Physical Sciences and Mathematics Commons^™

Examining Pollution And Forest Health: An Application Of Lichens As Bioindicators And Sentinal-5p Tropomi In Urban State Parks In Shelby County, Megan V. Farrell

Documents

This is a 51 page study on air pollution in urban areas by comparing the amounts of epiphytic lichen present at both T.O Fuller Park and Shelby Forest. This study shows the use of monitoring such environmental impacts.

Impacts Of Physical Parameterization Schemes And Soil Moisture Initialization On Boundary Layer Evolution In The Weather Research And Forecasting (Wrf) Model, Grace Cutting

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Numerical weather prediction (NWP) models have become a necessary addition to the atmospheric research community over the last several decades, and atmospheric modeling has been used internationally for numerous operational and research purposes. NWP models contain a vast number of combinations of physical and dynamical parameterization schemes; however, they are not always accurate in forecasting weather phenomena at a particular location, as different combinations of parameterization schemes represent differing conditions. Weather Research and Forecasting (WRF) model simulations were run to explore which of the commonly used planetary boundary layer (PBL) schemes best represented upper-air data (as well as PBL evolution) …

Why Micro-Size Objects Affect The Flow Much More Than Larger Ones: A Geometric Explanations With Applications Ranging From Volcanoes And Tornadoes To Blood, Fish, And Building Preservation, Laxman Bokati, Vladik Kreinovich

Departmental Technical Reports (CS)

At first glance, the larger the object, the larger should be its effect on the surroundings -- in particular, the larger should be its effect on the surrounding flow. However, in many practical situations, we observe the opposite effect: micro-size particles affect the flow much more than larger-size particles. This seemingly counterintuitive phenomena has been observed in many situations: lava flow in the volcanoes, air circulation in tornadoes, blood flow in a body, the effect of fish on water circulation in the ocean, and the effect of added particles on seeping water that damages historic buildings. In this paper, we …

Near-Infrared Accretion Signatures From The Circumbinary Planetary-Mass Companion Delorme 1 (Ab)B, S. K. Betti, K. B. Follette, K. Ward-Duong, Y. Aoyama, G. D. Marleau, J. Bary, C. Robinson, M. Janson, W. Balmer, G. Chauvin, P. Palma-Bifani

Astronomy: Faculty Publications

Accretion signatures from bound brown dwarf and protoplanetary companions provide evidence for ongoing planet formation, and accreting substellar objects have enabled new avenues to study the astrophysical mechanisms controlling the formation and accretion processes. Delorme 1 (AB)b, a ?1/430-45 Myr circumbinary planetary-mass companion, was recently discovered to exhibit strong Hα emission. This suggests ongoing accretion from a circumplanetary disk, somewhat surprising given canonical gas disk dispersal timescales of 5-10 Myr. Here, we present the first NIR detection of accretion from the companion in Paβ, Pa?3, and Br?3 emission lines from SOAR/TripleSpec 4.1, confirming and further informing its accreting nature. The …

The Earth Mover's Distance Through The Lens Of Algebraic Combinatorics, William Quentin Erickson

Theses and Dissertations

The earth mover's distance (EMD) is a metric for comparing two histograms, with burgeoning applications in image retrieval, computer vision, optimal transport, physics, cosmology, political science, epidemiology, and many other fields. In this thesis, however, we approach the EMD from three distinct viewpoints in algebraic combinatorics. First, by regarding the EMD as the symmetric difference of two Young diagrams, we use combinatorial arguments to answer statistical questions about histogram pairs. Second, we adopt as a natural model for the EMD a certain infinite-dimensional module, known as the first Wallach representation of the Lie algebra su(p,q), which arises in the Howe …

Stratigraphy, Sedimentology, And Deformational Significance Of Cambrian And Early Ordovician Strata Along The Southeast Wisconsin Arch, Allison Raeann Kusick

Theses and Dissertations

A detailed study of the stratigraphic units in and around the Wisconsin Arch of central and southeast Wisconsin are presented to refine the sedimentologic record and the geologic implications within the Cambrian and early Ordovician strata. The Cambrian and early Ordovician sediments in central and southeast Wisconsin unconformably overlie a topographic high composed of Precambrian basement rocks, called the Wisconsin Arch, and consist of various clastic deposits, dolostones, and several horizons of deformation. Bedrock cores, made available through the Wisconsin Geological and Natural History Survey (WGNHS), were analyzed, to understand sedimentation in the Cambrian and early Ordovician. My analyses focused …

