Physical Sciences and Mathematics Commons^™

Chemical Analysis, Databasing, And Statistical Analysis Of Smokeless Powders For Forensic Application, Dana-Marie Dennis

Electronic Theses and Dissertations

Smokeless powders are a set of energetic materials, known as low explosives, which are typically utilized for reloading ammunition. There are three types which differ in their primary energetic materials; where single base powders contain nitrocellulose as their primary energetic material, double and triple base powders contain nitroglycerin in addition to nitrocellulose, and triple base powders also contain nitroguanidine. Additional organic compounds, while not proprietary to specific manufacturers, are added to the powders in varied ratios during the manufacturing process to optimize the ballistic performance of the powders. The additional compounds function as stabilizers, plasticizers, flash suppressants, deterrents, and opacifiers. …

Liquid Crystal-Based Biosensors For The Detection Of Bile Acids, Sihui He

Electronic Theses and Dissertations

Bile acids are physiologically important metabolites, which are synthesized in liver as the end products of cholesterol metabolism and then secreted into intestine. They are amphiphilic molecules which play a critical role in the digestion and absorption of fats and fat-soluble vitamins through emulsification. The concentration of bile acids is an indicator for liver function. Individual suffering from liver diseases has a sharp increase in bile acid concentrations. Hence, the concentration level of bile acids has long been used as a biomarker for the early diagnosis of intestinal and liver diseases. Conventional methods of bile acid detection such as chromatography-mass …

Propagation Failure In Discrete Inhomogeneous Medium Using A Caricature Of The Cubic, Elizabeth Lydon

Electronic Theses and Dissertations

Spatially discrete Nagumo equations have widespread physical applications, including modeling electrical impulses traveling through a demyelinated axon, an environment typical in multiple scle- rosis. We construct steady-state, single front solutions by employing a piecewise linear reaction term. Using a combination of Jacobi-Operator theory and the Sherman-Morrison formula we de- rive exact solutions in the cases of homogeneous and inhomogeneous diffusion. Solutions exist only under certain conditions outlined in their construction. The range of parameter values that satisfy these conditions constitutes the interval of propagation failure, determining under what circumstances a front becomes pinned in the media. Our exact solutions represent …

Functional Characterization Of Green Sorption Media And Scaling Of Pilot Studies For Copper Removal In Stormwater Runoff, Cameron Houmann

Electronic Theses and Dissertations

Green adsorption media with the inclusion of renewable and recycled materials can be applied as a stormwater best management practice for copper removal. A green adsorption media mixture composed of recycled tire chunk, expanded clay aggregate, and coconut coir was physicochemically evaluated for its potential use in an upflow media filter. The results found that the use of the green adsorption media mixture in isolation or the coconut coir with an expanded clay filtration chamber could be an effective and reliable stormwater best management practice for copper removal. A suite of tests were conducted on the media mixture and the …

Synthesis Of Fluorene-Based Derivatives, Characterization Of Optical Properties And Their Applications In Two-Photon Fluorescence Imaging And Photocatalysis, Grace Githaiga

Electronic Theses and Dissertations

The two-photon absorption (2PA) phenomenon has attracted attention from various fields ranging from chemistry and biology to optics and engineering. Two of the common NLO applications in which organic materials have been used are three-dimensional (3D) fluorescence imaging and optical power limiting. Two-photon absorbing materials are, therefore, in great demand to meet the needs of emerging technologies. Organic molecules show great promise to meet this need as they can be customized through molecular engineering, and as the development of two-photon materials that suit practical application intensifies, so does research to meet this need. However, there remains some uncertainty in the …

Lightning-Based Search For Tgfs In The Fermi Gamma-Ray Burst Monitor, Kareem Omar

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Localized Surface Plasmon Resonance Fiber Optic Nanoprobe, Savannah Kaye

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Fabrication And Study Of Graphene-Based Nanocomposites For Sensing And Energy Storage, Matthew Mcinnis

