Physical Sciences and Mathematics Commons^™

Do Zoos And Aquariums Promote Attitude Change In Visitors? A Critical Evaluation Of The American Zoo And Aquarium Study, Lori Marino, Scott O. Lilienfeld, Randy Malamud, Nathan Nobis, Ron Broglio

Nathan M. Nobis, PhD

Modern-day zoos and aquariums market themselves as places of education and conservation. A recent study conducted by the American Zoo and Aquarium Association (AZA) (Falk et al., 2007) is being widely heralded as the first direct evidence that visits to zoos and aquariums produce long-term positive effects on people’s attitudes toward other animals. In this paper, we address whether this conclusion is warranted by analyzing the study’s methodological soundness. We conclude that Falk et al. (2007) contains at least six major threats to methodological validity that undermine the authors’ conclusions. There remains no compelling evidence for the claim that zoos …

Applied Quantum Chemistry: Spectroscopic Detection And Characterization Of The F2Bs And Cl2Bs Free Radicals In The Gas Phase, Bing Jin, Phillip M. Sheridan, Dennis J. Clouthier

Chemistry Faculty Publications

In this and previous work [D. J. Clouthier, J. Chem. Phys. 141, 244309 (2014)], the spectroscopic signatures of the X₂BY (X = H, halogen, Y = O, S) free radicals have been predicted using high level ab initio theory. The theoretical results have been used to calculate the electronic absorption and single vibronic level (SVL) emission spectra of the radicals under typical jet-cooled conditions. Using these diagnostic predictions, the previously unknown F₂BS and Cl₂BS free radicals have been identified and characterized. The radicals were prepared in a free jet expansion by subjecting precursor …

Hybrid Cement Clinker And Cement Made From That Clinker, Thomas Robl, Tristana Y. Duvallet, Robert Rathbone, Yongnin Zhou

Earth and Environmental Sciences Faculty Patents

A hybrid cement clinker incorporates specific ranges of clinker phases and falls within specific modulus values as set forth and described in this document.

Helicobacter Pylori Flha Binds The Sensor Kinase And Flagellar Gene Regulatory Protein Flgs With High Affinity, Jennifer Tsang, Takanori Hirano, Timothy R. Hoover, Jonathan L. Mcmurry

Faculty Articles

Flagellar biogenesis is a complex process that involves multiple checkpoints to coordinate transcription of flagellar genes with the assembly of the flagellum. In Helicobacter pylori, transcription of the genes needed in the middle stage of flagellar biogenesis is governed by RpoN and the two-component system consisting of the histidine kinase FlgS and response regulator FlgR. In response to an unknown signal, FlgS autophosphorylates and transfers the phosphate to FlgR, initiating transcription from RpoNdependent promoters. In the present study, export apparatus protein FlhA was examined as a potential signal protein. Deletion of its N-terminal cytoplasmic sequence dramatically decreased expression of two …

Temporal Mining For Distributed Systems, Yexi Jiang

FIU Electronic Theses and Dissertations

Many systems and applications are continuously producing events. These events are used to record the status of the system and trace the behaviors of the systems. By examining these events, system administrators can check the potential problems of these systems. If the temporal dynamics of the systems are further investigated, the underlying patterns can be discovered. The uncovered knowledge can be leveraged to predict the future system behaviors or to mitigate the potential risks of the systems. Moreover, the system administrators can utilize the temporal patterns to set up event management rules to make the system more intelligent.

With the …

Modeling And Simulation Of Evacuation Plan For Hancock Stadium, Nirmal Neranjan Weerasekara

Theses and Dissertations

The goal of this study is to use Modeling and Simulation of Evacuation Plan (MSEP) to support management to execute proper evacuation plan in case of emergency at Hancock Stadium in Illinois State University. Analyses of the research literature and evacuation scenarios are used to build a simulation system that will connect a description of emergency and evacuation situation with its context. It shows how an evacuation plan actually functions. The results of the study will help safety managers to understand the current situations of evacuation according to the specific simulation scenarios. The evacuation simulation is categorized according to the …

The Effect Of Sample And Sample Matrix On Dna Processing: Mechanisms For The Detection And Management Of Inhibition In Forensic Samples, Lilliana I. Moreno

