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Full-Text Articles in Physical Sciences and Mathematics

Formal Oscillatory Distributions, Alexander Karabegov Oct 2021

Formal Oscillatory Distributions, Alexander Karabegov

Mathematics

The formal asymptotic expansion of an oscillatory in- tegral whose phase function has one nondegenerate critical point is a formal distribution supported at the critical point which is applied to the amplitude. This formal distribution is called a formal oscillatory integral (FOI). We introduce the notion of a formal oscillatory distribution supported at a point. We prove that a formal distribution is given by some FOI if and only if it is an oscillatory distribution that has a certain nondegeneracy property. We also prove that a star product ? on a Poisson manifold M is natural in the sense of …


Mgrre_Pureoilscouttickets_Pinder._2_21127023530000, Mgrre Oct 2021

Mgrre_Pureoilscouttickets_Pinder._2_21127023530000, Mgrre

Legacy Scout Tickets from Pure Oil Company

No abstract provided.


Resampling And Super-Resolution Of Hexagonally Sampled Images Using Deep Learning, Dylan Flaute, Russell C. Hardie, Hamed Elwarfalli Oct 2021

Resampling And Super-Resolution Of Hexagonally Sampled Images Using Deep Learning, Dylan Flaute, Russell C. Hardie, Hamed Elwarfalli

Electrical and Computer Engineering Faculty Publications

Super-resolution (SR) aims to increase the resolution of imagery. Applications include security, medical imaging, and object recognition. We propose a deep learning-based SR system that takes a hexagonally sampled low-resolution image as an input and generates a rectangularly sampled SR image as an output. For training and testing, we use a realistic observation model that includes optical degradation from diffraction and sensor degradation from detector integration. Our SR approach first uses non-uniform interpolation to partially upsample the observed hexagonal imagery and convert it to a rectangular grid. We then leverage a state-of-the-art convolutional neural network (CNN) architecture designed for SR …


Online And Adjusted Human Activities Recognition With Statistical Learning, Yanjia Zhang Oct 2021

Online And Adjusted Human Activities Recognition With Statistical Learning, Yanjia Zhang

USF Tampa Graduate Theses and Dissertations

Wearable human activity recognition (HAR) is a widely application system for our daily life. It hasbeen built in many devices, such as smartphone, smartwatch, activity tracker, and health monitor. Many researchers try to develop a system which requires less memory space and power, but has fast and accurate classification results. Moreover, the objective of adjusting the classifier by the system self is also a study direction. In the present study, we introduced the machine learning methods to both smartphone data and smartwatch data and an adjusted model with the continuous generating data. Further, we also proposed a new HAR system …


Understanding Hyperporphyrin Spectra: Tddft Calculations On Diprotonated Tetrakis(-Aminophenyl)Porphyrin., Jeanet Conradie, Carl C. Wamser, Abhik Ghosh Oct 2021

Understanding Hyperporphyrin Spectra: Tddft Calculations On Diprotonated Tetrakis(-Aminophenyl)Porphyrin., Jeanet Conradie, Carl C. Wamser, Abhik Ghosh

Chemistry Faculty Publications and Presentations

A detailed TDDFT study (with all-electron STO-TZ2P basis sets and the COSMO solvation model) has been carried out on the effect of diprotonation on the UV-vis-NIR spectra of free-base tetraphenylporphyrin and tetrakis(-aminophenyl)porphyrin. The diprotonated forms have been modeled as their bis-formate complexes, i.e., as so-called porphyrin diacids. The dramatic redshift of the Q-band of the TAPP diacid has been explained in terms of an elevated "a" HOMO and lowered LUMOs, both reflecting infusion of aminophenyl character into the otherwise classic Gouterman-type frontier MOs. The exercise has also yielded valuable information on the performance of different exchange-correlation functionals. Thus, the hybrid …


The Dangers Of Doxing And Swatting: Why Texas Should Criminalize These Malicious Forms Of Cyberharassment, Hannah Mery Oct 2021

The Dangers Of Doxing And Swatting: Why Texas Should Criminalize These Malicious Forms Of Cyberharassment, Hannah Mery

St. Mary's Law Journal

Abstract forthcoming.


