Physical Sciences and Mathematics Commons^™

Determination Of A Catalytic Mechanism By Time Resolved Fourier Transform Infrared Spectroscopy And Time Domain Analysis Of Data From Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Jacob T. Davis

Theses and Dissertations

Heterobimetallic catalysts offer large potential for efficient and selective catalysis of a wide range of reactions. Better understanding of these catalytic mechanisms could yield further improvement in their catalytic abilities. Cp(CO)2Fe-Cu(IPr) (IPr = N,N-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) is a catalyst that has been reported to catalyze arene borylation. The catalytic mechanism of this catalyst that had been previously proposed had the initial step being a metal-metal cleavage. However, computational modeling suggested an alternate mechanism that could be more energetically favorable. Rather than a metal-metal cleavage as the initial step, we proposed a photoactivated carbonyl dissociation. To support this proposition, we performed time resolved …

Developing A Quantitative Understanding Of U-Substitution In First-Semester Calculus, Leilani Camille Heaton Fonbuena

Theses and Dissertations

In much of calculus teaching there is an overemphasis on procedures and manipulation of symbols and insufficient emphasis on conceptual understanding of calculus topics. As such students to struggle to understand and use calculus ideas in applied settings. Research shows that learning calculus topics from a quantitative reasoning-perspective results in more powerful and flexible conceptions of calculus topics like integration. However, topics beyond introducing integrals and the Fundamental Theorem of Calculus, like u-substitution, have yet to be explored from a quantity-based perspective. In this study, I conducted a set of two clinical interviews where we discussed quantitative meanings of integrals, …

Identity Work To Teach Mathematics For Social Justice, Navy B. Dixon

Theses and Dissertations

In this thesis, mathematics educators are conceptualized as individuals with multiple, simultaneous figured worlds that inform their decisions while planning. The study explores how two mathematics educators negotiated and orchestrated their figured worlds to plan two mathematics lessons for social justice. The results highlight how numerous the figured worlds each participant surfaced through background interviews. Some of the figured worlds were elicited by the interview questions (i.e., Race, Family, Social Justice Teaching) but other figured worlds organically surfaced through the interviews (i.e., Sexuality, Community, Activism, Critical Information Consumption). A discursive analysis of a selection of these figured worlds revealed conceptualizations …

Zeros Of A Family Of Complex-Valued Harmonic Rational Functions, Alexander Lee

Theses and Dissertations

The Fundamental Theorem of Algebra is a useful tool in determining the number of zeros of complex-valued polynomials and rational functions. It does not, however, apply to complex-valued harmonic polynomials and rational functions generally. In this thesis, we determine behaviors of the family of complex-valued harmonic functions $f_{c}(z) = z^{n} + \frac{c}{\overline{z}^{k}} - 1$ that defy intuition for analytic polynomials. We first determine the sum of the orders of zeros by using the harmonic analogue of Rouch\'e's Theorem. We then determine useful geometry of the critical curve and its image in order to count winding numbers by applying the harmonic …

Black Holes, Disk Structures, And Cosmological Implications In E-Dimensional Space, Subhash Kak, Menas C. Kafatos

Mathematics, Physics, and Computer Science Faculty Articles and Research

We examine a modern view of the universe that builds on achieved successes of quantum mechanics, general relativity, and information theory, bringing them together in integrated approach that is founded on the realization that space itself is e-dimensional. The global and local implications of noninteger dimensionality are examined, and how it may have increased from the value of zero to its current value is investigated. We find surprising aspects that tie to structures in the universe, black holes, and the role of observations.

Single-Shot, Ultrafast, Multi-Frame X-Ray Imaging Of Defect-Bearing Ablator Materials In Extreme Conditions, Daniel S. Hodge

Theses and Dissertations

Characterization of the dynamic behavior of defect-bearing ablator materials subjected to extreme conditions is essential in advancing fusion energy as an reliable and abundant energy source. By understanding how materials evolve spatially and temporally we can minimize hydrodynamic instabilities, which are major contributing factors to energy yield degradation in inertial confinement fusion (ICF) experiments. In this thesis we demonstrate the capabilities of an ultrafast x-ray imaging (UXI) detector, the Icarus V2, where we capture multiple frames of single void-bearing sample compressed by a high-intensity laser shockwave. Using the Matter in Extreme Conditions (MEC) instrument at the Linac Coherent Light Source …

Applications Of A Superposed Ornstein-Uhlenbeck Type Processes, Santatriniaina Avotra Randrianambinina, Julius Esunge

Journal of Stochastic Analysis

No abstract provided.

