Physical Sciences and Mathematics Commons^™

Computational Study On The Nucleation Of Polyoxovanadate-Alkoxide Clusters, S M Gulam Rabbani

Dissertations and Theses

Polyoxovanadate-alkoxide (POV-alkoxide) clusters are a new class of electroactive species with potential electrochemical applications in redox catalysis, energy storage, and optoelectronics. These clusters' redox properties can be tuned by the functionalization via heterometallic installation and changing alkoxide ligands. However, the formation mechanism of these POV-alkoxides in the solvothermal process is unknown, limiting the rational design to improve their electronic properties. This dissertation reports the speciation study of POV-alkoxide clusters, which is fundamental to controlling and manipulating the evolution of transient species during their nucleation and tuning the final product's properties. Chapter 2 and chapter 3 describe our computational study of …

The Derivation Of Geologic Ecosystem Services From Geodiversity In The Black Hills Region Of South Dakota And Wyoming, James Campbell Cooke

Dissertations and Theses

The ecosystem services approach seeks to recognize the benefits that people obtain from ecosystems, in order to highlight society’s dependence on natural systems. Ecosystem services fall into four categories: provisioning, regulating, cultural, and supporting services. Most of the ecosystem services research literature is focused on services that arise from biotic components of ecosystems. Ecosystems are dynamic complexes of biotic communities and their physical, non-living environment, interacting as a functional unit. The emphasis on biotic ecosystem services leaves understudied and undervalued the role of the abiotic, physical environment, especially in providing geologic ecosystem services. Geologic ecosystem services have been the focus …

Photophysical, Electrochemical, And Catalytic Studies Of Anthraquinone And Pyridoxyl-Based Sensors And Development Of Ruthenium Photosensitizers, Anwar Hussain

Dissertations and Theses

In the past, we have demonstrated the photophysical properties of several anthraquinone derivatives that act as a luminescent host for various environmental and biological cations. Here we extend our expertise in photochemistry to the class of chemicals containing the pyridoxal moiety. Several ligands were synthesized using eco-friendly, simple, one-step reactions via Schiff base and condensation reactions. The optical properties of these ligands were examined with a series of cations. We demonstrated the ability to detect the biologically important zinc ion in living cells such as RAW 264.7 and HEK 293 via fluorescence signaling. In addition, we extend our explorations to …

Establishing The Relative Composition Of Functionalized Thiols In Mixed Ligand Gold Nanoparticles By 1h-Nmr Spectroscopy, Matthias Carroll

All Master's Theses

Functionalized gold nanoparticles (AuNPs) are of interest for their optical and electrical properties, specifically the surface plasmon resonance phenomenon and potential applications for medicine and nano-circuitry. In this study, the ligand composition of small (~5 nm diameter) thiol functionalized AuNPs with mixed ligand monolayers was investigated to better understand how the molar feed ratio of ligands used during their synthesis influences the composition of ligands on the particle’s surface. The system under study was a combination of two ω-functionalized thiols, mercapto ethoxy ethoxy ethanol (MEEE) and mercapto pentyl trimethyl ammonium chloride (MPTMA). UV/Visible spectrophotometry, dynamic light scattering, and electron …

Angler Catch Rates, Opinions, And Abiotic Variable Relationships In The Lower Logan River, Utah, Tyler Coleman, Jim Derito, Chris Penne, Gary Thiede, Phaedra Budy

Watershed Sciences Student Research

Summer base flows for rivers are critical for maintaining water quality, healthy fish populations, and a functional aquatic ecosystem. Low summer base flows can increase water temperatures and lower dissolved oxygen levels. These conditions can cause Brown Trout (Salmo trutta) energetic stress and result in lower angler catch. The goal of this study was to determine if low river flows and higher water temperatures influence angler catch rates of Brown Trout on the lower Logan River, Utah and to better understand angler use of the lower river. We performed a creel survey on approximately 6.4 km of the …

The Differentialgeometry Package, Ian M. Anderson, Charles G. Torre

Downloads

This is the entire DifferentialGeometry package, a zip file (DifferentialGeometry.zip) containing (1) a Maple Library file, DifferentialGeometryUSU.mla, (2) a Maple help file DifferentialGeometry.help, (3) a Maple Library file, DGApplicatons.mla. This is the latest version of the DifferentialGeometry software; it supersedes what is released with Maple.

