Physical Sciences and Mathematics Commons^™

Hollow Mn3o4 Nanoparticles For Catalytic Oxidation Of Alkenes In Air, Nathan R. Loutsch

Honors Thesis

Oxidized hydrocarbons (epoxides, alcohols, carboxylic acids, ketones, and aldehydes) have many uses including fuel production, pollution treatment, and chemical synthesis. These compounds can be formed by oxidizing alkenes and alkanes with the assistance of a catalyst. Heterogeneous catalysts have greater recyclability, but traditionally have lower activity and selectivity. Due to the increased relative surface area, nanomaterials can overcome some of the physical limitations. The Hoefelmeyer lab developed a new nanomaterial: hollow Mn3O4 nanoparticles. Sensitive synthetic conditions have been optimized. Due to the increased relative number of edge and corner atoms, the reactive properties of most small nanomaterials increase. Because of …

What Senior U.S. Leaders Say We Should Know About Cyber, Dr. Joseph H. Schafer

Military Cyber Affairs

On April 6, 2023, the Atlantic Council’s Cyber Statecraft Initiative hosted a panel discussion on the new National Cybersecurity Strategy. The panel featured four senior officials from the Office of the National Cyber Director (ONCD), the Department of State (DoS), the Department of Justice (DoJ), and the Department of Homeland Security (DHS). The author attended and asked each official to identify the most important elements that policymakers and strategists must understand about cyber. This article highlights historical and recent struggles to express cyber policy, the responses from these officials, and the author’s ongoing research to improve national security cyber policy.

Programming An Autonomous Robot, Maxwell Brueggeman

Honors College Theses

Ravaged by hurricanes, Florida needed help restoring its natural beauty and returning its wildlife to their homes. This was the task for the IEEE SoutheastCon 2023 Hardware Competition. Florida’s restoration was simulated by returning various ducks and pillars that lay strewn across a game board to their proper places. Ducks needed to return to their pond, pillars needed to be stacked to create statues, and food needed to be placed in the manatee and alligator aquariums. Competing teams were challenged to create an autonomous robot capable of performing these tasks. During the first semester, sensor selection was tackled. Research was …

Understanding Quantum Field Theory And Standard Model To Explore Beyond Standard Model Physics, Alize Sucsuzer

Honors Program Theses and Projects

Motivated by the goal of participating in astroparticle physics research in graduate school, we aimed to understand the Standard Model of particle physics and the Feynman diagrams through which particle interactions are described, so that we could learn about the properties of certain astroparticles. The axiomatic principle that governs fundamental physics is manifest covariance, implying that the mathematical forms of the physical laws are the same to all observers. Maintaining covariance requires 4-vector representation using group theoretical techniques based on symmetries, as well as a transition from single-particle quantum physics to many-particle quantum field theory (QFT). The Standard Model of …

Crystal Chemistry, Optic And Magnetic Characterizations Of A New Copper Based Material Templated By Hexahydrodiazepine, Mansoura Bourwina, Rawia Msalmi, Sandra Walha, Mark M. Turnbull, Thierry Roisnel, Ahlem Guesmi, Ammar Houas, Naoufel Ben Hamadi, Houcine Naïli

Chemistry

Crystals of the new organic-inorganic material (DAP-H2)[CuBr₄] (1); (DAP = hexahydrodiazepine (C₅H₁₄N₂)) were successfully synthesized by slow evaporation and characterized by single-crystal X-ray diffraction, infrared spectroscopy, thermal analysis, UV-Vis-NIR diffuse reflectance spectroscopy, and magnetic measurements. X-ray investigation demonstrates that 1 crystallizes in the monoclinic space group C2/c. The supramolecular crystal structure of 1 is guided by several types of hydrogen bonding which connect anions and cations together into a three-dimensional network. The optical band gap was determined by diffuse reflectance spectroscopy to be 1.78 eV for a direct allowed transition, implying that …

Preparation, Characterization And Electron Yield Analysis On Highly Insulating Granular Particles, Heather Allen

Physics Capstone Projects

This study focuses on obtaining reliable electron yield measurements of highly insulating granular particles of various shape, size, and composition. Measurements of this kind have long been considered too difficult to collect on granular samples due to experimental complexities leading to a critical knowledge gap in the fundamental electrostatic behaviors of dust. A significant portion of this study was spent on preparing and characterizing granular samples before any type of measurement took place. Particles of varying sizes ranging from ~1 μm to ~100 μm, shapes including cubical, spherical, and angular, and composition including NaCl, MgO, Al₂O₃ and …

