air carbon dioxide (CO2) exchange, of which the latter has been difficult to constrain owing to sparse temporal and spatial data sets. Previous assessments of sea-air CO2 flux have targeted specific subregional areas of the western Arctic coastal ocean. Here a holistic approach is taken to determine the net sea-air CO2 flux over this broad region. We compiled and analyzed an extensive data set of nearly 600,000 surface seawater CO2 partial pressure (pCO2) measurements spanning 2003 …

Political Ecologies Of Resource Extraction: Agendas Pendientes, Anthony J. Bebbington

Geography

Research related to extractive industries has grown significantly over the last decade. As the commodities boom appears to be winding down, this essay outlines areas for potential future research. Emphasis is placed on the need for research on: the relationships among extractivism, climate change and societal transitions; the aggregate effects of the commodity boom on the environment, on societal structures, on elite formation and on cultural politics; the implications of resource extraction on the couplings of space and power at different scales and with particular reference to the Colombian peace process; and the gendered and generation dimensions of the effects …

Multipoint Spectroscopy And Stereoscopic Imaging Of Pharmaceutical Particles, Hicham Rifai

Masters

Particle and granule properties play a key role in the final product quality of pharmaceuticals. Thus the identification and monitoring of key chemical and physical parameters is essential in the production of pharmaceuticals. The existing off-line methods are generally slow and labour intensive. Near infra-red (NIR) multipoint spectroscopy and image analysis are an attractive alternative compared to the traditional methods because they are both nondestructive and non-interfering allowing the analysis in real time of particles physical and chemical properties. This research is a preliminary study performed at laboratory scale and aims at developing chemometric and imaging algorithms for real time …

Micro-Topological Effects On Redox-Sensitive Nutrient Availability Of Manganese, Iron, Sulfur, And Phosphorus, Lindsey C. Ruhl

Graduate College Dissertations and Theses

The working hypothesis for this study was that small elevation differences in field depressions affect the availability of redox active nutrients because the bottom of the depression remains waterlogged and in reducing conditions longer than the edge of the depression. Mn, Fe, S and P availabilities were investigated in a field depression with a 20 meter radius and 0.5 meter depth on a flood-prone, organic vegetable farm. One depression (Depression 1) was sampled seven times during three field seasons (May 2012-June 2014). The last two dates included sampling in an additional three depressions to allow a comparison among depressions on …

Studies Toward The Total Synthesis Of Subincanadine E, Corinne Marie Sadlowski

Graduate College Dissertations and Theses

Progress towards a concise total synthesis of subincanadine E is reported. This natural product was first isolated from the Picralima nitida cell suspension culture line in 1982 under the name pericine and later in 2002 from Aspidosperma subincanum as subincanadine E. It is the most potent compound of its class with in vitro cytotoxicity against both murine lymphoma L1210 and human epidermoid carcinoma KB cells (LD50, 0.3 ug/mL and 4.4 ug/mL, respectively) and was found to be six times more potent than codeine as an opiate agonist in a 3H-naloxone binding study (IC50, 0.6 umol/L).

The first-generation synthesis produced an …

Lexical Mechanics: Partitions, Mixtures, And Context, Jake Ryland Williams

Graduate College Dissertations and Theses

Highly structured for efficient communication, natural languages are complex systems. Unlike in their computational cousins, functions and meanings in natural languages are relative, frequently prescribed to symbols through unexpected social processes. Despite grammar and definition, the presence of metaphor can leave unwitting language users "in the dark," so to speak. This is not problematic, but rather an important operational feature of languages, since the lifting of meaning onto higher-order structures allows individuals to compress descriptions of regularly-conveyed information. This compressed terminology, often only appropriate when taken locally (in context), is beneficial in an enormous world of novel experience. However, what …

The Champlain Sea/Lake Champlain Transition Recorded In The Northeast Arm Of Lake Champlain, Usa-Canada, Ashliegh Theresa Belrose

Graduate College Dissertations and Theses

Sediment accumulated on a lakebed archives information about past climate and changes in the regional environment. Previous studies (Burgess, 2007; Koff, 2011; Palmer, 2012) in the Northeast Arm of Lake Champlain, specifically Missisquoi Bay and Saint Albans Bay, showed a period (~9,400 - 8,600 yBP) of elevated organic matter deposition in both bays, indicating a productive event that pre-dated any possible anthropogenic influence. However, the record was abruptly cut off and any documentation representing the span of time leading up to this event was not found. The elevated organic matter levels were explained as being the result of a warm, …

Using The Past As The Key To The Present: Informing Coastal Resource Management With Geologic Records, Benjamin D. Dejong

Graduate College Dissertations and Theses

Rising sea levels present an ongoing threat to communities and resources around the Chesapeake Bay, east coast, USA, where tide gauges indicate that the relative rise of sea level is approximately twice the rate of average, eustatic sea-level rise. This has significantly compromised the health and viability of salt marsh habitat on the Eastern Shore during the 20th century, and the biologists who are charged with managing coastal resources in the coming decades need to understand the nature and causes of high rates of regional sea-level rise to develop suitable adaptation plans.