Three-Dimensional Intrusion Geometries In The Monogenetic San Rafael (Utah) Sub-Volcanic Field Revealed By Nonlinear Inversion Of Magnetic Anomaly Data, Troy A. Berkey Oct 2021

Three-Dimensional Intrusion Geometries In The Monogenetic San Rafael (Utah) Sub-Volcanic Field Revealed By Nonlinear Inversion Of Magnetic Anomaly Data, Troy A. Berkey

USF Tampa Graduate Theses and Dissertations

Distributed volcanic fields are common on Earth and nearby planetary bodies. Unlike their central-vent counterparts, these volcanic centers are comprised of many individual basaltic magmatic dikes, which are often only expressed at the surface in the form of vents, domes, and lava flows. In situ imaging of the shallow (<1 km) subsurface can reveal important details about the 3D geometry of fissure systems that feed distributed eruptive centers, with implications for the nature of these eruptions: their mass flow rates, explosivity, durations, and volcanotectonic interaction. Luckily, dikes, sills, conduits and related near-surface structures tend to carry high remnant magnetizations, creating magnetic anomalies at the surface where sufficient magnetic contrast exists with the host rocks they intrude. In the San Rafael Sub-volcanic field (SRSVF), basaltic dikes intrude fractured and horizontally bedded Jurassic sandstones, now eroded to a depth of about 800 m beneath the paleo-surface. Detailed mapping and profiles with a Cs-vapor magnetometer reveal far more complex anomalies than can be attributed to simple planar dikes, including: sills, buds, and domes. We image these geometries using MagCube-parallel, an open-source nonlinear inversion code we developed that models complex geometry with multiple (<= 1,000) vertical-sided prisms. I show one normally polarized fissure system to include along strike: An ~3-14 m thick, ~50 m wide dome-like feature or laccolith at depths of ~9-20 m, a roughly vertical conduit ~15 m thick, ~36-50 m wide, at ~1-16 m depth near the center of the mapped fissure-like system, and a ~8-48 m. wide dike at ~2-17 m depth that is <1-6 m thick, with reducing magnitude northward. While model depth and thickness vary with magnetization contrast, the main geometric relationships do not. Magnetic mapping of a nearby fissure reveals the same types of structures. The implication of these structures is that the small-volume fissure eruptions were likely pulsatory, with episodes of horizontal intrusion of sills, and sufficient time to develop gravitational instabilities.


Low Hydrophobic Mismatch Scores Calculated For Hla-A/B/Dr/Dq Loci Improve Kidney Allograft Survival, Dulat Bekbolsynov, Beata Mierzejewska, Jadwiga Borucka, Robert S. Liwski, Anna L. Greenshields, Joshua Breidenbach, Bradley Gehring, Shravan Leonard-Murali, Sadik A. Khuder, Michael Rees, Robert C. Green Ii, Stanislaw M. Stepkowski Oct 2021

Low Hydrophobic Mismatch Scores Calculated For Hla-A/B/Dr/Dq Loci Improve Kidney Allograft Survival, Dulat Bekbolsynov, Beata Mierzejewska, Jadwiga Borucka, Robert S. Liwski, Anna L. Greenshields, Joshua Breidenbach, Bradley Gehring, Shravan Leonard-Murali, Sadik A. Khuder, Michael Rees, Robert C. Green Ii, Stanislaw M. Stepkowski