Evaluation Of Potential Rock Falls With Three-Dimensional Analysis: Example Of Oltanbey And Hasanbey Districts (Gümüşhane City Center), Selçuk Alemdağ, Rasim Taylan Kara, Hasan Tahsin Bostanci

Bulletin of the Mineral Research and Exploration

The central district campus of Gümüşhane, located on the Trabzon-Erzurum Highway, has a steep topography, and because of the effect of climatic and morphological structure, frequent rockfall events can cause loss of life and property from time to time. For these reasons, the slopes in some parts of the Oltanbey and Hasanbey districts of the central district of Gümüşhane, which pose a great threat in terms of rockfall potential, were chosen as the study area. In this study, three-dimensional rockfall analyzes were carried out using the RocPro3D program on the lines determined in the rockfall source zones with a high …

Polarization, Media Bias, And General Opinion, Knole Ihle '25

Student Research

This article researches the relationship between three different spheres of influence: party identification, issue selection process in media, and the following changes in public opinion. This relationship was examined through a random sample of news organizations based on a specific issue. The number of articles was then documented for each newspaper and measured against the articles produced apropos to that issue in the previous year. The discrepancy in articles produced is then compared to the succeeding policy shift to determine whether or not there is a correlation between these two relationships. Regarding the relationship between Ukraine-Russia War media and proceeding …

Heterogeneous Strain Distribution & The Effects Of High Frequency Climate Change On The Evolution Of Early-Stage Rift Systems: Case Studies From Lakes Tanganyika And Malawi (Nyasa), East Africa, Lachlan Wright

Dissertations - ALL

The break-up of the earth’s crust through the formation of continental rift basins is a fundamental aspect of plate-tectonics and the first step that ultimately leads to plate-spreading, new continent formation, and the creation of ocean basins. Within continental rifts, processes associated with extensional faulting drive uplift and subsidence of the landscapes forming rift valleys, and climatically influenced processes act upon these transient landscapes, erode them, modify relief, and produce sediments that infill the rift valleys creating the stratigraphic record. Continental rifts are highly sensitive to the interplay between extensional faulting, sedimentary processes, and climate change, and variations in the …

Ambientes De Inclusión Para El Desarrollo Del Pensamiento Numérico Con Población Con Síndrome De Down, Luisa Valeria Escobar Buitrago, Ingry Yuliana Torres Garzón, Juan David Firigua Bejarano

Educación

La importancia de tratar sobre una educación inclusiva es hacer que la humanidad obtenga la aceptación hacia la diversidad, donde se encuentre un mundo lleno de posibilidades reconociendo todos los tipos de población entre ella las personas con Síndrome de Down, lo cual consiste en que la educación esté centrado en el respeto y la valoración de la diversidad, haciendo un enfoque general en las necesidades que esta población tiene, desarrollando habilidades para su desenvolvimiento tanto personal como laboral en determinada sociedad, por lo tanto el objetivo principal de este trabajo es desarrollar el pensamiento numérico de los estudiantes de …

Silting Dynamics And Metal Contaminants In The Georgetown Inner Harbor, Ezekiel Wil Meyers

Electronic Theses and Dissertations

The Georgetown inner harbor is an abandoned oxbow-like river loop and a vital historic site with a wealth of traditional businesses and heavy local industry located within Winyah Bay. Since the modification of the Sampit River in 1949, chronic rapid silting has plagued the inner harbor. With these substantial amounts of fine-grained material accumulating inside the inner harbor, business operations along the waterfront, navigational and maritime operations, and contamination within the harbor are of major concern. The goals of this study were to (a) understand the silting dynamics inside the inner harbor, (b) identify heavy metals which might be of …

Extraction, Analysis, And Comparison Of Microplastics In Sc Marsh Substrates, Austin G. Sige