Dated geologic deposits and geophysical models suggest that …

Experimental Investigation And Analysis Of High-Enthalpy Nitrogen Flow Over Graphite, Andrew Lutz

Graduate College Dissertations and Theses

The high-enthalpy flow generated by hypersonic vehicles traveling within the Earth's atmosphere inherently delivers an elevated heat flux to the vehicle surface. In addition to conductive heating, the liberated energy generated by various exothermic chemical reactions occurring at the vehicle surface further augment the total heat load. Quantifying the rates at which these reactions take place is imperative and remains a significant challenge as developers attempt to design the next generation of thermal protection systems.

This study focused on nitrogen recombination and carbon nitridation, as these reactions are ubiquitous to the most aggressive atmospheric re-entry trajectories in which carbon-based ablative …

Sedimentologic Comparison Of The Late/Lower Early Middle Cambrian Altona Formation And The Lower Cambrian Monkton Formation, Ryan A. Brink

Graduate College Dissertations and Theses

The Altona Formation represents the oldest Cambrian sedimentary unit in northern New York, recording cyclic deposition in shallow marine and fluvial environments under both fair-weather and storm conditions. Five outcrops and one well log were measured and described at the centimeter scale and the top and bottom contacts of the Altona were identified. Based on the recognition of sedimentary structures such as hummocky cross stratification, oscillatory ripples, graded bedding, trough and tabular cross stratification, and bioturbation, as well as subtle lithologic changes, six lithofacies representing non-marine, middle to upper shoreface, offshore, and carbonate ramp environments were identified. The top contact …

The Interplay Between Deformation And Metamorphism During Strain Localization In The Lower Crust: Insights From Fiordland, New Zealand, Kathryn Elise Dianiska

Graduate College Dissertations and Theses

In this thesis, I present field, microstructural, and Electron Backscatter Diffraction (EBSD) analyses of rock fabrics from high strain zones in exposures of lower crustal Cretaceous plutons at Breaksea Entrance, Fiordland, New Zealand. The interplay between deformation and metamorphism occurs across multiple scales at the root of a continental arc. I show a series of steps in which retrogressive metamorphism is linked to the accommodation of deformation.

I define three main phases of deformation and metamorphism at Breaksea Entrance. The first phase (D1) involved emplacement of dioritic to gabbroic plutons at depths up to 60 km. The second phase (D2) …

Analytical And Decision Tools For Wildlife Population And Habitat Management, Kurt Rinehart

Graduate College Dissertations and Theses

The long-term success of wildlife conservation depends on maximizing the benefits of limited funds and data in pursuit of population and habitat objectives. The ultimate currency for wildlife management is progress toward long-term preservation of ample, wild, free wildlife populations and to this end, funds must be wisely spent and maximal use made from limited data.

Through simulation-based analyses, I evaluated the efficacy of various models for estimating population abundance from harvest data. Because managers have different estimators to choose from and can also elect to collect additional data, I compared the statistical performance of different estimation strategies (estimator + …

Evaluation Of Key Geomechanical Aspects Of Shallow And Deep Geothermal Energy, Robert Alexander Caulk

Graduate College Dissertations and Theses

Geothermal energy has become a focal point of the renewable energy revolution. Both shallow and deep types of geothermal energy have the potential to offset carbon emissions, reduce energy costs, and stimulate the economy. Before widespread geothermal exploration and exploitation can occur, both shallow and deep technologies require improvement by theoretical and experimental investigations. This thesis investigated one aspect of both shallow and deep geothermal energy technologies. First, a group of shallow geothermal energy piles was modeled numerically. The model was constructed, calibrated, and validated using available data collected from full-scale in-situ experimental energy piles. Following calibration, the model was …

I. A New Route To Azomethine Ylides: Shifting The Reliance On Amino Ester Precursors Ii. Applications In Total Synthesis, Natalie Kay Machamer

Graduate College Dissertations and Theses

Nitrogen-containing heterocycles have great utility in the biomedical and medicinal fields and one such heterocycle is the 5-membered pyrrolidine ring. The synthesis of pyrrolidine rings has been studied extensively with the routes relying on anodic oxidation, transition metals and dipolar cycloadditions with azomethine ylides. Previous work in the Waters group has been focused on new routes to azomethine ylides through a domino sequence. Through a thermal aza-Cope rearrangement followed by [3+2] dipolar cycloaddition the synthesis of a library of 2-allyl pyrrolidines was accomplished. It was discovered that by using allylic amines and glyoxals at room temperature a cycloadduct was isolated …

The Status Of Stonecats (Noturus Flavus) In The Laplatte And Missisquoi Rivers, Vermont, Elizabeth Puchala

Graduate College Dissertations and Theses

Stonecats (Noturus flavus, Rafinesque 1818) are designated as a Vermont state-listed endangered species because their known distribution is limited to two systems, the LaPlatte and Missisquoi rivers. The restricted distribution and lack of knowledge on abundance in either river is cause for concern in the continued survival of these populations. Based on the capture numbers and large size range of individuals, we predicted that the population in the LaPlatte River, which provides quality benthic habitat, is stable. However, the Missisquoi River population has the potential for increased intermittent mortalities from two sources, lampricide (3-trifluoromethyl-4-nitrophenol) treatment every four years and dewatering …

