Physical Sciences and Mathematics Commons^™

Access To Higher Education: Do Schools “Grant” Success?, Nathaniel Jones

Symposium of Student Scholars

University education can lead to upward income mobility for low-income students. Being exposed to other student’s life experiences that are different from their own may highlight activities and actions that they may want to consider aiding their success. According to the U.S. Bureau of Labor Statistics, the median weekly earnings in 2019 for all workers in the U.S. was $969. Of those, U.S. workers who held bachelor’s degrees earned $1,248. In 2016, the Brookings Institute found that Pell Grant recipients and first-generation student loan borrowers attended universities that had lower graduation rates and higher loan default rates in comparison to …

The Reactivity Of Metal Phosphites: Oxidative Rate Analysis, Jamie Kitchens

Symposium of Student Scholars

Phosphorous compounds are involved in many of the biomolecular processes deemed fundamental for life. DNA, ATP, and phospholipids are a few of the molecules where phosphates can be found in the body. Phosphates are geochemically characterized by their low solubility and poor reactivity. This has led to the investigation of reaction mechanisms that could lead to the formation of the phosphorous compounds found in organisms. The oxidation of phosphite into phosphate could be how phosphates were introduced to life, due to phosphites being more soluble and more reactive than phosphates. We will present the synthesis and oxidation reactivity of four …

The Chemistry Of Fermentation As It Relates To The Art Of Winemaking, Olivia Cochran

Symposium of Student Scholars

The process of fermentation can be traced back to the beginning of civilization. Countries, over time, have learned this scientific process and turned it into the backbone of their culture through the making and manufacturing of wine. While climate-change and global-warming have impacted the commercial marketability of wine, the scientific process has remained constant. This undergraduate project analyses the production, fermentation and analytical approach of producing high quality wine. Beginning from the picking of grapes, to testing the acidity through a series of titrations, winemaking is truly where science and art collide.

Energy Requirements For Abiotic Production Of Phosphorous Compounds At The Ice-Schreibersite Interface, Lindsay M. Hicks

Symposium of Student Scholars

Energy Requirements for Abiotic Production of Phosphorous Compounds at the

Ice-Schreibersite Interface

The Abbott-Lyon Lab is investigating the chemistry at the interface of simple ices and a meteoritic mineral analogue. Phosphorous is a key component of numerous biomolecules necessary for life. Lack of an abundance of biologically accessible mineral sources of phosphates on Earth, termed “The Phosphorous Problem,” has led some origin-of-life scientists to look to extraterrestrial sources like meteoritic metal phosphides as possible sources of available phosphates. Schreibersite (Fe₂NiP) is a common mineral in iron meteorites and a plausible source of biologically accessible phosphorous. This study will …

Using Eye-Tracking Data To Determine What Biochemistry Students Attend To When Completing A Revised Three-Dimensional Modeling Activity, Hailey Knoeferl

Symposium of Student Scholars

In biochemistry, three-dimensional models are being used to help students comprehend advanced topics within the subject. Because a greater cognitive load is often related to three-dimensional models, learning what raises the cognitive load is critical. From there, measures can be taken to help lower the cognitive load and make the material easier for students to understand. To understand cognitive load in relation to models, students were presented with three-dimensional serine protease models and their substrates and asked to match the clear surface plate to the backbone, and then the substrate to the surface plate. On the substrates, students were asked …

Environmental Impact On Competition In Ecological Communities, Isabel Ouko

Symposium of Student Scholars

We study the effects of environmental feedback on the ecological competition by analyzing the classic Lotka-Volterra model coupled with a simple model of the environment. In particular, we look for ways in which feedback between competing populations and the environment stabilizes or destabilizes coexistence between the species. To do so, we use a combination of mathematical analysis and computer software such as Matlab.

KEYWORDS; mathematical modeling, Lotka-Volterra, ecological competition, environmental feedback

Investigation Of Chemistry At Ice-Mineral Interfaces Of Phosphorus-Containing Meteorites Analogues, Kimberly Meyberg

Symposium of Student Scholars

The search for life outside of Earth has raised questions about how life began have intrigued origin-of-life researchers, such as the incorporation of phosphorus into biomolecules. Phosphorus exists on Earth mostly as phosphate, PO₄^3-, which is insoluble and unreactive in the geochemical conditions of the early Earth. The challenge of incorporating phosphorus into biomolecules is known as the “phosphorus problem,” prompting investigations of reactive phosphorus species delivered to the prebiotic Earth. Phosphorus-laden meteorites delivered schreibersite (Fe,Ni)₃P, a possible mineral source of phosphorus recognized for its redox chemistry potential and observed reactivity with aqueous …

