Physical Sciences and Mathematics Commons^™

Naphthalene-2,3-Dialdehyde: A Synthon To 7,9-Polymethylene-8h-Cyclohepta[B]Naphthalene-8-One And A Study Of Their Aromaticity, Edward O. Crapps

Dissertations

This report describes the synthesis of naphthalene-2,3-dialdehyde, and an analytical method for determining its purity by thin layer chromatography. Subsequently, the dialdehyde was condensed with various cyclic ketones to generate a series of polymethylene bridged naphthotropones. It was found that planarity and aromaticity increase with the size of the methylene bridge, although, the bridge must contain six or more methylene groups for the latter to be true. The claim for aromaticity is supported by NMR and IR data, which indicates the positive charge for a perchlorate cation salt is delocalized over the naphthalene and tropone ring system. Furthermore, from the …

Bags Vs. Strings: Hadrons In Type I And Type Ii Superconducting Vacua, V. Parameswaran Nair, C. Rosenzweig

Publications and Research

Two popular models for hadronic structure are bags and strings. Both involve analogies with superconductivity. We claim that the most appropriate analogies are type I superconductors for bags and type II superconductors for strings. The structures of hadrons is somewhat different for the two situations. In principle, and in practice in the real world, it is the similarities which are most important. These include linear confining potentials, linearly rising Regge trajectories and short distance Coulomb potentials. These are all generic properties of bound states in a superconductor and the main distinctions between bags and strings is under what circumstances these …

John Muir Newsletter, August/October 1984, Holt-Atherton Pacific Center For Western Studies

Muir Center Newsletters (1981-2015)

Holt-Atherton Pacific Center \\/ / University of the Pacific for Western Studies X^ / Stockton, Calif 95211 VOLUME 4 AUGUST/OCTOBER 1984 NUMBER 4 EDITORIAL STAFF: RONALD H. LIMBAUGH, KIRSTEN E. LEWIS PROJECT UPDATE Muir scholars take note: the microform project is rounding third and heading for home. Since the last newsletter we have completed the filming of Series II (journals) and Series IV (illustrative works), and have begun filming Series III (manuscripts). The last series to be filmed, Series I (correspondence), is fully controlled but not yet camera-ready. By November we expect to have all the filming completed and processed. …

Deformation And Linkage Of Gorenstein Algebras, Andrew R. Kustin, Matthew Miller

Faculty Publications

General double linkage of Gorenstein algebras is defined. Rigidity, genericity, and regularity up to codimension six all pass across general double linkage. Rigid strongly unobstructed codimension four Gorenstein algebras which lie in different Herzog classes are produced.

I. A Temperature Dependent Nmr Study Of 6,6-Dicarbethoxy-5,5-Dideuteodi-Benzo--[A,C]-[L, 3]-Cycloheptadiene Ii. The Synthesis Of Four Deuterated Analogs Of 6, 6-Dicarbethoxydibenzo-[A,C]-[1,3]-Cycloheptadiene, Patrick F. Jonas

Masters Theses

The kinetics of conformational interchange of 6,6-dicarbethoxydi-benzo- a,c - 1,3 -cyloheptadiene and its 5,5-dideuterated analog were studied using variable temperature NMR techniques. The free energy of activation for conformational interchange of the parent compound was found to be 9.02 kcal mol^-1 and that of the 5,5-dideuterated analog to be 9.42 kcal mol^-1. Values of the entropy of activation were found to be -19.91 e. u. and -18.12 e. u. respectively. The spectra were recorded on a Nicolet NMC-360 wide bore spectrometer and the data collected treated as an AB spin system.

The 4,8-dideutero, 4,5,5,8-tetradeutero and 5,5,7,7-tetradeutero analogs …

The Adsorption Of Atmospheric Xenon And Inert Gas Measurements In Size Separates Of The Allende Meteorite, Russel L. Palma

Physics and Astronomy Department Publications

No abstract provided.

Land Use Effects On Shallow Earth Resistivity, Gary James Barton

Masters Theses

No abstract provided.

Use Of Ft-Ir And Nmr Spectra Of The Thf Extracts Of Mid-Rank Bituminous Coals To Predict Plasticity, Samuel Adesoji Irefin

Masters Theses & Specialist Projects

Plasticity, which typically develops at 380-420°C, is a unique property of mid-ranked coals. The phenomenon of plasticity in coals has been known for a long time but is still poorly understood. Even among coals of identical subrank and chemical composition, large differences in plastic behavior are commonly encountered. Plastic coals go through a softening and swelling state upon heating before they resolidify. Concurrent with the plastic state of the coal, thermal decomposition of the coal takes place.

