Physical Sciences and Mathematics Commons^™

How Much Noise Is Too Much For Southern Resident Killer Whales In The Salish Sea? The Case For A Carrying Capacity Study., Rob Williams, Cindy R. Elliser, Ginny Broadhurst

Institute Publications

Background and rationale for the need of a carrying capacity study that will provide the necessary data to understand what amount of vessel noise is acceptable, while at the same time allowing marine life to maintain healthy populations.

Synthesis And Characterization Of Terbium(Iii) Complexes: Can We Manipulate The Emission Signature?, Ryan Gagnon

Belmont University Research Symposium (BURS)

Successful Lewis acid/base reactions of terbium(III) nitrate with 2,2’-bipyrdine (22’bpy), 1,10-phenanthroline (phen), and 2,6-pyridine dimethanol (pydm) have yielded the products: Tb(22’bpy)₂(NO₃)₃, Tb(phen)₂(NO₃)_3, and [Tb(pydm)₃](NO₃)₃, respectively. In accord with the well-known antenna-effect, the absorption spectrum of each complex is similar to the spectrum of the free ligand, while the emission spectrum of the complex is identical for the free terbium(III) ion. In contrast, the substitution of a ligand containing a third-row nonmetal strategically placed near the terbium may force interaction between the 3p nonmetal …

Toi-836: A Super-Earth And Mini-Neptune Transiting A Nearby K-Dwarf, F. Hawthorn, D. Bayliss, T. G. Wilson, A. Bonfanti, V. Adibekyan, Y. Alibert, S. G. Sousa, K. A. Collins, E. M. Bryant, A. Osborn, D. J. Armstrong, L. Abe, J. S. Acton, B. C. Addison, K. Agabi, R. Alonso, D. R. Alves, G. Anglada-Escudé, T. Bárczy, T. Barclay, D. Barrado, S. C. C. Barros, W. Baumjohann, P. Bendjoya, W. Benz, A. Bieryla, X. Bonfils, F. Bouchy, A. Brandeker, C. Broeg, D. J. A. Brown, M. R. Burleigh, M. Buttu, J. Cabrera, D. A. Caldwell, S. L. Casewell, D. Charbonneau, S. Charnoz, R. Cloutier, A. Collier Cameron, K. I. Collins, D. M. Conti, N. Crouzet, S. Czismadia, M. B. Davies, M. Deleuil, E. Delgado-Mena, L. Delrez, O. D. S. Demangeon, B.-O. Demoray, G. Dransfield, X. Dumusque, J. A. Egger, D. Ehrenreich, P. Eigmüller, A. Erickson, Z. Essack, A. Fortier, L. Fossati, M. Fridlund, M. N. Günther, M. Güdel, D. Gandolfi, H. Gillard, M. Gillon, C. Gnilka, M. R. Goad, R. F. Goeke, T. Guillot, A. Hadjigeorghiou, C. Hellier, B. A. Henderson, K. Heng, M. J. Hooton, K. Horne, S. B. Howell, S. Hoyer, J. M. Irwin, J. S. Jenkins, J. M. Jenkins, Eric L.N. Jensen, S. R. Kane, A. Kendall, J. F. Kielkopf, L. L. Kiss, G. Lacedelli, J. Laskar, D. W. Latham, A. Lecavalier Des Etangs, A. Leleu, M. Lendl, J. Lillo-Box, C. Lovis, D. Mékarnia, B. Massey, T. Masters, P. F. L. Maxted, V. Nascimbeni, L. D. Nielsen, S. M. O'Brien, G. Olofsson, H. P. Osborn, I. Pagano, E. Pallé, C. M. Persson, G. Piotto, P. Plavchan, D. Pollacco, D. Queloz, R. Ragazzoni, H. Rauer, I. Ribas, G. Ricker, D. Ségransan, S. Salmon, A. Santerne, N. C. Santos, G. Scandariato, F.-X. Schmider, R. P. Schwarz, S. Seager, A. Shporer, A. E. Simon, A. M. S. Smith, G. Srdoc, M. Steller, O. Suarez, G. M. Szabó, J. Teske, N. Thomas, R. H. Tilbrook, A. H. M. J. Triaud, S. Udry, V. Van Grootel, N. Walton, S. X. Wang, P. J. Wheatley, J. N. Winn, R. A. Wittenmyer, H. Zhang