Electronic Theses and Dissertations

The global, rapid increase in plastic production is a widespread problem for coastal environments such as marshes that present favorable conditions for plastic retention. This study looked at the microplastic abundance within three previously unstudied South Carolina marshes located in Myrtle Beach, Murrells Inlet, and Waties Island. A comparison between the microplastic types and abundances between locations provided knowledge about the impacts of sediment composition (sand, silt, clay, and organic matter) on microplastic sequestration. This study also produced a novel microplastic extraction methodology for cohesive marsh sediment that used elutriation to effectively break apart aggregates prior to chemical digestion and …

Improving Near Surface Refractivity Estimates In Marine Environments, Sarah Evelyn Wessinger

Electronic Theses and Dissertations

This study utilizes in-situ measurements and numerical weather prediction datasets collected during the Coupled Air-Sea Processes Electromagnetic Ducting Research East field campaign to assess how thermodynamic properties in the marine atmospheric surface layer influence evaporation duct shape and to develop a simple near-surface modified refractivity estimation method. This study utilizes a logarithmic linear parametric model, which describes evaporation ducts via three main parameters: evaporation duct height, evaporation duct curvature, and mixed layer slope. Notably, most studies utilizing this type of model assume the curvature, C0, to be a theoretical value derived assuming neutral atmospheric stability; a thermodynamic regime that is …

Arctic Sea Ice Loss In The Pacific Sector And Its Impacts On Sudden Stratospheric Warming Events, Jiarong Zhang

Electronic Theses and Dissertations

The Arctic sea ice is a critical indicator of climate change. The extent of sea ice coverage over the Arctic Ocean has dramatically declined over the past few decades. The impact has been extensively studied through observations suggesting a linkage between the anomalously warm Arctic surface associated with the Arctic sea ice loss and the mid-latitude surface cooling in the subsequent boreal winter. This linkage could involve the wintertime stratospheric circulation by enhancing the upward planetary wave activity and weakening the polar vortex. With recent advances in climate model, more relevant studies relied on numerical simulations and some suggested that …

On The Use Of Machine Learning For Causal Inference In Extreme Weather Events, Yuzhe Wang

Discovery Undergraduate Interdisciplinary Research Internship

Machine learning has become a helpful tool for analyzing data, and causal Inference is a powerful method in machine learning that can be used to determine the causal relationship in data. In atmospheric and climate science, this technology can also be applied to predicting extreme weather events. One of the causal inference models is Granger causality, which is used in this project. Granger causality is a statistical test for identifying whether one time series is helpful in forecasting the other time series. In granger causality, if a variable X granger-causes Y: it means that by using all information without …

Next-Generation Sequencing Shows Increasing Temperatures Affect Stream Fungal Communities, Regan Hodgson

Electronic Theses and Dissertations

Under climate change predictions, surface air temperature is expected to continue to rise and will likely affect functioning of stream ecosystems and microbial communities. Aquatic hyphomycetes are key fungal decomposers of plant litter in headwater streams controlling carbon, energy, and nutrient flows to higher trophic levels. This project addressed the effects of temperature on stream fungal communities in two recently conducted experiments (microcosm and streamside channel studies) using Illumina sequencing. The objectives were to determine (1) if temperature affects community structure of stream fungi based on relative abundances of ITS2 rDNA sequences, (2) if the effects of temperature on aquatic …

Investigating Applications Of Deep Learning For Diagnosis Of Post Traumatic Elbow Disease, Hugh James

McKelvey School of Engineering Theses & Dissertations

Traumatic events such as dislocation, breaks, and arthritis of musculoskeletal joints can cause the development of post-traumatic joint contracture (PTJC). Clinically, noninvasive techniques such as Magnetic Resonance Imaging (MRI) scans are used to analyze the disease. Such procedures require a patient to sit sedentary for long periods of time and can be expensive as well. Additionally, years of practice and experience are required for clinicians to accurately recognize the diseased anterior capsule region and make an accurate diagnosis. Manual tracing of the anterior capsule is done to help with diagnosis but is subjective and timely. As a result, there is …

Geology, Fluid Inclusion Characteristics And Mineral Resource Estimation Of The Güzelyayla Porphyry Cu-Mo Mineralization (Ne Türkiye), Mustafa Kemal Revan, Deniz Göç, Mustafa Özkan, Cüneyt Şen, Rasim Taylan Kara, Mustafa Tokoğlu, Semi Hamzaçebi̇, Rıfat Cihan Sevi̇m, Fatih Sezen, Celaleddin Bayraktar, Ömer Akgül