Improving Multi-Modal Food Detection System With Transfer Learning, Shivani Gowda

LMU/LLS Theses and Dissertations

Self-assessment of food intake is important for preventing and treating obesity. The current self-assessment methods of food intake are inaccurate and hard to use. In this thesis, we explore ways to improve machine learning (ML) food classification methods which are the core technical problem of food intake self-assessment. We present a food detection system that utilizes a state-of-the art multi-modal architecture called Vision and Language Transformer (ViLT). This architecture combines both food appearance via the image modality, and description via the textual modality to improve the accuracy of food classification. To further enhance the performance, we incorporate other improvements such …

Utilization Of Cellulose Symbiotic Culture Of Bacteria And Yeast (Scoby) With Sweet Tea Media As Methylene Blue And Brilliant Green Biosorbent Material, Leonard Mateus Sigiro, Ahmad Maksum, Donanta Dhaneswara

Journal of Materials Exploration and Findings

The cellulose from Symbiotic Culture of Bacteria and Yeast (SCOBY) can be used as a biosorbent for dye adsorption, such as Methylene Blue and Brilliant Green. This study used sweet tea with a 6% of sugar concentration and 14 days of fermentation time to synthesize biosorbent material from SCOBY. The results from this synthesis are then characterized using FTIR, SEM, and BET. From the result of characterization, it was found that SCOBY has pores formed from cellulose. The results of the average pore size are 1.5976nm with a pore volume of 0.229cc/g, while the specific surface area is 143.244m2/g. The …

Enhancing Compatibility And Mechanical Properties Of Natural Rubber Composites, Krisma Yessi Sianturi, Adam Febriyanto Nugraha, Belle Kristaura, Mochamad Chalid

Journal of Materials Exploration and Findings

Pure natural rubber (NR) exhibits low mechanical properties, necessitating the incorporation of additives like vulcanizing agents and fillers. Carbon black and silica, conventional fillers, are relatively expensive and not environmentally friendly. This study explores using Oil Palm Empty Fruit Bunch (OPEFB) fiber as an affordable, abundant, and biodegradable alternative filler for NR. However, compatibility issues arise between the nonpolar NR and the polar OPEFB fiber. A latex-starch hybrid coupling agent (CA (NR-St)) was added to the composite formulation to address this. NR, OPEFB fiber, and the coupling agent were mixed using an open roll mill with a 10 phr OPEFB …

Combining Frameworks To Improve Military Health System Quality And Cybersecurity, Dr. Maureen L. Schafer, Dr. Joseph H. Schafer

Military Cyber Affairs

Existing conceptual frameworks and commercially available technology could be considered to rapidly operationalize the use of Quality Measures (QM) within military health systems (Costantino et al. 2020). Purchased healthcare as well as digital healthcare services have paved the way for data collection from multiple information systems thus offering stakeholders actionable intelligence to both guide and measure healthcare outcomes. However, the collection of data secondary to Smart Devices, disparate information systems, cloud services, and the Internet of Medical Things (IOMT) is a complication for security experts that also affect clients, stakeholders, organizations, and businesses delivering patient care. We have combined three …

Use Of Social Media During The Covid-19 Pandemic Of 2020, Aliya Goncalves Almeida

Honors Program Theses and Projects

Nowadays billions of people use social media platforms as a way to keep in touch with family and friends, fill spare time, find content, find inspiration for things to do and buy, share, and discuss opinions with others, and the list goes on. This project focused and investigated on the use of social media during the years, in particular during quarantine/lockdown. Utilizing the public source data, I explored several research questions including how many hours people spent on social media, the popularity of social media apps, as well as what age group uses social media platforms (teenagers, young adults, adults). …

Dense & Attention Convolutional Neural Networks For Toe Walking Recognition, Junde Chen, Rahul Soangra, Marybeth Grant-Beuttler, Y. A. Nanehkaran, Yuxin Wen

Physical Therapy Faculty Articles and Research

Idiopathic toe walking (ITW) is a gait disorder where children’s initial contacts show limited or no heel touch during the gait cycle. Toe walking can lead to poor balance, increased risk of falling or tripping, leg pain, and stunted growth in children. Early detection and identification can facilitate targeted interventions for children diagnosed with ITW. This study proposes a new one-dimensional (1D) Dense & Attention convolutional network architecture, which is termed as the DANet, to detect idiopathic toe walking. The dense block is integrated into the network to maximize information transfer and avoid missed features. Further, the attention modules are …