Physics & Astronomy Faculty Works

We present the discovery of two exoplanets transiting TOI-836 (TIC 440887364) using data from TESS Sector 11 and Sector 38. TOI-836 is a bright (T = 8.5 mag), high proper motion (∼200 mas yr⁻¹), low metallicity ([Fe/H]≈−0.28) K-dwarf with a mass of 0.68 ± 0.05 M_⊙ and a radius of 0.67 ± 0.01 R⊙. We obtain photometric follow-up observations with a variety of facilities, and we use these data sets to determine that the inner planet, TOI-836 b, is a 1.70 ± 0.07 R_⊕ super-Earth in a 3.82-d orbit, placing it directly within the so-called …

Using Object Detection To Navigate A Game Playfield, Peter Kearnan Hyde-Smith

Master's Theses (2009 -)

Perhaps the crown jewel of AI is the self-navigating agent. To take many sources of data as input and use it to traverse complex and varied areas while mitigating risk and damage to the vehicle that is being controlled, visual object detection is a key part of the overall suite of this technology. While much efforts are being put towards real-world applications, for example self-driving cars, healthcare related issues and automated manufacturing, we apply object detection in a different way; the automation of movement across a video game play field. We take the TensorFlow Object Detection API and use it …

Enots Wolley Variations And Related Sequences, Nathan Myles Nichols

Master's Theses (2009 -)

The Enots Wolley sequence is a lexicographically earliest sequence (LES) that is closely related to the Yellowstone sequence. It is an open conjecture by N. J. Sloane that every number with at least two distinct prime factors appears as a term of the Enots Wolley sequence. In this thesis, this conjecture is proved for a variation of the Enots Wolley sequence that operates on the binary representation of a positive integer rather than the prime factorization. The methods used are then applied to prove some new properties of the prime factorization Enots Wolley sequence.

Rage Inhibitors In Neurodegenerative Diseases, V. Prakash Reddy, Puspa Aryal, Pallavi Soni

Chemistry Faculty Research & Creative Works

Nonenzymatic Reactions of Reducing Sugars with Primary Amino Groups of Amino Acids, Proteins, and Nucleic Acids, Followed by Oxidative Degradations Would Lead to the Formation of Advanced Glycation Endproducts (AGEs). the AGEs Exert Multifactorial Effects on Cell Damage Leading to the Onset of Neurological Disorders. the Interaction of AGEs with the Receptors for Advanced Glycation Endproducts (RAGE) Contribute to the Activation of Intracellular Signaling and the Expression of the Pro-Inflammatory Transcription Factors and Various Inflammatory Cytokines. This Inflammatory Signaling Cascade is Associated with Various Neurological Diseases, Including Alzheimer's Disease (AD), Secondary Effects of Traumatic Brain Injury (TBI), Amyotrophic Lateral Sclerosis …

The Coastal Monitor: Vol. 10 No. 1, John Tanacredi Ph.D.

The Coastal Monitor

New Year’s Day has always been, for me, a time to reflect and project into the near future. Nature’s influence on us all certainly tops my listing with several environmental concerns. For example, the frequency and intensity of hurricanes to Long Island. A decade has passed since Superstorm Sandy re-opened the “Old Inlet” on Long Island which now has mostly naturally closed. So, the new year immediately prompts me to assess the previous year’s Hurricane Ian, a Category 4 system, with winds exceeding 150 mph, which had considerable impact in Florida, and then proceeded north resulting in over 2 inches …

Sustainability Club, Brianna Bernhardt, Marissa Lindemann

Honors Expanded Learning Clubs

An environmental and agricultural-based club focusing on sustainability. Results in a cleaner school environment, knowledge about various sustainable practices, art projects, and an appreciation of nature.

Stem Club, Rohan Tatineni, Kevin Prososki

Honors Expanded Learning Clubs

The goal of STEM club is to teach the students various basic scientific principles and relate them to experiments and the real world. In addition, the scientific method will be taught and be a main focus of the club along with the engineering design process.

Synthesis And Characterization Of Hydroxy-Functionalized Copper Indium Disulfide Quantum Dots, Julia Schexnayder

WWU Honors College Senior Projects

Quantum dots offer tunable electronic and optical properties due to the quantum confinement effect, making them desirable for various applications. However, their native hydrophobic form requires surface chemistry modification for certain applications. This research explores the method of ligand exchange using 11-mercapto-1-undecanol for improving the stability of copper indium disulfide (CIS) quantum dot (QD) nanoparticles in polar environments. The effects of this ligand exchange on QD chemical composition, optical properties, hydroxy-reactivity, and hydrodynamic radius are characterized. Analysis of characterization results indicates successful surface modification through hydroxyfunctionalization, as confirmed by 1H-NMR and IR spectroscopy. The desired optical properties of the QDs …