FIU Electronic Theses and Dissertations

The presence of inhibitory substances in biological forensic samples has, and continues to affect the quality of the data generated following DNA typing processes. Although the chemistries used during the procedures have been enhanced to mitigate the effects of these deleterious compounds, some challenges remain. Inhibitors can be components of the samples, the substrate where samples were deposited or chemical(s) associated to the DNA purification step. Therefore, a thorough understanding of the extraction processes and their ability to handle the various types of inhibitory substances can help define the best analytical processing for any given sample. A series of experiments …

The Speleogenesis Of Vallgornera Cave (Mallorca, Spain): A Mineralogical And Morphological Study, Jacqueline Amelia Diehl

USF Tampa Graduate Theses and Dissertations

Cova des Pas de Vallgornera (CPV) is morphologically and scientifically, the most prominent karst feature of Mallorca Island (Spain). It consists of over 74 km of passages developed within two carbonate lithologies (reef front and back reef facies) of Upper Miocene age. Two distinct cave patterns are recognized, both tightly controlled by the type of facies; spongework mazes and collapse chambers are characteristic for the reef front unit, whereas linear, fracture-guided galleries develop in the back reef carbonates. CPV is abundantly decorated with a variety of speleothems.

The overarching goal of this study is to provide evidence towards the cave's …

Inhibition Of Zn(Ii) Binding Type Ia Topoisomerases By Organomercury Compounds And Hg(Ii), Bokun Cheng, Thirunavukkarasu Annamalai, Shayna Sandhaus, Priyanka Bansod, Yuk-Ching Tse-Dinh

Department of Chemistry and Biochemistry

Type IA topoisomerase activities are essential for resolving DNA topological barriers via an enzyme-mediated transient single strand DNA break. Accumulation of topoisomerase DNA cleavage product can lead to cell death or genomic rearrangement. Many antibacterial and anticancer drugs act as topoisomerase poison inhibitors that form stabilized ternary complexes with the topoisomerase covalent intermediate, so it is desirable to identify such inhibitors for type IA topoisomerases. Here we report that organomercury compounds were identified during a fluorescence based screening of the NIH diversity set of small molecules for topoisomerase inhibitors that can increase the DNA cleavage product of Yersinia pestis topoisomerase …

Tables For Dihedral Angles Between The Adjacent Faces Of Platonic Solids & Various Uniform Polyhedra, Harish Chandra Rajpoot Rajpoot Hcr

Harish Chandra Rajpoot H.C. Rajpoot

These data tables have been prepared by the author Mr H.C. Rajpoot by using his data tables of the various polyhedra for determining the dihedral angle between any two adjacent faces with a common edge of different uniform polyhedra or polyhedral shells. These are very useful for the construction & preparing the wire-frame models of the uniform polyhedral shells having different regular polygonal faces. A polyhedral shell can be easily constructed/framed by continuously fixing all its adjacent (flat) faces each two as a pair at their common edge at an angle equal to the dihedral angle between them. These tables …

Determination Of Abraham Model Solute Descriptors For The Monomeric And Dimeric Forms Of Trans-Cinnamic Acid Using Measured Solubilities From The Open Notebook Science Challenge, Andrew Lang, Jean-Claude Bradley, Michael H. Abraham, William E. Acree Jr., Samantha N. Beck, David A. Bulger, Elizabeth A. Clark

College of Science and Engineering Faculty Research and Scholarship

Background: Calculating Abraham descriptors from solubility values requires that the solute have the same form when dissolved in all solvents. However, carboxylic acids can form dimers when dissolved in non-polar solvents. For such compounds Abraham descriptors can be calculated for both the monomeric and dimeric forms by treating the polar and non-polar systems separately. We illustrate the method of how this can be done by calculating the Abraham descriptors for both the monomeric and dimeric forms of trans-cinnamic acid, the first time that descriptors for a carboxylic acid dimer have been obtained. Results: Abraham descriptors were calculated for the monomeric …

Predicting Abraham Model Solvent Coefficients, Andrew Lang, Jean-Claude Bradley, Michael H. Abraham, William E. Acree Jr.

