Physical Sciences and Mathematics Commons^™

Advanced General Chemistry, Alexandra E. Strom

Open Educational Resources: Textbooks

Textbook adapted for CHM 118 at Smith College:

This course is for students with a very strong background in chemistry. The elementary theories of stoichiometry, atomic structure, bonding, structure, energetics and reactions are quickly reviewed. The major portions of the course involve a detailed analysis of atomic theory and bonding from an orbital concept, an examination of the concepts behind thermodynamic arguments in chemical systems, and an investigation of chemical reactions and kinetics. The laboratory deals with synthesis, physical properties and kinetics.

Mixed Quantum/Classical Calculations Of Rotationally Inelastic Scattering In The Co + Co System: A Comparison With Fully Quantum Results, Dulat Bostan, Bikramaditya Mandal, Carolin Joy, Michał Żółtowski, François Lique, Jérôme Loreau, Ernesto Quintas-Sánchez, Adrian Batista-Planas, Richard Dawes, Dmitri Babikov

Chemistry Faculty Research and Publications

An updated version of the CO + CO potential energy surface from [R. Dawes, X. G. Wang and T. Carrington, J. Phys. Chem. A 2013, 117, 7612] is presented, that incorporates an improved treatment of the asymptotic behavior. It is found that this new surface is only slightly different from the other popular PES available for this system in the literature [G. W. M. Vissers, P. E. S. Wormer and A. Van Der Avoird, Phys. Chem. Chem. Phys. 2003, 5, 4767]. The differences are quantified by expanding both surfaces over a set of analytic functions and comparing the behavior of …

Nanoscale Studies Of Magnesium Carbonate Precipitation At Ambient Conditions, Ian Shortt

Material Science and Engineering Dissertations

Currently approximately 8% of global greenhouse gas emissions can be attributed to the construction industry; of these emissions, a little over half of these emissions are due to the production of traditional calcium-based cements. Magnesium carbonate cements present a promising alternative to traditional calcium-based cements, both in terms of emission reductions and in terms of strength. The primary drawback to magnesium carbonate cements is that ambient curing is not yet viable. The objective of this dissertation is to therefore develop greater understanding of the precipitation pathways undertaken by hydrated magnesium carbonates under near-ambient conditions. In the first section of this …

Season Influences Interspecific Responses Of Canopy-Forming Kelps To Future Warming And Acidification At High Latitude, Lauren E. Bell, Lily Westphal, Evan O' Brien, Jason A. Toy, Haleigh Damron, Kristy J. Kroeker

Biological Sciences Faculty Publications

Variability in primary producers' responses to environmental change may buffer higher trophic levels against shifts in basal resource composition. Then again, in instances where there is a lack of functional redundancy because consumers rely on a few species to meet their energetic requirements at specific times of the year, altered community production dynamics may significantly impact food web resilience. In high-latitude kelp forests, a complementary annual phenology of seaweed production supports coastal marine consumers' metabolic needs across large seasonal variations in their environment. Yet, marine consumers in these systems may face significant metabolic stress under the pronounced low pH conditions …

Extending Natural Mates In Euclidean 3-Space And Applications To Bertrand Pairs, Yun Myung Oh, Alexander Navarro

Faculty Publications

In Euclidean 3-space, a family of curves, the co-successor, is motivated and then introduced in relation to the natural mate. A complete characterization of co-successors is proved, followed by an application of the co-successor towards describing Bertrand curves and their mates.

Role Of Relative Humidity In New Particle Formation From Ozonlysis Of Atmospheric Volatile Organic Compounds, Christopher Snyder

Graduate College Dissertations and Theses

The impact of relative humidity (RH) on organic new particle formation (NPF) from ozonolysis of biogenic volatile organic compounds (BVOCs) remains an area of active debate. Previous reports provide contradictory results indicating both depression and enhancement of NPF under conditions of moderate RH, while others ignore the potential impact. Only several reports have suggested that the effect may depend on absolute mixing ratio of the precursor volatile organic compound (VOC, ppbv). However, before any experiments could be completed, development of new methods was necessary to overcome the limitation of sampling ultrafine nanoparticles (<50 nm aerodynamic diameter) with aerosol mass spectrometry. This dissertation includes a report on a new Particle Growth Apparatus (PaGA) that artificially grows particles from as small as 17 nm to over 110nm. Considerable effort was made to identify the most suitable growth matrix (squalane) and optimize particle growth for reproducibility and sensitivity.