An Exploration Of Computational Text Analysis Of Co-Design Discourse In A Research-Practice Partnership, Mei Tan, Victor R. Lee

Publications

In combination with contextualized human interpretation, computational text analysis offers a quantitative approach to interrogating the nature of participation and social positioning in discourse. Using meeting transcript data from the development of a co-design research-practice partnership, we examine the roles and forms of participation that contribute to an effective collaboration between a multileveled school system and researcher partners. We apply computational methods to explore the language of co-design and multi-stakeholder perspectives in support of educational improvement science efforts and our theoretical understanding of partnership roles. Results indicate participation patterns align with documented roles in co- design partnerships and highlight the …

Geometry And Coding: Introducing An Interactive And Integrated Mathematics-Computer Science Unit, Kimberly Beck, Jessica F. Shumway

Publications

As part of a collaborative project between Utah State University, the Cache County School District, and Stanford, instructional units were designed for fifth-grade students. These units integrated math concepts of geometrical shapes and computer science concepts of sequences, conditionals, and loops. One component of the unit was implemented in math classrooms by math teachers, and the other component was implemented in computer labs. This presentation will focus on the math unit as presented at the National Council of Teachers of Mathematics (NCTM-V).

Using Mineral Magnetism To Characterize Compositions Of Fe-Ti Oxide Phases Of The Sulphur Creek Lava Flow (Kulshan), Elika Zilis

WWU Honors College Senior Projects

The aim of this study is to examine variations in the composition of Fe-Ti oxide minerals in the Sulphur Creek lava flow (SE margin of Kulshan), using magnetic techniques and electron microscopy. Geochemical and petrological data from these rocks dated ~9.8 ka may be a product of two distinct magma pulses (Garvey, 2002) with two distinct compositions: andesitic basalt and basalt. The composition of cubic oxides (magnetite and ulvöspinel) is influenced by the geochemistry of the crystallizing magma and can be used to provide information about the chemical evolution of these magmas, but also to help frame future paleomagnetic studies …

Final Report: Turtle Creek Park, Auden Block, Juliette Chandler, Bethany Fitch, Haley Dickinson, Will Earley

Final Reports in ENST 411: Environmental Community Projects

During the Spring 2023 semester, we worked as a group with East Buffalo Township supervisors to develop plans for newly-acquired Turtle Creek Park. Specifically, our project centered on facilitating community engagement with Phase One of the restoration plan and helping the Supervisors lay a foundation for future phases of the park's revitalization. Our report details our work on mapping the park's trail system, identifying and mapping areas of poor drainage, and creating a series of interpretive signs for public education about the park, its natural history, and its ecology.

Investigation Of Cofactor Activities Of Endothelial Microparticle- Thrombomodulin With Liposomal Surrogate, Valentinas Gruzdys, Lin Wang, Dan Wang, Rachel Huang, Xue-Long Sun

Chemistry Faculty Publications

Thrombomodulin (TM) is a type I transmembrane glycoprotein mainly expressed on the endothelial cells, where it binds thrombin to form the thrombin-TM complex that can activate protein C and thrombin-activable fibrinolysis inhibitor (TAFI) and induce anticoagulant and anti-fibrinolytic reactions, respec-tively. Cell activation and injury often sheds microparticles that contain membrane TM, which circulate in biofluids like blood. However, the biological function of circulating microparticle-TM is still unknown even though it has been recognized as a biomarker of endothelial cell injury and damage. In comparison with cell membrane, different phospholipids are exposed on the microparticle surface due to cell membrane "flip-flop"upon …

Using Capillary Electrophoresis To Quantify Competitive Binding Of Adsorbates To Silver Nanoparticles, Christopher D. Chung , '23

Senior Theses, Projects, and Awards

Silver nanoparticles (AgNPs) are increasingly used commercially and medically due to their antimicrobial and antibacterial properties. With increased use comes increased release of AgNPs into the environment, and once released, AgNPs can form coronas with molecules ranging from biomolecules to proteins to natural organic matter (NOM). The molecules in the corona adsorb to the surface of the AgNPs, drastically altering their innate properties such as cytotoxicity and binding behavior. In this study, we characterize and quantify model AgNP-adsorbate systems by obtaining their relevant reaction parameters through three different affordable analytical techniques, including dynamic light scattering (DLS), UV-vis spectroscopy, and capillary …

Using Caulobacter Crescentus As A Model To Probe The Environmental Reactivity Of Silver Nanoparticles, Madeline M. Farber , '23

