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Articles 67411 - 67440 of 302622

Full-Text Articles in Physical Sciences and Mathematics

Impulse Effect On The Food-Limited Population Model With Piecewise Constant Argument, Fatma Karakoç Dec 2020

Impulse Effect On The Food-Limited Population Model With Piecewise Constant Argument, Fatma Karakoç

Applications and Applied Mathematics: An International Journal (AAM)

The qualitative study of mathematical models is an important area in applied mathematics. In this paper, a version of the food-limited population model with piecewise constant argument under impulse effect is investigated. Differential equations with piecewise constant arguments are related to difference equations. First, a representation for the solutions of the food-limited population model is stated in terms of the solutions of corresponding difference equation. Then using linearized oscillation theory for difference equations, a sufficient condition for the oscillation of the solutions about positive equilibrium point is obtained. Moreover, asymptotic behavior of the non-oscillatory solutions are investigated. Later, applying the …


Multilayer Security Of Rgb Image In Discrete Hartley Domain, Umar H. Mir, Deep Singh, D. C. Mishra, Parveiz N. Lone Dec 2020

Multilayer Security Of Rgb Image In Discrete Hartley Domain, Umar H. Mir, Deep Singh, D. C. Mishra, Parveiz N. Lone

Applications and Applied Mathematics: An International Journal (AAM)

In this article, we present RGB image encryption and decryption using random matrix affine cipher (RMAC) associated with discrete Hartley transform (DHT) and random matrix shift cipher (RMSC). The parameters in RMAC and RMSC phases act as two series of secret keys whose arrangement is imperative in the proposed algorithm. The computer simulations with results and examples are given to analyze the efficiency of the proposed approach. Further, security analysis and comparison with the prior techniques successfully supports the robustness and validation of the proposed technique.


Estimating The Age And Mechanism Of Boulder Transport Related With Extreme Waves Using Lichenometry, Maria A. Oliveira, Esteve Llop, César Andrade, Cristina Branquinho, Ronald Goble, Sónia Queiroz, Maria C. Freitas, Pedro Pinho Dec 2020

Estimating The Age And Mechanism Of Boulder Transport Related With Extreme Waves Using Lichenometry, Maria A. Oliveira, Esteve Llop, César Andrade, Cristina Branquinho, Ronald Goble, Sónia Queiroz, Maria C. Freitas, Pedro Pinho

Department of Earth and Atmospheric Sciences: Faculty Publications

Tsunamis and storms cause considerable coastal flooding, numerous fatalities, destruction of structures, and erosion. The characterization of energy and frequency associated with each wave contribute to the risk assessment in coastal regions. Coastal boulder deposits represent a physical proof of extreme inundation and allow us to study the effects of marine floods further back in time than instrumental and historical records. Age estimation of these deposits is challenging due to lack of materials (such as sand, shells, corals, or organic matter) that retain information about the passage of time. Lichenometry, a simple age estimation method, which is cost effective, quick …


Quantum Oscillations From Networked Topological Interfaces In A Weyl Semimetal, I. Lin Liu, Colin Heikes, Taner Yildirim, Chris Eckberg, Tristin Metz, Hyunsoo Kim, Sheng Ran, William D. Ratcliff, Johnpierre Paglione, For Full List Of Authors, See Publisher's Website. Dec 2020

Quantum Oscillations From Networked Topological Interfaces In A Weyl Semimetal, I. Lin Liu, Colin Heikes, Taner Yildirim, Chris Eckberg, Tristin Metz, Hyunsoo Kim, Sheng Ran, William D. Ratcliff, Johnpierre Paglione, For Full List Of Authors, See Publisher's Website.

Physics Faculty Research & Creative Works

Layered transition metal chalcogenides are promising hosts of electronic Weyl nodes and topological superconductivity. MoTe2 is a striking example that harbors both noncentrosymmetric Td and centrosymmetric T' phases, both of which have been identified as topologically nontrivial. Applied pressure tunes the structural transition separating these phases to zero temperature, stabilizing a mixed Td–T' matrix that entails a network of interfaces between the two nontrivial topological phases. Here, we show that this critical pressure range is characterized by distinct coherent quantum oscillations, indicating that the difference in topology between topologically nonvtrivial Td and T' phases gives …


Uganda As A Role Model For Pandemic Containment In Africa, Ahmed M. Sarki, Alex Ezeh, Saverio Stranges Dec 2020

Uganda As A Role Model For Pandemic Containment In Africa, Ahmed M. Sarki, Alex Ezeh, Saverio Stranges

Epidemiology and Biostatistics Publications

No abstract provided.