Computer Science Faculty Publications

We evaluated the impact of human leukocyte antigen (HLA) disparity (immunogenicity; IM) on long-term kidney allograft survival. The IM was quantified based on physicochemical properties of the polymorphic linear donor/recipient HLA amino acids (the Cambridge algorithm) as a hydrophobic, electrostatic, amino acid mismatch scores (HMS\AMS\EMS) or eplet mismatch (EpMM) load. High-resolution HLA-A/B/DRB1/DQB1 types were imputed to calculate HMS for primary/re-transplant recipients of deceased donor transplants. The multiple Cox regression showed the association of HMS with graft survival and other confounders. The HMS integer 0-10 scale showed the most survival benefit between HMS 0 and 3. The Kaplan-Meier analysis showed that: …


Maris: Scalable Online Scenario Development Tool For Rangeland Conservancy Managers Using High Spatial-Temporal Resolution Carrying Capacity Maps And Livestock Market Data, L. G. J. Boerboom, R. O. Ohuru, A. G. Toxopeus, W. Nieuwenhuis, C. A. J. M. De Bie, P. K. Mwangi, M. L. Schouwenburg, R. L. G. Lemmens Oct 2021

Maris: Scalable Online Scenario Development Tool For Rangeland Conservancy Managers Using High Spatial-Temporal Resolution Carrying Capacity Maps And Livestock Market Data, L. G. J. Boerboom, R. O. Ohuru, A. G. Toxopeus, W. Nieuwenhuis, C. A. J. M. De Bie, P. K. Mwangi, M. L. Schouwenburg, R. L. G. Lemmens

IGC Proceedings (1993-2023)

Although the management of livestock numbers within the bounds of carrying capacity of African rangelands is a way to manage risks, both scientists and practitioners, caution against a momentary and local use of carrying capacity as a management indicator. Carrying capacity should be seen in wider spatial and temporal/seasonal context as well as in a social and economic context. Given the large numbers of conservancies across Kenya, and its Maasai Mara region in particular, with many more landowner members, it is difficult for conservancies’ managers to contextualize phenomena such as carrying capacity and market price over space and time.

We …


Assessing The Impacts Of Different Initiatives On The Rehabilitation Of Pastoral And Silvopastoral Ecosystems: Big Data Oriented Approach, Said Moukrim, Said Lahssini, Mustapha Naggar, K. Menzou, H. Mharzi-Alaoui, A. Labbaci, L. Rhazi Oct 2021

Assessing The Impacts Of Different Initiatives On The Rehabilitation Of Pastoral And Silvopastoral Ecosystems: Big Data Oriented Approach, Said Moukrim, Said Lahssini, Mustapha Naggar, K. Menzou, H. Mharzi-Alaoui, A. Labbaci, L. Rhazi

IGC Proceedings (1993-2023)

Moroccan forests, through the provision of goods and ecosystem services, underpins benefits to local communities and play a crucial role for rural area development. The legal framework recognizes to people, living near public forests, the right to graze their domestic livestock. Over the years, the grazing pressure is at levels far beyond the forestland’s carrying capacity throughout the country. Such pressure has been demonstrated as the main cause of forest cover loss and land degradation in Morocco and still threatening the sustainability of forests. To reduce the heavy grazing pressure on forest ecosystems and ensure their regeneration, several initiatives have …


Land Users – Land Watchers, J. H. Stefánsson, B. Marteinsdóttir Oct 2021

Land Users – Land Watchers, J. H. Stefánsson, B. Marteinsdóttir

IGC Proceedings (1993-2023)

GróLind is a collaborative project with the aim of monitoring Icelandic vegetation and soil resources. It was founded in 2017 by the Icelandic National Associations of Sheep Farmers, the Farmers Association of Iceland, Ministry of Industries and Innovation, and the Soil Conservation Service of Iceland. GróLind is a collaborative project and cooperation with stakeholders, such as the science community, landowners, and others, is a fundamental concept in the project.

