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Full-Text Articles in Physical Sciences and Mathematics

Machine Learning In Finances, Elma Kastrat, Akinyemi Apampa, Satyanand Singh May 2023

Machine Learning In Finances, Elma Kastrat, Akinyemi Apampa, Satyanand Singh

Publications and Research

In our study we work on an optimization of an appropriate stock portfolio base on available information. Our work takes into consideration the average return and any associated risk. We produce an investment strategy that predictively allows a portfolio to grow with high yields.


Seasonal And Diurnal Variations Of Kelvin-Helmholtz Instability At Terrestrial Magnetopause, S. Kavosi, J. Raeder, Jay R. Johnson, K. Nykyri, C. J. Farrugia May 2023

Seasonal And Diurnal Variations Of Kelvin-Helmholtz Instability At Terrestrial Magnetopause, S. Kavosi, J. Raeder, Jay R. Johnson, K. Nykyri, C. J. Farrugia

Faculty Publications

Kelvin-Helmholtz Instability is ubiquitous at Earth’s magnetopause and plays an important role in plasma entry into the magnetosphere during northward interplanetary magnetic fields. Here, using one solar cycle of data from NASA THEMIS (Time History of Events and Macro scale Interactions during Substorms) and MMS (Magnetospheric Multiscale) missions, we found that KHI occurrence rates show seasonal and diurnal variations with the rate being high near the equinoxes and low near the solstices. The instability depends directly on the Earth’s dipole tilt angle. The tilt toward or away from the Sun explains most of the seasonal and diurnal variations, while the …


Prioritizing Professional Development At The Interface Of Natural Resources And Agriculture, Katherine J. Starzec May 2023

Prioritizing Professional Development At The Interface Of Natural Resources And Agriculture, Katherine J. Starzec

The Journal of Extension

Continuous professional development is critical for Extension staff, and many agriculture-focused Extension employees are tasked with outreach related to a wide variety of natural resource topics. The purpose of this study is to help prioritize trainings needed by Kansas Extension agents and specialists based on their current level of knowledge and interest in staying up to date on 18 different natural resource topics. Responses to a statewide survey were analyzed using the Borich model. Results indicate priority professional development needs related to soil health; effects of climate; invasive species, harmful algal blooms; and groundwater, surface water, and air quality.


Improvement Of A Low-Cost Diy Wave Gauge, Matthew F. Virden, Nigel A. Temple, Bret M. Webb, Eric L. Sparks May 2023

Improvement Of A Low-Cost Diy Wave Gauge, Matthew F. Virden, Nigel A. Temple, Bret M. Webb, Eric L. Sparks

The Journal of Extension

The impacts of waves on shorelines and nearshore ecosystems has highlighted the need for extension and other environmental professionals to have access to accurate and affordable wave measurements. The development of a low-cost DIY wave gauge improved the accessibility of these measurements; however, the original design was limited in battery life. Here, an improved version of the low-cost DIY wave gauge, the DIY Feather Wave Gauge, is presented with the same performance, longer battery life, smaller design, and cheaper cost along with tutorials, parts lists, and other resources. This new gauge has been used to improve shoreline management recommendations.


Biodiversity In Eastern Kentucky: Effects Of Habitat Change, Surface Top Mining, And Current Reclamation Practices, Sydney Pardieu May 2023

Biodiversity In Eastern Kentucky: Effects Of Habitat Change, Surface Top Mining, And Current Reclamation Practices, Sydney Pardieu

Undergraduate Theses

Biodiversity is a key component in maintaining the valuable ecosystem services that are vital to the way humans interact with and rely on the environment. The Appalachian Region in Eastern North America is one of the most biodiverse temperate broadleaf forests in the world and is home to hundreds of endangered or endemic species. Despite the high biodiversity, the region is also heavily mined, particularly by mountain top removal, causing habitat change and pollution. Current reclamation practices for mined lands are lacking in effective reclamation criterion, and state statutes provide little or no attention to the preservation of biodiversity. Therefore, …


Integrating Art And Design With Environmental Science, Laura D. Hinson May 2023

Integrating Art And Design With Environmental Science, Laura D. Hinson

The Confluence

This article demonstrates how combining art and design and environmental sciences would benefit both fields by analyzing how utilizing art and design in environmental sciences can help enhance aspects of the teaching process and environmental studies, specifically those dealing with climatology and pollution. Additionally, by taking an ecocritical approach to analyzing art and its creation, this article will detail how artists can become more conscious of the impacts creating certain types of art has on the environment while also noting environmental changes documented through art.