Installation instructions

A New Non-Inheriting Homogeneous Solution Of The Einstein-Maxwell Equations With Cosmological Term, Ian M. Anderson, Charles G. Torre

Publications

We find a new homogeneous solution to the Einstein-Maxwell equations with a cos- mological term. The spacetime manifold is R × S3. The spacetime metric admits a simply transitive isometry group G = R × SU(2) and is Petrov type I. The spacetime is geodesically complete and globally hyperbolic. The electromagnetic field is non- null and non-inheriting: it is only invariant with respect to the SU(2) subgroup and is time-dependent in a stationary reference frame.

Measuring Vegetation Density In Marsh Grass Photographs Using Convolutional Neural Networks, Lucas W. Welch

UNF Graduate Theses and Dissertations

A marsh is a wetland dominated by various species of grasses rather than trees. It supports an important ecosystem, providing habitats for many kinds of animals and posing a crucial impact on coastal climates. Marshes are rapidly changing, and it is vital for scientists to track these changes to understand the health of them. To do so, biologists perform vegetation monitoring to estimate the coverage of vegetation in an area of marsh. This task often calls for extensive human labor carefully examining pixels in photos of marsh sites to calculate vegetation density for a variety of marsh grass species. This …

Secure Multi-Robot Adaptive Information Sampling With Continuous, Periodic And Opportunistic Connectivity, Tamim Khatib

UNF Graduate Theses and Dissertations

Multi-robot teams are an increasingly popular approach for information gathering in large geographic areas, with applications in precision agriculture, natural disaster aftermath surveying, and pollution tracking. In a coordinated multi-robot information sampling scenario, robots share their collected information amongst one another to form better predictions. These robot teams are often assembled from untrusted devices, making the verification of the integrity of the collected samples an important challenge. Furthermore, such robots often operate under conditions of continuous, periodic, or opportunistic connectivity and are limited in their energy budget and computational power. In this thesis, we study how to secure the information …

Non-Chromatographic Oligonucleotide Purification And Automated Polyethyleneglycol Synthesis, Dhananjani N. A. M. Eriyagama

Dissertations, Master's Theses and Master's Reports

Synthetic oligodeoxynucleotides (ODN) have various applications in many areas such as, synthetic biology, chemical biology, antisense drug development, and data storage. As a result, there is a high demand for synthetic ODNs. Many advances have been made with ODN synthesis the purification still remains a bottleneck. The non-chromatographic purification method is developed to address this problem. Similarly, polyethylene glycols (PEGs) have been used in many areas including pharmaceutical applications, surface science, and nanomedicine due to its unique properties. However, monodispersed PEG synthesis is expensive with existing methods. A novel automated solid phase synthesis method is developed to obtain monodispersed PEGs. …

Addressing Ascertainment Bias In The Study Of Cardiovascular Disease Burden In Opioid Use Disorders - Application Of Natural Language Processing Of Electronic Health Records, Jade Huang Singleton

Theses and Dissertations--Epidemiology and Biostatistics

In the United States, the prevalence of long-term exposure to opioid drugs, for both medically and nonmedically indicated purposes, has increased considerably since the mid-1990’s. Concerns have emerged about the potential health effects of opioid use. There is also growing interest in other possible connections with opioid use including cardiovascular disease. Electronic health records (EHR) contain information about patient care in the form of structured codes and unstructured notes. Natural language processing (NLP) provides a tool for processing unstructured textual data in EHR clinical notes and extracts useful information for research with structured formats. The purpose of this dissertation was …

Vietnamese Document Analysis: Dataset, Method And Benchmark Suite, Khang Nguyen, An Nguyen, Nguyen D. Vo, Tam Nguyen

Computer Science Faculty Publications

Document image understanding is increasingly useful since the number of digital documents is increasing day-by-day and the need for automation is increasing. Object detection plays a significant role in detecting vital objects and layouts in document images and contributes to providing a clearer understanding of the documents. Nonetheless, previous research mainly focuses on English document images, and studies on Vietnamese document images are limited. In this study, we extensively benchmark state-of-the-art object detectors and analyze the performance of each method on Vietnamese document images. Moreover, we also investigate the effectiveness of four different loss functions on the experimental object detection …