Electronic Theses and Dissertations

Graphite is an allotrope of carbon made up of atomically thin sheets, each covalently bound together, forming a π-conjugated network. An individual layer, called graphene, has extraordinary electrical, thermal and physical properties that provide the opportunity for innovating new functional composites. Graphene can be produced directly on a metallic substrate by chemical vapor deposition or by chemical oxidation of graphite, forming a stable aqueous suspension of graphene oxide (GO), which allows for convenient solution processing techniques. For the latter, after thermal or chemical reduction, much of the properties of the starting graphene re-emerge due to the reestablishment of π-conjugation. The …

High Efficiency And Wide Color Gamut Liquid Crystal Displays, Zhenyue Luo

Electronic Theses and Dissertations

Liquid crystal display (LCD) has become ubiquitous and indispensable in our daily life. Recently, it faces strong competition from organic light emitting diode (OLED). In order to maintain a strong leader position, LCD camp has an urgent need to enrich the color performance and reduce the power consumption. This dissertation focuses on solving these two emerging and important challenges. In the first part of the dissertation we investigate the quantum dot (QD) technology to improve the both the color gamut and the light efficiency of LCD. QD emits saturated color and grants LCD the capability to reproduce color vivid images. …

Electromechanical Lifting Actuation Of A Mems Cantilever And Nano-Scale Analysis Of Diffusion In Semiconductor Device Dielectrics, Imen Rezadad

Electronic Theses and Dissertations

This dissertation presents experimental and theoretical studies of physical phenomena in micro- and nano-electronic devices. Firstly, a novel and unproven means of electromechanical actuation in a micro-electro-mechanical system (MEMS) cantilever was investigated. In nearly all MEMS devices, electric forces cause suspended components to move toward the substrate. I demonstrated a design with the unusual and potentially very useful property of having a suspended MEMS cantilever lift away from the substrate. The effect was observed by optical micro-videography, by electrical sensing, and it was quantified by optical interferometry. The results agree with predictions of analytic and numerical calculations. One potential application …

Computerized Evaluatution Of Microsurgery Skills Training, Payal Jotwani

Electronic Theses and Dissertations

The style of imparting medical training has evolved, over the years. The traditional methods of teaching and practicing basic surgical skills under apprenticeship model, no longer occupy the first place in modern technically demanding advanced surgical disciplines like neurosurgery. Furthermore, the legal and ethical concerns for patient safety as well as cost-effectiveness have forced neurosurgeons to master the necessary microsurgical techniques to accomplish desired results. This has lead to increased emphasis on assessment of clinical and surgical techniques of the neurosurgeons. However, the subjective assessment of microsurgical techniques like micro-suturing under the apprenticeship model cannot be completely unbiased. A few …

Opportunistic Networks In Campus Environments, Salih Safa Bacanli

Electronic Theses and Dissertations

Opportunistic communication is an active research area in wireless sensor networks. Exploiting the opportunities to communicate between devices in an unstable network is one of the main challenges of the opportunistic communication. In this thesis, we propose an infrastructure-independent opportunistic mobile social networking strategy for efficient message broadcasting in campus environments. Specifically, we focus on the application scenario of university campuses. In our model, the students' smartphones forward messages to each other. The messages are created spontaneously as independent events in various places of the campus. The events can be either urgent security alerts or private announcements to the students …

Development Of A Nano-Sensing Approach And A Portable Prototype For Real-Time Detection And Quantification Of Free Mercury In Stream-Flow: Combining Science And Engineering In Pro Of The Environment, Warinya Chemnasiri

Electronic Theses and Dissertations

Mercury (Hg) is a well-known hazardous environmental contaminant existing in several forms, but all are toxic to human in one way or the others. Since Hg usually settles into water polluting the environment and accumulating in living organisms, it is crucial to monitor Hg levels in the aquatic ecosystem. Although there are many well established techniques currently used to detect Hg, most of them require elaborate and time-consuming sample preparation and pre-concentration procedures, as well as costly and bulky equipment that limit their practical application in the field. In order to overcome the existent limitations in Hg determination methods, Hernandez …

