Physical Sciences and Mathematics Commons^™

Reactive End Capped Polybenzimidazole Oligomers For High Temperature Thermosets And Improved Membranes For Electrochemical Devices, Caroline Marie Rohlfing

Theses and Dissertations

Polybenzimidazoles (PBI) are heterocyclic polymers that possess high thermal and oxidative stability. The inherent strength and chemical and thermal stability of PBI make it ideal for use in extreme environments; however, the current processing of PBI molded parts makes the process practically and economically unfavorable. These intrinsic properties make PBIs of particular interest for many industrial applications, varying from fabrics to membrane materials to molded parts. Processing these molded parts is extremely difficult, as the high glass transition temperature and extremely high melting point (>500°C) of PBI result in poor flow properties of PBI resins even at high temperatures. …

Dust Production And Transport In A Long-Lived Fluvial-Eolian System In The Pampas Of South America, Blake Marcus Stubbins

Theses and Dissertations

Wind-blown dust from southern South America links the terrestrial, marine, atmospheric, and biologic components of Earth’s climate system. The Pampas of central Argentina (~33-40° S) contain an extensive upper Miocene to Holocene eolian record that spans the relatively warm conditions of the Late Miocene to cooler climates of the Plio-Pleistocene and Holocene. We collected 13 loess, paleosol, and fluvial samples from the upper Miocene Cerro Azul and Rio Negro Formations which resulted in n = 5129 new detrital zircon U-Pb ages. Late Miocene rivers conveyed sediment from northern Patagonia, the Andes adjacent to the Pampas, and the Sierras Pampeanas to …

Sustainable Approaches To Photo-, Thermo-, And Electro-Chemical Reactions Of Amines, James David Sitter

Theses and Dissertations

In recent years, sustainable routes for chemical synthesis have garnered renewed interest. As the world continues to fight pollution and rising costs, it is imperative that new routes of synthesis that continuously fight the issues of pollution and waste are discovered, defined and explored. While traditional synthesis routes that require energy input typically require the burning of fossil fuels to produce heat, the amount of resources that go into the production of these fossil fuels and the sequestration of its waste to minimize its impact on the carbon footprint is enormous. Furthermore, sustainable chemistry research aims to decrease and minimize …

Utilizing Deep Learning Methods In The Identification And Synthesis Of Gene Regulations, Jiandong Wang

Theses and Dissertations

Gene expression is the fundamental differentiation and development process of life. Although all cells in an organism have essentially the same DNA, cell types and activities vary due to changes in gene expression. Gene expression can be influenced by many gene regulations. RNA editing contributes to the variety of RNA and proteins by allowing single nucleotide substitution. Reverse transcription can alter the expression status of genes by inducing genetic diversity and polymorphism via novel insertions, deletions, and recombination events. Gene regulation is critical to normal development because it enables cells to respond rapidly to environmental changes. However, identifying gene regulations …

Exploring The Current Training Of Undergraduate Geology Students And Teaching Spatial Skills To Improve Student Outcomes, Ann Marie Klyce

Theses and Dissertations

Spatial skills, which represent the ability to mentally manipulate objects (Schneider & McGrew, 2012; Atit et al., 2020) have been shown to be correlated with entrance, persistence and success in STEM (Shea et al., 2001; Wai et al., 2009). Specifically, these skills have been shown to be necessary to geologists and geoscientists (Hegarty, 2014; Gagnier et al., 2016). While we recognize the importance of these skills, explicit training in them is rarely offered (NRC 2006). Consequently, cognitive scientists and discipline based education researchers have begun concerted efforts to offer training in spatial skills to improve student outcomes (e.g. Uttal et …

Sparse Partitioned Empirical Bayes Ecm Algorithms For High-Dimensional Linear Mixed Effects And Heteroscedastic Regression, Anja Zgodic

Theses and Dissertations

Variable selection methods in both the frequentist and Bayesian frameworks are powerful techniques that provide prediction and inference in high-dimensional linear regression models. These methods often assume independence between observations and normally distributed errors with the same variance. In practice, these two assumptions are often violated. To mitigate this, we develop efficient and powerful Bayesian approaches for linear mixed modeling and heteroscedastic linear regression. These method offers increased flexibility through the development of empirical Bayes estimators for hyperparameters, with computationally efficient estimation through the Expectation Conditional-Minimization (ECM) algorithm. The novelty of these approaches lies in the partitioning and parameter expansion, …

