Physical Sciences and Mathematics Commons^™

Neutron Spectroscopy Of The Parity-Violating 0.734 Ev Neutron Resonance In Lanthanum-139 In Preparation For The Noptrex Time Reversal Violation Experiment, Danielle Schaper

Theses and Dissertations--Physics and Astronomy

One of the most outstanding questions in physics is the matter-antimatter asymmetry of the Universe, resulting from excess baryogenesis processes during the early moments of the formation of the Universe. At present, the types of processes needed to explain this matter excess, so-called `CP-violating processes' are known to exist within the present framework of the Standard Model of particle physics. However, decades of research has shown that our understanding of the origin of these processes is incomplete, as we do not presently know of enough sources of CP-violating processes to account for the large baryon asymmetry that we observe. The …

Milky Way Morphology Probed By 6d Astrometric Data From The Gaia Space Telescope, Joshua Taylor Harry

Theses and Dissertations--Physics and Astronomy

At varying height above and below the plane of the Milky Way, I have used astrometric methods to classify stars of different galactic components of the Milky Way - the thin disk, thick disk, and stellar halo. This work complements prior study of Milky Way sub-structure - notably involving number density and/or pairwise correlations - which demonstrate non-steady state effects in the galaxy, such as axial/north-south symmetry breaking or more complex phenomena like the Gaia snail. This has motivated my exploration of stellar population changes with height about the Milky Way mid-plane, and the study of symmetry in such changes …

Reinforcement Learning: Low Discrepancy Action Selection For Continuous States And Actions, Jedidiah Lindborg

Electronic Theses and Dissertations

In reinforcement learning the process of selecting an action during the exploration or exploitation stage is difficult to optimize. The purpose of this thesis is to create an action selection process for an agent by employing a low discrepancy action selection (LDAS) method. This should allow the agent to quickly determine the utility of its actions by prioritizing actions that are dissimilar to ones that it has already picked. In this way the learning process should be faster for the agent and result in more optimal policies.

Characterization Of Functionalized Carbon Nanotubes And Polystyrene/Cnt Composites Prepared With Microwave-Induced Polymerization, Allen Hulette

Electronic Theses and Dissertations

The use of carbon nanotubes in polymer composites can increase the mechanical properties of the resulting product. Carbon nanotubes are known to have chemical interactions that make them attracted to one another and fall out of solution. To reduce this agglomeration and disperse the mechanical properties throughout the composite, functional groups are covalently added to the carbon nanotubes. Another known property of carbon nanotubes is their ability to absorb microwaves and convert it into other forms of energy. This research investigates the effects of carbon nanotube absorption of microwaves and initiation of styrene monomer polymerization. Grignard reactions are used to …

Cryptography Through The Lens Of Group Theory, Dawson M. Shores

Electronic Theses and Dissertations

Cryptography has been around for many years, and mathematics has been around even longer. When the two subjects were combined, however, both the improvements and attacks on cryptography were prevalent. This paper introduces and performs a comparative analysis of two versions of the ElGamal cryptosystem, both of which use the specific field of mathematics known as group theory.

Eeg Signals Classification Using Lstm-Based Models And Majority Logic, James A. Orgeron

Electronic Theses and Dissertations

The study of elecroencephalograms (EEGs) has gained enormous interest in the last decade with the increase of computational power and availability of EEG signals collected from various human activities or produced during medical tests. The applicability of analyzing EEG signals ranges from helping impaired people communicate or move (using appropriate medical equipment) to understanding people's feelings and detecting diseases.

We proposed new methodology and models for analyzing and classifying EEG signals collected from individuals observing visual stimuli. Our models rely on powerful Long-Short Term Memory (LSTM) Neural Network models, which are currently the state of the art models for performing …

Toward Novel Optical Functionalities Through Intelligent Photonic Structure Design, Robert J. Williamson

Electronic Theses and Dissertations

Photonic Metamaterials is a branch of electromagnetism that has been of great interest in recent years. This is further enhanced by the introduction of micro- and nanofabrication methods capable of producing metamaterial structures with which it is possible to create specific optical phenomena. The study of iso-frequency k-surfaces is of importance when discussing optical interactions with media. Previous research found evidence of materials exhibiting k-surfaces of bi-hyperbolic nature, though they failed to find any further hyperboloid dispersions. In this thesis we describe the k-surface topologies and including tri- and tetra-hyperbolic as well as analyze the polariton-interactions that cause these hyperbolic …