Bulletin of the Mineral Research and Exploration

Magmatic processes that emerged with the evolution of the Neotethys ocean and associated lithospheric plates caused the formation of significant mineralization in the Tethys belt. The Eastern Pontides, which are located in the northeast of Turkey and are a part of the Tethys metallogenic belt,
are particularly rich in porphyry-type mineralization and represent an important region for Cu-Mo exploration. A large number of Cu, Pb and Zn anomalies have been determined in a large region including the Güzelyayla Cu-Mo field by stream sediment sampling. The Güzelyayla occurrence
is Cu-Mo mineralization associated with andesitic/basaltic volcanic rocks and intrusive dacites crosscutting these …

Microplastic Accumulation In The Digestive Tract Of Young-Of-Year Atlantic Sharpnose Sharks (Rhizoprionodon Terraenovae) In The Grand Strand, Sc, Andrew Curtis Sitlinger

Electronic Theses and Dissertations

This study focused on the presence and accumulation of microplastic fibers in the digestive tract and livers of young-of-year Atlantic Sharpnose Sharks (Rhizopriondon terraenovae) from two sampling locations along the Grand Strand of South Carolina. R. terraenovae is a small, mesopredatory elasmobranch found abundantly along northwestern Atlantic Ocean coastlines. Thirty specimens of R. terraenovae were collected from May through August of 2020. Microplastics were found in all specimens. A total of 672 plastic particles were identified over the course of the study, with an average of 22.4 ± 10.5 (SD) plastics per specimen. The majority of the plastics were classified …

Habitat Use And Diel Movements Of Silver Carp Hypophthalmichthys Molitrix In Two Southeastern Reservoirs, Levi Umland

Honors College Theses

Bigheaded carp have spread rampantly throughout the Mississippi watershed and continue to spread by navigating through rivers, locks, and dams. The long-term effects these species will have on our ecosystems and natural resources is unknown. Their movements, behavior, and general seasonal patterns are well studied within rivers. However, their movements and behavior within reservoirs is poorly understood due to their initial numbers within reservoirs being lower than in rivers. To address this gap, I investigated the distribution and movement rates of Silver Carp within two reservoirs, Kentucky Reservoir and Barkley Reservoir, and possible correlative variables, including wind, temperature, residency, sex, …

Distribution And Soil Characteristics Associated With The Neches River Rose-Mallow (Hibiscus Dasycalyx), Morgan E. Langlinais

Electronic Theses and Dissertations

The Neches River rose-mallow, Hibiscus dasycalyx, is a rare herbaceous perennial endemic to East Texas. The threatened, obligate wetland species is currently at risk of being lost in the wild due to habitat loss, encroachment of nonnative and native plant species, and hybridization with two other Hibiscus congeners, Hibiscus laevis and Hibiscus moscheutos. Known locations of each of the three Hibiscus species were used to measure select soil characteristics and habitat variables associated with each of the rose-mallows. H. dasycalyx was concluded to be associated with more fertile soils and slightly more canopy coverage than H. laevis and …

Multi-Trace Matrix Models From Noncommutative Geometry, Hamed Hessam

Electronic Thesis and Dissertation Repository

Dirac ensembles are finite dimensional real spectral triples where the Dirac operator is allowed to vary within a suitable family of operators and is assumed to be random. The Dirac operator plays the role of a metric on a manifold in the noncommutative geometry context of spectral triples. Thus, integration over the set of Dirac operators within a Dirac ensemble, a crucial aspect of a theory of quantum gravity, is a noncommutative analog of integration over metrics.

Dirac ensembles are closely related to random matrix ensembles. In order to determine properties of specific Dirac ensembles, we use techniques from random …

Extracellular Vimentin Is Sufficient To Promote Cell Attachment, Spreading, And Motility By A Mechanism Involving N-Acetyl Glucosamine-Containing Structures, Robert Bucki, Daniel V. Iwamoto, Xuechen Shi, Katherine E. Kerr, Fitzroy J. Byfield, Lukasz Suprewicz, Karol Sklodowski, Julian Sutaria, Pawel Misiak, Agnieszka Z. Wilczewska, Sekar Ramachandran, Aaron Wolfe, Minh H. Thanh, Eli Whalen, Alison E. Patteson, Paul A. Janmey

Physics - All Scholarship

Vimentin intermediate !laments form part of the cytoskeleton

of mesenchymal cells, but under pathological conditions often

associatedwith in"ammation, vimentin !laments depolymerize as

the result of phosphorylation or citrullination, and vimentin

oligomers are secreted or released into the extracellular environment.