In this project, the state of vegetation and soils are evaluated. Currently, a citizen science project is being developed within GróLind, in which land-users will annually monitor, using a mobile app, …


The Role Of Indigenous Knowledge In The Effective Collective Management Of The Communal Rangelands, A. Finca, S. Linnane, D. Getty, J. H. Slinger Oct 2021

The Role Of Indigenous Knowledge In The Effective Collective Management Of The Communal Rangelands, A. Finca, S. Linnane, D. Getty, J. H. Slinger

IGC Proceedings (1993-2023)

Numerous scientific studies have highlighted the complexities associated with the collective management of communal rangelands. To date, policy interventions in rangelands have largely ignored people’s traditional ways of managing, with adverse effects on rangeland productivity. Thus, local knowledge has not been considered in spatial planning, despite the fact that local rural communities are often repositories of key indigenous knowledge. Hence this study set out to evaluate the role of indigenous knowledge in the management of the communal rangeland in Cata and Guquka, now and in the future. This was achieved through the use of Participatory GIS (PGIS), specifically participatory mapping …


Semi-Empirical Modeling Of Liquid Carbon's Containerless Solidification, Philip Chrostoski Oct 2021

Semi-Empirical Modeling Of Liquid Carbon's Containerless Solidification, Philip Chrostoski

Dissertations

Elemental carbon has important structural diversity, ranging from nanotubes through graphite to diamond. Previous studies of micron-size core/rim carbon spheres extracted from primitive meteorites suggest they formed around such stars via the solidification of condensed carbon-vapor droplets, followed by gas-to-solid carbon coating to form the graphite rims. Similar core/rim particles result from the slow cooling of carbon vapor in the lab. The long-range carbon bond-order potential was used to computationally study liquid-like carbon in (1.8 g/𝐜𝐦𝟑) periodic boundary (tiled-cube supercell) and containerless (isolated cluster) settings. Relaxations via conjugate-gradient and simulatedannealing nucleation and growth simulations using molecular dynamics were done to …


Establishing Α Oph As A Prototype Rotator: Precision Orbit With New Keck, Chara, And Rv Observations, Tyler Gardner, John D. Monnier, Francis C. Fekel, Michael H. Williamson, Fabien Baron, Sasha Hinkley, Michael Ireland, Adam L. Kraus, Stefan Kraus, Rachael M. Roettenbacher, Gail Schaefer, Judit Sturmann, Laszlo Sturmann, Theo A. Ten Brummelaar Oct 2021

Establishing Α Oph As A Prototype Rotator: Precision Orbit With New Keck, Chara, And Rv Observations, Tyler Gardner, John D. Monnier, Francis C. Fekel, Michael H. Williamson, Fabien Baron, Sasha Hinkley, Michael Ireland, Adam L. Kraus, Stefan Kraus, Rachael M. Roettenbacher, Gail Schaefer, Judit Sturmann, Laszlo Sturmann, Theo A. Ten Brummelaar

Information Systems and Engineering Management Research Publications

Alpha Ophiuchi (Rasalhague) is a nearby rapidly rotating A5IV star that has been imaged by infrared interferometry. α Oph is also part of a known binary system, with a companion semimajor axis of ∼430 mas and a high eccentricity of 0.92. The binary companion provides the unique opportunity to measure the dynamical mass to compare with the results of rapid rotator evolution models. The lack of data near periastron passage limited the precision of mass measurements in previous work. We add new interferometric data from the MIRC combiner at the CHARA Array as well as new Keck adaptive optics imaging …


Behind The Scenes: On The Relationship Between Developer Experience And Refactoring, Eman Abdullah Alomar, Mohamed Wiem Mkaouer, Anthony Peruma, Christian D. Newman, Ali Ouni Oct 2021

Behind The Scenes: On The Relationship Between Developer Experience And Refactoring, Eman Abdullah Alomar, Mohamed Wiem Mkaouer, Anthony Peruma, Christian D. Newman, Ali Ouni