Red Riding On Hood: Exploring How Galaxy Colour Depends On Environment, Pankaj C. Bhambhani, Ivan K. Baldry, Sarah Brough, Alexander D. Hill, M A. Lara-Lopez, J Loveday, Benne Holwerda

Faculty and Staff Scholarship

Galaxy populations are known to exhibit a strong colour bimodality, corresponding to blue star-forming and red quiescent subpopulations. The relative abundance of the two populations has been found to vary with stellar mass and environment. In this paper, we explore the effect of environment considering different types of measurements. We choose a sample of 49 911 galaxies with 0.05 < z < 0.18 from the Galaxy And Mass Assembly survey. We study the dependence of the fraction of red galaxies on different measures of the local environment as well as the large-scale `geometric’ environment defined by density gradients in the surrounding cosmic web. We find that the red galaxy fraction varies with the environment at fixed stellar mass. The red fraction depends more strongly on local environmental measures than on large-scale geometric environment measures. By comparing the different environmental densities, we show that no density measurement fully explains the observed environmental red fraction variation, suggesting the different measures of environmental density contain different information. We test whether the local environmental measures, when combined together, can explain all the observed environmental red fraction variation. The geometric environment has a small residual effect, and this effect is larger for voids than any other type of geometric environment. This could provide a test of the physics applied to cosmological-scale galaxy evolution simulations as it combines large-scale effects with local environmental impact.

Fractal Newton Methods, Ali Akgül, David E. Grow

Mathematics and Statistics Faculty Research & Creative Works

We introduce fractal Newton methods for solving (Formula presented.) that generalize and improve the classical Newton method. We compare the theoretical efficacy of the classical and fractal Newton methods and illustrate the theory with examples.

Physiological Distancing Affects Climate Change Through Spatial Differences, Janette Williams

Department of Environmental Studies: Undergraduate Student Theses

Psychological distancing is best described as the human ability to separate ourselves socially, temporally, and spatial and use it to manipulate our perspectives. It is the belief that in order to perceive or understand the information, you have to be within a spatial range(Harvard Business Review,2015). Psychological distancing has been linked to climate change perspectives based on spatial differences. People who are closely affected by climate change and experience more are going to have more ideas and be proactive. The reduced distance by spatial differences correlated with perceptions of climate change. People who are farther from the coast and experience …

The Role Of Gender And Curiosity On Transformational Leadership: A Mixed-Methods Study, Brooke Colleen Mott

School of Natural Resources: Dissertations, Theses, and Student Research

Environmental leaders are tasked with finding innovative solutions to dynamic environmental challenges. Leaders must gain and use new knowledge and experiences that motivate resolving gaps in one’s knowledge (i.e., curiosity) and thereby find forward-thinking solutions. Although curiosity is an integral part of human existence, it may be experienced in various ways. Studies have shown that men and women may possess different leadership styles. Nevertheless, the influence of curiosity on leadership between genders has not been as readily explored. Women exhibit unique characteristics for successful leadership in many contexts, but they are often underrepresented in natural resource management overall. Characteristics of …

Sub-Chandrasekhar Type Ia Supernovae Scenarios With Increased Pathways For Neutronization, Fernando Hernan Rivas

Doctoral Dissertations

Type Ia supernovae are thermonuclear explosions of white dwarfs (WD), electron-degenerate cores of old intermediate mass stars(under 8$M_{\odot}$). Reaching energies of $10^{51}$\si{\erg}, they outshine whole galaxies as they synthesize and distribute most of the iron group elements (IGE; V, Cr, Mn, Fe, Co, Ni) into the interstellar medium, thus being one of the main agents in cosmic chemical evolution. Also, given their notably homogeneous lightcurves, they form the last step in the cosmic distance ladder outdistancing Cepheid variables by orders of magnitude. Though calibration of said lightcurves is dependent on a high number of confirmed events, the limits of statistical …

Synthesizing, Purifying, And Characterizing Molten Chloride Salts, Phillip W. Halstenberg

Doctoral Dissertations

Molten chloride salts have vast potential as heat transfer fluids with both nuclear and concentrated solar power applications. For application in energy systems, the characteristics that govern these systems must be well understood. This work focuses on inorganic molten chloride salts with a special emphasis on the experimental aspect of chemical research. Chapter 2 covers the synthetic approaches for the formation of molten chloride mixtures. Many salts can be purchased from industrial suppliers, but most must be purified therefore, Chapter 3 evaluates various methodology developed for removal of impurities in salt mixtures. Once the salt of proper content and purity …