The Impact Of The Diabetes Management Incentive On Diabetes-Related Services: Evidence From Ontario, Canada., Thaksha Thavam, Rose Anne Devlin, Amardeep Thind, Gregory S Zaric, Sisira Sarma Dec 2020

The Impact Of The Diabetes Management Incentive On Diabetes-Related Services: Evidence From Ontario, Canada., Thaksha Thavam, Rose Anne Devlin, Amardeep Thind, Gregory S Zaric, Sisira Sarma

Epidemiology and Biostatistics Publications

Financial incentives have been introduced in several countries to improve diabetes management. In Ontario, the most populous province in Canada, a Diabetes Management Incentive (DMI) was introduced to family physicians practicing in patient enrollment models in 2006. This paper examines the impact of the DMI on diabetes-related services provided to individuals with diabetes in Ontario. Longitudinal health administrative data were obtained for adults diagnosed with diabetes and their family physicians. The study population consisted of two groups: DMI group (patients enrolled with a family physician exposed to DMI for 3 years), and comparison group (patients affiliated with a family physician …


Participatory Video As A Novel Recovery-Oriented Intervention In Early Psychosis: A Pilot Study., Arlene G Macdougall, Sahana Kukan, Elizabeth Price, Sarah Glen, Richelle Bird, Laura Powe, Joshua C. Wiener, Paul H Lysaker, Kelly K Anderson, Ross Mg Norman Dec 2020

Participatory Video As A Novel Recovery-Oriented Intervention In Early Psychosis: A Pilot Study., Arlene G Macdougall, Sahana Kukan, Elizabeth Price, Sarah Glen, Richelle Bird, Laura Powe, Joshua C. Wiener, Paul H Lysaker, Kelly K Anderson, Ross Mg Norman

Epidemiology and Biostatistics Publications

BACKGROUND: Personal narrative plays an important role in the process of recovery from psychotic illnesses. Participatory video is a novel, active intervention that can be used as a tool for fostering narrative development among people with psychosis.

AIM: To assess the feasibility, acceptability and potential clinical utility of participatory video as an innovative tool for promoting recovery in early psychosis.

METHODS: Ten outpatients of an early psychosis intervention programme were recruited to participate in 13 biweekly workshops to plan, film and produce documentary-style videos of their experiences. Feasibility was measured through recruitment and retention. Acceptability was measured through workshop attendance …


The Carmenes Search For Exoplanets Around M Dwarfs: Lp 714-47 B (Toi 442.01): Populating The Neptune Desert, S. Dreizler, I. J. M. Crossfield, D. Kossakowski, P. Plavchan, S. V. Jeffers, J. Kemmer, R. Luque, N. Espinoza, E. Pallé, K. Stassun, E. Matthews, B. Cale, J. A. Caballero, M. Schlecker, J. Lillo-Box, M. Zechmeister, S. Lalitha, A. Reiners, A. Soubkiou, B. Bitsch, M. R. Zapatero Osorio, P. Chaturvedi, A. P. Hatzes, G. Ricker, R. Vaderspek, D. W. Latham, S. Seager, J. Winn, J. M. Jenkins, J. Aceituno, P. J. Amado, K. Barkaoui, M. Barbieri, N. M. Batalha, F. F. Bauer, B. Benneke, Z. Benkhaldoun, C. Beichman, J. Berberian, J. Burt, R. P. Butler, D. A. Caldwell, A. Chintada, A. Chontos, J. L. Christiansen, D. R. Ciardi, C. Cifuentes, K. A. Collins, K. I. Collins, D. Combs, M. Cortés-Contreras, J. D. Crane, T. Daylan, D. Dragomir, E. Esparza-Borges, P. Evans, F. Feng, E. E. Flowers, A. Fukui, B. Fulton, E. Furlan, E. Gaidos, C. Geneser, S. Giacalone, M. Gillon, E. Gonzales, V. Gorjian, C. Hellier, D. Hidalgo, A. W. Howard, S. Howell, D. Huber, H. Isaacson, E. Jehin, Eric L.N. Jensen, A. Kaminski, S. R. Kane, K. Kawauchi, J. F. Kielkopf, H. Klahr, M. R. Kosiarek, L. Kreidberg, M. Kürster, M. Lafarga, J. Livingston, D. Louie, A. Mann, A. Madrigal-Aguado, R. A. Matson, T. Mocnik, J. C. Morales, P. S. Muirhead, F. Murgas, S. Nandakumar, N. Narita, G. Nowak, M. Oshagh, P. Parviainen, V. M. Passegger, D. Pollacco, F. J. Pozuelos, A. Quirrenbach, M. Reefe, I. Ribas, P. Robertson, C. Rodríguez-López, M. E. Rose, A. Roy, A. Schweitzer, J. Schlieder, S. Shectman, A. Tanner, H. V. Şenavci, J. Teske, J. D. Twicken, J. Villasenor, S. X. Wang, L. M. Weiss, J. Wittrock, M. Yilmaz, F. Zohrabi Dec 2020