The PaGA was then utilized in the …

A Gis Tool For Optimal Forage Species Selection, David B. Hannaway, Christopher Daly, Michael D. Halbleib, Linda Brewer, Sophie Baur, Chelsea Clark, Emilie Krecklow, Scott Bassett

IGC Proceedings (1993-2023)

To determine appropriate forage species for US ecoregions, geographic information technologies (GIS) are being used to create climatic and soil factor maps. Excel spreadsheets and RStudio are used to create response functions of forage species to minimum and maximum temperature, annual precipitation, soil pH, soil salinity, and salinity. National forage data and expert opinion will evaluate quantitative tolerances, seasonal yield profiles, and pollinator suitability. These maps and agronomic and livestock use information will be shared with forage specialists and farmers to provide alternatives for improved perenniality, increased diversity, and system circularity. Future work will include development and evaluation of climate …

Steklov Eigenvalue Problems On Nearly Spherical And Annular Domains, Nathan Philip Schroeder

CGU Theses & Dissertations

We consider Steklov eigenvalues on nearly spherical and nearly annular domains in d dimensions where d is any given positive integer. By using the Green-Beltrami identity for spherical harmonic functions, the derivatives of Steklov eigenvalues with respect to the domain perturbation parameter can be determined by the eigenvalues of a matrix involving the integral of the product of three spherical harmonic functions. By using the addition theorem for spherical harmonic functions, we determine conditions when the trace of this matrix becomes zero. These conditions can then be used to determine when spherical and annular regions are critical points while we …

Fluid-Rock And Fluid-Steel Interaction In Geothermal Energy Development In The Appalachain Basin, Samuel H. Bowman

Graduate Theses, Dissertations, and Problem Reports

The ever-increasing demand for clean energy requires creative solutions. In the United States, unconventional energy sources such as geothermal are conventionally limited to the western half of the country. The Appalachian Basin in the Eastern United States is one such possible creative solution, although the comparatively low temperature gradient presents a significant challenge to delivering economically feasible geothermal energy. An emerging technology is enhanced geothermal systems, these are engineered reservoirs where a working fluid (typically water) is cycled between the subsurface energy source and the energy collection facility at the surface. The liquid water interacts with the geothermal reservoir rock …

Synergetic Effects Of Democracy And Economic Development On Income Inequality And The Role Of Relative Political Capacity, Nazif Sali

CGU Theses & Dissertations

Diving into the complex dynamics of income inequality, this dissertation studies the multifaceted relationships between democracy, economic development, and inequality, placing a spotlight on the mediating influence of Relative Political Capacity (RPC). Uncovering the pivotal role of RPC as democracies advance and economies progress, this research navigates the contours of income inequality. By dissecting distinct sub-samples of OECD and non-OECD countries, nuanced insights surface. Employing robust methodologies such as ordinary least squares regressions and fixed effects analysis, I argue that targeted policies addressing inequality can not only foster inclusive economic growth but also fortify the foundations of democratic institutions. As …

Exploring Loss Functions In Machine Learning, Yujie Wang

CGU Theses & Dissertations

The loss function plays a critical role in machine learning. It is fundamental in training, evaluating, and optimizing machine learning models, directly impacting their effectiveness and efficiency in solving specific tasks. We explore three new loss functions and their applications. Softmax Cross-Entropy Loss, stands as a prevalent choice in neural network classification tasks. It treats all misclassifications uniformly. However, multi-class classification problems often have many semantically similar classes. We should expect that these semantically similar classes will have similar parameter vectors. We introduce a weighted loss function, the tree loss as a drop-in replacement for the cross entropy loss. The …

Artificial Intelligence And News Consumption: A Study Of Trust, Credibility And Transparency In Automated Journalism, Julia Lobo Paes

Dissertations and Theses

According to Gallup poll (2023), over the last 50 years there has been a decline in how much Americans trust mass media. While in the 1970’s 72% of the population responded that they trust the media a 'great deal/fair amount', this number dropped to 34% in 2023. Given the decreasing public trust in news, this thesis focused particularly on analyzing trust in the organization, trust in the news story and perceived credibility in AI generative content. In addition to articles created by AI, this study also aimed to analyze how the public perceives information that has been personalized and distributed …

Strategyproof Mechanisms For Group-Fair Obnoxious Facility Location Problems, Jiaqian Li, Minming Li, Hau Chan