Mass Spectrometric Analysis Of Lignin Model Compounds: Fundamental Investigations Of Ionization And Supramolecular Interactions For Lignocellulosic Biomass Applications, Kimberly Dean

Theses and Dissertations--Chemistry

Lignocellulosic biomass is pivotal for the development of renewable energy sources and materials essential to mitigate the exploitation of fossil fuels causing climate change and environmental pollution issues. The conversion of biomass into fuel requires the hydrolysis of cellulose and a biproduct of this process is the isolation of millions of tons of lignin as biorefinery waste. Lignin is a complex high molecular weight polymer whose structure remains undefined and critically limits potential industrial applications of lignocellulosic biomass. The advancement of analytical methods for structural elucidation of lignin and its ensemble of phenolic compounds is therefore essential to advance this …

1,2-Diamination Of Alkenes Via Reduction Of 1,2,3-Triazolinium Ions, Setareh Saryazdi

Theses and Dissertations--Chemistry

1,2-Diamine substructures are prevalent functional motifs in natural products, pharmaceutical compounds, and ligands. The interesting functionalities of 1,2-diamines have inspired many synthetic chemists to design various methodologies for preparing these structures from simple precursors such as alkenes. In this work, we described two different but related methods using simple and easily accessible reagents for 1,2-diamination of alkenes. In the first method, an alkene undergoes 1,3-dipolar cycloaddition with an organic azide to form a 1,2,3-triazoline. Subsequent N-alkylation of the generated 1,2,3-triazoline gives the 1,2,3-triazolinium ion, which is then hydrogenated over Raney Ni with a balloon of H₂ to produce …

Application Of Mass Spectrometry For Characterization Of Plant-Based Phenolics And Alkaloids, Masoumeh Dorrani

Theses and Dissertations--Chemistry

Plant-derived compounds have the potential to produce value-added compounds with a variety of applications. For example, the lignin part of the lignocellulosic biomass, produced in large quantities as waste from the paper and pulp industries, is a rich source of phenolics with potential applications in the renewable energy sector, pharmaceutical, and chemical industries. On the other hand, plant alkaloids are the primary source for developing plant-derived therapeutics. Unfortunately, the recalcitrant nature of plant cell walls, low extraction yields of small secondary metabolites, and the lack of effective analytical methods for a rapid and accurate identification of plant-based compounds and plant’s …

Relative Primeness And Borel Partition Properties For Equivalence Relations, John D. Clemens

Mathematics Faculty Publications and Presentations

We introduce a notion of relative primeness for equivalence relations, strengthening the notion of non-reducibility, and show for many standard benchmark equivalence relations that non-reducibility may be strengthened to relative primeness. We introduce several analogues of cardinal properties for Borel equivalence relations, including the notion of a prime equivalence relation and Borel partition properties on quotient spaces. In particular, we introduce a notion of Borel weak compactness, and characterize partition properties for the equivalence relations ��₂ and ��₁. We also discuss dichotomies related to primeness, and see that many natural questions related to Borel reducibility of equivalence …

Joint Full-Waveform Ground-Penetrating Radar And Electrical Resistivity Inversion Applied To Field Data Acquired On The Surface, Diego Domenzain, John Bradford, Jodi Mead

Mathematics Faculty Publications and Presentations

We exploit the different but complementary data sensitivities of ground-penetrating radar (GPR) and electrical resistivity (ER) by applying a multiphysics, multiparameter, simultaneous 2.5D joint inversion without invoking petrophysical relationships. Our method joins full-waveform inversion (FWI) GPR with adjoint derived ER sensitivities on the same computational domain. We incorporate a stable source estimation routine into the FWI-GPR. We apply our method in a controlled alluvial aquifer using only surface-acquired data. The site exhibits a shallow groundwater boundary and unconsolidated heterogeneous alluvial deposits. We compare our recovered parameters to individual FWI-GPR and ER results, and we compare them to log measurements of …

Male Mastodon Landscape Use Changed With Maturation (Late Pleistocene, North America), Joshua H. Miller, Daniel C. Fisher, Brooke E. Crowley, Ross Secord, Bledar A. Konomi