Estimating The Parameters Of A Simple Linear Regression Model Without Using Differential Calculus, Mamunur Rashid, Jyotirmoy Sarkar

Mathematics Faculty Publications

To estimate the parameters of a simple linear regression model, students who already know calculus can minimize the total squared deviations by setting its first-order partial derivatives to zero and solving simultaneously. For students who do not know calculus, most teachers/textbooks simply state the formulas without justifying them. Students accept the formulas on faith; and for given data, they evaluate the estimates using a calculator or a statistical software. In this paper, we justify the formulas without invoking calculus. We hope the users of statistics will benefit from our proposed justifications.

The Effects Of Rising Ambient Temperatures On Thermoregulation And Range Shifts Of Northern Flying Squirrels, Elise K. Gudde

Electronic Theses and Dissertations

Climate change may potentially alter a species’ range distribution and thus the relationship between environmental temperatures and animal performance as a response to climate warming has become an important area of research. Two species of flying squirrel in North America, the southern flying squirrel (Glaucomys volans) and the northern flying squirrel (Glaucomys sabrinus) have undergone northward range shifts, with climate warming being the suspected driver. Because they are nocturnal and tree nesting, flying squirrels may be particularly susceptible to warmer temperatures, as they will experience the highest daily ambient temperatures during their resting phase. I used G. sabrinus as a …

Synthesis, Characterization, And Reactivity Studies Of Highly Reduced Early-Metal Complexes Supported By Imidazolin-2-Iminato Ligands, Maria Alejandra Gomez Torres

Open Access Theses & Dissertations

Our group has shown that reduction of titanium complexes supported by the sterically encumbering N-donor ligands 1,3â??bis(Dipp)imidazolinâ??2â??iminato (ImDippNâ??) and ketimine guanidinate (ketGuan = [(tBuC=N)C(NDipp)2]-) gives access to electron rich platforms featuring a metal coordinated, reduced, dearomatized arene substituent, which act as an electronic reservoir capable of facilitating multi-electron transfer chemistry driven by the rearomatization driving force. For instance, the arene-masked Ti(II) synthon (DippketGuan)(η6-ImDippN)Ti (Dipp = 2,6-iPr2C6H3) (TiDipp) is a versatile and potent one- and two-electron reductant capable of distinctive late-metal type reactivity such as transfer hydrogenation and catalytic olefin hydrogenation. Interestingly, TiDipp can mediate the reversible cleavage of thiophene and, …

Investigating The Effects Of Decoupling Cache And Core Speed On Power, Throughput, And Energy, David Daniel Pruitt

Open Access Theses & Dissertations

A variety of computer systems from HPC to mobile systems are power limited and performance sensitive. These systems use very similar components at different scales. Dynamic Voltage and Frequency Scaling (DVFS) features enable modulation of CPU performance and efficiency characteristics to power, energy and timing requirements.Programs have a variety of computational characteristics. If a CPU subsystem substantially limits a particular programâ??s execution progress, that programâ??s throughput will vary proportionally with the subsystemâ??s clock frequency. In contrast, if a CPU subsystem does not substantially limit throughput, the impact of a change in its clock frequency will result in a diminimus change …

Pressure-Induced Phase Transition And Electronic Structure Changes In Equiatomic Fev, Homero Reyes Pulido

Open Access Theses & Dissertations

Classical molecular dynamics methods can accurately describe a broad set of many-atomssystems. Although more economical, the results given by this framework lack the precision capable of density functional theory (DFT). Therefore, the structural stability of the B2 phase of a body-centered-cubic iron-vanadium (FeV) alloy using DFT on the electronic structure level is analyzed to verify and further explain classical results obtained by our group in this same alloy. Using Quantum Espresso and Phonopy for the computational simulations, the plotted band structure, electronic density of states (eDOS), phonon dispersions, charge density, and Fermi surfaces for various compressed unit cells are presented. …

Variations In Copper Form Exposure Differentially Modulate Zea Mays (Corn) Physiological Responses, Carolina Valdes Bracamontes