Structure Property Investigation And Applications Of Self-Assembled Triphenylamine Bis Urea Macrocycles, Md Faizul Islam

Theses and Dissertations

Porous organic crystals can be advantageous as nanoreactors and in sensing, separations, and storage. The Shimizu group utilizes bifurcated urea hydrogen bonding to direct the assembly small building block into pillars and columns affording functional porous crystals. Recently, our group has examined the incorporation of triphenylamines within the framework of bis-urea macrocycles. These macrocycles assemble into columns that contain the solvent of crystallization bound within the channels. Heating the crystals leads to removal of the solvent and activates the host for guest exchange by single-crystal-to-single[1]crystal transformations. Different electron accepting molecules can be encapsulated inside the pore of the host …

Molecular Devices For Measuring Weak Solvophobic Interactions And The Development Of Pedagogical Tools For Organic Chemistry Students, Alexander N. Manzewitsch

Theses and Dissertations

The main topics of this dissertation are: 1) the development and discussion of a new molecular balance for measuring alkyl-alkyl interactions in a wide array of organic solvents, 2) the development of linear solvation energy relationships between solvent interaction parameters and solvent accessible surface area (SASA) in CH-arene interactions, and 3) the development of online resources for helping undergraduate students perform organic chemistry mechanisms problems well.

The solvophobic effect, that is the forced association between two solutes due to intermolecular attraction of the solvent molecules, is ubiquitous in organic chemistry and responsible for many significant phenomena thereof. However, there is …

Denoising-Based Domain Adaptation Network For Eeg Source Imaging, Runze Li

Electronic Thesis and Dissertation Repository

Electrophysiological source imaging (ESI) is a widespread and no-invasive technique in neuroscientific research and clinical diagnostics. It provides a well-established and high temporal resolution of source activity and gives the brain signal by analyzing the corresponding EEG signal.

However, it is still a major challenge to deal with the domain shift problem between the datasets of different subjects or sessions in ESI problem. Furthermore, the variable noise included in the EEG signals inevitably influence the accuracy of localization of source activity.

In this paper, we propose a novel denoising autoencoder-based unsupervised domain adaptation (DAE-UDA) algorithm to tackle these problems. To …

Pc-01 Synthesis Of Zinc Glycoconjugated Phthalocyanines As A Potential Phototherapeutic, Jessica A. Silva-Conejo, Katrina Mccarter, Tessa Greene, Joshua V. Ruppel

SC Upstate Research Symposium

Photodynamic Therapy (PDT) uses photosensitizers that are activated by light to produce singlet oxygen that can cause cell damage and potential cell death. Phthalocyanines are promising photosensitizers due to their absorption at clinically relevant wavelengths, meaning that they absorb at a wavelength that can penetrate deeper into tissues.

One challenge with using Phthalocyanines is that they have very low solubility in biological media. One potential approach to increase solubility is through glycoconjugation. Glycoconjugation can also be used as a strategy to increase selectivity toward targeted tissues. Glycoconjugated phthalocyanines can be synthesized using a copper catalyzed azide-alkyne cycloaddition reaction, otherwise known …

How Technology May Be Used For Future Disease Prediction: A Systematic Literature Review, Rich P. Manprisio, Mohammed Salam

Research Days

Exasperated by the current pandemic, our healthcare system continues to struggle with the accuracy and effectiveness of disease treatments. However, despite these growing challenges, technological advancements have aided potential disease prediction. There has been a positive correlation between utilizing technologies and leveraging them for disease predictions. Thanks to our continued reliance and technological advancement, current research shows that it has many viable options to aid the healthcare field. This systematic review looks at the current state of how technologies have been and can be used to improve healthcare.