The Carmenes Search For Exoplanets Around M Dwarfs: Lp 714-47 B (Toi 442.01): Populating The Neptune Desert, S. Dreizler, I. J. M. Crossfield, D. Kossakowski, P. Plavchan, S. V. Jeffers, J. Kemmer, R. Luque, N. Espinoza, E. Pallé, K. Stassun, E. Matthews, B. Cale, J. A. Caballero, M. Schlecker, J. Lillo-Box, M. Zechmeister, S. Lalitha, A. Reiners, A. Soubkiou, B. Bitsch, M. R. Zapatero Osorio, P. Chaturvedi, A. P. Hatzes, G. Ricker, R. Vaderspek, D. W. Latham, S. Seager, J. Winn, J. M. Jenkins, J. Aceituno, P. J. Amado, K. Barkaoui, M. Barbieri, N. M. Batalha, F. F. Bauer, B. Benneke, Z. Benkhaldoun, C. Beichman, J. Berberian, J. Burt, R. P. Butler, D. A. Caldwell, A. Chintada, A. Chontos, J. L. Christiansen, D. R. Ciardi, C. Cifuentes, K. A. Collins, K. I. Collins, D. Combs, M. Cortés-Contreras, J. D. Crane, T. Daylan, D. Dragomir, E. Esparza-Borges, P. Evans, F. Feng, E. E. Flowers, A. Fukui, B. Fulton, E. Furlan, E. Gaidos, C. Geneser, S. Giacalone, M. Gillon, E. Gonzales, V. Gorjian, C. Hellier, D. Hidalgo, A. W. Howard, S. Howell, D. Huber, H. Isaacson, E. Jehin, Eric L.N. Jensen, A. Kaminski, S. R. Kane, K. Kawauchi, J. F. Kielkopf, H. Klahr, M. R. Kosiarek, L. Kreidberg, M. Kürster, M. Lafarga, J. Livingston, D. Louie, A. Mann, A. Madrigal-Aguado, R. A. Matson, T. Mocnik, J. C. Morales, P. S. Muirhead, F. Murgas, S. Nandakumar, N. Narita, G. Nowak, M. Oshagh, P. Parviainen, V. M. Passegger, D. Pollacco, F. J. Pozuelos, A. Quirrenbach, M. Reefe, I. Ribas, P. Robertson, C. Rodríguez-López, M. E. Rose, A. Roy, A. Schweitzer, J. Schlieder, S. Shectman, A. Tanner, H. V. Şenavci, J. Teske, J. D. Twicken, J. Villasenor, S. X. Wang, L. M. Weiss, J. Wittrock, M. Yilmaz, F. Zohrabi

Physics & Astronomy Faculty Works

We report the discovery of a Neptune-like planet (LP 714-47 b, P = 4.05204 d, mb = 30.8 ± 1.5M⊕, Rb = 4.7 ± 0.3 R⊕) located in the “hot Neptune desert”. Confirmation of the TESS Object of Interest (TOI 442.01) was achieved with radial-velocity follow-up using CARMENES, ESPRESSO, HIRES, iSHELL, and PFS, as well as from photometric data using TESS, Spitzer, and ground-based photometry from MuSCAT2, TRAPPIST-South, MONET-South, the George Mason University telescope, the Las Cumbres Observatory Global Telescope network, the El Sauce telescope, the TÜBİTAK National Observatory, the University of Louisville Manner Telescope, and WASP-South. We also present …


Deep Learning-Based Reconstruction Of Volumetric Ct Images Of Vertebrae From A Single View X-Ray Image, Mingren Xiang Dec 2020