Entanglement And Coherence In Classical And Quantum Optics, Kumel Kagalwala

Electronic Theses and Dissertations

We explore the concepts of coherence and entanglement as they apply to both the classical and quantum natures of light. In the classical domain, we take inspiration from the tools and concepts developed in foundational quantum mechanics and quantum information science to gain a better understanding of classical coherence theory of light with multiple degrees of freedom (DoFs). First, we use polarization and spatial parity DoFs to demonstrate the notion of classical entanglement, and show that Bell's measure can serve as a useful tool in distinguishing between classical optical coherence theory. Second, we establish a methodical yet versatile approach called …

A Simulation-Based Task Analysis Using Agent-Based, Discrete Event And System Dynamics Simulation, Anastasia Angelopoulou

Electronic Theses and Dissertations

Recent advances in technology have increased the need for using simulation models to analyze tasks and obtain human performance data. A variety of task analysis approaches and tools have been proposed and developed over the years. Over 100 task analysis methods have been reported in the literature. However, most of the developed methods and tools allow for representation of the static aspects of the tasks performed by expert system-driven human operators, neglecting aspects of the work environment, i.e. physical layout, and dynamic aspects of the task. The use of simulation can help face the new challenges in the field of …

Attosecond Transient Absorption Spectroscopy Of Atoms And Molecules, Yan Cheng

Electronic Theses and Dissertations

One of the most fundamental goals of attosecond science is to observe and to control the dynamic evolutions of electrons in matter. The attosecond transient absorption spectroscopy is a powerful tool to utilize attosecond pulse to measure electron dynamics in quantum systems directly. In this work, isolated single attosecond pulses are used to probe electron dynamics in atoms and to study dynamics in hydrogen molecules using the attosecond transient absorption spectroscopy technique. The target atom/molecule is first pumped to excited states and then probed by a subsequent attosecond extreme ultraviolet (XUV) pulse or by a near infrared (NIR) laser pulse. …

A Dangerous Polymer: Organic Synthesis Of Poly(Glutamine), Corbain Swain

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Resource Management In Cloud And Big Data Systems, Lena Mashayekhy

Wayne State University Dissertations

Cloud computing is a paradigm shift in computing, where services are offered and acquired on demand in a cost-effective way. These services are often virtualized, and they can handle the computing needs of big data analytics. The ever-growing demand for cloud services arises in many areas including healthcare, transportation, energy systems, and manufacturing. However, cloud resources such as computing power, storage, energy, dollars for infrastructure, and dollars for operations, are limited. Effective use of the existing resources raises several fundamental challenges that place the cloud resource management at the heart of the cloud providers' decision-making process. One of these challenges …

2015 Nebraska Groundwater Quality Monitoring Report

Nebraska Department of Environmental Quality: Reports

The 2001 Nebraska Legislature passed LB329 (Neb. Rev. Stat. §46-1304) which, in part, directed the Nebraska Department of Environmental Quality (NDEQ) to report on groundwater quality monitoring in Nebraska. Reports have been issued annually since December 2001. The text of the statute applicable to this report follows: “The Department of Environmental Quality shall prepare a report outlining the extent of ground water quality monitoring conducted by natural resources districts during the preceding calendar year. The department shall analyze the data collected for the purpose of determining whether or not ground water quality is degrading or improving and shall present the …

Creating Computer Availability Maps, Scott Bacon

Library Faculty Publications

During the fall semester of 2012, the Kimbel Library and Bryan Information Commons conducted a LibQUAL+ survey to gauge how patron needs were being met. Many survey respondents commented that there were not enough computers for use in the library buildings. This issue was remedied by the addition of over 70 percent more computer workstations in the new commons building, a move that was well received by patrons. However, these desktops still filled up quickly, especially during midterms and finals, so the library decided to create a dynamic system to show patrons which computers were available for use at any …

Universal Electric Current Of Interacting Resonant-Level Models With Asymmetric Interactions: An Extension Of The Landauer Formula, Akinori Nishino, Naomichi Hatano, Gonzalo Ordonez

Scholarship and Professional Work - LAS

We study the electron transport in open quantum-dot systems described by the interacting resonant-level models with Coulomb interactions. We consider the situation in which the quantum dot is connected to the left and right leads asymmetrically. We exactly construct many-electron scattering eigenstates for the two-lead system, where two-body bound states appear as a consequence of one-body resonances and the Coulomb interactions. By using an extension of the Landauer formula, we calculate the average electric current for the system under bias voltages in the first order of the interaction parameters. Through a renormalization-group technique, we arrive at the universal electric current, …