Articles

Refactoring is widely recognized as one of the efficient techniques to manage technical debt and maintain a healthy software project through enforcing best design practices, or coping with design defects. Previous refactoring surveys have shown that code refactoring activities are mainly executed by developers who have sufficient knowledge of the system’s design, and disposing of leadership roles in their development teams. However, these surveys were mainly limited to specific projects and companies. In this paper, we explore the generalizability of the previous results by analyzing 800 open-source projects. We mine their refactoring activities, and we identify their corresponding contributors. Then, …


Mgrre_Pureoilscouttickets_Crowfoot_1_21127022320000, Mgrre Oct 2021

Mgrre_Pureoilscouttickets_Crowfoot_1_21127022320000, Mgrre

Legacy Scout Tickets from Pure Oil Company

No abstract provided.


Integrating Compound Flood Conditions Through 2d Hydraulic Modeling For Simulating Flood Risk Processes In Coastal Cities, Francisco Pena Guerra Mr. Oct 2021

Integrating Compound Flood Conditions Through 2d Hydraulic Modeling For Simulating Flood Risk Processes In Coastal Cities, Francisco Pena Guerra Mr.

FIU Electronic Theses and Dissertations

Low elevation coastal karst environments are highly vulnerable to flooding conditions due to climate change. Trends in rising global temperatures have increased the frequency and intensity of extreme precipitation, hydrometeorological phenomena and sea level rise, exacerbating the impact of pluvial, fluvial, coastal and groundwater flood hazards. Compound flooding events amplify flood hazards and pose a higher threat to residents and infrastructure in unison compared to independent phenomena. Recent advancements in coupling hydrologic and hydraulic modeling frameworks have improved our ability to account for the combined effects of extreme pluvial, fluvial, and coastal flood hazards. This innovation in the hydroinformatics field …


Centering Equity In Sustainable Food Systems Education, Eleanor J. Sterling, Erin Betley, Selena Ahmed, Sharon Akabas, Daniel J. Clegg, Shauna Downs, Betty Izumi, Pamela Koch, Sara M. Kross, Karen Spiller, Lemir Teron, Will Valley Oct 2021

Centering Equity In Sustainable Food Systems Education, Eleanor J. Sterling, Erin Betley, Selena Ahmed, Sharon Akabas, Daniel J. Clegg, Shauna Downs, Betty Izumi, Pamela Koch, Sara M. Kross, Karen Spiller, Lemir Teron, Will Valley

The Sustainability Institute Publications

Sustainable food systems education (SFSE) is rapidly advancing to meet the need for developing future professionals who are capable of effective decision-making regarding agriculture, food, nutrition, consumption, and waste in a complex world. Equity, particularly racial equity and its intersectional links with other inequities, should play a central role in efforts to advance SFSE given the harmful social and environmental externalities of food systems and ongoing oppression and systemic inequities such as lack of food access faced by racialized and/or marginalized populations. However, few institutional and intra-disciplinary resources exist on how to engage students in discussion about equity and related …


A Local Baseline Of The Black Hole Mass Scaling Relations For Active Galaxies. Iv. Correlations Between MBh And Host Galaxy Σ, Stellar Mass, And Luminosity, Vardha N. Bennert, Tommaso Treu, Xuheng Ding, Isak Stomberg, Simon Birrer, Tomas Snyder, Matthew A. Malkan, Andrew W. Stephens, Matthew W. Auger Oct 2021

A Local Baseline Of The Black Hole Mass Scaling Relations For Active Galaxies. Iv. Correlations Between MBh And Host Galaxy Σ, Stellar Mass, And Luminosity, Vardha N. Bennert, Tommaso Treu, Xuheng Ding, Isak Stomberg, Simon Birrer, Tomas Snyder, Matthew A. Malkan, Andrew W. Stephens, Matthew W. Auger