Open Access Theses & Dissertations

In the present study, Zea mays seedlings grown under nano Cu(OH)2 (nCu), bulk Cu(OH)2 (bCu), and ionic CuSO4 (iCu) compound exposure were harvested after six days. The nutritional profile was determined to be significantly disrupted in the roots by 1000 ppm bCu treatment, resulting in a 58.7% reduction in potassium compared to the control. In the shoots, a significant decrease of manganese was observed for 10 and 1000 ppm iCu treatments with 55.7% and 64.2% reductions, respectively. The overall protein content and catalase (CAT) enzymatic activity, however, remained unaffected in either roots or shoots, while an absence of polyphenol oxidase …

Biological Interaction Of Mn-Based Nanomaterials With Capsicum Annuum L. Under Salinity Stress, Yuqing Ye

Open Access Theses & Dissertations

The foliar application of nanomaterials as a method to overcome abiotic stress is relatively new compared to their use as fertilizers or pesticides in agricultural practice. It is also vital to understand the interface between leaf and nanomaterials, as nanomaterials might translocate into crop edible tissues, thus, causing potential toxicity in living beings during food consumption. In this dissertation, salt-stressed Capsicum annuum L was exposed to manganese (Mn) -based nanomaterials (Mn2O3 nanoparticles (MnNPs) and graphene quantum dots doped with Mn (GQD-Mn)) at different stages (seed germination and full life cycle). The dissertation focuses on investigating the mechanism of how Mn-based …

Searching For Gravitational Wave Associations With High-Energy Astrophysical Transients, Brandon Joseph Piotrzkowski

Theses and Dissertations

Gravitational waves (GW) have become an invaluable tool in modern astronomy, especiallyin conjunction with other astronomical observations. GWs are created in highly dynamical systems such as compact binary coalescences (CBC) which are comprised of black holes and/or neutron stars. The Laser Interferometer Gravitational Wave Observatory (LIGO), Virgo Observatory, and KAGRA have now collectively identified almost a hundred of these events. GWs have also been predicted to come from core collapse supernovae. Both of these types of systems have been shown to produce other detectable transients, such as gamma- ray bursts (GRB) and neutrino bursts. Observations of the same astrophysical system …

Predicting Order Status Using Xgboost, Kegan J. Penovich

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

Invista, a Koch subsidiary, is a multinational producer of fibers, resins, and intermediaries, particularly nylon. To keep the company operating required them to take over 1.5 million orders over the course of - years, less than a third of which arrived on-time. Orders arriving other than when expected can cause many problems for any company. While arriving late is a clear problem, it also troublesome for them to arrive early. In the face of this, it becomes important to be able to tell a-priori if an order will arrive on-time or not.

To address this problem, we made use of …

Recognizing And Reducing Ambiguity In Mathematics Curriculum And Relations Of Θ-Functions In Genus One And Two: A Geometric Perspective, Shantel Spatig

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

Anxiety and mathematics come hand in hand for many individuals. This is due, in
part, to the fact that the only experience they have with mathematics is what some
mathematics educators refer to as "schoolmath," which uses a somewhat different
language than real mathematics. The language of schoolmath can cause individu-
als to have confusion and develop misconceptions related to several mathematical
concepts. One such concept is a fraction. In chapter one of this report, one possible
reason for this is discussed and a possible solution is purposed.
In chapter three of this report, genus-two curves admitting an elliptic involution …

A Bayesian Hierarchical Approach For Modeling Virtual Species With Realistic Functional Trait Relationships, Sarah Bogen

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

Understanding the spatial and temporal dynamics of plant populations has important implications for the fields of ecology and conservation. A rich body of mathematical modeling approaches, including reaction-diffusion equations and integrodifference equations, have been developed to mechanistically model population spread based on species demography and seed dispersal characteristics. However, with over 390,000 plant species on Earth, it is not feasible to collect complete information on all species for the purpose of drawing generalized conclusions. One means of overcoming such a problem is through trait-based modeling, which seeks to represent realistic combinations of organismal traits rather than focusing on individual species. …

An Unmanned Surface Vehicle: Autonomous Sensor Integration System For Bathymetric Surveys, Fernando Sotelo Torres

Open Access Theses & Dissertations

Unmanned Surface Vehicles (USVs) have been applied to earth sciences, with only a few studies conducted in water environments, as these systems provide autonomous measurement capabilities and transferability to other environmental settings. In this thesis, a reliable, yet economical, USV has been developed for bathymetric surveying of lakes. The system combines an autonomous navigation framework, environmental sensors and a multibeam echosounder to collect submerged topography, temperature, windspeed and monitor the vehicle status during prescribed path planning missions.