Hymenachne Amplexicaluis [(Rudge) Nees] Genetic Resources Collection In México, A Suitable Grass For Flood Plains In Tropical Areas, J. F. Enriquez-Quiroz, A. R. Quero-Carrillo, J. Perez-Perez, A. Hernandez-Garay, E. Garcia-Moya May 2023

Hymenachne Amplexicaluis [(Rudge) Nees] Genetic Resources Collection In México, A Suitable Grass For Flood Plains In Tropical Areas, J. F. Enriquez-Quiroz, A. R. Quero-Carrillo, J. Perez-Perez, A. Hernandez-Garay, E. Garcia-Moya

IGC Proceedings (1993-2023)

Hymenachne amplexicaluis [( Rudge ) Nees; 2n= 2x= 24; Azuche, West Indian marsh grass] is a native Central and South America C3 grass that grows well under intermittent flooding conditions. It produces good seed set and stolons to thrive on new areas assuring its survival, combined with an efficient N metabolism to promote vigorous new growing leaves and tillers (Antel et al., 1998). Azuche is a dual attribute species when introduced to new areas; it has valuable forage attributes but also is a potential weed (Hill, 2000). As Azuche is a native species, one must deal with in …


Critical Analysis Of Tropical Forage Breeding In Brazil, J. A. Usberti Jr., P. B. Alcantara May 2023

Critical Analysis Of Tropical Forage Breeding In Brazil, J. A. Usberti Jr., P. B. Alcantara

IGC Proceedings (1993-2023)

Forage grasses account for 90% of the Brazilian forage seed market while the genera Brachiaria, Panicum and others are responsible for 85, 10 and 5% of the traded grass seeds, respectively. Most of the forage grass and legume cultivars available for sowing in Brazil were selected in germplasm banks during the last 20 years, while few of them were derived from artificial crossings, followed by selection for desirable forage traits. The selection of new genetic materials in germplasm banks (exploitation of naturally-occurring genetic variability) is still feasible but the chances of success are decreasing through time. From now on, …


Application Of Screening In Rangeland Monitoring: Quantifying Early-Warning Signals Of State Transitions In Nebraska, Daniel S. Bauloye May 2023

Application Of Screening In Rangeland Monitoring: Quantifying Early-Warning Signals Of State Transitions In Nebraska, Daniel S. Bauloye

School of Natural Resources: Dissertations, Theses, and Student Research

Woody encroachment, desertification, and exotic annual grass invasion are regime shifts (i.e., state-transitions) with detrimental effects on ecosystem health and services in grasslands of the North American Great Plains. Traditional approaches to rangeland monitoring are capable of detecting regime shifts after they have already occurred (i.e., diagnosing them); however, proactive management requires earlier warning. Regime shift screening is a new approach to rangeland monitoring capable of providing earlier warning of regime shifts. Regime shift screening proposes assessing the presence, persistence, and non-stationarity of regime shift signals; however, no studies have systematically evaluated these characteristics in real-world landscapes. In this thesis, …


Occurrence Of Radionuclides And Hazardous Elements In The Transboundary River Basin Kyrgyzstan–Kazakhstan, Mariya A. Severinenko, Vladimir P. Solodukhin, Bekmamat M. Djenbaev, The National Academy Of Science Of The Kyrgyz Republic G. Lennik, Baktiyar T. Zholboldiev, Daniel D. Snow May 2023

Occurrence Of Radionuclides And Hazardous Elements In The Transboundary River Basin Kyrgyzstan–Kazakhstan, Mariya A. Severinenko, Vladimir P. Solodukhin, Bekmamat M. Djenbaev, The National Academy Of Science Of The Kyrgyz Republic G. Lennik, Baktiyar T. Zholboldiev, Daniel D. Snow

Nebraska Water Center: Faculty Publications

Important for irrigation, the transboundary river basin between Kyrgyzstan and Kazakhstan is vulnerable to geochemical and anthropogenic sources of pollution. The use of water use indices, together with measurements of the elemental and radionuclide composition of the water and bottom sediments, provides a means for evaluating the continued use of the water from this region. Recent monitoring shows the highest concentrations of hazardous contaminants include lead and thorium contained in the bottom and banks of the Kichi-Kemin River. These contaminants are likely remnants of an accidental spill at the Aktyuz tailing dump in 1964. The specific activity of the Th-232 …