School of Computing: Faculty Publications

We study the group-fair obnoxious facility location problems from the mechanism design perspective where agents belong to different groups and have private location preferences on the undesirable locations of the facility. Our main goal is to design strategyproof mechanisms that elicit the true location preferences from the agents and determine a facility location that approximately optimizes several group-fair objectives. We first consider the maximum total and average group cost (group-fair) objectives. For these objectives, we propose deterministic mechanisms that achieve 3-approximation ratios and provide matching lower bounds. We then provide the characterization of 2-candidate strategyproof randomized mechanisms. Leveraging the characterization, …

Altruism In Facility Location Problems, Houyu Zhou, Hau Chan, Minming Li

School of Computing: Faculty Publications

We study the facility location problems (FLPs) with altruistic agents who act to benefit others in their affiliated groups. Our aim is to design mechanisms that elicit true locations from the agents in different overlapping groups and place a facility to serve agents to approximately optimize a given objective based on agents’ costs to the facility. Existing studies of FLPs consider myopic agents who aim to minimize their own costs to the facility.We mainly consider altruistic agents with well-motivated group costs that are defined over costs incurred by all agents in their groups. Accordingly, we define Pareto strategyproofness to account …

Effects Of Voice Pitch On Social Perceptions Vary With Relational Mobility And Homicide Rate, Toe Aung, Et. Al

Research Collection School of Social Sciences

Fundamental frequency (fo) is the most perceptually salient vocal acoustic parameter, yet little is known about how its perceptual influence varies across societies. We examined how fo affects key social perceptions and how socioecological variables modulate these effects in 2,647 adult listeners sampled from 44 locations across 22 nations. Low male fo increased men’s perceptions of formidability and prestige, especially in societies with higher homicide rates and greater relational mobility in which male intrasexual competition may be more intense and rapid identification of highstatus competitors may be exigent. High female fo increased women’s perceptions of flirtatiousness where relational mobility was …

Environmental Attitudes Of Local Government Scholars In Tiaong, Quezon, Philippines, Justine A. Marasigan, Ma. Larissa Lelu P. Gata

Journal of Public Affairs and Development

This study aimed to analyze the environmental attitudes of local government scholars in Tiaong, Quezon, Philippines. The quantitative research design was used to determine the level of environmental attitudes using the New Ecological Paradigm (NEP) Scale. It was also utilized to examine the relationship between environmental attitudes and independent variables which include demographic characteristics such as age, gender, and economic status, academic background such as student classification, scholastic standing, scholarship privileges, and membership in student and/or youth organizations, and experience with ecological extremes. A total of 301 respondents participated in an online survey administered through Google Forms ®. The respondents …

Life Cycle Greenhouse Gas Emissions In Maize No-Till Agroecosystems In Southern Brazil Based On A Long-Term Experiment, Guilherme Rosa Da Silva, Adam J. Liska, Cimelio Bayer

Department of Biological Systems Engineering: Papers and Publications

Brazilian agriculture is constantly questioned concerning its environmental impacts, particularly greenhouse gas (GHG) emissions. This research study used data from a 34-year field experiment to estimate the life cycle GHG emissions intensity of maize production for grain in farming systems under no-tillage (NT) and conventional tillage (CT) combined with Gramineae (oat) and legume (vetch) cover crops in southern Brazil. We applied the Feedstock Carbon Intensity Calculator for modeling the “field-to-farm gate” emissions with measured annual soil N₂O and CH₄ emissions data. For net CO₂ emissions, increases in soil organic C (SOC) were applied as a proxy, …

Understanding Catalyst Design Principles In Transition Metal Mixed Anionic Chalcogenides For Electrocatalytic Energy Conversion, Ibrahim Abdullahi

Doctoral Dissertations

"This research focused on the synthetic design of transition metal mixed anionic chalcogenide catalysts containing various ligand types around the central metal atom (chalcogen anion and chalcogen-based organic ligand) generating diverse crystal structure types applied for water splitting and carbon dioxide reduction reactions (CO₂RR).