The main objective of this study is to provide a methodological framework to build a USV, with independent decision-making, efficient control, and long-range …

Competition Between Halogen And Chalcogen Bonding And Their Role In Probing Organic Transformations, Andrew Peloquin

All Dissertations

Halogen bonding, the attractive interaction of an electrophilic region on a halogen atom with a nucleophilic region on another atom or molecule, provides a highly directional tool in forming solid-state motifs. This interaction, along with the related chalcogen bonding interactions, forms powerful synthons, which, when combined with other typical intermolecular attractions such as hydrogen bonding, allow for the design of supramolecular structures and inputs to crystal engineering. This dissertation research serves two primary purposes: (1) to catalog halogen and chalcogen bonding interactions with various donor molecules and (2) to utilize these interactions to probe interesting organic transformations.

In order to …

Isolation And Characterization Of Extracellular Vesicles From Various Biological Matrices Using Capillary-Channeled Polymer (C-Cp) Fiber Solid-Phase Extraction Spin-Down Tips, Kaylan Jackson

All Dissertations

A number of recent works have emphasized the need to isolate nanometer-scale analytes, like extracellular vesicles (EVs), from various biologically-relevant fluids. Exosomes are a subset of small EVs that range from 30-200 nm in diameter that serve as biomolecular snapshots of their cell of origin containing mother cell-specific DNA, miRNA, mRNA, and proteins. As critical components of intercellular communication, exosomes and other EVs play significant roles in many physiological and pathological processes. Diverse populations of these vesicles can be collected from biofluids, including blood, saliva, and urine, from cell culture conditioned media and primary cells, and even from plant …

Radioluminescence Based Biochemical Sensing And Imaging Strategies To Measure Local Drug Release And Ph, Gretchen B. Schober

All Dissertations

In this dissertation we describe methods for measuring infection relevant biochemical analytes using radioluminescent and ultrasound luminescent materials. Films and nanoparticles fabricated with europium doped gadolinium oxysulfide (Gd₂O₂S:Eu³⁺) are used to quantitatively measure radiolabeled pharmaceutical concentration, specifically tritium labeled vancomycin (³H-vancomycin). Europium and dysprosium doped strontium aluminate is used to fabricate an ultrasound modulated, pH sensing film. These methods are indicated for theranostic evaluation of implant associated infection. Bacterial biofilms are inherently resistant to traditional antibiotic treatment and can coat biomedical implants. These biofilm related infections are difficult or impossible to eradicate …

Development Of A Reverse Engineered, Parameterized, And Structurally Validated Computational Model To Identify Design Parameters That Influence American Football Faceguard Performance, William Ferriell

All Dissertations

Traumatic brain injury (TBI) continues to have the greatest incidence among athletes participating in American football. The headgear design research community has focused on developing accurate computational and experimental analysis techniques to better assess the ability of headgear technology to attenuate impacts and protect athletes from TBI. Despite efforts to innovate the headgear system, minimal progress has been made to innovate the faceguard. Although the faceguard is not the primary component of the headgear system that contributes to impact attenuation, faceguard performance metrics, such as weight, structural stiffness, and visual field occlusions, have been linked to athlete safety. To improve …

Evaluating Privacy Adaptation Presentation Methods To Support Social Media Users In Their Privacy-Related Decision-Making Process, Moses Namara

All Dissertations

Several privacy scholars have advocated for user-tailored privacy (UTP). A privacy-enhancing adaptive privacy approach to help reconcile users' lack of awareness, privacy management skills and motivation to use available platform privacy features with their need for personalized privacy support in alignment with their privacy preferences. The idea behind UTP is to measure users' privacy characteristics and behaviors, use these measurements to create a personalized model of the user's privacy preferences, and then provide adaptive support to the user in navigating and engaging with the available privacy settings---or even implement certain settings automatically on the user's behalf. To this end, most …

Revealing The Role Of Electrostatics In Molecular Recognition, Ion Binding And Ph-Dependent Phenomena, Mihiri Hewa Bosthanthirige

All Dissertations

In this dissertation, we study the role of electrostatics in molecular recognition, ion binding and pH-dependent phenomena. In this work that includes three different research projects, the Poisson-Boltzmann (PB) model is used to describe the biological system and Delphi (which is a popular tool for solving the PB equation (PBE)) to study the electrostatics of biomolecular systems.