A Probabilistic Exploration Of Food Supplementation And Assistance, Logan Mattingly May 2023

A Probabilistic Exploration Of Food Supplementation And Assistance, Logan Mattingly

Honors College Theses

Food insecurity is a stark threat that grips our country and affects households throughout our country. Dietary insufficiency manifests itself in ways that affect health and public safety. According to researchers, individuals who suffer from food insecurity have a higher risk of aggression, anxiety, suicide ideation and depression. These problems tend to occur unequally distributed among those households with lower income. In this work, an exploratory analysis within these data sets will be performed to examine the socio-economic, biographical, nutritional, and geographical principal components of food insecurity among survey participants and how the US Supplemental Nutrition Assistance Program (SNAP) effects …


Music On Canvas: A Quest To Generate Art That Evokes The Feeling Of Music, My Linh (Lucy) Tran May 2023

Music On Canvas: A Quest To Generate Art That Evokes The Feeling Of Music, My Linh (Lucy) Tran

Mathematics, Statistics, and Computer Science Honors Projects

Although the idea of connecting music and art dates back to ancient Greece, recent advancements in computing have made automating this feasible. This project represents a quest to transform music into art, using three methodologies where each is an improvement towards generating images that convey our feelings and imaginations during music listening. The three methods respectively involve:

1. An element-wise mapping of sound and colors
2. Using song tags
3. Tuning an Artificial Intelligence (AI) model to generate pictorial text captions.

To create artistic images, methods two and three utilize an existing text-to-image generative AI.


What Are The Impacts Of Deer Browsing And Japanese Stiltgrass (Microstegium Vinenium) On Native Sapling Growth In A Residential Wetland In Southeastern Georgia?, Josie Richards May 2023

What Are The Impacts Of Deer Browsing And Japanese Stiltgrass (Microstegium Vinenium) On Native Sapling Growth In A Residential Wetland In Southeastern Georgia?, Josie Richards

Honors College Theses

Wetlands promote biodiversity, act as climate stabilizers, and regulate water flow, yet are vulnerable to invaders. An invasive species can affect the biodiversity, abiotic conditions, and increase vulnerability of an ecosystem over time and deer browsing can actively affect new growth by removing the apical buds of young woody vegetation. Japanese stiltgrass (Microstegium vimineum), a wetland specific invader, has been shown to compete against native species for limited resources and actively crowd them out. Growth of native saplings can be further complicated by the presence of white tailed deer (Odocoileus virginianus), which browse woody vegetation and limit recruitment of trees. …


Photodynamic Therapy Agents: The Power Of Mjöllnir To Eradicate Cancer, Sidney M. Hopper May 2023

Photodynamic Therapy Agents: The Power Of Mjöllnir To Eradicate Cancer, Sidney M. Hopper

Honors College Theses

After its discovery back in the 1900s, photosensitizers became a critical study for potential treatments and cures for medical issues, including cancer. It was discovered that porphyrins appeared to target and accumulate in proliferating cells, and to reach the cells, a certain wavelength of light with maximum absorbance associated with the porphyrin was necessary to achieve cell death. Photodynamic therapy involves making use of porphyrins or metalloporphyrins as activators when exposed to such light. When activated, these compounds generate reactive oxygen species (ROS), such as HO- or O2-, which can react with nucleic acids found in DNA and RNA. In …


Optimizing Greenhouses: A Comparative Analysis Of Csb+Sju Greenhouses, Jervon Sands May 2023

Optimizing Greenhouses: A Comparative Analysis Of Csb+Sju Greenhouses, Jervon Sands

CSB and SJU Distinguished Thesis

This research aims to determine the optimal design of modern greenhouses through a comparative analysis of three on campus greenhouses. Temperature and humidity measurements as well as physical observations for each site were compared to standard measurements and ideal greenhouse design components. The results of a comparative analysis allowed for the three on-campus greenhouses to be ranked against this section. The trends found in the data confirmed the findings of previous research. Recommendations for operating an optimal greenhouse derived from the analysis and observations along with suggestions for experimental improvements based on a previous study are also included.