License Plate Image Quality Enhancement Utilizing Super Resolution Generative Adversarial Networks, Mark Moelter

Electronic Theses and Dissertations

This thesis focuses primarily on enhancing the image quality of blurred license plates through the use of Super-Resolution Generative Adversarial Networks (SRGANs) [1]. We propose a synthetic dataset with SRGAN model to promote blurred image quality enhancement, and allow for model evaluation on a multitude of image input and output size combinations. SRGAN is mainly used for low-resolution image enhancement, but by heavily blurring the input images, the model is tested on its ability to blindly deblur and upsample images to the desired super-resolution (SR) size. The model enhances the image quality to nearly that of the reference images. The …

Analysis Of Microdroplets And Microorganisms By Single Entity Electrochemistry, Junaid U. Ahmed

Theses and Dissertations

Single Entity Electrochemistry (SEE) is an emerging electrochemical technique that has been used to characterize discrete entities by measuring the change in current or potential during individual stochastic events (collision or adsorption) of an entity with an ultramicroelectrode (UME) of similar dimensions. The shape and magnitude of the SEE signal depend on the underlying mechanism of interaction with the UME surface. There is a critical need for quantitative models that correlate the SEE signal with properties of the entity-UME system, including effects of acquisition instrumentation, to prevent misinterpretation of data.

This research focused on integrated experiments and simulations to quantify …

Physical Characteristics And Classification Of The Large Amplitude Variable Star V1719 Cygni, Ashley Lieber, Logan Siems, Julia Kennefick, Michael Fitzgerald

Inquiry: The University of Arkansas Undergraduate Research Journal

Pulsating stars are used as standard candles which are helpful in determining distances to stellar objects along with the relationship between their period and apparent luminosity. The focus of this study was the variable star, V1719 Cygni, which is often classified as a Delta (δ) Scuti star, but there exists debate that it should be classified as a RR Lyrae star due to its abnormal light curve and similar characteristics between the two variable star categories. Observational data was taken in 2019 using the Las Cumbres Observatory international telescope network. The resulting data were calibrated using comparison stars in the …

Human-Machine Collaboration In Healthcare Innovation, Breeze Fenton

Electronic Theses and Dissertations

Almost every individual has visited a healthcare institute, whether for an annual checkup, surgery, or a nursing home. Ensuring healthcare institutes are using human-machine collaboration systems correctly can improve daily operations. A maturity assessment and an implementation plan have been developed to help healthcare institutes monitor the human-machine collaboration systems. A maturity model, the Smart Maturity Model for Health Care (SMMHC), is a tool designed for maturity assessment. A four-step implementation plan was also created in this research. The implementation plan views the maturity of the institute and develops a strategy on how to improve it. The research utilized Integrated …

Elucidating Mechanisms For S-Nitrosoglutathione Reductase Activity And Control In Plants Using O-Aminobenzoyl-S-Nitrosoglutathione And A Novel Photo-Sensitive Probe, Leslie Ventimiglia

Electronic Theses and Dissertations

S-nitrosoglutathione reductase, (GSNOR) is widely accepted as the master regulator of stress through NO signaling and protein S-nitrosylation. GSNOR mediates stress response through the catalysis of its principal substrate S-nitrosoglutathione (GSNO). The instigation of various stressors in plants cause observable changes in plant phenotype, which are associated with changes in GSNOR activity. There are no current methods for measuring GSNOR activity directly in living plants. In this paper, a previously developed fluorogenic pseudo-substrate for human GSNOR, OAbz-GSNO, was applied to the Solanum lycopersicum plant model. OAbz-GSNO was identified as a promising novel pseudo- substrate to study changes …

Examining The Optical Properties Of Monosodium Urate For The Detection Of Gout Using A Magneto-Optical Device (Mod), Victoria Marino