Physics

The tight correlations between the mass of supermassive black holes (MBH) and their host-galaxy properties have been of great interest to the astrophysical community, but a clear understanding of their origin and fundamental drivers still eludes us. The local relations for active galaxies are interesting in their own right and form the foundation for any evolutionary study over cosmic time. We present Hubble Space Telescope optical imaging of a sample of 66 local active galactic nuclei (AGNs); for 14 objects, we also obtained Gemini near-infrared images. We use state-of-the-art methods to perform surface photometry of the AGN host …


Electrochemical Synthesis Of P-(Β-Hydroxyethyl Sulfone) Aniline, Hao Guo, Dong-Fang Niu, Shuo-Zhen Hu, Xin-Sheng Zhang Oct 2021

Electrochemical Synthesis Of P-(Β-Hydroxyethyl Sulfone) Aniline, Hao Guo, Dong-Fang Niu, Shuo-Zhen Hu, Xin-Sheng Zhang

Journal of Electrochemistry

Para-ester is the most important intermediate for the preparation of ethylene sulfone type reactive dyes, which is usually used in the dyeing of cellulose fibers and synthetic fibers. P-(β-hydroxyethyl sulfone) aniline is an important intermediate for the synthesis of para-ester. In this paper, p-(β-hydroxyethyl sulfone) aniline was prepared by electrochemical method, having the advantages of simple process, mild reaction condition, less environmental pollution, easy reaction control and so on. It has strong development potential and industrial application prospect. The electrochemical reduction of p-nitrophenyl-β-hydroxyethyl sulfone on a lead plate electrode to prepare p-(β-hydroxyethyl …


Synthesis Of Nickel Phosphide/Nitrogen Phosphorus Co-Doped Carbon And Its Application In Lithium Ion Batteries, Jian Hu, Yan-Shuang Meng, Qian-Ru Hu Oct 2021

Synthesis Of Nickel Phosphide/Nitrogen Phosphorus Co-Doped Carbon And Its Application In Lithium Ion Batteries, Jian Hu, Yan-Shuang Meng, Qian-Ru Hu

Journal of Electrochemistry

In recent years, the nickel-based phosphide has drawn great attention because of its low intercalation/deintercalation platform and lower polarization compared to sulfides and oxides as anodes for next-generation high-energy lithium-ion batteries. The Ni2P anode can deliver high theoretical specific capacity of 542 mAh·g-1, but it subject to a conversion reaction mechanism, which make them unsuitable for commercial applications. The agglomeration of Ni2P nanoparticles during material fabrication and the structural deterioration of electrode associated with large volume change during charge-discharge process lead to poor cycle stability and low utilization of active materials. Meanwhile, the low …


Performance And Mechanism Of PtXCuY/C Electrocatalyst For Methanol Oxidation, Jia Tang, Xiao-Ming Zhang, Shan-Sheng Yu, Su-Li Wang, Gong-Quan Sun Oct 2021

Performance And Mechanism Of PtXCuY/C Electrocatalyst For Methanol Oxidation, Jia Tang, Xiao-Ming Zhang, Shan-Sheng Yu, Su-Li Wang, Gong-Quan Sun

Journal of Electrochemistry

Direct methanol fuel cell (DMFC), which directly converts the chemical energy of methanol fuel into electrical energy, has the advantages of high energy conversion efficiency, environmental friendliness, and abundance of fuel sources. DMFC is considered as the promising substitutes in the field of portable devices, military applications, and stationary power stations, while the broad application is severely hindered by the sluggish kinetic of methanol oxidation reaction (MOR) in the anode and the high cost of platinum (Pt)-based anodic electrocatalysts. Herein, a series of carbon supported PtxCuy (PtxCuy/C) binary metal electrocatalysts, featured with high …


Mathematical Expression And Quantitative Analysis Of Impedance Spectrum On The Interface Of Glassy Carbon Electrode, Lei Cheng, Pu-Xuan Yan, You-Jun Fan, Hua-Hong Zou, Hong Liang Oct 2021