Chemical Industrial Safety And Environmental Considerations, James Stewart

Symposium of Student Scholars

Chemical Industrial Safety and Environmental Considerations

James Stewart

Department of Chemistry and Biochemistry, Kennesaw State University, Kennesaw, GA, 30144

Workplace safety, particularly in the chemical manufacturing and treatment industries, is always at the core of any competent business strategy of any modern industrially- or manufacturing-focused company. Due to the inherent and sometimes readily apparent nature of chemical hazards, safety in these industries has been, by necessity, a practical consideration since their inception. However, only relatively recently has it developed into a significant philosophical focus of businesses, regulatory agencies such as OSHA, and associated non-regulatory bodies such as the U.S. Chemical …

Electrochemical And Spectroscopic Characterization Of Cerium Salts And Nanoceria Material, Emily Velarde, Wei Zhou

Symposium of Student Scholars

The nanoscale form of cerium oxide, nanoceria (nano-CeO_x), has drawn great attention in recent years in electrochemical, nanomaterial research and medicinal studies due to its antibacterial properties, UV absorption, and its biochemical function as possible radical scavenger. Many new synthesis methods have achieved uniform and biocompatible nanoceria particles, and our lab has created cerium oxide particles that shows UV/Vis. absorption and X-ray patterns similar to the commercial nanoceria and nanoceria made in other research laboratories with novel synthetic methods.

This study focuses on charactering and comparing electrochemical properties of cerium inorganic salts and synthesized nanoceria. Preliminary results …

Bioanalytical Determination Of Glucose Concentration In Sports Drinks Using Uv/Vis Spectroscopy, Laney Hedgeman, Brianna Bond

Symposium of Student Scholars

Abstract

The purpose of our project is to indirectly monitor the enzymatic activity of glucose oxidase as it reacts with the glucose present in sports drinks through the quantitative analysis of the generated ferricyanide. As glucose oxidase catalyzes the oxidation of beta-D-glucose in the presence of oxygen, D-glucono-1,5-lactone is produced along with hydrogen peroxide. The hydrogen peroxide is used in a subsequent reaction with ferrocyanide catalyzed by horse radish peroxidase to produce water and the chromophore ferricyanide. This compound absorbs in the ultraviolet/visible spectrum at 420 nm, which can be quickly measured using Ultraviolet/Visible Spectroscopy. Since the molar ratio of …

Reporting Of Eating Disorder Deaths, Katherine Mobley, Amy Hord

Symposium of Student Scholars

Those affected by eating disorders experience disturbances in eating behaviors which are often related to underlying psychiatric disorders such as anxiety, depression, or obsessive-compulsive disorder (Parekh, 2017, Drieberg et al., 1998 p.53). The duplicitous nature of the disorder makes it difficult to diagnose, and the tole it takes on an individual’s physical health makes its mortality rate the second highest among psychiatric disorders (Guinhut et al., 2021 p.130). Even if the correct education and resources are accessible to certain individuals, negative stigmatization about the disorder can make sufferers unlikely to seek help (Becker et al., 2010). Findings from analysis of …

Fungi Associated With Herbaceous Plants In Coastal Northern California, Greg Huffman

Natural Sciences and Mathematics | Biological Sciences Master's Theses

The presence of fungal species associated with herbaceous plants was monitored in coastal Marin County, California, USA. The research involved a combination of field sampling surveys and data collection using a stratified random design, pathogen identification through microbiological and molecular analysis, and descriptive analysis and ordination of results. A total of two years of repeated sampling (four times a year) was organized to allow for the detection of seasonal differences in pathogen presence on aerial plant parts. The objective of this study was to identify microbial species present on herbaceous plants using ITS1 sequence analysis. Throughout March of 2018 to …

Real-Time Monitoring Of Fdm 3d Printer For Fault Detection Using Machine Learning: A Bibliometric Study, Vaibhav Kisan Kadam, Satish Kumar, Arunkumar Bongale

Library Philosophy and Practice (e-journal)

Additive Manufacturing has wide application range including healthcare, Fashion, Manufacturing, Prototypes, Tooling etc. AM techniques are subjected to various defects that may be printing defects or anomalies in machine. There is gap between current AM techniques and smart manufacturing since current AM lacks in build sensors necessary for process monitoring and fault detection. Both of these issues can be solved by incorporating real-time monitoring into AM. So the study is carried out to identify recent work done in AM to improve current system. For this bibliometric study Scopus database is used, study is kept limited to year 2010-2021 and English …

Exploring Thorium As Nuclear Reactor Fuel In India - A Nuclear Data Perspective, J Saranya .