Senior Theses, Projects, and Awards

Silver nanoparticles (AgNPs) are an increasingly common environmental pollutant with antimicrobial and antibacterial properties. The elucidation of their interaction with cellular membranes and subsequent mechanisms of toxicity are critical areas of research that need to be better understood in order to manage potential adverse environmental effects. This work investigates the interaction of AgNPs with large unilamellar vesicles (LUVs) as a model membrane system. Similar studies conducted by others in this field have largely been conducted with uncoated AgNPs, ignoring the effect of environmental conditions on the formation of an eco-corona on AgNPs. Thus, in this study, the spent medium (SM) …

Master Equation Modeling Of Prompt Dissociation Kinetics For Isoprene Derived Criegee Intermediates, Rory R. Schmidt , '23

Senior Theses, Projects, and Awards

Isoprene ozonolysis is a major atmospheric producer of atmospheric oxidizers and aerosols. This complex reaction pathway forms an exothermic cascade, where constant competition between bimolecular sinks, unimolecular isomerizations, and collisional relaxation dictate reactivity. This work focuses on two isoprene derived Criegee intermediates, methacrolein oxide (MACR oxide) and formaldehyde oxide (FO). While the potential energy surface of FO is well understood, the reactivity of energetically excited FO has not been explored in detail. MACR oxide isomerization and primary products have been adequately characterized and explored computationally and experimentally, but the potential energy surface beyond isopropenyl dioxirane has not received the same …

Biophysical And X-Ray Crystallographic Characterizations On Complexes Of G-Quadruplexes With Small-Molecule Ligands, Ming Ye , '23

Senior Theses, Projects, and Awards

DNA can fold into G-quadruplexes (GQs), non-canonical secondary structures formed by stacking of G-tetrads. GQs are important in many biological processes, which makes them promising therapeutic targets for anticancer and antiviral drugs. Therefore, investigating the interaction between GQs and small-molecule ligands is important.

This thesis work surveyed the DNA-ligand interactions of over 20 GQ-ligand complexes via biophysical and X-ray crystallographic methods. Two sets of GQ-ligand complexes were characterized in detail. One set is a group of purine-only sequences, named GA, with a highly selective GQ ligand, N-methyl mesoporphyrin IX (NMM). The other set is a human telomeric sequence, Tel22, with …

Method Design For Separation Of Non-Canonical Dna Structures Via Capillary Electrophoresis, Erin V. Chen , '23

Senior Theses, Projects, and Awards

G-quadruplex DNA structures are highly relevant subjects of biochemical study, implicated in human diseases and cancer. Conventional methods for G-quadruplex DNA structure separation are time-consuming, environmentally unfriendly, and low throughput. Thus, there is a pressing need for alternative methods of separation to be developed for G-quadruplex DNAs. Here we present work in designing a separation method using the capillary electrophoresis instrument. Capillary electrophoresis is a highly automated, reusable, and quantitative technique that separates analytes based on their size and charge. A capillary method for G-quadruplex separation would be a valuable analytical tool to supplement the biophysical methods available by addressing …

Raise The Sun: A Qtbipoc Zine Workshop, Chris O. Stone , '23

Senior Theses, Projects, and Awards

No abstract provided.

Development Of Innovative Multi-Drug Approaches To Counteract Illicit Drug Abuse In The Uae Population, Manal Ali Alhefeiti

Dissertations

The abuse of addictive substances is on the rise in the United Arab Emirates (UAE) population. Consequently, the UAE government spends about Dhs 5.5 billion annually on the rehabilitation of drug addicts. Blood, urine, and hair tests can reveal signs of sporadic or chronic drug use. Given the list of banned chemicals in the UAE, our main objective in this work was to develop a novel analytical method to identify and measure banned substances, especially prescription and over-the-counter drugs in the UAE. We developed and validated a rapid, sensitive and reliable liquid chromatography-mass spectrometry/mass spectrometry (LC-MS/MS) approach for the targeted …

The Extremes Of Galaxy Formation & Evolution, Kelly E. Whalen

Dartmouth College Ph.D Dissertations

Galaxy populations are shaped by the physical processes that regulate their star formation and central black hole growth throughout cosmic time. The primary aim of this thesis is to understand how these processes occur and how they shape evolution in some of the most extreme galaxies in the Universe including quasars, compact starbursts, and ultra-diffuse dwarfs. Gas-rich major mergers funnel large amounts of gas towards the nucleus, triggering rapid AGN accretion and compact star formation. In this work, I study powerful quasars and extreme, massive, compact starburst galaxies within the context of merger-driven galaxy evolution scenarios. One aim of this …