The coking ability of a coal can be directly related to the plasticity of the coal. In liquefaction reactions, plastic coals tend to …

Impact Of Several Chemical And Physical Properties Of Two H-Coal Recycle Solvent Streams On Their Relative Solvent Quality, Joe Collins

Masters Theses & Specialist Projects

The purpose of this study was to follow the solvent quality curve of the recycle solvent streams of the H-Coal Pilot Plant run by Ashland Petroleum Company at Catlettsburg, Kentucky. This was done with the use of a microautoclave (shaker-bomb liquefaction unit). Several physical and chemical properties of these recycle oils were determined, and these values were correlated with the observed solvent quality. It is shown that the relative, solvent quality of these recycle oils correlate well with many of the chemical and some of the physical properties determined in this study.

Evalution Of Drainage Tile To Alleviate Salt Building In Heavy Soils Irrigated With Brackish Water And Cropped With Rice And Soybeans, T. C. Keisling, J. T. Gilmour, H. D. Scott, A. M. Sadeghi, R. E. Baser

Arkansas Water Resources Center Technical Reports

The use of tile drains for alleviating soluble salt accumulation on silt loam soil was investigated during 1984. Although the chemical analyses of the floodwater and tile drainage water were very similar suggesting that the floodwater was moving to the tile drain, the overall results so far indicate that this is not a feasible solution owing to lack of significant drainage. Application of DRAINMOD utilizing soil and weather data from Arkansas showed no significant effluent from the tile drains for our experimental site during rice production. This was attributed to the extremely slow saturated hydraulic conductivity values for this particular …

Precedings Of Arkansas Lakes Symposium Limnological Studies Of Lake Chicot, Arkansas, Joe F. Nix, Frank R. Schiebe

Arkansas Water Resources Center Technical Reports

Lake Chicot is an oxbow lake that was created more than 600 years ago by the meandering of the Mississippi River. It is located in Chicot county in southeastern Arkansas adjacent to the present Mississippi River. As the largest natural lake in Arkansas it earned an early reputation for its good fishing and recreational value. Development of a levee system forced the enlargement of the lakes watershed to its present 350 square miles. Initially this alteration affected only the volume flow through the lake, drastically reducing the water residence time. Because the watershed was located in one of the most …

Identification Of Critical Water Levels In Flooded Rice Fields, Carl L. Griffis

Arkansas Water Resources Center Technical Reports

A mathematical model was developed to simulate the transient hydrology of a flooded rice field. With the model, users can determine the critical interlevee areas in which to monitor the water levels so that the irrigation well can be turned on at the critical low water level, and turned off at the critical high water level, in order to maximize water application efficiency. Sensitivity analysis performed with the model showed that it will be necessary to calibrate the model for each specific field. A calibration procedure has been developed.

[See Pdf For Notation]-Reularity For The Solution Of Strongly Nonlinear Eigenvalue Problems On Orlicz-Sobolev Spaces, Pierre A. Vuillermot

Mathematics Technical Papers

We present a new method to prove the [see pdf for notation]-regularity of the eigenfunctions for Dirichlet problems with strictly convex Young functionnonlinearities in their principal part. The basic idea is threefold: we first invoke the topological methods of [12] to infer the existence of a countable infinity of [see pdf for notation]-eigensolutions; we then use Schauder's inversion technique to associate with each one of these eigensolutions a unique [see pdf for notation]-solution of an auxiliary Dirichlet problem; we finally prove the [see pdf for notation]-regularity of the original elgensolutions from the [see pdf for notation]-regularity of the auxiliary solutions, …

Effects Of Urbanization On The Hydrologic Regime Of Johnson Creek, Portland, Oregon, William Vandewater Clement

Dissertations and Theses

The Johnson Creek watershed, Portland, Oregon, has undergone urbanization at an increasing rate. Excessive flooding has occurred in the lower portions of the watershed, resulting in an estimated 1.5 million dollars worth of flood losses annually. In attempts to mitigate the flooding damages millions of dollars have been spent to channelize the creek, and over 200 thousand dollars has been spent during the last 20 years on preliminary feasibility studies alone.