College of Science and Engineering Faculty Research and Scholarship

Background: The Abraham general solvation model can be used in a broad set of scenarios involving partitioning and solubility, yet is limited to a set of solvents with measured Abraham coefficients. Here we extend the range of applicability of Abraham’s model by creating open models that can be used to predict the solvent coefficients for all organic solvents. Results: We created open random forest models for the solvent coefficients e, s, a, b, and v that had out-of-bag R2 values of 0.31, 0.77, 0.92, 0.47, and 0.63 respectively. The models were used to suggest sustainable solvent replacements for commonly used …

Are There Really Two Different Bell’S Theorems?, Travis Norsen

Physics: Faculty Publications

This is a polemical response to Howard Wiseman’s recent paper, “The two Bell’s theorems of John Bell”. Wiseman argues that, in 1964, Bell established a conflict between the quantum mechanical predictions and the joint assumptions of determinism and (what is now usually known as) “parameter independence”. Only later, in 1976, did Bell, according to Wiseman, first establish a conflict between the quantum mechanical predictions and locality alone (in the specific form that Bell would sometimes call “local causality”). Thus, according to Wiseman, the long-standing disagreements about what, exactly, Bell’s theorem does and does not prove can be understood largely as …

A Kansa-Radial Basis Function Method For Elliptic Boundary Value Problems In Annular Domains, Xiao Yan Liu, Andreas Karageorghis, C. S. Chen

Faculty Publications

We employ a Kansa-radial basis function (RBF) method for the numerical solution of elliptic boundary value problems in annular domains. This discretization leads, with an appropriate selection of collocation points and for any choice of RBF, to linear systems in which the matrices possess block circulant structures. These linear systems can be solved efficiently using matrix decomposition algorithms and fast Fourier transforms. A suitable value for the shape parameter in the various RBFs used is found using the leave-one-out cross validation algorithm. In particular, we consider problems governed by the Poisson equation, the inhomogeneous biharmonic equation and the inhomogeneous Cauchy–Navier …

A Soil Parameters Geodatabase For The Modeling Assessment Of Agricultural Conservation Practices Effects In The United States, Mauro Di Luzio, Martin L. Norfleet, Jeffrey G. Arnold, Jimmy R. Williams, James R. Kiniry

International Journal of Geospatial and Environmental Research

Soil parameters for hydrology modeling in cropland dominated areas, from the regional to local scale, are part of critical biophysical information whose deficiency may increase the uncertainty of simulated conservation effects and predicting potential. Despite this importance, soil physical and hydraulic parameters lack common, wide-coverage repositories combined to digital maps as required by various hydrology-based agricultural water quality models.

This paper describes the construction of a geoprocessing workflow and the resultant hydrology-structured soil hydraulic, physical, and chemical parameters geographic database for the entire United States, named US-SOILM-CEAP. This database is designed to store a-priori values for a suit of models, …

Training Opportunities Available To Ohio Lake Erie Basin Local Decision-Makers Regarding The Economic And Fiscal Benefits Of Coastal And Watershed Stewardship, Wendy A. Kellogg, Erica Matheny

Erica Matheny

This paper presents new knowledge about the current status of training on the economic value of stewardship practices in the Ohio Lake Erie basin. Local decision-makers shape coastal and watershed conditions but often do not appreciate the economic, fiscal, and ecological benefits that could be gained from sound stewardship practices. This study investigated the information and training about economic benefits available in the Ohio Lake Erie basin. Training providers and technical assistance professionals helped identify key training needs and challenges to decision-maker awareness of benefits. We found relatively few organizations offering training that incorporate economic or fiscal benefits into their …

Protolunar Disk Evolution And The Depletion Of Volatile Elements In The Moon, Robin M. Canup, Channon Visscher, Julien Salmon, Bruce Fegley Jr.

Faculty Work Comprehensive List

We explore how the evolution of the protolunar disk could lead to a depletion in K, Na, and Zn in the Moon relative to Earth even in the absence of escape.