Deep Learning-Based Reconstruction Of Volumetric Ct Images Of Vertebrae From A Single View X-Ray Image, Mingren Xiang

Theses and Dissertations

Computed tomography is often used in medical fields today because it creates more detailed information for doctors than regular X-ray images. However, one major side effect is that patients may be exposed to a large dose of radiation because it takes hundreds of X-ray images to compute a CT scan. Another shortcoming is that patients are required to lay down on the CT machine for the scan, which is usually not the ideal position when diagnosing spine related issues such as cervical spondylosis and lumbar disc herniation. The prime motivation for this study is to reconstruct CT images using only …


Progression Magazine, 2020 Winter, Coastal Carolina University Dec 2020

Progression Magazine, 2020 Winter, Coastal Carolina University

Progression Magazine

Magazine of the College of Science at Coastal Carolina University.


Lightgwas: A Novel Machine Learning Procedure For Genome-Wide Association Study, Ambrozio Bruno, Luca Longo, Lucas Rizzo Dec 2020

Lightgwas: A Novel Machine Learning Procedure For Genome-Wide Association Study, Ambrozio Bruno, Luca Longo, Lucas Rizzo

Articles

This paper proposes a novel machine learning procedure for genome-wide association study (GWAS), named LightGWAS. It is based on the LightGBM framework, in addition to being a single, resilient, autonomous and scalable solution to address common limitations of GWAS implementations found in the literature. These include reliance on massive manual quality control steps and specific GWAS methods for each type of dataset morphology and size. Through this research, LightGWAS has been contrasted against PLINK2, one of the current state-of-the-art for GWAS implementations based on general linear model with support to firth regularisation. The mean differences measured upon standard classification metrics, …


A Comparative Analysis Of Rule-Based, Model-Agnostic Methods For Explainable Artificial Intelligence, Giulia Vilone, Lucas Rizzo, Luca Longo Dec 2020

A Comparative Analysis Of Rule-Based, Model-Agnostic Methods For Explainable Artificial Intelligence, Giulia Vilone, Lucas Rizzo, Luca Longo

Articles

The ultimate goal of Explainable Artificial Intelligence is to build models that possess both high accuracy and degree of explainability. Understanding the inferences of such models can be seen as a process that discloses the relationships between their input and output. These relationships can be represented as a set of inference rules which are usually not explicit within a model. Scholars have proposed several methods for extracting rules from data-driven machine-learned models. However, limited work exists on their comparison. This study proposes a novel comparative approach to evaluate and compare the rulesets produced by four post-hoc rule extractors by employing …


Nato And The Ifrc: A Comparative Case Study, Abigail Kosiak Dec 2020

Nato And The Ifrc: A Comparative Case Study, Abigail Kosiak

Undergraduate Honors Capstone Projects

This research analyzes the North Atlantic Treaty Organization's (NATO) Multinational Telemedicine System (MnTS) Project and works to answer five main questions:

1) What challenges did the NATO MnTS Project face that are directly related to the fact that the project included members from different countries and worked to create a system that operates across national borders?

2) How do these challenges compare to those faced by a non-governmental organization (NGO) like the International Federation of the Red Cross and Red Crescent Societies (IFRC)?

3) What successes has the IFRC had with its current operational model?

4) In what ways could …


Tuning Magnetic Confinement Of Spin-Triplet Superconductivity, Wen Chen Lin, Daniel J. Campbell, Sheng Ran, I. Lin Liu, Hyunsoo Kim, Andriy H. Nevidomskyy, David Graf, Nicholas P. Butch, Johnpierre Paglione Dec 2020

Tuning Magnetic Confinement Of Spin-Triplet Superconductivity, Wen Chen Lin, Daniel J. Campbell, Sheng Ran, I. Lin Liu, Hyunsoo Kim, Andriy H. Nevidomskyy, David Graf, Nicholas P. Butch, Johnpierre Paglione

Physics Faculty Research & Creative Works

Electrical magnetoresistance and tunnel diode oscillator measurements were performed under external magnetic fields up to 41 T applied along the crystallographic b axis (hard axis) of UTe2 as a function of temperature and applied pressures up to 18.8 kbar. In this work, we track the field-induced first-order transition between superconducting and magnetic field-polarized phases as a function of applied pressure, showing suppression of the transition with increasing pressure until the demise of superconductivity near 16 kbar and the appearance of a pressure-induced ferromagnetic-like ground state that is distinct from the field-polarized phase and stable at zero field. Together with …