Foliar Expression Of Candidate Genes Involved In Condensed Tannin Biosynthesis In White Clover (Trifolium Repens), Stephen N. Panter, J. Simmonds, A. Winkworth, A. Mouradov, G. C. Spangenberg

IGC Proceedings (1993-2023)

Bloat disease in cattle and sheep is caused by the rapid microbial degradation of protein-rich fodder in the rumen. This leads to the production of protein foams that trap gases, causing bloat, a condition that is often fatal to livestock and costly to farmers. Condensed tannins (CTs) are phenolic polymers produced by the phenylpropanoid pathway of plants (Figure 1). CTs bind to proteins under acidic to neutral conditions, such as those present in the rumen, slowing their breakdown. A diet with a CT content of between 2% and 4% by dry weight, which is provided by some pasture legumes (e.g. …

Discovery, Isolation And Characterisation Of Promoters In White Clover (Trifolium Repens), C. M. Labandera, Y. H. Lin, E. Ludlow, M. Emmerling, U. John, P. W. Sale, C. Pallaghy, G. C. Spangenberg

IGC Proceedings (1993-2023)

The availability of a suite of promoters with a range of spatial, temporal and inducible expression patterns is of significant importance to control targeted expression of genes for molecular breeding in forage species. A range of resources and tools have been developed for promoter isolation and characterisation in white clover (Trifolium repens L.), including a comprehensive BAC library and a 15K unigene microarray.

Novel Genotypes Of The Subtropical Grass Eragrostis Curvula For The Analysis Of Apomixis (Diplospory), S. Cardone, P. Polci, J. P. Selva, M. Mecchia, S. C. Pessino, P. Voigt, G. C. Spangenberg, V. Echenique

IGC Proceedings (1993-2023)

Eragrostis curvula (Schrad.) Nees is a variable grass native to Southern Africa. Its several forms, known as lovegrasses, were introduced to Australia, USA and Argentina as forage perennial grasses. Apomixis is a common trait in the genus Eragrostis, with diplospory being the most frequent type. Sexual reproduction also occurs in Eragrostis, although not frequently. Since most tetraploid Eragrostis lines are apomictic, the generation of a sexual tetraploid strain is a requirement for linkage analysis of the gene(s) governing the apomictic character. Furthermore, isogenic lines of the same ploidy, reproducing alternatively by sexuality or apomixes, represent an ideal system …

Isolation And Characterisation Of Genes Encoding Malate Synthesis And Transport Determinants In The Aluminum-Tolerant Australian Weeping-Grass (Microlaena Stipoides), R. M. Polotnianka, E. Ribarev, L. Mackin, K. A. Sivakumaran, G. D. Nugent, U. P. John, G. C. Spangenberg

IGC Proceedings (1993-2023)

Acid soils cover some 40% of the Earth’s arable land where they represent a major limitation to plant production. Plant growth on acid soils is primarily limited due to aluminium (Al) solubilized by acidity into toxic Al³⁺ cations which will inhibit root growth resulting in poor uptake of water and nutrients. Many important pasture species lack sufficient Al tolerance within their germplasm to allow effective breeding for this character.

Development And Use Of A Tool For Automated Alignments Of Genes In The Rice Bac's Genbank Card Against Other Species, P. Barre, G. Darrieutort, J. Auzanneau, B. Julier

IGC Proceedings (1993-2023)

In many cases, the analysis of the genetic bases of any trait requires molecular markers and if possible co-dominant PCR-based ones. In perennial fodder species, the number of publicly available markers (microsatellites and Sequence Tagged Site (STS)) is limited. Our goal is to use sequences from model grass species, i.e. rice, wheat, maize, barley, in L. perenne in order to develop STS markers in interesting regions such as under a QTL (Quantitative Trait Loci) or around a candidate gene,. As the genome sequence of rice is now available, the objective was to use the sequences of genes included in the …

Application Of Molecular Markers Derived From Medicago Truncatula In White Clover (Trifolium Repens L.), C. Jones, M. T. Abberton

IGC Proceedings (1993-2023)

White clover is the major forage legume of temperate areas. Genome maps have been produced recently (Jones et al., 2003; Barrett et al., 2004) and the location of QTL for important agricultural traits reported (Abberton et al., 2004). White clover is closely related to the model legume Medicago truncatula and there is likely to be considerable benefit in applying genomic resources from model to crop. However, the extent of synteny between the species must be established. Here we present preliminary results detailing progress towards this goal.