University Departments

No abstract provided.

Development And Implementation Of A Pressure-Temperature Control System For The Physical Vapor Deposition Of Copper And Niobium From A Molybdenum Filament In The Development Of Superconducting 3d Printed Rf Cavity Particle Accelerators, Chandler J. Fleuette

Student Research Projects

This report covers the development of the pressure-temperature control system used in the production of small superconducting RF cavities for particle accelerators. To test the validity of the created program, a model for the process was created and tested. The model was used to fine tune the control system before integrating it into the lab. The end goal of the control system is to measure the pressure inside of a deposition vacuum chamber, convert that pressure to a temperature, and use that temperature in tandem with a PID controller to control the current passing though a molybdenum filament which is …

Host–Guest Interactions In A Metal–Organic Framework Isoreticular Series For Molecular Photocatalytic Co2 Reduction, Philip M. Stanley, Johanna Haimerl, Christopher Thomas, Alexander Urstoeger, Michael Schuster Prof. Dr., Natalia B. Shustova Prof. Dr., Angela Casini Prof. Dr., Bernhard Rieger Prof. Dr., Julien Warnan Dr., Roland A. Fischer Prof. Dr.

Faculty Publications

A strategy to improve homogeneous molecular catalyst stability, efficiency, and selectivity is the immobilization on supporting surfaces or within host matrices. Herein, we examine the co-immobilization of a CO2 reduction catalyst [ReBr(CO)3(4,4′-dcbpy)] and a photosensitizer [Ru(bpy)2(5,5′-dcbpy)]Cl2 using the isoreticular series of metal–organic frameworks (MOFs) UiO-66, -67, and -68. Specific host pore size choice enables distinct catalyst and photosensitizer spatial location—either at the outer MOF particle surface or inside the MOF cavities—affecting catalyst stability, electronic communication between reaction center and photosensitizer, and consequently the apparent catalytic rates. These results allow for a rational understanding of an optimized supramolecular layout of catalyst, …

Evaluating Methods For Research In Physical Weed Control And Farm Asset Tracking, Johnny J. Sanchez

Electronic Theses and Dissertations

Effective weed control has long been recognized as critical for agricultural production, yet weeds remain a major constraint to production and economic return in many agroecosystems. Moreover, improvements in physical weed control are necessary to address increasing problems of herbicide resistance in weeds of grain and fiber crops and the high cost of hand weeding in vegetables. From tractor-mounted cultivation tools to autonomous weeders, weeding implements are affected by weeds, crops, soil conditions, and actuator effectiveness. In order to address these complex and often interacting factors concerning weed control, new and innovative tools must be designed and evaluated. Chapter one …

10be Chronology Of Moraines Deposited During The Last Glaciation By The Khumbu Glacier, Nepalese Himalaya, Laura Alexandra Mattas

Electronic Theses and Dissertations

Understanding the global pattern of glaciation can aid interpretation of what caused late-Pleistocene glacial cycles. Here I investigate the glacial history of the Khumbu Glacier of the Mount Everest region of Nepal. Prominent hypotheses for Himalayan glaciation suggest important roles for orbitally modulated insolation change and the Asian summer monsoon. Here I test these hypotheses by developing a 10Be surface-exposure chronology of moraines constructed by the Khumbu Glacier during the last glacial period. My chronology is underpinned by detailed glacial-geomorphic mapping constructed by use of drone and satellite imagery. The ages presented in this study indicate that the Khumbu glacier …

From Disease Description And Gene Discovery To Functional Cell Pathway: A Decade-Long Journey For Tmco1, Helen Batchelor-Regan, Baozhong Xin, Aimin Zhou, Heng Wang

Chemistry Faculty Publications

A decade has passed since transmembrane coiled-coil domains 1 (TMCO1) defect syndrome was identified in 11 undiagnosed patients within the Old Order Amish of Northeastern Ohio-a disorder characterized by a distinctive craniofacial dysmorphism, skeletal anomalies and global developmental delay. Twenty seven patients, from diverse ethnic groups, have been reported with pathogenic TMCO1 variants now recognized to cause cerebrofaciothoracic dysplasia (CFTD). The implication of previously uncharacterized TMCO1 within disease has instigated a 10-year journey to understand the function of TMCO1 protein in Ca2+ homeostasis. TMCO1 is an ER Ca2+ leak channel which facilitates Ca2+ leak upon ER "overload" through the novel …