The author saw a need to verify that there has been a change in the rainfall-runoff relationships in the upper Johnson Creek basin since 1941 and to quantify this …

Scs 94: Algebraic Theories For Proper Filter Monads, Oswald Wyler

Seminar on Continuity in Semilattices

No abstract provided.

A Focus Of Attention Algorithm For Expert Systems, Kevin W. Whiting, Arlan R. Dekock, John Bruce Prater

Computer Science Technical Reports

This research is primarily concerned with increasing the performance of expert systems. A refined focus of attention strategy and its affect on performance are discussed. Early expert systems used a brute force approach to process the knowledge base. Each production rule in the knowledge base was evaluated each cycle. More recently, processing efficiency has been increased by focusing the attention of the inference engine on a subset of the rules by "filtering" for further testing, only rules that could possibly fire given the current content of the context base. Focus of attention as developed in this research increases performance over …

Color Computer Graphics As Applied To Introductory Calculus Instruction, Kathy B. Windhorst, Ralph E. Lee

Computer Science Technical Reports

The use of computer graphics to support and enhance the presentation of introductory calculus concepts is described.

Computer graphics provides more accurate graph sketching, consistent presentations and the ability to develop mathematical models incrementally. The addition of extensive use of color aids even more, adding contrast, color keying, dimensionality, and interest to an illustration.

Ten lessons have been designed, developed, and evaluated. They employ a set of subroutines which interface to the NBC APC microcomputer graphics software. These lessons as developed and evaluated may be used interactively in the classroom or by individuals, or noninteractively in the classroom by the …

Water Current, Volume 16, No. 4, July/August 1984

Water Current Newsletter

Director's Report
Summary of UCOWR Annual Meeting
Symposium on Multiobjective Optimization
Groundwater Research Possibilties Explored
Nebraska Water Conference Council Fall Meeting
Research Review: Tillage Practice Effects on Water Conservation and the Efficiency and Management of Surface Irrigation Systems
NARD Annual Meeting

Glaciochemical Investigations As A Tool In The Historical Delineation Of The Acid Precipitation Problem, William B. Lyons, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Precipitation in the Northern Hemisphere has been recently recognized to have hydrogen ion concentrations 10 to 100 times higher than expected for natural precipitation (Likens and Bormann 1974, Cogbill and Likens 1974, Lewis and Grant 1980). However, controversy has arisen regarding the nature of the acidity of the precipitation sampled and whether, indeed, the pH of North American precipitation has increased over time (Miller and Everett 1979, Lerman 1979, Stensland 1980, Sequeria 1981, Carlson and Rodhe 1982). In most locations pH records have been constructed rather imperfectly due to differences in sampling, handling, and analytical procedures used (Galloway and Likens …

Research Note: Pcbs In The Acushnet River Estuary, Jacek Sulanowski

Bridgewater Review

Much media attention has recently been devoted to potentially toxic substances disseminated throughout various components of the environment. In almost every case these substances had been manufactured and distributed under the assumption that they did not pose a threat to man. Indeed when tested by methods current at the time of their initial introduction the substances were considered benign. It was only later when technologically advanced and more sensitive methods of analyses were developed that the presence of these substances was considered to be of real concern. Unfortunately, in the interval between introduction and detection, the accumulation of these substances …

Soil Testing: Improving Reliability, John H. Grove

Soil Science News and Views

Late summer is a good time to check forage and row crop fields for possible nutritional problems and to make plans for fall soil sampling. "Problem" areas can be identified for selective sampling and the test results can be used to plan fertilizer and lime expenses for the next crop production season. Fields scheduled for tobacco, small grain and/or double cropping need to be sampled first in order to determine lime, phosphorus (P) and potassium (K) needs before fall application.

Ciegen: A System For Testing Knowledge Base Compilation Heuristics On A Microcomputer, Jayne D. Ward, Billy E. Gillett, Arlan R. Dekock

Computer Science Technical Reports

The expert system has proven itself to be a valuable aid in diagnosing and treating problems in domains requiring expertise. The commercial world has been alerted to this fact and the thrust is to make the expert system portable and available on small computers.

The goal of this research has been to lay the groundwork for a domain independent expert system builder on a microcomputer. The result of this effort was CIEGEN, a system consisting of a rule compiler, inference engine, and rule generator developed on the IBM PC. It is domain independent, responsible for transforming a knowledge base of …

Winds Over Water: A Bibliography, Janet M. Witte

Marine & Environmental Sciences Faculty Reports

This bibliography was compiled as an outgrowth of the Satellite Surface Stress (S3) Working Group, which was sponsored by NASA/Goddard Space Flight Center and NASA/Jet Propulsion Laboratory (JPL) from the fall of 1982 to the spring of 1984 (Contracts NAS5-26714 and 956773). I wish to thank the Working Group Chairman, Dr. James J. O'Brien, for providing me with the impetus to compile this work. I also wish to thank the other members of the Working Group for adding their moral support (as well as many of the references).