Screening Of Perennial Grasses And A Mutant Maize Collection By Fourier-Transformed Infrared (Ftir) Spectroscopy For Improved Biofuel Traits, S. C. Thain, P. Morris, S. Hawkins, C. Morris, I. S. Donnison

IGC Proceedings (1993-2023)

Currently the potential of biomass crops, including grasses, is limited because most species have not been bred for this purpose. However traits such as lignification, phenolic cross-linking and carbohydrate accessibility, which are also important for nutritive quality in forage grasses, can affect potential biofuel quality in applications such as combustion, fast-pyrolysis or fermentation. A collection of Lolium and Festuca species known to exhibit a range of lignin, cell wall phenolic and carbohydrate concentrations have been used to test optimum characteristics for biofuel processing. This collection formed a “calibration” set for subsequent high through-put FTIR chemical screening of additional plant lines: …

A Proposal For An International Transcriptome Initiative For Forage And Turf: Microarray Tools For Expression Profiling In Ryegrass, Clover And Grass Endophytes, T. Webster, N. Nguyen, C. Rhodes, S. A. Felitti, R. Chapman, D. Edwards, G. C. Spangenberg

IGC Proceedings (1993-2023)

Knowledge of the expression pattern of genes provides a valuable insight into gene function and role in determining the observed heritable phenotype. High–density cDNA and oligonucleotide microarrays represent powerful tools for transcriptome analysis to gain an understanding of gene expression patterns for thousands of genes. Internationally coordinated efforts in transcriptome analyses and sharing of microarray resources will benefit the advancement of our understanding of gene function in forage and turf species.

Effects Of Various Dietary Carbohydrate Sources On The Growth Performance And Body Composition Of The Dog Conch, Laevistrombus Canarium, Jen-Hong Chu

Journal of Marine Science and Technology

This study investigates the effects of dietary supplementation with various carbohydrate sources on the growth and dietary nutrient utilization efficiency of a 0.72-g dog conch, Laevistrombus canarium. Five treatment diets had supplementation with alpha-starch (Sta), dextrin (Dex), pullulan gum (Pg), xanthan gum (Xg), and carboxymethyl cellulose (CMC). At the end of the feeding trial, the best growth performance (weight gain, 442.23%) and diet efficiency (protein efficiency ratio, 1.25, and feed conversion ratio [FCR], 2.04) were exhibited by the dog conch fed the Sta diet, whereas the lowest growth performance was observed in the dog conch fed the Xg and CMC …

Cost Advantages Of Far East/Europe Trunk Route Deployment With Port Selection In East Asia, Tai Hui-Huang, Chang Chin-Wei

Journal of Marine Science and Technology

To cater to the gradually increasing sizes of ships, several traditional container ports in East Asia built deep-water wharves to attract shipping carriers to berth, a decision that is considered highly reasonable because it allows for shipping carriers to gain a cost advantage. For traditional Far East/Europe (F/E) trunk routes, shipping carriers must deploy vessels that are large enough at hub ports to maintain low transshipment costs. However, for a port to attract shipping carriers, it should be able to first meet the cargo demand of these carriers. The port would also need to improve the loading ratio to enjoy …

Influence Of Vacuum Condition On Rapid Chloride Migration (Rcm) Test For Chloride Penetration Resistance Of Concrete, Chih-Yen Lin, Chun-Fu Chang, Chung-Chia Yang

Journal of Marine Science and Technology

NT Build 492 regulates that the pressure be set at 7.5–37.5 torr and be maintained for 3 h for vacuum processing. This large range of acceptable vacuum pressure is awkward for research, and 3 h of pump-down time may be excessive. In this study, vacuum conditions were divided into vacuum pressure and pump-down time groups: various vacuum pressures and pump-down times were used to preprocess specimens to explore the effect of vacuum conditions on the RCM test. The salt ponding test was also conducted to identify the optimal vacuum conditions. It is shown that the relationship between vacuum pressure and …

Exhaust Noise Elimination Using Silencers Fortified With Perforated Tubes, Extended Tubes, Penetrable Resin Inlet And Orifice Plate, Min-Chie Chiu, Ho-Chih Cheng

Journal of Marine Science and Technology

Pneumatic equipment in marine diesel engine and associated piping system often emit extremely high level of noises when releasing pressure. Concerning the crew’s hearing health, discovering an efficient noise silencing device becomes essential. A silencer fortified with extended tubes, perforated tubes, orifice plate, and penetrable resin inlet is presented in order to competently dampen the blown-up noises. A simplified objective function by means of FEM, Artificial Neural Networks (ANNs), and a Genetic Algorithm (GA) is established to enable the numerical calculation when using a finite element method. Three silencer designs, silencer A (with element A, a penetrable resin inlet), B …

Deep Learning–Based, Oceantdlx Sea Ice Detection Model For Sar Image, Liu Lin, Li Wanwu, Li Hang, Sun Yi