Near-Optimal Online Multiselection In Internal And External Memory, Jonathan P. Sorenson, Jérémy Barbay, Ankur Gupta, S. Srinivasa Rao

Scholarship and Professional Work - LAS

We introduce an online version of the multiselection problem, in which q selection queries are requested on an unsorted array of n elements. We provide the first online algorithm that is 1-competitive with online algorithm proposed by Kaligosi et al.[ICALP 2005] in terms of comparison complexity. Our algorithm also supports online search queries efficiently.

We then extend our algorithm to the dynamic setting, while retaining online functionality, by supporting arbitrary insertions and deletions on the array. Assuming that the insertion of an element is immediately preceded by a search for that element, we show that our dynamic online algorithm performs …

Patterns Of Terrestrial And Limnologic Development In The Northern Greater Yellowstone Ecosystem (Usa) During The Late-Glacial/Early-Holocene Transition, Teresa R. Krause, Yanbin Lu, Cathy Whitlock, Sherilyn C. Fritz, Kenneth L. Pierce

Department of Earth and Atmospheric Sciences: Faculty Publications

A high-resolution record of pollen, charcoal, diatom, and lithologic data from Dailey Lake in south-western Montana describes postglacial terrestrial and limnologic development from ice retreat ca. 16,000 cal yr BP through the early Holocene. Following deglaciation, the landscape surrounding Dailey Lake was sparsely vegetated, and erosional input into the lake was high. As summer insolation increased and ice recessional processes subsided, Picea parkland developed and diatoms established in the lake at 13,300 cal yr BP. Closed subalpine forests of Picea, Abies, and Pinus established at 12,300 cal yr BP followed by the development of open Pinus and Pseudotsuga forests at …

A Fast Visible Infrared Imaging Radiometer Suite Simulator For Cloudy Atmospheres, Chao Liu, Ping Yang, Shaima L. Nasiri, Steven Platnick, Kerry G. Meyer, Chenxi Wang, Shouguo Ding

Department of Earth and Atmospheric Sciences: Faculty Publications

A fast instrument simulator is developed to simulate the observations made in cloudy atmospheres by the Visible Infrared Imaging Radiometer Suite (VIIRS). The correlated k distribution technique is used to compute the transmissivities associated with absorbing atmospheric gases. The bulk scattering properties of ice clouds are based on the ice model used for the Moderate Resolution Imaging Spectroradiometer Collection 6 ice cloud products, and those of water clouds are computed with the Lorenz-Mie theory. Two fast radiative transfer models based on precomputed ice cloud look-up tables are used for the VIIRS solar and infrared channels. The accuracy and efficiency of …

First Report On Dinosaur Tracks From The Burro Can Yon Formation, San Juan County, Utah, Usa – Evidence Of A Diverse, Hitherto Un Known Lower Cretaceous Dinosaur Fauna, Jesper Milan, Luis M. Chiappe, David B. Loope, James I. Kirkland, Martin G. Lockley

Department of Earth and Atmospheric Sciences: Faculty Publications

The newly discovered White Mesa tracksite in the Burro Canyon Formation represents a snap shot of a diverse, Lower Cretaceous dinosaur fauna from south-eastern Utah. The tracks were found at a construction site where the sand stone had been bull dozed and broken up. All tracks were found as deep, well-preserved natural casts on the under side of the sand stone slabs. Individual theropod tracks are 19–57 cm in length; one peculiar track shows evidence of a possible pathological swelling in the middle of digit III and an apparently didactyl track is tentatively as signed to a dromaeosaurid. Individual sauropod …

Pcb Food Web Dynamics Quantify Nutrient And Energy Flow In Aquatic Ecosystems, Anne M. Mcleod, Gord Paterson, Ken G. Drouillard, Douglas G. Haffner