Modulated Piezoreflectivity And The Photoelasticity Of Molecular Crystals, T. Luty, Craig J. Eckhardt

Craig J. Eckhardt Publications

Analysis of the optical response of a molecular crystal undergoing an external, periodic modulation is presented in terms of classical dipole theory. The case of modulated strain is treated in particular and identification of such strain with acoustic phonons with q=0 permits use of lattice dynamical theory to elucidate the acoustic phonon–exciton interaction. It is shown that extrema in the piezomodulated reflectivity (PMR) locate transverse and longitudinal exciton–polariton frequencies under specific experimental conditions. Model calculations demonstrate the great difference in the PMR for strong and weakly coupled systems. Relation of the PMR intensity to the elasto-optic coefficients and the storage …

Ab Initio Studies Of Hxypo And Xypoh Molecules, Mark S. Gordon, Jerry A. Boatz, Michael W. Schmidt

Mark S. Gordon

Molecular orbital calculations have been carried out on a sequence of HXYPOH molecules, with X and Y = H, CH3, NH2, OH, OCH3, and F. The molecular structures are predicted with the ST0-2G* basis set. For the prediction of energies of isomerization to XYPOH species, single-point 3-21G* and 6-31G* calculations were used. The molecular dissociation energies of HXYPO to HPO + XY and to XPO + HY were calculated by augmenting the latter two basis sets with MP2 and MP3 perturbation corrections.

Hydrogen Abstractions By Triplet Methylene And Silylene, Mark S. Gordon

Mark S. Gordon

While the most common reactions of singlet methylenes are insertions into Y -H or multiple bonds, 1-3 triplet methylenes tend to abstract hydrogens from Y -H bonds. 1·2 Singlet silylenes are also known to insert,4-6 while little is known about the corresponding triplets. Several theoretical papers have been devoted to analyses of the insertions of singlet CH/-12 and SiHP-15 into a variety of bonds and the abstractions of hydrogen from H216-20 and CH417 by triplet methylene. Ab initio calculations including correlation predict that carbenes insert into Y-H9•11 ·12·15 bonds with no barrier, in agreement with the prevailing experimental evidence;1·2 however, …

Centers Of Polymer Research; Polymer Science In Czechoslovakia, Slovakia Ii: Universities And Research Institutes, Otto Vogl, E. Borsig, J. Beniska

Otto Vogl

No abstract provided.

Spin Systems On Hierarchical Lattices. Ii. Some Examples Of Soluble Models, Miron Kaufman, Robert B. Griffiths

Miron Kaufman

Several examples are given of soluble models of phase-transition phenomena utilizing classical discrete spin systems with nearest-neighbor interaction on hierarchical lattices. These include critical exponents which depend continuously on a parameter, the Potts model on a lattice with two different coupling constants, surface tension, and excess free energy of a line of defects. In each case we point out similarities and differences with a corresponding Bravais-lattice model.

Duality And Potts Critical Amplitudes On A Class Of Hierarchical Lattices, Miron Kaufman

Miron Kaufman

By using the duality transformation on a class of hierarchical lattices, I show that the Potts critical amplitudes above and below the critical temperature are equal. Logarithmic modifications of the power-law singularity occur when the exponent 2—alpha is an even integer, but do not occur when 2—alpha equals an odd integer.

Inverting The Ratio Of The Complex Parallel And Perpendicular Reflection Coefficients Of An Absorbing Substrate Using A Transparent Thin-Film Coating, R. M.A. Azzam

Electrical Engineering Faculty Publications

An absorbing substrate can be coated with a transparent thin film of refractive index N₁ (within a certain range) and thickness d such that the ratio of complex reflection coefficients for the p_and s polarizations of the film-covered substrate ρ = R_p/R_s is the inverse of that of the film-free substrate ρ¯ = R¯_p/R¯_s at an angle of incidence ø. A method to determine the relationship among ø, N₁, and d that inverts ρ (i.e., makes ρ = 1/ρ¯) for a given substrate at a given wavelength is described and is …