Journal of Marine Science and Technology

This study constructs four deep-learning OceanTDLx series models and uses a WinR-AdaGrad gradient descent algorithm to train and optimize the constructed models. Through an analysis of the loss, accuracy, and time consumption of the four models (i.e., OceanTDL2, OceanTDL3, OceanTDL5 and OceanTDL8), we reveal that the models’ performance does not improve when the number of layers is increased and that OceanTDL5 provides the optimal performance. OceanTDL5 is compared with OceanTDA9 (a model that we previously constructed), and the curves for training loss_batch and training accuracy_batch indicate that OceanTDL5 is more suitable than OceanTDA9 for detecting distributed targets, particularly semi-melted sea …

Application Of Unmanned Aerial Vehicle–Based Infrared Images In Determining Characteristics Of Sea Surface Temperature Distribution, Hsing-Yu Wang, Hui-Ming Fang, Yun-Chih Chiang

Journal of Marine Science and Technology

This study investigated the temperature field of a body of water by using rotary-wing unmanned aerial vehicles (DJI Mavic 2 Enterprise Dual) comprising visible light and infrared cameras to determine sea temperature distribution. With a flight height of 150 m, image overlap of 80%, and image resolution of 4.75 cm/pixel, the proposed method was more effective than the conventional portable conductivity–temperature–depth device in rapidly measuring sea surface temperature and determining sea temperature distribution. The discharged heated water of the Hoping Power Plant traveled 100–330 m from the wastewater outfall and then gradually diffused in the range of 100–490 m before …

Mth 50 Syllabus, Koby Kohulan

Open Educational Resources

No abstract provided.

Prevalence And Trends Of Depression Among Cyberbullied Adolescents - Youth Risk Behavior Survey, United States, 2011 – 2019, Jason Nicholson, Catherine Marcum, George E. Higgins

International Journal of Cybersecurity Intelligence & Cybercrime

The difference in depression between non-cyberbullied and cyberbullied youth is not well understood. To describe the prevalence and trends in depression among cyberbullied adolescents. Using cross-sectional, nationally-representative data from the YRBS 2011 - 2019, we estimated the prevalence and trends of depression across the total years and within cyberbullied groups that include biological sex and race and ethnicity among adolescents. The results indicated the prevalence of depression was higher among those that were cyberbullied. Within the cyberbullied groups the total trend was higher than the non-cyberbullied, females had a higher prevalence of depression than males, and Hispanics had a higher …

Exploration Of C9or72c9-500 Sk2, Sk3 Channel Expression, Teresa L. Garrett

Festival of Research

ALS (also known as Lou Gehrig's Disease) is a neurodegenerative disease that weakens muscles and impacts physical function. The C9 Gene is responsible for creating proteins that help neurons send and receive signals across the synapse. Small Conductance calcium activated potassium channels (SK channels) affect the hyperpolarization phase of an action potential. Hypothesis: SK2 and SK3 clusters of C9 positive cells should decrease in size and intensity when exposed to a disease state compared to C9 negative controls.

Dynamic Equations, Control Problems On Time Scales, And Chaotic Systems, Martin Bohner

Mathematics and Statistics Faculty Research & Creative Works

The unification of integral and differential calculus with the calculus of finite differences has been rendered possible by providing a formal structure to study hybrid discrete-continuous dynamical systems besides offering applications in diverse fields that require simultaneous modeling of discrete and continuous data concerning dynamic equations on time scales. Therefore, the theory of time scales provides a unification between the calculus of the theory of difference equations with the theory of differential equations. In addition, it has become possible to examine diverse application problems more precisely by the use of dynamical systems on time scales whose calculus is made up …

Threat Construction And Framing Of Cyberterrorism In The U.S. News Media, Mehmet F. Bastug, Ismail Onat, Ahmet Guler

International Journal of Cybersecurity Intelligence & Cybercrime

This research aims to explore the influence of news media on the fear of cyberterrorism and how cyberterrorism is framed in the media. Using a mixed-method approach as a research strategy, this paper reports on two studies that explore the influence of news reading on the fear of cyberterrorism. The first study analyzed survey responses from 1,190 participants and found that increased exposure to reading news media was associated with increased fear of cyberterrorism. The second study, built on the first, sought to investigate how cyberterrorism is framed and constructed as a threat by the US local and national newspapers. …