New Method For Beyond The Standard Model Invisible Particle Searches In Tau Lepton Decays, E. De La Cruz-Burelo, A. De Yta-Hernandez, M. Hernandez-Villanueva Dec 2020

New Method For Beyond The Standard Model Invisible Particle Searches In Tau Lepton Decays, E. De La Cruz-Burelo, A. De Yta-Hernandez, M. Hernandez-Villanueva

Faculty and Student Publications

Motivated by models proposed to explain Standard Model anomalies, and the unprecedented τ+τ- data to be collected by the Belle II experiment during the next years, we study the kinematics of tau pair decays and propose a new method to search for lepton flavor violating processes in tau lepton decays to invisible beyond Standard Model particles, such as τ→ℓα, where ℓ is either an electron or a muon, and α is a massive particle that escapes undetected. The new method improves by one order of magnitude the expected upper limit on the τ→ℓα production in 3×1 prong tau decays and …


College Of Natural Sciences 2020 Year-End Publication, College Of Natural Sciences Dec 2020

College Of Natural Sciences 2020 Year-End Publication, College Of Natural Sciences

College of Natural Sciences Newsletters and Reports

This is the inaugural issue of the College of Natural Sciences' year-end publication.

Contents:

[Page] 4 COVID-19 Response
[Page] 6 Student Success
[Page] 8 Faculty Excellence
[Page] 10 Awards and Recognition


Contrasting Hydrodynamic Responses To Atmospheric Systems With Different Scales: Impact Of Cold Fronts Vs. That Of A Hurricane, Wei Huang, C. Li Dec 2020

Contrasting Hydrodynamic Responses To Atmospheric Systems With Different Scales: Impact Of Cold Fronts Vs. That Of A Hurricane, Wei Huang, C. Li

VIMS Articles

In this paper, subtidal responses of Barataria Bay to an atmospheric cold front in 2014 and Hurricane Barry of 2019 are studied. The cold fronts had shorter influencing periods (1 to 3 days), while Hurricane Barry had a much longer influencing period (about 1 week). Wind direction usually changes from southern quadrants to northern quadrants before and after a cold front’s passage. For a hurricane making its landfall at the norther Gulf of Mexico coast, wind variation is dependent on the location relative to the location of landfall. Consequently, water level usually reaches a trough after the maximum cold front …


Unifying Chemistry And Machine Learning For The Study Of Noncovalent Interactions, Jacob A. Townsend Dec 2020

Unifying Chemistry And Machine Learning For The Study Of Noncovalent Interactions, Jacob A. Townsend

Doctoral Dissertations

Gas separations are in great demand for carbon emission reduction, natural gas purification, oxygen isolation, and much more. Many of these separations rely on cost-prohibitive methods such as cryogenic distillation or strong-binding solvents. As a result, novel materials are being developed to subvert the energetic expense of gas separation processes. These studies focus on improving the performance of alternative materials, including (but not limited to) metal-organic frameworks, covalent organic frameworks, dense polymeric membranes, porous polymers, and ionic liquids.

In this work, the atomistic effects of functional units are explored for gas separations processes using electronic structure theory and machine learning. …


Modeling User-Affected Software Properties For Open Source Software Supply Chains, Tapajit Dey Dec 2020

Modeling User-Affected Software Properties For Open Source Software Supply Chains, Tapajit Dey

Doctoral Dissertations

Background: Open Source Software development community relies heavily on users of the software and contributors outside of the core developers to produce top-quality software and provide long-term support. However, the relationship between a software and its contributors in terms of exactly how they are related through dependencies and how the users of a software affect many of its properties are not very well understood.

Aim: My research covers a number of aspects related to answering the overarching question of modeling the software properties affected by users and the supply chain structure of software ecosystems, viz. 1) Understanding how software usage …


Using Second Harmonic Generation To Study Gram-Positive Bacterial Membranes, Lindsey N. Miller Dec 2020

Using Second Harmonic Generation To Study Gram-Positive Bacterial Membranes, Lindsey N. Miller