Theranostic Applications Of Sirna Bioconjugates In Cancer Detection And Treatment, Sunil S. Shah

Seton Hall University Dissertations and Theses (ETDs)

Abstract

The emerging field of RNA nanotechnology has led to rapid advances in the applications of RNA in chemical biology, medicinal chemistry, and biotechnology. At the forefront of its utility is the ability to self-assemble multiple siRNAs into nanostructure formulations capable of targeting selected oncogenes and potentiating the gene therapy of malignant tumors. Self-assembled siRNA integrates multiple siRNAs within a single molecular platform for silencing multiple oncogenic mRNA targets with high precision and efficacy to potentially induce cancer cell apoptosis through the RNA interference (RNAi) pathway. Furthermore, the conjugation of siRNA self-assemblies with bio-active probes results in multi-functional theranostic (therapy+diagnostic) …

Using Chemical Speciation Modelling To Discuss Variations In Patch Test Reactions To Different Aluminium And Chromium Salts, Saman Nikpour, Yolanda S. Hedberg

Chemistry Publications

Background: Allergic contact dermatitis to metals is diagnosed by applying a metal salt in a patch test. The bioavailability of the metal salt might depend on the choice of metal salt, the concentration, sweat composition, and pH.

Objectives: The main purpose of this study was to apply chemical speciation modelling, which is based on experimentally derived input data and calculates the concentrations of chemical forms (species) in solutions, to reproduce and discuss clinical patch test results of aluminium and chromium.

Methods: Joint Expert Speciation System (JESS), Hydra/Medusa, and Visual Minteq were employed to study the bioavailable fraction and chemical form …

Keap1 Cancer Mutants: A Large-Scale Molecular Dynamics Study Of Protein Stability., Carter J Wilson, Megan Chang, Mikko Karttunen, Wing-Yiu Choy

Chemistry Publications

We have performed 280 μs of unbiased molecular dynamics (MD) simulations to investigate the effects of 12 different cancer mutations on Kelch-like ECH-associated protein 1 (KEAP1) (G333C, G350S, G364C, G379D, R413L, R415G, A427V, G430C, R470C, R470H, R470S and G476R), one of the frequently mutated proteins in lung cancer. The aim was to provide structural insight into the effects of these mutants, including a new class of ANCHOR (additionally NRF2-complexed hypomorph) mutant variants. Our work provides additional insight into the structural dynamics of mutants that could not be analyzed experimentally, painting a more complete picture of their mutagenic effects. Notably, blade-wise …

Semiclassical Theory Of Laser-Assisted Dissociative Recombination, Ilya I. Fabrikant, H. B. Ambalampitiya, I. F. Schneider

Department of Physics and Astronomy: Faculty Publications

We study the process of laser-assisted dissociative recombination of an electron with a molecular cation using a semiclassical approach. In the region outside a reaction sphere the electron motion in the combined laser and Coulomb fields is treated classically. Within the sphere the laser-field effects are neglected, and the recombination probability is obtained from quantum-mechanical cross sections calculated for the laser-free process. Specific calculations are performed for dissociative recombination of H₂⁺ in the field of the intensity 2.09 GW/cm² and the wavelength 22.8 μm. In the energy region above 1 meV the cross section is significantly …

Population Properties Of Compact Objects From The Second Ligo-Virgo Gravitational-Wave Transient Catalog, R. Abbott, T. D. Abbott, Marco Cavaglia, For Full List Of Authors, See Publisher's Website.

Physics Faculty Research & Creative Works

We report on the population of 47 compact binary mergers detected with a false-alarm rate of < 1 yr^-1 in the second LIGO-Virgo Gravitational-Wave Transient Catalog. We observe several characteristics of the merging binary black hole (BBH) population not discernible until now. First, the primary mass spectrum contains structure beyond a power law with a sharp high-mass cutoff; it is more consistent with a broken power law with a break at 39.7^+20.3_-9.1 M_⊙ or a power law with a Gaussian feature peaking at 33.1^+4.0_-5.6 M_⊙ (90% credible interval). While the primary mass distribution must extend to …

Increased Connectivity And Depth Improve The Effectiveness Of Marine Reserves, Jordan Goetze, Shaun K. Wilson, Ben Radford, Rebecca Fisher, Tim Langlois, Jacquomo Monk, Nathan A. Knott, Hamish A. Malcolm, Leanne M. Currey-Randall, Daniel Ierodiaconou, David Harasti, Neville Barrett, Russell C. Babcock, Nestor E. Bosch, Danny Brock, Joachim Claudet, David Fairclough, Stephen J. Newman, Michael J. Travers, Corey Wakefield