Violacein Induces P44/42 Mitogen-Activated Protein Kinase‑Mediated Solid Tumor Cell Death And Inhibits Tumor Cell Migration, Toral Mehta, Koen P. Vercruysse, Terrance Johnson, Anthony Okechukwu Ejiofor, Elbert Myles, Quincy A. Quick

Chemistry Faculty Research

Microbial secondary metabolites have emerged as alternative novel drugs for the treatment of human cancers. Violacein, a purple pigment produced by Chromobacterium violaceum, was investigated in the present study for its anti‑tumor properties in tumor cell lines. Clinically applicable concentrations of violacein were demonstrated to inhibit the proliferative capacity of tumor cell lines according to a crystal violet proliferation assay. The underlying mechanism was the promotion of apoptotic cell death, as indicated by poly(ADP ribose) polymerase cleavage and p44/42 mitogen‑activated protein kinase signaling determined by western blot analysis. Collectively, this provided mechanistic evidence that violacein elicits extracellular-signal regulated kinase‑induced apoptosis …

Supramolecular Chemistry For Undergraduate Students, David V. Dearden, Roger G. Harrison

Journal of Undergraduate Research

The goal of this proposal was to train graduate and undergraduate students through research experiences in supramolecular chemistry in a multi-group environment. Academically, our objective was to synthesize and characterize new supramolecular host molecules and to develop applications for these molecules. We believe we have been quite successful, as demonstrated by the presentations and publications listed below and as shown by the receipt of a National Science Foundation grant by one of the teams involved in this research, in a year when such grants were particularly difficult to obtain.

Pharm: An Environment For Physical Acoustics Research And Mentoring, Kent L. Gee, Tracianne B. Neilsen

Journal of Undergraduate Research

PHARM (PHysical Acoustics Research and Mentoring) has been operating partially with support from a MEG grant. The primary purpose of this mentoring environment is to provide undergraduates in Physics and Applied Physics opportunities to gain experience in fundamental areas of physical acoustics. It has also included students in Mechanical and Electrical Engineering and Mathematics. Within the acoustics community, “physical acoustics” refers to a number of subfields (e.g., outdoor sound propagation, aeroacoustics, and nonlinear acoustics). A large number of students have been able to participate in projects related to these areas. Many of these projects have been and are being documented …

The Riemann Curvature Tensor, Its Invariants, And Their Use In The Classification Of Spacetimes, Jesse Hicks

Presentations and Publications

The equivalence problem in general relativity is to determine whether two solutions of the Einstein field equations are isometric. Petrov has given a classification of metrics according to their isometry algebras. This talk discusses the use of the Petrov classification scheme, together with the use of scalar curvature invariants, to address the equivalence problem. These are the slides for a presentation at the Mathematics Association of America Spring 2015 conference at Brigham Young University.

Structural Patterns At All Scales In A Nonmetallic Chiral Au_133(Sr)_52 Nanoparticle, Chenjie Zeng, Yuxiang Chen, Kristin Kirschbaum, Kannatassen Appavoo, Matthew Y. Sfeir, Rongchao Jin

Publications and Research

Structural ordering is widely present in molecules and materials. However, the organization of molecules on the curved surface of nanoparticles is still the least understood owing to the major limitations of the current surface characterization tools. By the merits of x-ray crystallography, we reveal the structural ordering at all scales in a super robust 133–gold atom nanoparticle protected by 52 thiolate ligands, which is manifested in self-assembled hierarchical patterns starting from the metal core to the interfacial –S–Au–S– ladder-like helical “stripes” and further to the “swirls” of carbon tails. These complex surface patterns have not been observed in the smaller …

Development Of An Optical Method For The Detection Of Homocysteine As A Disease Biomarker Using Fluorescein-Aldehydes, Aabha Barve

Dissertations and Theses

Homocysteine is a natural occurring aminothiol. It is an intermediate product in the metabolism of methionine. Methionine is an essential amino acid required for protein synthesis. Metabolic irregularities disrupt homocysteine levels in plasma. Elevated homocysteine levels are directly linked to folate and cobalamin (vitamin B12) deficiencies, and are an independent risk factor for cardiovascular diseases. High homocysteine levels have also been associated with Alzheimer's, osteoporosis, renal failure, cancer, birth defects and pregnancy complications. The association of elevated homocysteine levels with cardiovascular disease and other diseases has generated great interest in the detection of homocysteine.