An Embodied Approach To Evolving Robust Visual Classifiers, Karol Zieba

Graduate College Dissertations and Theses

From the very creation of the term by Czech writer Karel Capek in 1921, a "robot" has been synonymous with an artificial agent possessing a powerful body and cogitating mind. While the fields of Artificial Intelligence (AI) and Robotics have made progress into the creation of such an android, the goal of a cogitating robot remains firmly outside the reach of our technological capabilities. Cognition has proved to be far more complex than early AI practitioners envisioned. Current methods in Machine Learning have achieved remarkable successes in image categorization through the use of deep learning. However, when presented with novel …

The Impact Of Engagement With Community Supported Agriculture On Human Attitude Towards The Sustainable Food Movement, Ariana Margarita Cano

Graduate College Dissertations and Theses

With a total of 164 community supported agriculture programs (CSA), Vermont is leading the "locavore" movement in the United States, ranked number one in the country with the most CSAs and Food Hubs per capita. ("Locavore Index," 2013)

CSAs have a large positive impact on reducing carbon emissions, advancing local economic growth, and promoting healthy lifestyles of consumers. The purpose of this study is to explore the overall experience of individuals in comparison to their current social norm, individual attitudes, identity, and intentions of change, and understand any change overtime in their individual attitude and behavior.

Attitude change was measured …

A Comparative Examination Of The Safety Programs At Ucla, Umn, And Uvm In Response To Recent Chemistry Laboratory Incidents, Victoria Carhart

Graduate College Dissertations and Theses

Laboratory safety has recently become more of an imperative in research laboratories than it has ever been in the past. Recent accidents at several universities have escalated the awareness of safety concerns in laboratory workspaces among the general public and created a greater need for a stronger culture of safety in chemistry research overall. Historically, results and publications have been the top priority of most researchers, not laboratory safety.

This thesis discusses a number of laboratory accidents. The first happened in December of 2008 at the University of California, Los Angeles (UCLA) and resulted in the death of a graduate …

Sustainable Agriculture In Vermont: Economics Of Climate Change Best Management Practices And The Complexity Of Consumer Perceptions Of Raw Milk, Alexander Paul Helling

Graduate College Dissertations and Theses

Changing weather patterns, the declining social fabric of rural communities, and economic uncertainty increasingly pose challenges to Vermont communities. The socially and environmentally embedded production practices within sustainable agriculture present a potential solution to these problems. In order to make the most of the potential benefits of these practices society must maximize their adoption. This requires an understanding of both farmer adoption of these practices and consumer perceptions of the resulting food products. This thesis contributes two original articles on sustainable agriculture through the analysis of factors driving both farmer adoption and consumer perceptions of products and practices often thought …

Burst Pressure Properties And Ex Vivo Analysis Of Alginate-Based Hydrogels For Tissue Sealant Applications, Patrick Nelson Charron

Graduate College Dissertations and Theses

Lung diseases, cancers, and trauma can result in injury to the connective tissue lining the lung, i.e., the pleura. Pleural injuries lead to pneumothoraxes or pleural effusions, i.e., air or fluid leaking out of the lung respectively, and potential lung collapse - an immediately life threatening condition. While several bioengineered soft tissue sealants exist on the market, there is only one sealant FDA-approved for use in pulmonary surgery. In addition, very limited techniques are presented in the literature for characterizing the burst properties of hydrogel tissue sealants. For my thesis, I proposed to develop a protocol for characterizing the burst …

Phosphate Removal And Recovery From Wastewater By Natural Materials For Ecologically Engineered Wastewater Treatment Systems, Daniel Thomas Curran

Graduate College Dissertations and Theses

Eutrophication due to excess loading of phosphorus (P) is a leading cause of water quality degradation within the United States. The aim of this study was to investigate P removal and recovery with 12 materials (four calcite varieties, wollastonite, dolomite, hydroxylapatite, eggshells, coral sands, biochar, and activated carbon. This was accomplished through a series of batch experiments with synthetic wastewater solutions ranging from 10-100 mg PO₄-P/ L. The results of this study were used to establish large-scale, calcite-based column filter experiments located in the Rubenstein School of Environment and Natural Resources' Eco-Machine. Influent and effluent wastewater samples were routinely collected …

Catalytic Main Group Element Bond Formation Reactions Toward The Preparation Of Conjugated Materials, Neil Mucha

Graduate College Dissertations and Theses

Polymers incorporating main group elements offer different and interesting properties compared to their all carbon analogues. For example, π-conjugated polymers incorporating phosphorus in the main chain of the polymer have generated interest due to their unique thermal and electronic properties, which primarily result from delocalization of the phosphorous lone pair within aromatic units. Similarly, interest in polysilanes stems from conductivity resulting from σ electron delocalization, though current methods of preparation for both of these types of materials are lacking. In this dissertation, both early and late transition-metal compounds were used to dehydrocouple phosphine and silane substrates. The use of dehydrocoupling …