Doctoral Dissertations

Understanding how small-molecules, such as drugs, interact with bacterial membranes can quickly unravel into much more perplexing questions. No two bacterial species are alike, especially when comparing their membrane compositions which can even be altered by incorporating fatty acids from their surrounding environment into their lipid-membrane composition. To further complicate the comparison, discrete alterations in small-molecule structures can result in vastly different membrane-interaction outcomes, giving rise to the need for more "label-free" studies when analyzing drug mechanisms. The work presented in this dissertation highlights the benefits to using nonlinear spectroscopy and microscopy techniques for probing small-molecule interactions in living bacteria. …


Intelligent Therapeutic Robot: Design, Development, And Control, Asif Al Zubayer Swapnil Dec 2020

Intelligent Therapeutic Robot: Design, Development, And Control, Asif Al Zubayer Swapnil

Theses and Dissertations

This research contributes to developing an Intelligent Therapeutic Robot (iTbot) designed to provide therapy to patients with upper limb impairment due to stroke, injury, and other trauma. This robot aims to implement robotic rehabilitation based on principles of motor rehabilitation and Neuroplasticity. The iTbot, as developed in this research, can provide end-effector type rehabilitation exercises in various configurations, including motion in the vertical and horizontal plane. It can provide passive, active, and active-assisted rehabilitation therapies to patients with limited upper limb mobility.

The iTbot has been designed with simplicity in mind with a minimum viability approach. With a minimum amount …


The Importance Of Frontier Orbital Symmetry In The Adsorption Of Diiodobenzene On Mos2(0001), Prescott E. Evans, Zahra Hooshmand, Talat S. Rahman, Peter Dowben Dec 2020

The Importance Of Frontier Orbital Symmetry In The Adsorption Of Diiodobenzene On Mos2(0001), Prescott E. Evans, Zahra Hooshmand, Talat S. Rahman, Peter Dowben

Peter Dowben Publications

Evidence of a role of frontier orbital symmetry, in the adsorption process of diiodobenzene on MoS2(0001), appears in the huge differences in the rate of adsorption between 1,3-diiodobenzene, 1,2-diiodobenzene and 1,4-diiodobenzene isomers on MoS2. Experiments indicate that the rate of adsorption of 1,3-diiodobenzene on MoS2(0001) is much greater than that of the 1,2-diodobenzene and 1,4-diiodbenzene isomers. As the differences in calculated diiodobenzene isomer-MoS2 system adsorption energies and electron affinities are negligible, frontier orbital symmetry appears to play a significant role in diiodobenzene adsorption on MoS2(0001). The experimental and theory results, in combination, suggest …


Macromolecular Structure Determination At X-Ray Free Electron Lasers From Single-Particle Imaging To Time-Resolved X-Ray Crystallography, Ishwor Poudyal Dec 2020

Macromolecular Structure Determination At X-Ray Free Electron Lasers From Single-Particle Imaging To Time-Resolved X-Ray Crystallography, Ishwor Poudyal

Theses and Dissertations

X-ray free-electron lasers (XFELs) open the possibility of obtaining diffraction information from a single biological macromolecule. This is because XFELs can generate extremely intense X-ray pulses which are so short that diffraction data can be collected before the sample is destroyed. By collecting a sufficient number of single-particle diffraction patterns from many tilts of a molecule relative to the X-ray beam, the three-dimensional electron density can be reconstructed ab-initio. The resolution and therefore the information content of the data will ultimately depend largely on the number of patterns collected at the experiment. We estimate the number of diffraction patterns required …


On The Plastic-Free Path: Plastic-Free Living, Hannah Natzke Dec 2020

On The Plastic-Free Path: Plastic-Free Living, Hannah Natzke

Honors Projects

What is living plastic-free like? This project explores the trials and triumphs of living a plastic-free life. Although this project is only mandates that the participant lives plastic-free for a month, it still investigates the challenges faced by longer plastic-free living.


The Prairie Naturalist, Vol. 52, Issue 2, December 2020 Dec 2020

The Prairie Naturalist, Vol. 52, Issue 2, December 2020

The Prairie Naturalist

Comparing Native Bee Communities on Reconstructed and Remnant Prairie in Missouri • Joseph LaRose, Elisabeth B. Webb, and Deborah Finke

Patterns and Potential Causes of Changing Winter Bird Distributions in South Dakota • David L. Swanson, Reza Goljani Amipkhiz, and Mark D. Dixon

Greater prairie-chickens and sharp-tailed grouse have similarly high nest survival in the Nebraska Sandhills • Larkin A. Powell, Walter H. Schacht, Julia P. Ewalt, and Katie R. McCollum