Mechanochemical Synthesis Of Task-Specific Conjugated Porous Networks Towards Enhanced Energy Storage, Juntian Fan

Doctoral Dissertations

Conjugated scaffolds with high electronic conductivity, high surface area, etc. are promising materials for diverse technological applications, especially in the electrochemical field. However, the current synthesis methods are still limited to the traditional solution-based method or the ionothermal method, which always require an inert atmosphere shield, large amounts of organic solvents, noble catalysts, long reaction time up to days, and high temperatures, etc. Therefore, there is a common goal of developing conjugated scaffolds through facile, green, straightforward pathways. Mechanochemistry, which is an efficient, sustainable, solvent-free methodology, could provide a unique reaction environment to synthesize this kind of functionalized materials, resulting …

Space-Angle Discontinuous Galerkin Finite Element Method For Radiative Transfer Equation, Hang Wang

Doctoral Dissertations

Radiative transfer theory describes the interaction of radiation with scattering and absorbing media. It has applications in neutron transport, atmospheric physics, heat transfer, molecular imaging, and others. In steady state, the radiative transfer equation is an integro-differential equation of five independent variables, which are 3 dimensions in space and 2 dimensions in the angular direction. This high dimensionality and the presence of the integral term present serious challenges when solving the equation numerically. Over the past 50 years, several techniques for solving the radiative transfer equation (RTE) have been introduced. These include, but are certainly not limited to, Monte Carlo …

Utilizing Ultra-Performance Chromatography High-Resolution Mass Spectrometry To Investigate Fatty Acid Mediated Antibiotic Tolerance, Brittni Woodall

Doctoral Dissertations

The lipid membrane is the first component necessary to sustain life. To maintain homeostasis, segregate cellular machinery, provide protection from the environment, and reproduce, an organism must establish a boundary in which the processes can occur. Throughout the last two decades, research has propelled our knowledge of lipid membranes much beyond original hypotheses. Once thought of to be static and uniform, the understanding of the lipid membrane has evolved to encompass a structure that is responsive, unique, and intricately constructed by the organism itself. By chance or by choice, organisms adapt the lipid membrane according to the environment for which …

Fabrication, Measurements, And Modeling Of Semiconductor Radiation Detectors For Imaging And Detector Response Functions, Corey David Ahl

Doctoral Dissertations

In the first part of this dissertation, we cover the development of a diamond semiconductor alpha-tagging sensor for associated particle imaging to solve challenges with currently employed scintillators. The alpha-tagging sensor is a double-sided strip detector made from polycrystalline CVD diamond. The performance goals of the alpha-tagging sensor are 700-picosecond timing resolution and 0.5 mm spatial resolution. A literature review summarizes the methodology, goals, and challenges in associated particle imaging. The history and current state of alpha-tagging sensors, followed by the properties of diamond semiconductors are discussed to close the literature review. The materials and methods used to calibrate the …

Pointing Control And Stabilization Of The High-Energy Uv Laser For Laser-Assisted Charge Exchange, Martin Joseph Kay

Doctoral Dissertations

Laser-Assisted Charge Exchange (LACE) is an experimental method of charge exchange injection into a proton accumulator ring that is being developed at the Spallation Neutron Source (SNS) in Oak Ridge National Laboratory (ORNL) as an alternative to hazardous injection foils. The current scheme of LACE requires a high-energy, low-repetition-rate UV (355 nm) laser beam (140 mJ pulses at 10 Hz) to be transported over 65 meters to the laser-particle interaction point (IP) in a high-radiation area of the accelerator. Thermal effects and other disturbances along the free-space laser transport line cause the beam to slowly drift away from the IP …

Total Absorption Spectroscopy Of Mo-106 And Tc-106, Michael Cooper

Doctoral Dissertations

Total absorption spectroscopy is a method of gamma-ray spectroscopy that has gained prominence in the past several decades, as nuclear data revisions are performed on older nuclear data, which is often incomplete. A strong understanding of underlying nuclear data, particularly fission and beta decay data, is essential for nuclear reactors and nuclear fuel decay heat. This PhD work involves the analysis of fission fragments 106Mo [Mo-106] and 106Tc [Tc-106]. These neutron rich isotopes contribute upwards of 6% of the cumulative fission yield of 241Pu [Pu-241] fission, and 4% of 239Pu [Pu-239] fission. Prior data for these two fission fragments only …