Radon In Utah Homes, Madison Mackay May 2023

Radon In Utah Homes, Madison Mackay

Physics Capstone Projects

Radon gas can be found nearly everywhere. It is formed by the decay of radium, which is found in rocks, soil, plants, and animals. Radon gas can become trapped in buildings and is dangerous at high levels. It is particularly known to be high in many areas of the state of Utah. It is important for the average citizen in Utah to understand more about radon and what levels they may be exposed to. An experiment was done to try an alternate, faster method of testing for radon gas. This experiment was performed in several different locations in Utah. While …


Search For B Mesogenesis At Babar, J. P. Lees, V. Poireau, E. Grauges, A. Palano, G. Eigen, D. N. Brown, Yu. G. Kolomensky, M. Fritsch, H. Koch, R. Cheaib, C. Hearty, T. S. Mattison, J. A. Mckenna, R. Y. So, V. E. Blinov, A. R. Buzykaev, V. P. Druzhinin, E. A. Kozyrev, Milind Purohit, Et. Al. May 2023

Search For B Mesogenesis At Babar, J. P. Lees, V. Poireau, E. Grauges, A. Palano, G. Eigen, D. N. Brown, Yu. G. Kolomensky, M. Fritsch, H. Koch, R. Cheaib, C. Hearty, T. S. Mattison, J. A. Mckenna, R. Y. So, V. E. Blinov, A. R. Buzykaev, V. P. Druzhinin, E. A. Kozyrev, Milind Purohit, Et. Al.

Faculty Publications

A new mechanism has been proposed to simultaneously explain the presence of dark matter and the matter-antimatter asymmetry in the Universe. This scenario predicts exotic B-meson decays into a baryon and a dark-sector antibaryon (ψD) with branching fractions accessible at B factories. We present a search for B→ΛψD decays using data collected by the BABAR experiment at SLAC. This reaction is identified by fully reconstructing the accompanying B meson and requiring the presence of a single Λ baryon in the remaining particles. No significant signal is observed, and bounds on the B→Λψ …


Designing Programming Languages For Writing Maintainable Software, Aaron Friesen May 2023

Designing Programming Languages For Writing Maintainable Software, Aaron Friesen

Honors Theses

Maintainability is crucial to the long-term success of software projects. Among other factors, it is affected by the programming language in which the software is written. Programming language designers should be conscious of how their design decisions can influence software maintainability. Non-functional properties of a language can affect the readability of source code in ways beyond the control of programmers. Language features can cause or prevent certain classes of bugs, and runtime issues especially can require significant maintenance effort. Tools external to the language, especially those developed and distributed by language implementers, can aid in the creation of maintainable software. …


New Insights Into The Paleovegetation Of The Ancient Underwater Forest Located In The Northern Gulf Of Mexico, Karla Lizarraga Garcia May 2023

New Insights Into The Paleovegetation Of The Ancient Underwater Forest Located In The Northern Gulf Of Mexico, Karla Lizarraga Garcia

Master's Theses

A well-preserved remnant of an ancient bald cypress forest (hereafter, Underwater Forest) constitutes the only known archive of a glacial refuge on the once exposed continental shelf of the Northern Gulf of Mexico. This forest existed around 41-72 yBP (MIS 3-5) according to the existing dating methods applied on previous studies. As the climate conditions and sea levels changed, the vegetation of this glacial refuge shifted from bald cypress forests to open marshes, altering the vegetation dynamics. The present research analyzed four new cores (21DF-5A, 21DF-5B, 15DF-6, and 16DF-3A), which provided additional insights into the vegetation that once existed in …


Producer Long-Term Marketing Opportunities With Ethanol Plants, Austin Harthoorn, Logan Lloyd, Cory Walters, Kate Brooks May 2023

Producer Long-Term Marketing Opportunities With Ethanol Plants, Austin Harthoorn, Logan Lloyd, Cory Walters, Kate Brooks

Cornhusker Economics

Commodity marketing operates in a complex decision environment with constant information flow, which can conceal long-run financially profitable marketing opportunities for producers. In the corn marketing space, the competitive role of ethanol plants throughout the state may provide producers with long-run financial gains by strategically approaching marketing decisions. In this article, we characterize whether producers can gain financially from strategically marketing corn to ethanol plants. For example, do ethanol plants provide a better long-run return from pre-harvest hedging, spring sale, or harvest sale?