Senior Honors Projects

Currently, there is a need for a cost-effective and more efficient option for gout diagnosis. Traditionally, gout is diagnosed by the presence of monosodium urate in blood or synovial fluid. The purpose of this research is to quantify the magneto-optical properties of monosodium urate crystals using a magneto-optical device (MOD). Characterization of these magnetic and optical properties is achieved through measuring the initial light intensity and the transmitted light intensity of a laser shone through a sample of monosodium urate with or without a static magnetic field. The comparison of the transmitted intensity through a solution of MSU crystals with …

Comparison Of External Load Patterns Over A Season In Collegiate Soccer Players, Colton Dowd

Williams Honors College, Honors Research Projects

Soccer (football) is the most played sport in the world. In turn, soccer also accounts for a considerable number of injuries at all levels. Injuries in soccer are not only detrimental to team performance, but they can also place financial burden on organizations, in addition to causing harm to players health down the line. As such, it is important that these injuries are limited and managed to avoid the various consequences that accompany serious injury. PURPOSE: This study attempted to quantify the external loads of NCAA DI soccer athletes over the course of a Fall season. These external load values …

"Demeter" Soil Monitoring System, Ryan Matthews, Rachel Rummer, Temilolu Fayomi, Alex Fuller

Williams Honors College, Honors Research Projects

The purpose of this project is to develop a soil monitoring system that can remotely sense and relay soil conditions back to a user. The deMETER soil probe, Demeter is the Greek goddess of the harvest, is designed to aid hobbyist gardeners, small-scale farms, and nurseries to monitor their dynamic soil conditions and maximize their harvest. The probe is a self-powered system that can monitor the moisture and essential nutrients of the soil profile to determine which areas should receive water and fertilizer. This would significantly cut water and fertilizer waste. The solution will include an embedded system with sensors …

Creating An Arcgis Dashboard For Climate Data Management And Visualization, Sydney Noel Case

Senior Independent Study Theses

The College of Wooster Department of Earth Sciences has collected over the past 12 years (and continues to collect) hourly local climate indicator data including stream level and temperature, air temperature and pressure, precipitation levels, and relative humidity. This data is collected at the College’s research station, Fern Valley, located in Holmes County, Ohio and serves as a storytelling component for regional climate change. Upon initial investigation, the extensive dataset revealed a fundamental data storage problem within Earth Sciences, as there lacked a singular location to store complex datasets. Several technological solutions were explored to create a long-term data storage, …

Realization Of A Micro-Cavity Via The Integration Of Silicon Nitride And Lithium Niobate Using Micro Transfer Printing, Adarsh Ananthachar, Maria V. Kotlyar, Samir Ghosh, Sarvagya Dwivedi, Simone Iadanza, Liam O'Faolain, Shamsul Arafin, Brian Corbett

Conference Papers

We combine Lithium Niobate and Silicon Nitride using transfer printing and realize a micro-cavity with an experimentally measured intrinsic Q-factors of 50,000. We believe this is the first realization of such type of a micro-cavity.

Fluorescent Labelling Of Ribosomal Rna In Live Mammalian Cells, Amir Agharezaee

Legacy Theses & Dissertations (2009 - 2024)

This thesis describes a bio-orthogonal chemistry-based approach for new methods of fluorescence labelling of RNA in live HeLa cells via an IEDDA reaction of TCO with tetrazine. The key step of the approach is synthesis of two nucleobase analogues which were modified with TCO and a masked 5′-phosphate group using aryl phosphonamidite chemistry. Synthesis of tubercidin and uridine analogues were considered in this investigation for incorporation into RNA in live HeLa cells. Synthetic approach was successful at installing the handle containing TCO to tubercidin and uridine to make compounds 12 and 21 respectively (the synthesis of both of which are …

Dynamic Impacts Of Hadley Circulation On Saharan Desert Warming Amplification, Alejandro Manuel Ayala

Legacy Theses & Dissertations (2009 - 2024)

Changes in temperature due to climate change are not spatially uniform, and deserts and other drylands, which are greatly underrepresented in climate studies, are warming at a much faster rate than much of the globe with increasing concentrations of greenhouse gases. This strong warming amplification over deserts, termed Desert Amplification (DA), is most pronounced over the world’s largest and driest Sahara Desert and the Arabian Peninsula. The Sahara and Arabian deserts are formed in the subtropical subsiding branch of the Hadley Circulation (HC) and so the changes in large-scale subsidence associated with adiabatic heating could impact the DA dynamically. While …