An optical method for the detection …

Performance Metrics For Depth-Based Signal Separation Using Deep Vertical Line Arrays, John K. Boyle

Dissertations and Theses

Vertical line arrays (VLAs) deployed below the critical depth in the deep ocean can exploit reliable acoustic path (RAP) propagation, which provides low transmission loss (TL) for targets at moderate ranges, and increased TL for distant interferers. However, sound from nearby surface interferers also undergoes RAP propagation, and without horizontal aperture, a VLA cannot separate these interferers from submerged targets. A recent publication by McCargar and Zurk (2013) addressed this issue, presenting a transform-based method for passive, depth-based separation of signals received on deep VLAs based on the depth-dependent modulation caused by the interference between the direct and surface-reflected acoustic …

A Connection Between Obscuration And Star Formation In Luminous Quasars, Chien-Ting J. Chen, Ryan C. Hickox, Stacey Alberts, Chris M. Harrison

Dartmouth Scholarship

We present a measurement of the star formation properties of a uniform sample of mid-IR selected, unobscured and obscured quasars (QSO1s and QSO2s) in the Bo\"otes survey region. We use an spectral energy distribution (SED) analysis for photometric data spanning optical to far-IR wavelengths to decompose AGN and host galaxy components. We find that when compared to a matched sample of QSO1s, the QSO2s have higher far-IR detection fractions, far-IR fluxes and infrared star formation luminosities (L^SF_IR) by a factor of ∼2. Correspondingly, we show that the AGN obscured fraction rises from 0.3 to 0.7 between 4−40×10 …

Binding-Induced, Turn-On Fluorescence Of The Egfr/Erbb Kinase Inhibitor, Lapatinib, James N. Wilson

James N Wilson

We report the photophysical properties, binding-induced turn-on emission, and fluorescence imaging of the cellular uptake and distribution of lapatinib, an EGFR/ERBB inhibitor. Lapatinib, a type II, i.e. inactive state, inhibitor that targets the ATP binding pocket of the EGFR family of receptor tyrosine kinases. DFT calculations predict that the 6-furanylquinazoline core of lapatinib should exhibit an excited state with charge transfer character and an S0 to S1 transition energy of 3.4 eV. Absorption confirms an optical tran- sition in the near UV to violet, while fluorescence spectroscopy shows that photoemission is highly sensi- tive to solvent polarity. The hydrophobicity of …

Mathematical Analysis Of Great Rhombicuboctahedron (An Archimedean Solid) By H.C. Rajpoot, Harish Chandra Rajpoot Rajpoot Hcr

Harish Chandra Rajpoot H.C. Rajpoot

All the important parameters of a great rhombicuboctahedron (an Archimedean solid), having 12 congruent square faces, 8 regular hexagonal faces, 6 congruent regular octagonal faces each of equal edge length, 72 edges & 48 vertices lying on a spherical surface with certain radius, have been derived by the author H.C. Rajpoot by applying "HCR's Theory of Polygon" to calculate the solid angle subtended by each square face, regular hexagonal face & regular octagonal face & their normal distances from the center of great rhombicuboctahedron, dihedral angles between the adjacent faces, inscribed radius, circumscribed radius, mean radius, surface area & volume. …

Alan Turing: The Man Behind The Machine, Christopher D. Goff

College of the Pacific Faculty Presentations

No abstract provided.

Capillary Effects In Guided Crystallization Of Organic Thin Films, Alta Fang, Anna K. Hailey, Abigail Grosskopf, John E. Anthony, Yueh-Lin Loo, Mikko Haataja

Chemistry Faculty Publications

Recently, it has been demonstrated that solvent-vapor-induced crystallization of triethylsilylethynyl anthradithiophene (TES ADT) thin films can be directed on millimeter length scales along arbitrary paths by controlling local crystal growth rates via pre-patterning the substrate. Here, we study the influence of capillary effects on crystallization along such channels. We first derive an analytical expression for the steady-state growth front velocity as a function of channel width and validate it with numerical simulations. Then, using data from TES ADT guided crystallization experiments, we extract a characteristic channel width, which provides the smallest feature size that can be obtained by this technique.

The Fierce Green Fire: Vol 5 Issue 17, Wofford College Environmental Studies Program

The Fierce Green Fire

No abstract provided.