A series of catalysts were synthesized starting with isolated metal complexes (ME_n) with a central metal core (M = Co, Ni, Cu, and Cr) through molecular clusters, to bulk nanostructured solids of similar M-E coordination. Bis(dichalcogenoimidodiphosphinato) were employed as ligands in the metal complexes, and anionic chalcogen (E = S, Se, and …

Multiple Imputation For Robust Cluster Analysis To Address Missingness In Medical Data, Arnold Harder, Gayla R. Olbricht, Godwin Ekuma, Daniel B. Hier, Tayo Obafemi-Ajayi

Mathematics and Statistics Faculty Research & Creative Works

Cluster Analysis Has Been Applied To A Wide Range Of Problems As An Exploratory Tool To Enhance Knowledge Discovery. Clustering Aids Disease Subtyping, I.e. Identifying Homogeneous Patient Subgroups, In Medical Data. Missing Data Is A Common Problem In Medical Research And Could Bias Clustering Results If Not Properly Handled. Yet, Multiple Imputation Has Been Under-Utilized To Address Missingness, When Clustering Medical Data. Its Limited Integration In Clustering Of Medical Data, Despite The Known Advantages And Benefits Of Multiple Imputation, Could Be Attributed To Many Factors. This Includes Methodological Complexity, Difficulties In Pooling Results To Obtain A Consensus Clustering, Uncertainty Regarding …

Wetting Transition Of 3d-Printed Surface Features, Delia Weitzel

Williams Honors College, Honors Research Projects

This project aims to build on the previous research of prior students in the study of the wetting transition of a textured, 3D-printed surface. The surfaces studied will be constructed by a resin printer in the lab and will be composed of an array of uniform, microscopic pillars. Features of the textured surface, such as pillar diameter, pillar spacing, and pillar height, will be varied to study the impact on the wetting transition of water, oil, and a combination of water and oil. The wetting transition is defined as a transition from a state where the surface cavities are occupied …

Determination Of Spore Viability In Concrete Across Several Factors Using Most Probable Number, Samuel Boyer

Williams Honors College, Honors Research Projects

To determine the lowest concentration of spore added to polyurethane-cement composite (PUCCO) particles that can still germinate after curing in concrete. This research project is a small addition to the larger research project being undertaken by Mirza Mohammed Rashiduzzaman for his Masters. The larger project involves the use of fungal spores added in concrete to act as a self-healing component when cracks form in the concrete structure over time. These spores are suspended in a protective oil and loaded into small, hardened sponge-like PUCCO cubes to act as growth points when water and air can reach the PUCCO in the …

Corrosion Inhibitors: Mitigating The Degradation Of Rebar, Jake R. Hughes

Williams Honors College, Honors Research Projects

Our conjecture was twofold: first, that two compounds historically used as food preservatives could act as environmentally friendly inhibitors against rebar corrosion, and second, that molecular properties have a quantifiable influence on inhibition efficiency (%IE). To evaluate the two compounds, cyclic potentiodynamic polarization was used to determine corrosion current density (i_corr) and %IE. The “green” inhibitor candidates included sodium metabisulfite and ascorbic acid, which yielded maximum %IE values of -123900% and 91%, respectively. Results indicated that sodium metabisulfite is not a suitable inhibitor, while ascorbic acid showed potential to extend reinforced concrete’s design life without posing health or …

Modeling Inflation Using A Fast Fourier Transform (Fft), Blake Smith

Williams Honors College, Honors Research Projects

This paper utilizes a Fast Fourier Transform (FFT) algorithm to construct a trigonometric interpolant for the Consumer Price Index (CPI), which is then differentiated and used to obtain a continuous function for “instantaneous” (i.e., month-wise) inflation, as opposed to a 12-month percent-change. Fourier coefficients are analyzed to investigate underlying periodicities in the newly constructed function. This metric does not hold significant predictive value but it may prove helpful in retroactive analysis of inflation trends.

Hysplit In Simulating The Atmospheric Dispersion Of Hazardous Aerosols: A Case Study In St. Louis, Missouri, Ahmet Tolga Odabasi

Masters Theses

"Atmospheric dispersion and transmission play an important role in the behavior and effects of air pollution. Human health can be adversely affected by air pollution in a variety of ways, both immediately and over time. The Hybrid Single Particle Lagrangian Integrated Trajectory Model (HYSPLIT) modeling program, a computer model and software package, tracks the transport trajectories and distributions of air pollution and various pollutants, including radioactive pollutants, in the atmosphere. It also facilitates research on pollution sources. This study simulated the transport of hazardous aerosols in St. Louis region for the years 2020, 2021, and 2022 using the HYSPLIT modeling …