Arousing Motives Or Eliciting Stories? On The Role Of Pictures In A Picture–Story Exercise, Philipp Schäpers, Stefan Krumm, Filip Lievens, Nikola Stenzel

Research Collection Lee Kong Chian School Of Business

Picture–story exercises (PSE) form a popular measurement approach that has been widely used for the assessment of implicit motives. However, current theorizing offers two diverging perspectives on the role of pictures in PSEs: either to elicit stories or to arouse motives. In the current study, we tested these perspectives in an experimental design. We administered a PSE either with or without pictures. Results from N = 281 participants revealed that the experimental manipulation had a medium to large effect for the affiliation and power motive domains, but no effect for the achievement motive domain. We conclude that the herein chosen …

Engaging Students Through Conversational Chatbots And Digital Content: A Climate Action Perspective., Thomas Menkhoff, Benjamin Gan

Research Collection Lee Kong Chian School Of Business

In this case study, we report experiences deploying a conversational chatbot as a pre-class and post-class engagement tool for undergraduate students enrolled in sustainability-related courses aimed at educating them about the severity of climate change and the importance of climate action by offsetting one’s carbon footprint (e.g, by planting trees or mangroves in SEA). The intitiative supports the university’s sustainability efforts in general and our new sustainability major in particular aimed at helping students to achieve sustainability-related learning outcomes with reference to climate change and climate action (SDG 13), one of the 17 Sustainable Development Goals established by the United …

Valuation Of Asian Options In A High Volatility Market With Jumps, Zeeshan Khalid

Theses

The evaluation of financial derivatives represents a central part of financial risk management. There are many types of derivatives among other path-dependent options. In this study, we aim at valuing Asian options. They are path dependent and have several benefits. For instance, their values are habitually lower than European options. Also, an Asian option on a commodity drops the risk value close to maturity. Though, the disadvantage is that they are in general difficult to value since the distribution of the payoff is usually unknown. It is agreed in the literature that a stochastic process with a jumps model for …

Cheating Detection In Online Exams Based On Captured Video Using Deep Learning, Aysha Sultan Alkalbani

Theses

Today, e-learning has become a reality and a global trend imposed and accelerated by the COVID-19 pandemic. However, there are many risks and challenges related to the credibility of online exams which are of widespread concern to educational institutions around the world. Online exam system continues to gain popularity, particularly during the pandemic, due to the rapid expansion of digitalization and globalization. To protect the integrity of the examination and provide objective and fair results, cheating detection and prevention in examination systems is a must. Therefore, the main objective of this thesis is to develop an effective way of detection …

Data-Driven Modeling Of Student Performance In The Time Of Distance Learning, Iman Saad Megdadi

Theses

One of the important aspects that all academic institutions work towards improving is Student Performance. It is obviously the primary indicator of success or failure of institutions. Student performance predictions are vital to instructors and educational decision makers to help, across all levels, tailor learning according to the students’ needs. Therefore, it is essential for Higher Education Institutions to predict student performance in distance learning which has been, and remains, the primary method of learning in some countries due to Corona Virus pandemic. For this reason, this research is going to predetermine a fitting definition of student performance in time …

An Analysis Of Energy Production And Efficiency In Various Longbow Archery Models, Hannah Mcpherson

Honors Projects

An analysis of the energy production and efficiency of three lab-tested longbow models is undertaken. The first model, which is constructed to not allow flexing of limbs and which uses a frictionless cart and track in place of an arrow, demonstrated an efficiency of 50% +/- 40%. The second model, which is constructed similarly to the first with the exception of a wooden dowel now being used as an arrow-like object, demonstrated an efficiency of 13% +/- 3%. The last model, a 3D printed longbow with flexible limbs using the wooden dowel as an arrow-like object, demonstrated an efficiency of …

A Support Theorem For A Wave Equation, Aysha Khaled Alshamsi

Theses

It is well known that the fundamental solution to the classical wave equation Δ𝑢 (𝑥, 𝑡) − ∂_𝑡𝑡𝑢(𝑥,𝑡) = 0 is supported on the light cone {(𝑥, 𝑡) ∈ ℝ^𝑛× ℝ : ||𝑥|| = |𝑡|} if and only if the dimension 𝑛 is odd and ≥ 3. Because we are living in a 3-dimensional world we can hear each other clearly; One has a pure propagator without residual waves. In this thesis we consider the wave equation

2||𝑥||Δ_𝑘𝑢_𝑘(𝑥, 𝑡) − ∂_𝑡𝑡𝑢(𝑥,𝑡) = 0, (𝑥, 𝑡) ∈ ℝ^𝑛 × ℝ …