Department of Earth and Atmospheric Sciences: Faculty Publications

Under harsh Pleistocene climates, migration and other forms of seasonally patterned landscape use were likely critical for reproductive success of mastodons (Mammut americanum) and other megafauna. However, little is known about how their geographic ranges and mobility fluctuated seasonally or changed with sexual maturity. We used a spatially explicit movement model that coupled strontium and oxygen isotopes from two serially sampled intervals (5+ adolescent years and 3+ adult years) in a male mastodon tusk to test for changes in landscape use associated with maturation and reproductive phenology. The mastodon’s early adolescent home range was geographically restricted, with no evidence of …

Using Drones To Evaluate Revegetation Success On Natural Gas Pipelines, Anthony Nelson Mesa

Graduate Theses, Dissertations, and Problem Reports

The Appalachian region of the United States has significant growth in the production of natural gas. Developing the infrastructure required for this resource creates significant disturbances across the landscape, as both well pads and transportation pipelines must be created in this mountainous terrain. Midstream infrastructure, which includes pipeline rights-of-way and associated infrastructure, can cause significant environmental degradation, especially in the form of sedimentation. The introduction of this non-point source pollutant can be detrimental to freshwater ecosystems found throughout this region. This ecological risk has necessitated the enactment of regulations related to midstream infrastructure development. Weekly, inspectors travel afoot along pipeline …

Dirhenium Compounds Containing The Diphosphine Ligands Ph2pch2pph2, Ph2pch(Cn)Pph2, Or Ph2pch(Ch3)Pph2: A Comparative Study, Hannah C. Arthur

Undergraduate Honors Theses

When M₂L₁₀ complexes containing two rhenium(III) atoms in a quadruple bond react with an excess of the diphosphine ligand Ph₂PCH₂PPh₂, the bond order decreases, and the rhenium is reduced to rhenium(II). When two diphosphine ligands are bonded to the dirhenium center, they can adopt a trans-trans, trans-cis, or cis-cis configuration. NMR spectra of compounds that adopt the cis-cis arrangement show unusually large downfield shifts for one of the bridgehead methylene hydrogens (P-CH₂-P). To understand the unusual chemical shift, the hydrogens first have to be assigned. The strategy for …

Representation Theory And Its Applications In Physics, Jakub Bystrický

Honors Theses

Representation theory is a branch of mathematics that allows us to represent elements of a group as elements of a general linear group of a chosen vector space by means of a homomorphism. The group elements are mapped to linear operators and we can study the group using linear algebra. This ability is especially useful in physics where much of the theories are captured by linear algebra structures. This thesis reviews key concepts in representation theory of both finite and infinite groups. In the case of finite groups we discuss equivalence, orthogonality, characters, and group algebras. We discuss the importance …

Development Of Ph-Sensitive And Amine-Reactive Lifters For The Detection Of Latent Fingermarks, Andrei Gregory Mlakar

Graduate Research Theses & Dissertations

Latent fingermarks are among the most common forms of physical evidence left at crime scenes. Being composed largely of eccrine and sebaceous secretions, they are typically invisible unless they are treated with, e.g., powders or cyanoacrylate fumes. Drawbacks to these and other commonly used methods, however, may include limited substrate compatibility, safety hazards, inability to detect older marks, and the need for expensive instrumentation and expert practitioners. Fingermarks on curved, reflective, patterned, or luminescent substrates are particularly challenging to image with most common techniques. After treatment, fingermarks on such difficult substrates may be transferred to, or “lifted” by, flexible adhesives, …

Modeling Of Sub-Terahertz Wakefield Structures For Electron-Bunch Acceleration, Cassandra Phillips

Graduate Research Theses & Dissertations

Dielectric-lined waveguides have been extensively studied to potentially support high-gradient acceleration in beam-driven dielectric wakefield acceleration (DWFA) and for beam manipulations. In this thesis, we investigate the wakefield generated by a relativistic bunch passing through a dielectric waveguide with different transverse sections. I specifically consider the case of a structure consisting of two dielectric slabs, along with rectangular and square structures. Numerical simulations performed with the fine-difference time-domain WarpX program reveal interesting features of the transverse wake and possible experiments at the Argonne Wakefield Accelerator (AWA) are proposed.