We investigate three important contracting times--forward contract for harvest delivery (called pre-harvest hereafter), harvest delivery, and spring …


Studying Competing Reaction Pathways In Methanol Decomposition On Platinum Catalysts Under Ultra-High Vacuum (Uhv) Conditions Using Tpd And Sfg Spectroscopy, Quy Loi, Kevin Alvorado Jimenez, Sarah Lelea, Lauren Villegas, Jerry Larue May 2023

Studying Competing Reaction Pathways In Methanol Decomposition On Platinum Catalysts Under Ultra-High Vacuum (Uhv) Conditions Using Tpd And Sfg Spectroscopy, Quy Loi, Kevin Alvorado Jimenez, Sarah Lelea, Lauren Villegas, Jerry Larue

Student Scholar Symposium Abstracts and Posters

Catalysts are important in manufacturing processes, as they make them more efficient and useful. To develop better catalysts, we need to know how they work by studying how methanol breaks down on platinum. TPD and TD-SFG spectroscopy are used to study by providing the vibrational spectra of methanol on the platinum surface as temperature changes.


Formula 101 Using 2022 Formula One Season Data To Understand The Race Results, Christopher Garcia, Oliver Lopez May 2023

Formula 101 Using 2022 Formula One Season Data To Understand The Race Results, Christopher Garcia, Oliver Lopez

Student Scholar Symposium Abstracts and Posters

The reason why I am interested in Formula One is that my friend showed me what Formula One was all about. It became interesting to see the action of the sport, including the battles the drivers have during the race and how fast they go through a corner. Also, when qualifying comes around, they push their car to the absolute limit to gain a few seconds off their opponents. The drivers only in the top 10 receive points from the winner getting 25 points, the last driver in the top 10 getting 1 point, and those below the top ten …


Radar Signatures In Tropical Cyclone Tornadic And Nontornadic Supercells, Michaela Wood May 2023

Radar Signatures In Tropical Cyclone Tornadic And Nontornadic Supercells, Michaela Wood

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Tropical cyclones (TCs) contain highly-sheared environments that are conducive for supercell thunderstorms. These TC supercells sometimes produce tornadoes, often with little warning. Given the often-close proximity of tornadic and nontornadic TC supercells, environments may not be well-distinguished, pointing to the potential value of radar observations. In this study, dual-polarimetric radar signatures of a sample of TC supercells are examined in the context of known supercell structure and microphysics. Tornadic and nontornadic TC supercells are compared with their midlatitude counterparts, and the environments and characteristic structure of these storms are shown to be notably different. An attempt is made to distinguish …


Impact Of Lithological Variation And Topology On The Connectivity And Intensity Of Fracture Networks In Carbonates, Fahad Qassim May 2023

Impact Of Lithological Variation And Topology On The Connectivity And Intensity Of Fracture Networks In Carbonates, Fahad Qassim

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Assessing fracture network connectivity in reservoirs remains a challenging task because of the complex nature of fracture networks at various length scales, which significantly impacts fluid flow behavior. Outcrop studies are essential for understanding subsurface fracture networks because intersecting fracture sheets' length, orientation, height distribution, and, therefore, network connectivity and intensity are difficult to measure from wellbores and are typically below seismic resolution. Nevertheless, fracture network connectivity is a crucial parameter and a critical factor in understanding, evaluating, and predicting fluid flow behavior in hydrocarbon reservoirs, aquifers, hazardous waste and CO2 storage systems, and geothermal energy exploitation. Moreover, fracture …


Domain Wall Saddle Point Morphology In Ferroelectric Triglycine Sulfate, C. J. Mccluskey, A. Kumar, Alexei Gruverman, I. Luk’Yanchuk, J. M. Gregg May 2023

Domain Wall Saddle Point Morphology In Ferroelectric Triglycine Sulfate, C. J. Mccluskey, A. Kumar, Alexei Gruverman, I. Luk’Yanchuk, J. M. Gregg

Alexei Gruverman Publications

Ferroelectric domain walls, across which there is a divergence in polarization, usually have enhanced electrical conductivity relative to bulk. However, in lead germanate, head-to-head and tail-to-tail walls are electrically insulating. Recent studies have shown that this is because, when oppositely oriented domains meet, polar divergence is obviated by a combination of domain bifurcation and suspected local dipolar rotation. To explore the uniqueness, or otherwise, of this microstructure, we have used tomographic piezoresponse force microscopy to map three-dimensional domain morphologies in another uniaxial ferroelectric system: triglycine sulfate. This mapping reveals an abundance of domain wall saddle points, which are characteristic of …


Hollow Mn3o4 Nanoparticles For Catalytic Oxidation Of Alkenes In Air, Nathan R. Loutsch May 2023

Hollow Mn3o4 Nanoparticles For Catalytic Oxidation Of Alkenes In Air, Nathan R. Loutsch