In the extracellular space, vimentin can bind surfaces of cells

and the extracellular matrix, and the interaction between extracellular

vimentin and cells can trigger changes in cellular functions,

such as activation of !broblasts to a !brotic phenotype. The

mechanism by which extracellular vimentin binds external cell

membranes and whether vimentin alone can act as an adhesive

anchor for cells is largely …

How The Perceived Value Of Education, Parental Influences, And Students' Perceived Success Affect Post-Graduate Decisions, Valerie Blanchard

Honors Projects in Mathematics

While technical education has been enhanced in many ways over the past few decades, college is still the preferred post-graduate path for many students and is the societal norm. This study will analyze the value that students view in their career path that leads them to make their post-graduate decisions. The goal of this research is to better understand why students pursue college and how these decisions come to be with specific attention paid to the impact of gender, interests, and self-efficacy. This understanding can educate others about the gravity of social norms and can start conversations about how to …

Active Vs Passive Investing, Garret Buchheit

Honors Theses

With the increased popularity of passive investing, the long-term investment success of active management is being questioned more frequently. For this reason, this research seeks to find whether actively managed funds produce sufficient returns that cover the fees and management costs associated with them. A comparative analysis was made with 5401 actively managed U.S. mutual funds and several common market indices over three, five, and ten-year time spans ranging from 2012 to 2021. Additionally, an analysis was made comparing active and passive management in the recessionary period of 2007 to 2009. Finally, analysis was conducted on annual holdings turnover rates …

Pfas Mass Balance, Donovan Vitale

Honors Theses

First-generation, PFOS-dominant Aqueous Film Forming Foam (AFFF) concentrate of approximately 200 gallons was released to the sewer system from the Kalamazoo/Battle Creek International Airport on March 30, 2021. The AFFF release migrated to the Kalamazoo Water Reclamation Plant (KWRP), raising plant effluent above the Department of Environment, Great Lakes, and Energy (EGLE) PFOS water quality standard for a total of 46 days post-spill, although the influent concentrations exhibited sharp declines after only 7 days. By sampling influent, effluent, and biosolids daily, the only known long duration, high-frequency PFAS data set of an accidental AFFF release was generated. This study has …

Lawrence County Archives Website, Brianna Hawkins, Areeb Mohammed, David Niederweis, Mary-Kate Rynders

Honors Capstone Projects and Theses

No abstract provided.

What Is Nonclassical About Uncertainty Relations?, Lorenzo Catani, Matthew S. Leifer, Giovanni Scala, David Schmid, Robert W. Spekkens

Mathematics, Physics, and Computer Science Faculty Articles and Research

Uncertainty relations express limits on the extent to which the outcomes of distinct measurements on a single state can be made jointly predictable. The existence of nontrivial uncertainty relations in quantum theory is generally considered to be a way in which it entails a departure from the classical worldview. However, this perspective is undermined by the fact that there exist operational theories which exhibit nontrivial uncertainty relations but which are consistent with the classical worldview insofar as they admit of a generalized-noncontextual ontological model. This prompts the question of what aspects of uncertainty relations, if any, cannot be realized in …

Explainable Ai Helps Bridge The Ai Skills Gap: Evidence From A Large Bank, Selina Carter, Jonathan Hersh

Economics Faculty Articles and Research

Advances in machine learning have created an “AI skills gap” both across and within firms. As AI becomes embedded in firm processes, it is unknown how this will impact the digital divide between workers with and without AI skills. In this paper we ask whether managers trust AI to predict consequential events, what manager characteristics are associated with increasing trust in AI predictions, and whether explainable AI (XAI) affects users’ trust in AI predictions. Partnering with a large bank, we generated AI predictions for whether a loan will be late in its final disbursement. We embedded these predictions into a …