Mathematical Expression And Quantitative Analysis Of Impedance Spectrum On The Interface Of Glassy Carbon Electrode, Lei Cheng, Pu-Xuan Yan, You-Jun Fan, Hua-Hong Zou, Hong Liang

Journal of Electrochemistry

Glassy carbon electrode (GCE) is a common basic electrode for various electrochemical sensors, and the detection properties are determined by its interfacial characteristics. In this paper, we established an equivalent circuit including electrolyte resistance (Rel), charge transport resistance (Rct), diffusion impedance (Rdi, Cdi), electrochemical (oxidation/reduction) reaction impedance (RR, CR), surface adsorption impedance (Rads , Cads), double-layer capacitance (CDL), and derived the mathematical expression for the equivalent circuit. The Rel and CDL are contributed by inactive …


The Ratio Method: Addressing Complex Tort Liability In The Fourth Industrial Revolution, Harrison C. Margolin, Grant H. Frazier Oct 2021

The Ratio Method: Addressing Complex Tort Liability In The Fourth Industrial Revolution, Harrison C. Margolin, Grant H. Frazier

St. Mary's Law Journal

Emerging technologies of the Fourth Industrial Revolution show fundamental promise for improving productivity and quality of life, though their misuse may also cause significant social disruption. For example, while artificial intelligence will be used to accelerate society’s processes, it may also displace millions of workers and arm cybercriminals with increasingly powerful hacking capabilities. Similarly, human gene editing shows promise for curing numerous diseases, but also raises significant concerns about adverse health consequences related to the corruption of human and pathogenic genomes.

In most instances, only specialists understand the growing intricacies of these novel technologies. As the complexity and speed of …


The Importance Of Lithologic Variability And Stratigraphic Architecture In The Development Of Eogenetic Karst Systems, Nicholas J. Soto-Kerans Oct 2021

The Importance Of Lithologic Variability And Stratigraphic Architecture In The Development Of Eogenetic Karst Systems, Nicholas J. Soto-Kerans

USF Tampa Graduate Theses and Dissertations

Integrative characterizations of karst systems on low-lying eogenetic carbonate platforms are rare and often limited to areas of direct observation where caves can be entered and explored. Because hydraulic properties of eogenetic limestones have been implicitly assumed to be homogeneous, classical models of carbonate island karst development stressed the importance of geochemical interfaces in controlling cave and vug development. These studies have explained the largest cavern systems as results of either 1) mixing dissolution at platform margins or 2) microbially-mediated dissolution processes at water tables.

New data from core descriptions and wireline logs obtained in 18 boreholes drilled in the …


Study On Improving The Production Of Ammonium Persulfate By Ion Membrane Electrolysis, Yi-Hang Qu, Min Cui, Cong Zhang, Chong Li, Peng Li, Ju-Jie Ren Oct 2021

Study On Improving The Production Of Ammonium Persulfate By Ion Membrane Electrolysis, Yi-Hang Qu, Min Cui, Cong Zhang, Chong Li, Peng Li, Ju-Jie Ren

Journal of Electrochemistry

In china, the production of ammonium persulfate in factories mostly adopts the electrolysis method with simple process and high purity. However, there exists the problem of high energy consumption in the electrolysis process, which restricts the further development of ammonium persulfate in many fields. Aiming at this phenomenon, the equipment and technology to produce ammonium persulfate using electrolysis were designed and studied in order to reduce energy consumption. A new type of zero-pole distance and ion-exchange membrane industrial electrolytic cell was provided for the electrolysis production of ammonium persulfate. An ion-exchange membrane was used to separate the electrolytic cell into …


Effect Of Alkyl Chain Length Of Symmetrical Quaternary Ammonium Hydroxide On Oxalic Acid Electroreduction Reaction, Bo Huang, Xin-Sheng Zhang, Dong-Fang Niu, Shuo-Zhen Hu Oct 2021