Branching Fractional Brownian Motion, Reece Beattie-Hauser

Masters Theses

"Fractional Brownian Motion (FBM) is a Gaussian process whose increments are correlated over long times. FBM is an example of anomalous diffusion, and recently it has been used to model the distribution of serotonergic fibers in the brain [1, 2]. To better represent these fibers, branching FBM (bFBM), where FBM trajectories may randomly split into two, is introduced. One-dimensional bFBM is studied in both sub diffusive and super diffusive regimes, examining three potential behaviors of the correlations (memory) in a branching event: both trajectories retain the memory of previous steps, only one keeps the memory, and neither keeps the memory. …

Comparative Study Of Crypto Volatility And Price Forecasting Using A Mixture Of Time Series And Machine Learning Models, Abhishek Kafle

Masters Theses

"Forecasting financial product volatility and price is crucial for informed decision-making in investment and risk management. The models considered include GARCH, LSTM, GRU, BiLSTM, and hybrid models that incorporate various combinations of these models. We present a comparative analysis of forecasting volatility and price using the aforementioned models.

We also introduce a user-friendly dashboard for model training and evaluation, enabling users to upload datasets and customize model parameters. The dashboard allows users to select the type of model, specify the dataset range for training, determine the number of epochs, adjust the number of layers for deep …

Variability In Semidiurnal Surface And Internal Tides In Global Ocean Model Simulations, Harpreet Kaur

Dissertations

This dissertation focuses on semidiurnal (D2) surface and internal tides. Chapter 2 investigates the transition of M₂ barotropic Kelvin waves into Hybrid Kelvin-Edge (HKE) waves and the associated generation of internal tides at widening shelves using theory and a realistic global baroclinic Hybrid Coordinate Ocean Model (HYCOM) simulation. To understand the effect of complex, realistic bathymetry on the HKE wave transition, we perform quasi-realistic barotropic HYCOM simulations of the Celtic Sea/Bay of Biscay shelf areas. We conclude that the HKE wave transition is most likely masked by the effects of complex bathymetry and offshelf baroclinic fluxes cannot be exclusively …

Ecocultural Monitoring And Erosion Mitigation In Powers Creek, A Baduwa’T Tributary, In Blue Lake, California, Sebastian Castillo, Lillyauna Perry, Daniel Price, Lokey Struve

Cal Poly Humboldt Capstone Honor Roll

Riparian areas are of great ecological and cultural importance. They provide a variety of ecosystem services, protecting water quality, minimizing climatological changes, and acting as valuable wildlife habitat. They are often also places of connection and access to resources for indigenous communities. Powers Creek, a tributary of the Baduwa’t, is one such place for the Blue Lake Rancheria tribal community. Through the utilization of the process based restoration methodology, our team was able to develop dynamic, place-based solutions for the environmental ails impacting Powers Creek. On-site vegetation and rock weirs were employed as low-tech bioengineering technologies in order to slow …

Eco-Cultural Restoration Of Mouralherwaqh: Site Description And Invasive Species Treatment Plan In King Salmon, California, Natalie Bridget Calderon, Myion Rickey, King Baptista, Owen Bardsley, Jillian Snowhook

Cal Poly Humboldt Capstone Honor Roll

In July of 2022, the Wiyot Tribe bought back one of their first pieces of ancestral forest within the Mouralherwaqh "more-RAH-share-wahg" village area (Wiyot, 2022). Before this repatriation, the Tribe owned less than 1% of their ancestral lands; after, the Tribe’s land holdings increased by 10% (Reclaiming Mouralherwaqh | Humboldt NOW | Cal Poly Humboldt, 2022). Mouralherwaqh is a 46 acre coastal site located near present day King Salmon, California and has high ecological and culturally significant values (Wiyot, 2022). Prior to the change of ownership, Mouralherwaqh was privately-owned and in 2014 underwent a clear-cut timber harvest within eight-acres of …

Neutrosophie : Un Cadre Interdisciplinaire Pour Une Meilleure Compréhension De L’Incertitude Et De L’Indétermination, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

La neutrosophie, un cadre philosophique et scientifique relativement récent introduit dans les années 1990,1 propose une approche robuste pour comprendre et modéliser l’indétermination, la contradiction et l’incertitude. Explorons les concepts fondamentaux de la neutrosophie et quelques diverses applications à travers plusieurs disciplines, notamment les mathématiques, la physique, la sociologie, la psychologie et la biologie.