Great Lakes Institute for Environmental Research Publications

Measuring in situ nutrient and energy flows in spatially and temporally complex aquatic ecosystems represents a major ecological challenge. Food web structure, energy and nutrient budgets are difficult to measure, and it is becoming more important to quantify both energy and nutrient flow to determine how food web processes and structure are being modified by multiple stressors. We propose that polychlorinated biphenyl (PCB) congeners represent an ideal tracer to quantify in situ energy and nutrient flow between trophic levels. Here, we demonstrate how an understanding of PCB congener bioaccumulation dynamics provides multiple direct measurements of energy and nutrient flow in …

Substrate-Assisted And Enzymatic Pretransfer Editing Of Nonstandard Amino Acids By Methionyl-Trna Synthetase, Grant B. Fortowsky, Daniel J. Simard, Mohamed M. Aboelnga, James W. Gauld

Chemistry and Biochemistry Publications

Aminoacyl-tRNA synthetases (aaRSs) are cen- tral to a number of physiological processes, including protein biosynthesis. In particular, they activate and then transfer their corresponding amino acid to the cognate tRNA. This is achieved with a generally remarkably high fidelity by editing against incorrect standard and nonstandard amino acids. Using docking, molecular dynamics (MD), and hybrid quantum mechanical/molecular mechanics methods, we have inves- tigated mechanisms by which methionyl-tRNA synthetase (MetRS) may edit against the highly toxic, noncognate, amino acids homocysteine (Hcy) and its oxygen analogue, homo- serine (Hse). Substrate-assisted editing of Hcy-AMP in which its own phosphate acts as the mechanistic …

Aspirin Inhibits Formation Of Cholesterol Rafts In Fluid Lipid Membranes, Richard J. Alsop, Laura Toppozini, Drew Marquardt, Norbert Kučerka, Thad A. Harroun, Maikel C. Rheinstädter

Chemistry and Biochemistry Publications

Aspirin and other non-steroidal anti-inflammatory drugs have a high affinity for phospholipid membranes, altering their structure and biophysical properties. Aspirin has been shown to partition into the lipid head groups, thereby increasing membrane fluidity. Cholesterol is another well known mediator of membrane fluidity, in turn increasing membrane stiffness. As well, cholesterol is believed to distribute unevenly within lipid membranes leading to the formation of lipid rafts or plaques. In many studies, aspirin has increased positive outcomes for patients with high cholesterol. We are interested if these effects may be, at least partially, the result of a non-specific interaction between aspirin …

Hierarchical Analysis Of Genetic Structure In The Habitat-Specialist Eastern Sand Darter (Ammocrypta Pellucida), Robert Ginson, Ryan P. Walter, Nicholas E. Mandrak, Courtney L. Beneteau, Daniel D. Heath

Great Lakes Institute for Environmental Research Publications

Quantifying spatial genetic structure can reveal the relative influences of contemporary and historic factors underlying localized and regional patterns of genetic diversity and gene flow - important considerations for the development of effective conservation efforts. Using 10 polymorphic microsatellite loci, we characterize genetic variation among populations across the range of the Eastern Sand Darter (Ammocrypta pellucida), a small riverine percid that is highly dependent on sandy substrate microhabitats. We tested for fine scale, regional, and historic patterns of genetic structure. As expected, significant differentiation was detected among rivers within drainages and among drainages. At finer scales, an unexpected lack of …

Benefits Of Turbid River Plume Habitat For Lake Erie Yellow Perch (Perca Flavescens) Recruitment Determined By Juvenile To Larval Genotype Assignment, Lucia B. Carreon-Martinez, Ryan P. Walter, Timothy B. Johnson, Stuart A. Ludsin, Daniel D. Heath

Great Lakes Institute for Environmental Research Publications

Nutrient-rich, turbid river plumes that are common to large lakes and coastal marine ecosystems have been hypothesized to benefit survival of fish during early life stages by increasing food availability and (or) reducing vulnerability to visual predators. However, evidence that river plumes truly benefit the recruitment process remains meager for both freshwater and marine fishes. Here, we use genotype assignment between juvenile and larval yellow perch (Perca flavescens) from western Lake Erie to estimate and compare recruitment to the age-0 juvenile stage for larvae residing inside the highly turbid, south-shore Maumee River plume versus those occupying the less turbid, more …