Chapter two aims to investigate the role of electrostatic forces in molecular recognition. We calculated electrostatic forces between binding partners separated at various distances. To accomplish this goal, we developed a method to find an appropriate direction to move one chain of protein …

The Pursuit For Gamma-Ray Emitting Pulsar Wind Nebulae With The Fermi-Large Area Telescope, Jordan Eagle

All Dissertations

Pulsar wind nebulae are highly magnetized particle winds, descending from core collapse supernovae (CC SNe), and each powered by an energetic, rapidly rotating neutron star. There are at least 125 Galactic pulsar wind nebulae (PWNe) that have been discovered from radio wavelengths to TeV gamma-rays, the majority of which were first identified in radio or X-ray surveys. An increasing number of PWNe are being identified in the TeV band by ground-based air Cherenkov Telescopes such as HESS, MAGIC, and VERITAS such that they constitute the dominant source class of Galactic TeV emitters. High-energy sources like PWNe may be responsible for …

Tempering The Adversary: An Exploration Into The Applications Of Game Theoretic Feature Selection And Regression, Stephen Mcgee

All Dissertations

Most modern machine learning algorithms tend to focus on an "average-case" approach, where every data point contributes the same amount of influence towards calculating the fit of a model. This "per-data point" error (or loss) is averaged together into an overall loss and typically minimized with an objective function. However, this can be insensitive to valuable outliers. Inspired by game theory, the goal of this work is to explore the utility of incorporating an optimally-playing adversary into feature selection and regression frameworks. The adversary assigns weights to the data elements so as to degrade the modeler's performance in an optimal …

Minimal Differential Graded Algebra Resolutions Related To Certain Stanley-Reisner Rings, Todd Anthony Morra

All Dissertations

We investigate algebra structures on resolutions of a special class of Cohen-Macaulay simplicial complexes. Given a simplicial complex, we define a pure simplicial complex called the purification. These complexes arise as a generalization of certain independence complexes and the resultant Stanley-Reisner rings have numerous desirable properties, e.g., they are Cohen-Macaulay. By realizing the purification in the context of work of D'alì, et al., we obtain a multi-graded, minimal free resolution of the Alexander dual ideal of the Stanley-Reisner ideal. We augment this in a standard way to obtain a resolution of the quotient ring, which is likewise minimal and multi-graded. …

Controlled Manipulation Of Droplets On Fibers: Fundamentals And Printing Applications, Yueming Sun

All Dissertations

In this dissertation, the drop interactions with a single fiber is discussed under an application angle for the development on new Drop-on-Demand (DOD) printhead using a fiber-in-a-tube platform[1] to print highly viscous materials[2]. To control the drop formation and manipulation on fiber, one needs to know how the fiber wetting properties and the fiber diameter influence drop formation. And then, one needs to know the effects of fiber movement in the device on drop formation. These two questions constitute the main theme of this dissertation.

Before this study, it was accepted that the liquids could not form axisymmetric droplets if …

Understanding Dynamics Of Polymers Under Confinement: A Molecular Dynamics And Neutron Scattering Study, Supun Samindra Kamkanam Mohottalalage

All Dissertations

The current study probes the structure, dynamics, and rheological behavior of associating polymers including ionomers in melts and solutions as well as conjugated polymers confined into nanoparticles, using molecular dynamics (MD) simulations and neutron scattering techniques. The study focuses on two families of associative polymers, ion containing macromolecules and conjugated polymers.

Polymers that consist of ionizable groups along their backbone found uses in a broad range of applications. Examples include light weight energy storage and generation systems, and biomedical applications, where the polymers act as ion exchange membranes, and actuators. The ionic groups tend to form clusters that are in …

Advanced High Dimensional Regression Techniques, Yuan Yang

All Dissertations

This dissertation focuses on developing high dimensional regression techniques to analyze large scale data using both Bayesian and frequentist approaches, motivated by data sets from various disciplines, such as public health and genetics. More specifically, Chapters 2 and Chapter 4 take a Bayesian approach to achieve modeling and parameter estimation simultaneously while Chapter 3 takes a frequentist approach. The main aspects of these techniques are that they perform variable selection and parameter estimation simultaneously, while also being easily adaptable to large-scale data. In particular, by embedding a logistic model into traditional spike and slab framework and selecting of proper prior …