X Ray Phase And Coherent Scatter Imaging Measurements, Pikting Cheung

Legacy Theses & Dissertations (2009 - 2024)

Traditional x-ray images are good for distinguishing between materials with very different absorption coefficients. However, detecting breast cancer using conventional x-ray imaging is hard because cancer tissue has similar absorption coefficients as normal tissue. Annually 43,600 women will die from breast cancer. The odds of survival are better if the cancer is diagnosed at an early stage, but mammography tends to have high rates of missed cancers. Mammography also tends to have a high false-positive rate, which leads to unnecessary biopsies. Two techniques with potential to add additional information to breast imaging have been investigated. X-ray phase imaging has been …

Spatiotemporal Variability Of Snow Depth On Arctic Sea Ice In Cmip6 Models And Satellite Data, Shengzhe Chen

Legacy Theses & Dissertations (2009 - 2024)

The Arctic has experienced rapid environmental changes in recent decades. Motivated by the important role of snow over sea ice in influencing Arctic climate variability and change, this dissertation aims to improve our knowledge of spatiotemporal variability of snow depth and processes over Arctic sea ice in the observations and model simulations.First, we evaluate snow depth over Arctic sea ice during 1993–2014 simulated by the models from the Coupled Model Intercomparison Project phase 6 (CMIP6) against recent satellite retrievals. The CMIP6 models capture some aspects of the observed snow depth climatology and variability. The observed variability lies in the middle …

The Surface Heating Efficiency Of Atmospheric Energy Flux Events During Arctic Winter, Christopher Joseph Cardinale

Legacy Theses & Dissertations (2009 - 2024)

The flux of moist static energy (MSE) into the polar regions plays a key role in the energy budget and climate of the polar regions. While usually studied from a vertically integrated perspective (Fwall), this dissertation examines its vertical structure, using the NASA-MERRA-2 reanalysis to compute climatological and anomalous fluxes of sensible, latent, and potential energy across 70◦N and 65◦S. This dissertation applies an energy budget analysis to winter-season synoptic periods of increased tropospheric (Ftrop) and stratospheric (Fstrat) energy flux convergence events and examines the processes that drive Arctic anoma lous surface warming and sea ice loss during Ftrop events. …

Discrimination Between Human And Non-Human Blood Using Raman Spectroscopy And A Self-Reference Algorithm For Forensic Purposes : Method Expansion And Validation, Harrison Dickler

Legacy Theses & Dissertations (2009 - 2024)

Determining whether the origin of a bloodstain is human or non-human is an important capability of a forensic investigation. In their pioneering work, Bian et al. (Journal of biomedical optics, 2017) introduced a self-reference peak algorithm for the analysis of bloodstain Raman spectra and demonstrated a great potential of this approach for differentiating human and nonhuman blood. However, this work only used three non-human species in the creation of their model. This study investigates the capability of a self-referencing peak algorithm to discriminate between human and 18 non-human species based on the Raman spectra of blood samples. The intensity ratios …

Methodology Studies For Dearomatized Dimer And Beta-Lactone-Mediated Native Chemical Ligation In Organic Synthesis, Xinhao Fan

Legacy Theses & Dissertations (2009 - 2024)

Chapter 1: Dimers of naphthalenol derivatives were synthesized by photocatalysis, cobalt(II) acetylacetonate. Several functional groups were tolerant of its skeleton. This novel dimer was connected through a reversible sigma bond. Its reversibility was confirmed by chiral HPLC and 1H-NMR experiments. Through EPR and Stern-Volmer quenching experiments, we proposed the reaction mechanism. The reversibility property can be potentially beneficial in polymers, self-healing, and memory materials.Chapter 2: We report an epimerization-free native chemical ligation reaction by β-lactone-mediated peptides. This approach can achieve Thr-Xaa efficiently and rapidly. Besides, it has a broad side-chain tolerance. Through the competition reaction experiment, it was demonstrated that …

Synthesis Of Oligonucleotides Containing Unnatural Backbone And Regulation Of Crispr Activity Using Inverse Electron Demand Diels-Alder Chemistry, Alyssa Hoy

Legacy Theses & Dissertations (2009 - 2024)