Effect Of Alkyl Chain Length Of Symmetrical Quaternary Ammonium Hydroxide On Oxalic Acid Electroreduction Reaction, Bo Huang, Xin-Sheng Zhang, Dong-Fang Niu, Shuo-Zhen Hu

Journal of Electrochemistry

Glyoxylic acid with the dual characteristics of acid and aldehyde is an important chemical raw material and organic synthesis intermediate, which is extensively used in the perfumery, pharmaceutical and fine chemical industries. A family of symmetric quaternary ammonium hydroxides (QAHs) with different alkyl chain lengths was used as the additives in generating glyoxylic acid from oxalic acid electroreduction reaction (OAER). The effects of alkyl chain length on OAER and the corresponding side reaction, i.e., hydrogen evolution reaction (HER), were investigated. Linear sweep voltammetric (LSV) results showed that the adsorption of the additives suppressed more on the HER than that on …


Numerical Study On The Influences Of Flow Channel And Rib Width Ratio On The Performance Of Gas Diffusion Layer, Rong-Qiang Wei, Shi-An Li, Yi-Hui Liu, Zhi Yang, Qiu-Wan Shen, Guo-Gang Yang Oct 2021

Numerical Study On The Influences Of Flow Channel And Rib Width Ratio On The Performance Of Gas Diffusion Layer, Rong-Qiang Wei, Shi-An Li, Yi-Hui Liu, Zhi Yang, Qiu-Wan Shen, Guo-Gang Yang

Journal of Electrochemistry

Proton exchange membrane fuel cell (PEMFC) has the advantages of low noise, high power density, and zero emission. It is widely used in ships, automobiles, aviation and other fields. PEMFC is composed of bipolar plate (BP), gas diffusion layer (GDL), catalytic layer (CL) and proton exchange membrane (PEM). GDL has a supporting catalytic layer and proton exchange membrane, which provides gas diffusion for the reaction and a channel for the reaction to produce water, and transmits the anodic oxidation reaction. In the assembly of fuel cells, a certain assembly pressure is required to ensure air-tightness and effective conductivity. The assembly …


Janus-Tinbco2 For Hydrogen Evolution Reaction With High Conductivity And Catalytic Activity, Li-Li Xu, Dong-Yan Ren, Xiao-Feng Zhao, Yong Yi Oct 2021

Janus-Tinbco2 For Hydrogen Evolution Reaction With High Conductivity And Catalytic Activity, Li-Li Xu, Dong-Yan Ren, Xiao-Feng Zhao, Yong Yi

Journal of Electrochemistry

Exploring the potential hydrogen evolution reaction (HER) catalysts with the high activity and high conductivity has always been a hot spot in the research of renewable energy development. Ti2C, as one of the 2D-MXene, has excellent properties relating to many active sites, mechanical stability, conductivity, etc., and has become a potential HER catalyst. However, the modification of the surface of Ti2C by terminal O will reduce the conductivity, thereby limiting the transport of electrons between the valence band and the conduction band. In this study, an electric double layer Janus-TiNbCO2 was constructed by Nb doping. …


Preparation Of Modified Titanium Based Pbo2 Electrode And Its Rapid Detection Of Cod, Qi Sun, Yan-He Han, Xiao-Lu Fu Oct 2021

Preparation Of Modified Titanium Based Pbo2 Electrode And Its Rapid Detection Of Cod, Qi Sun, Yan-He Han, Xiao-Lu Fu

Journal of Electrochemistry

In the traditional Ti/β-PbO2 electrode, the crystal lattice difference between β-PbO2 and Ti matrix is large, and the prepared electrode is easy to fall off and has a short service life. It needs to be modified in actual use. Based on the advantages of α-PbO2 material and Ag material in terms of adhesion and conductivity, respectively, the above two materials are selected as the intermediate layer of Ti/β-PbO2 electrode to improve electrode performance. In this paper, by preparing Ti/α/β-PbO2 and Ti/Ag/β-PbO2 electrodes …