Fisheries Research Articles

Marine reserves are a key tool for the conservation of marine biodiversity, yet only ~2.5% of the world's oceans are protected. The integration of marine reserves into connected networks representing all habitats has been encouraged by international agreements, yet the benefits of this design has not been tested empirically. Australia has one of the largest systems of marine reserves, providing a rare opportunity to assess how connectivity influences conservation success. An Australia-wide dataset was collected using baited remote underwater video systems deployed across a depth range from 0 to 100 m to assess the effectiveness of marine reserves for protecting …

Assessing Hawaiian Climate Resilience Plans On Flood Management, Maggie Chen

Master's Projects and Capstones

Island coastal communities are increasingly vulnerable to climate change impacts, including storms, flooding, and sea-level rise. In 2017, the state of Hawaiʻi saw an unprecedented number of minor flood events due to a combination of higher mean sea levels and seasonal tidal patterns. This research assessed the the climate resilience and adaptation initiatives in Hawaiʻi’s Resilience plans as they address coastal hazards. This research examined the robustness of resilience strategies to flooding due to climate change. This report focused on a community’s resilience to the physical impacts of climate change specifically on flood events and other environmental hazards that contribute …

An Evaluation Of Unmanned Aircraft System (Uas) As A Practical Tool For Salt Marsh Restoration Monitoring, San Francisco Bay, Ca, Kevin Eng

Master's Projects and Capstones

Salt marshes in the San Francisco Bay area provide essential ecosystem services from critical habitat to buffering coastal flooding and are the focus of substantial ecological restoration, necessitating improved restoration monitoring approaches. Metrics such as land cover classification, bare ground elevation, and vegetation height provide an understanding of the functionality and health of tidal wetlands. Unlike traditional monitoring methods, which rely on time and labor-intensive field surveys or macroscale remote sensing techniques, unmanned aircraft systems (UAS) provide site specific high spatial resolution data that is comparable to satellite and manned aircraft derived imagery. I compared published literature and provided primary …

Carbon Biogeochemical Cycling In The Sierra Nevada: How To Maintain The Sierra Nevada As Net Carbon Sink Over The Long-Term, Eric Canteenwala

Master's Projects and Capstones

The Sierra Nevada region is an important carbon sink, storing about 3500 MMTCO₂e or eight times the total amount of carbon emitted annually throughout California. However, recent climate-driven disturbances such as wildfires, drought and bark beetle infestations threaten the stability of this carbon pool over the long-term. The existing literature on how treatments impact carbon biogeochemical cycling in the Sierra Nevada was reviewed and interviews were used to identify the top barriers to increasing the pace and scale of treatments. Combinations of forest management treatments such as thinning, prescribed fire and reforestation can help maintain the Sierra Nevada …

Population Properties Of Compact Objects From The Second Ligo-Virgo Gravitational-Wave Transient Catalog, R. Abbott, T. D. Abbott, S. Abraham, F. Acernese, K. Ackley, A. Adams, C. Adams, R. X. Adhikari, V. B. Adya, C. Affeldt, M. Agathos, K. Agatsuma, N. Aggarwal, O. D. D. Aguiar, L. Aiello, A. Ain, P. Ajith, G. Allen, A. Allocca, Tiffany Z. Summerscales

Faculty Publications

We report on the population of 47 compact binary mergers detected with a false-alarm rate of (BBH) population not discernible until now. First, the primary mass spectrum contains structure beyond a power law with a sharp high-mass cutoff; it is more consistent with a broken power law with a break at 39.7-+9.120.3 M? or a power law with a Gaussian feature peaking at 33.1-+5.64.0 M? (90% credible interval). While the primary mass distribution must extend to ~65 M? or beyond, only 2.9-+1.73.5% of systems have primary masses greater than 45 M?. Second, we find that a fraction of BBH systems …

Photoemission Electron Microscopy For Direct Observation Of Photonic And Plasmonic Phenomena, Theodore Stenmark

Dissertations and Theses

Photoemission electron microscopy (PEEM) is a high-resolution microscopy technique that collects photoemitted electrons from the sample surface to form an image. PEEM offers a non-scanning imaging method with a spatial resolution in the range of 5-100nm by combining the advantages of light excitation and electron imaging. Our work looks at PEEM as an analysis tool for photonic and plasmonic phenomena. Photonic wave guiding structures exhibiting a strong dispersion relation have attracted considerable attention for applications in integrated optics, communications and sensing devices. Line defects in a photonic crystal (PC) slab offer a highly efficient way to create light with group …