This thesis describes the synthesis of an oligonucleotide containing an unnatural neutralbackbone. The backbone was constructed using bio-orthogonal inverse electron demand Diels- Alder chemistry between trans-cyclooctene (TCO) and tetrazine (Tz). A TCO phosphoramidite was synthesized and attached to solid support for strand propagation. Uridine monomers containing either bis-TCO or bis-Tz were also synthesized. The oligonucleotide strand was formed by sequential ligation of the bis-Tz and bis-TCO monomers. The oligonucleotide was analyzed using mass spectrometry. This thesis also describes the synthesis of sgRNAs containing non-canonical nucleobases, m1A, m6A, s2U and s4U using the ‘split-and-click’ methodology. The synthetic sgRNAs were assembled using …

Understanding Changes In Precipitation, Wildfires, And Possible Governing Factors Over Central Equatorial Africa, Yan Jiang

Legacy Theses & Dissertations (2009 - 2024)

Tropical rainforests are global epicenters of biodiversity and modulators of climate. A long-term drying trend has occurred in the Congo Basin since the 1980s and this raises great concerns for sustaining the Congolese rainforest and local rain-fed agriculture. Motivated by documented rainfall changes and the need to improve understanding of main factors influencing precipitation variability and changes in Central Equatorial Africa (CEA), this dissertation conducts synthesized studies on 1) quantifying variations in precipitation seasonality by focusing on dry season duration, 2) estimating cascading wildfire risks associated with changes in precipitation patterns, and estimating impacts of 3) the tropical Indian Ocean …

A Novel Phase And Spectroscopic Imaging Technique To Evaluate Cellular Functions, Ting Chean Khoo

Legacy Theses & Dissertations (2009 - 2024)

This thesis presents the application of Raman spectroscopy, digital holographic microscope (DHM) and transport intensity equation (TIE) in imaging biological samples. Raman spectroscopy is a non-destructive technique that can provide chemical structure, concentration, temperature, and molecular interactions. On the other hand, DHM and TIE provide physical measurements such as height, width, area and volume.We applied Raman spectroscopy to study iron-bound transferrin (Tf) in intact human breast cancer cells. Iron is an essential element required for human life and is highly regulated in the body. As the exact mechanisms of iron-bound Tf in cells are not well known, we developed a …

A Synoptic-Dynamic Analysis Of The Structure And Evolution Of Persistent North Pacific Wintertime Ridge Regimes, Tyler Christopher Leicht

Legacy Theses & Dissertations (2009 - 2024)

Along the west coast of North America (NA), a majority of the precipitation for the entire year falls during winter as a result of approximately a dozen cyclones or atmospheric rivers. However, persistent upper-level ridges can prevent the occurrence of wintertime precipitation events and lead to extended drought, significant water shortages, and adverse economy-wide impacts for major population centers in California. An increased understanding of the dynamical and thermodynamical processes that govern upper-level ridge formation, persistence, and dissipation during the rainy season along western NA would allow decision makers to better manage water resources and motivates this thesis. Persistent upper-level …

Development And Applications Of Touch Chemistry Biometrics Analysis Of Latent Fingermarks By Maldi-Ms, Cameron M. Longo

Legacy Theses & Dissertations (2009 - 2024)

Fingerprint evidence has long been a pillar of forensic science and has been used for over a century as a means of identifying an individual. This is accomplished through the comparison of friction ridge patterns, which are inherently unique to each individual, and the practice of visualizing fingerprints and comparing them has become a well-studied field. While these techniques have been optimized and improved over time, they generally rely only on the physical pattern to provide information about the donor, and not the content of the fingerprint material itself. In the modern era, steps have been made to extract from …

X Ray Phase And Coherent Scatter Imaging Measurements, Mahboob Ur Rehman

Legacy Theses & Dissertations (2009 - 2024)

In conventional radiography, anatomical information of the patients can be obtained, distinguishing different tissue types, e.g. bone and soft tissue. However, it is difficult to obtain appreciable contrast between two different types of soft tissues. Instead, coherent x-ray scattering can be utilized to obtain images which can differentiate between normal and cancerous cells of breast. An x-ray system using a conventional source and simple slot apertures was tested. Materials with scatter signatures that mimic breast cancer were buried in layers of fat of increasing thickness and imaged. The result showed that the contrast and signal to noise ratio (SNR) remained …