Honors Thesis

Oxidized hydrocarbons (epoxides, alcohols, carboxylic acids, ketones, and aldehydes) have many uses including fuel production, pollution treatment, and chemical synthesis. These compounds can be formed by oxidizing alkenes and alkanes with the assistance of a catalyst. Heterogeneous catalysts have greater recyclability, but traditionally have lower activity and selectivity. Due to the increased relative surface area, nanomaterials can overcome some of the physical limitations. The Hoefelmeyer lab developed a new nanomaterial: hollow Mn3O4 nanoparticles. Sensitive synthetic conditions have been optimized. Due to the increased relative number of edge and corner atoms, the reactive properties of most small nanomaterials increase. Because of …


What Senior U.S. Leaders Say We Should Know About Cyber, Dr. Joseph H. Schafer May 2023

What Senior U.S. Leaders Say We Should Know About Cyber, Dr. Joseph H. Schafer

Military Cyber Affairs

On April 6, 2023, the Atlantic Council’s Cyber Statecraft Initiative hosted a panel discussion on the new National Cybersecurity Strategy. The panel featured four senior officials from the Office of the National Cyber Director (ONCD), the Department of State (DoS), the Department of Justice (DoJ), and the Department of Homeland Security (DHS). The author attended and asked each official to identify the most important elements that policymakers and strategists must understand about cyber. This article highlights historical and recent struggles to express cyber policy, the responses from these officials, and the author’s ongoing research to improve national security cyber policy.


Programming An Autonomous Robot, Maxwell Brueggeman May 2023

Programming An Autonomous Robot, Maxwell Brueggeman

Honors College Theses

Ravaged by hurricanes, Florida needed help restoring its natural beauty and returning its wildlife to their homes. This was the task for the IEEE SoutheastCon 2023 Hardware Competition. Florida’s restoration was simulated by returning various ducks and pillars that lay strewn across a game board to their proper places. Ducks needed to return to their pond, pillars needed to be stacked to create statues, and food needed to be placed in the manatee and alligator aquariums. Competing teams were challenged to create an autonomous robot capable of performing these tasks. During the first semester, sensor selection was tackled. Research was …


Understanding Quantum Field Theory And Standard Model To Explore Beyond Standard Model Physics, Alize Sucsuzer May 2023

Understanding Quantum Field Theory And Standard Model To Explore Beyond Standard Model Physics, Alize Sucsuzer

Honors Program Theses and Projects

Motivated by the goal of participating in astroparticle physics research in graduate school, we aimed to understand the Standard Model of particle physics and the Feynman diagrams through which particle interactions are described, so that we could learn about the properties of certain astroparticles. The axiomatic principle that governs fundamental physics is manifest covariance, implying that the mathematical forms of the physical laws are the same to all observers. Maintaining covariance requires 4-vector representation using group theoretical techniques based on symmetries, as well as a transition from single-particle quantum physics to many-particle quantum field theory (QFT). The Standard Model of …


Crystal Chemistry, Optic And Magnetic Characterizations Of A New Copper Based Material Templated By Hexahydrodiazepine, Mansoura Bourwina, Rawia Msalmi, Sandra Walha, Mark M. Turnbull, Thierry Roisnel, Ahlem Guesmi, Ammar Houas, Naoufel Ben Hamadi, Houcine Naïli May 2023

Crystal Chemistry, Optic And Magnetic Characterizations Of A New Copper Based Material Templated By Hexahydrodiazepine, Mansoura Bourwina, Rawia Msalmi, Sandra Walha, Mark M. Turnbull, Thierry Roisnel, Ahlem Guesmi, Ammar Houas, Naoufel Ben Hamadi, Houcine Naïli

Chemistry

Crystals of the new organic-inorganic material (DAP-H2)[CuBr4] (1); (DAP = hexahydrodiazepine (C5H14N2)) were successfully synthesized by slow evaporation and characterized by single-crystal X-ray diffraction, infrared spectroscopy, thermal analysis, UV-Vis-NIR diffuse reflectance spectroscopy, and magnetic measurements. X-ray investigation demonstrates that 1 crystallizes in the monoclinic space group C2/c. The supramolecular crystal structure of 1 is guided by several types of hydrogen bonding which connect anions and cations together into a three-dimensional network. The optical band gap was determined by diffuse reflectance spectroscopy to be 1.78 eV for a direct allowed transition, implying that …