Explorations In Baseball Analytics: Simulations, Predictions, And Evaluations For Games And Players, Katelyn Mongerson

Theses and Dissertations

From statistics being reported in newspapers in the 1840s, to present day, baseballhas always been one of the most data-driven sports. We make use of the endless publicly available baseball data to build models in R and Python that answer various baseball- related questions regarding predicting and optimizing run production, evaluating player effectiveness, and forecasting the postseason. To predict and optimize run production, we present three models. The first builds a common tool in baseball analysis called a Run Expectancy Matrix which is used to give a value (in terms of runs) to various in-game decisions. The second uses the …

Tdcosmo - Xii. Improved Hubble Constant Measurement From Lensing Time Delays Using Spatially Resolved Stellar Kinematics Of The Lens Galaxy, Anowar J. Shajib, Pritom Mozumdar, Geoff C.-F. Chen, Tommaso Treu, Michele Cappellari, Shawn Knabel, Sherry H. Suyu, Vardha N. Bennert, Joshua A. Frieman, Dominique Sluse, Simon Birrer, Frederic Courbin, Christopher D. Fassnacht, Lizvette Villafaña, Peter R. Williams

Physics

Strong-lensing time delays enable the measurement of the Hubble constant (H₀) independently of other traditional methods. The main limitation to the precision of time-delay cosmography is mass-sheet degeneracy (MSD). Some of the previous TDCOSMO analyses broke the MSD by making standard assumptions about the mass density profile of the lens galaxy, reaching 2% precision from seven lenses. However, this approach could potentially bias the H₀ measurement or underestimate the errors. For this work, we broke the MSD for the first time using spatially resolved kinematics of the lens galaxy in RXJ1131−1231 obtained from the Keck Cosmic …

Large-Scale Volcanism On The Terrestrial Planets, Keenan Ben Golder

Doctoral Dissertations

Evidence for mafic volcanism has been found on each planet in the inner Solar System. Lava flows on these planets range in size from 10s to 1000s of kilometers in extent. I investigated large-scale lava flows on Mercury, Earth, and Mars throughout the chapters in this dissertation. Each of these lava flows provides an avenue to study the emplacement and evolution of lava on various planets and under differing conditions, the factors that affect their overall extent, and potential source areas.

Chapter One investigates large-scale lava flows in the Cerberus region on Mars, specifically to understand their emplacement history, material …

Different Approaches To Overcome Antibiotic Resistance, Samantha Biaesch

Chemistry

In the recent years, there has been a growing demand for the development of antibiotic treatments as bacterial infections have acquired defense mechanisms to commonly used antibiotics, such as penicillin. During the growth of bacterial cells, resistant mutants are able to survive antibiotic treatment and continue proliferation. Thus, creating a resistant bacterial cell population that can no longer be targeted through antibiotic treatment. Due to the recent need of new approaches, there has been an explosion of research in developing techniques that combat bacterial resistance. Both bacteriophage-RNA aptamer binding and modifications in bacterial tRNA show potential to be exploited for …

Evaluating And Improving Snow Prediction In The National Water Model In New York State Using New York State Mesonet Data, Sierra Liotta

Atmospheric & Environmental Sciences

When snow melts, the water drains into nearby streams and rivers which can impact water supply and flood hazards. The National Water Model (NWM) provides high quality forecast data for streamflow in the continental United States using mathematical representations of hydrologic processes. This research evaluates how the land surface model (LSM), Noah-MP, in the NWM simulates snowpack and snowmelt in New York State. To evaluate the representation of snow melt in Noah-MP, we examine point simulations at the New York State Mesonet (NYSM) sites where Noah-MP is forced by NYSM meteorological observations to avoid biases in the meteorological input and …

Investigating The Difference Between Members In The High-Resolution Rapid Refresh Ensemble (Hrrre) During The February 23rd, 2022 Winter Storm, Michael Barletta

Atmospheric & Environmental Sciences

Probabilistic forecasting is one tool that is being used to help create more accurate and understandable forecasts. Using percentages and probabilities allows for more depth to a forecast and allows forecasters to be able to convey a clearer message of what exactly they are expecting. Ensembles are a set of forecast models that have either different starting conditions, boundary conditions or parameter settings. They are one way of creating probabilistic forecasts and can help in the understanding of the likelihood of a specific outcome. Forecasters use ensembles to attempt to analyze the range of possible outcomes and the likelihood of …