Captive Ring-necked Pheasant Response to Very High Experimental Doses of Lead • Travis J. Runia and Alex J. Solem

Trends in a Greater Prairie Chicken Population Established by Translocation …


Total Synthesis Of Cytotoxic Mansouramycins From Amino Acids, Beatriz Gamez Dec 2020

Total Synthesis Of Cytotoxic Mansouramycins From Amino Acids, Beatriz Gamez

Theses and Dissertations

Natural products produced by plants, animals, and microorganisms are of significant importance in chemistry for being major sources of molecular scaffolds essential for new drug discovery. Mansouramycins are cytotoxic bioactive compounds containing isoquinoline skeletons with substituents on the quinone and pyridine rings that may be difficult to synthesize. Synthetic processes exist for compounds B and D, however, there exists an absence of simple synthetic approaches to all four alkaloids.

This project aims to provide a general total synthetic pathway to Mansouramycins A—D from amino acids for possible use in cancer treatment via these isoquinolinequinones. Preliminary experimentation suggests there may be …


The Dmap-Catalyzed Acylation Of Alcohol -- A Mechanistic Study, Tania Veronica Alvarez Castro Dec 2020

The Dmap-Catalyzed Acylation Of Alcohol -- A Mechanistic Study, Tania Veronica Alvarez Castro

Theses and Dissertations

The mechanistic studies of Acylation of Alcohols catalyzed by 4-(N,N- Dimethyl-amino)-pyridine (DMAP) has been heavily studied in the literature. This reaction has attracted considerable interest from the synthetic and mechanistic points of view in recent years. In this research, the acylation of alcohols is prepared from cyclohexanol and acetic anhydride that is catalyzed by DMAP using triethyl amine (NEt3) as the auxiliary base and dichloromethane (DCM) as solvent. The reaction and final product will be analyzed by using gas chromatography (GC) and reaction progress kinetic analysis (RPKA). The mechanistic insights obtained in the present study should be useful for understanding …


Synthesis, Characterization, And Application Of Meso-Tetraphenyl Metalloporphyrin Photocatalysts Under Visible Light, Alexis Echavarria Dec 2020

Synthesis, Characterization, And Application Of Meso-Tetraphenyl Metalloporphyrin Photocatalysts Under Visible Light, Alexis Echavarria

Theses and Dissertations

The photocatalytic activity of meso-Tetraphenyl Metalloporphyrins with different metal centers was investigated. The synthesized metalloporphyrin photocatalysts was performed and analyzed using FT-IR spectroscopy, UV-VIS spectroscopy, and powder X-Ray Diffraction analysis. The synthesized TPP crystals were determined to be tetragonal crystal structure and the structure was observed in all synthesized metalloporphyrin catalysts. The Soret (B) bands, Q bands, FT-IR functional groups were identified. Reaction progress was investigated by sampling at intervals of one hour and analysis of the samples was performed using Gas Chromatography-Mass Spectrometry. GC-MS analysis was used to identify the products of the photochemical catalytic redox reactions performed under …


Reinforcement Learning Environment For Orbital Station-Keeping, Armando Herrera Iii Dec 2020

Reinforcement Learning Environment For Orbital Station-Keeping, Armando Herrera Iii

Theses and Dissertations

In this thesis, a Reinforcement Learning Environment for orbital station-keeping is created and tested against one of the most used Reinforcement Learning algorithm called Proximal Policy Optimization (PPO). This thesis also explores the foundations of Reinforcement Learning, from the taxonomy to a description of PPO, and shows a thorough explanation of the physics required to make the RL environment. Optuna optimizes PPO's hyper-parameters for the created environment via distributed computing. This thesis then shows and analysis the results from training a PPO agent six times.


On Coupled Reaction Diffusion Equations And Their Applications, Juan J. Huerta Dec 2020

On Coupled Reaction Diffusion Equations And Their Applications, Juan J. Huerta

Theses and Dissertations

Reaction-diffusion equations are nonlinear partial differential equations that have been used extensively in mathematical modeling. An interesting case in this type of equation is the Fisher-Kolmogorov system, which has been used to study a low-grade glioma, a group of primary brain tumors. In the first part of this thesis, a stochastic version of the Fisher-Kolmogorov system will be studied, and exact and numerical solutions will be presented.

The second part of this thesis will show how the speed of information propagation affects disease spread and vaccination uptake through networks in epidemics. In this model, the information reaches different people at …