Exploring The Morphometrics Of The Diatom Fragilariopsis Kerguelensis As A Proxy For Paleo-Sea Surface Temperature In The Late Pleistocene-Holocene Southern Ocean, Joseph Anthony Ruggiero

Graduate Research Theses & Dissertations

The Southern Ocean has played a large role in moderating global climate since its inception in the Oligocene. With the onset of anthropogenic global warming, it is now more necessary than ever that we understand the world’s climate during periods of rapidly fluctuating temperature in the past. Climatic forecasts are informed by paleoenvironmental conditions of the past during these turbulent periods, which we can examine using proxy data. This thesis assesses a potential proxy for Sea Surface Temperature (SST) through morphometric analysis of the Southern Ocean diatom Fragilariopsis kerguelensis in the Amundsen Sea, West Antarctica. This proxy is based off …

Modeling The Broader Impact Of Science And Health Using Social Media, Abdul Rahman Shaikh

Graduate Research Theses & Dissertations

Research and development have always initiated innovation and breakthroughs in technology. These technological advancements in recent years have provided a global medium for research to be disseminated through online platforms. These web-based platforms and the interactions that take place on them affect the dissemination, impact, and perception of online information. This thesis investigates the broader impact of science and health using social media posts, online patents, videos, and images by building machine learning and topic models. First, this study predicts patent citations to scientific research and identifies important factors essential to economic impact. We found that the citation of research …

Electrocatalytic Processes For Energy Storage & Conversion, Apurv Saxena

Doctoral Dissertations

"The continuous excessive usage of fossil fuels has resulted in its fast depletion leading to an escalating energy crisis as well as several environmental issues leading to increased research towards sustainable energy conversion. Electrocatalysts play crucial role in the development of numerous novel energy conversion devices including fuel cells and solar fuel generators.

High-efficiency and cost-effective catalysts are required for large-scale implementation of these new devices. Over the last few years transition metal chalcogenides have emerged as highly efficient electrocatalysts for several electrochemical devices such as water splitting, carbon dioxide electroreduction and, solar energy converters. These transition metal chalcogenides exhibit …

Laterally Heterogeneous Seismic Anisotropy Investigated By Shear Wave Splitting Analyses, Yan Jia

Doctoral Dissertations

"Numerous geophysical studies suggest that seismic anisotropy is a nearly ubiquitous property of the Earth’s crust and upper mantle. In this study, we utilize the shear wave splitting technique to investigate the piercing-point-dependent azimuthal anisotropy beneath the northeastern edge of the Sichuan Basin in central China, and the spatial and temporal variations of anisotropy near the 2019 M7.1 Ridgecrest earthquake in California, respectively. A clear back azimuthal dependence of the splitting parameters and the lack of a 90° or 180° periodicity of azimuthal variation in the observed fast orientations provide strong evidence for the existence of piercing-point-dependent anisotropy beneath the …

Disorder Effects In Frustrated Magnets And Absorbing State Transitions, Xuecheng Ye

Doctoral Dissertations

"Correlation, topology, and disorder can fundamentally affect the properties of interacting many-particle systems. After a short introduction which covers the basic concepts of phase transitions and scaling as well as the physics of Josephson junctions, the dissertation focuses on three separate projects.

The first project is motivated by the stripe and nematic phases observed e.g. in cuprate superconductors and iron pnictides. To understand the effects of disorder on such phases, we have investigated the behavior of the diluted J₁-J₂ Ising model. Spinless impurities generate a random-field disorder for the spin-density (stripe) order parameter, which destroys the stripe …

Deep Learning-Based Surrogate Models For Post-Earthquake Damage Assessment, Xinzhe Yuan

Doctoral Dissertations

"Seismic damage assessment is a critical step to enhance community resilience in the wake of an earthquake. This study aims to develop deep learning-based surrogate models for widely used fragility curves to achieve more accurate and rapid assessment in practice. These surrogate models are based on artificial neural networks trained from the labelled ground motions whose resulting damage classes on targeted structures are determined by nonlinear time history analyses. The development of various surrogate models is progressed in four phases. In Phase I, the multilayer perceptron (MLP) is used to develop multivariate seismic classifiers with up to 50 hand-crafted intensity …

Finding Aid For The Evelyn Uhrhan Irving Collection (Mum00146)

Archives & Special Collections: Finding Aids

Correspondence of modern language professor Evelyn Uhrhan Irving with various public officials and media outlets on foreign policy and domestic matters.