Physical Sciences and Mathematics Commons^™

Ozone Complexes With Substituted Aromatic Compounds, David C. Eaton

Honors Theses

Ozone has been observed to complex with aromatic compounds at low temperatures. The ability of an aromatic system to complex with ozone appears to be due to the inductive effect of the substituent on the pi system. The experimental work was done in the solid phase at temperatures of -175° C to -186° C. Under these conditions all the substituted aromatics with electron withdrawing groups did not complex including benzene. The complexes are highly colored. To insure the reversibility of the pi complex, infrared spectra were taken of some of the aromatic species before and after complexing.

A Facile One Step Synthesis Of Some New 2-Hydroxy-4,6-Bis Aryl S-Triazines And Related Compounds, Howard Steven Grossberg

Honors Theses

In the past few years the symmetrical triazines have developed extreme importance in biochemical research as well as importance in industrial applications. In our research we have developed a facile, one-step synthesis of a number of 2-hydroxy-4, 6-bis aryl symmetrical triazines based upon the addition of the anion of urea and an aromatic nitrile, with the aryl group including a number of halogenated benzenes, pyridine, or benzene itself. The structure of these compounds had been proved by microanalysis and by both infra-red and mass spectroscopy. The further versatility of the synthesis has also been explored, and by replacing the urea …

The Preparation And Kinetic Studies Of Two Sterically Hindered Gold (Iii) Complexes, James Forrest Stevens

Honors Theses

Previous studies indicate substitution of bromide ion for chloride ion in [Au(Et4dien~H)c.i] +occurs at a rate almost independent of the bromide ion concentration, while similar reactions with [Au(dien-H)Cl]+, [Au(Me2dien-H)c!]+ and [Au(Me4dien-H)c~+ show rates dependent on bromide ion concentration as usually encountered for square planar complexes. There is retardation of the reaction by steric and electronic effects with increased N-alkyl substitution of the triamine. It has also been postulated that substitution of [Au(Et2dien-H)cJ]+ proceeds via a ring-opening mechanism. The purpose of this research was to study further the effect of steric hindrance on rates of substitution of two additional gold(III) complexes. …

The Prairie Naturalist Volume 8, Nos. 1 And 2. March-June 1976

The Prairie Naturalist

THE POTAMOGETONACEAE IN NORTH DAKOTA ▪ G. E. Larson

NOTES

January Record for Western Grebe at Amenia, North Dakota ▪ J. M. Wiehe and J. F. Cassel

An Observation of Possible Mallard Adoption ▪ R. A. Stromstad

Unusual Mortality in California Gulls ▪ G. R. Lingle

Great Horned Owl Predation of Penned Gray Partridge ▪ J. W. Schulz

BOOK REVIEWS

North Dakota's Own Bird Book ▪ B. and A. Gammell

North Dakota's Wildlife ▪ Staff

A New Bird Book for Minnesota ▪ D. H. Johnson

Two New Waterfowl Books ▪ T. J. Dwyer

Two Canadian Bird References ▪ Staff

Canadian …

Observation Of Vibrationally Excited Nitrogen With A Simplified Electron Transmission Apparatus, J.A. Michejda, Paul Burrow

Paul Burrow Publications

A simple electron transmission apparatus is used to observe vibrationally excited N₂ in the first two vibrational levels. The method is based on the pronounced peaks appearing in the total electron scattering cross section in the range of energy 2–4 eV. Because of the wide spacing between these peaks, good energy resolution is not required and measurements can be performed without an electron monochromator.

Presumpscot River Basin - Cumberland County Tidewater Water Quality Management Plan, Bureau Of Water Quality Control

Maine Collection

Presumpscot River Basin - Cumberland County Tidewater Water Quality Management Plan

Maine Department of Environmental Protection, Bureau of Water Quality Control, Division of Water Quality Evaluation and Planning, August, Maine (June 1976).

"Prepared pursuant to Section 303 (e) of the Federal Water Pollution Act Amendments of 1972"

Contents: Letter of Transmittal / Table of Contents / Appendices and Tables / I. Summary, Conclusions, Recommendations / II. Introduction / III. Water Quality / IV. Planning Activities / Appendices / Tables

Generalized Stability Of Motion And Vector Lyapunov Functions, Deborah A. Pace, Roger W. Mitchell

Mathematics Technical Papers

The direct theory for stability of motion in terms of vector Lyapunov functions and the general comparison method is well-developed [4, 5, 6, 7] and effectively applied for large scale dynamical systems [1, 3]. However, the problem of constructing vector Lyapunov functions and developing appropriate perturbation theory has seen very little progress. Perhaps one of the reasons for this situation is that the stability definitions by means of the standard norm are not flexible enough for such a venture.

Innovative Wind Machines, Executive Summary And Final Report, United States, Energy Research And Development Administration, Division Of Solar Energy

Fuel Sources

The work reported herein was supported by the U.S. Energy Research and Development Administration through the National Science Foundation, and represents an initial evaluation of two innovative wind machines. The first is a vortex concentrator, which is a vertical wing placed in the natural wind in a way that a strong wing tip vortex occurs; a turbine is then placed behind the wing tip in the concentrated energy region of the vortex to convert the energy to more directly-useful forms. The second concept involves a vertical axis turbine with straight blades; the blades are composed of special circulation controlled airfoils …

Effect Of Solvent Polarity On The Singlet-Triplet Energy Gap Of Methyl-2-Anthroate, William Gregg Hawkins

Honors Theses

Nonradiative processes cause the fluorescence quantum yield to be less than one. Elucidation of nonradiative decay mechanisms without knowing the location of triplet states is difficult. Determination of the fluorescence quantum yield (Øf) as a function of temperature can provide valuable information about relative location of triplet states and the nonradiative processes which result from having a triplet near the energy of the first excited singlet state. Methyl-2-anthroate is very sensitive to solvent polarity. The Øf values and S1 energies vary greatly, depending on the solvent environment. Temperature studies on Øf have indicated the intersystem crossing (ISC) to a nearby …

Optimum Structural Probability Bounds For The Right-Tail Of The Paretian Law, Danny D. Dyer

Mathematics Technical Papers

The two-parameter Pareto density function [see PDF for equation] is widely used in applied statistics. For example, in reliability theory (1.1) represents the failure-time distribution of a "work-hardened" component whose.hazard function is inversely proportional to time. Because of its long right-tail, (1.1) is often a probability model for certain socioeconomic phenomena (e.g., distribution of city population sizes, distribution of personal incomes which exceed tax-exempt levels). One of the more recent characterizations of the Pareto distribution is due to Revankar, et. at. [15]. They show that within the population of individuals that under-report their income for income tax purposes, the average …

Evaluation Of A Precision Filing Test For Predicting Dental Technic Performance, Douglass Roberts

Loma Linda University Electronic Theses, Dissertations & Projects

A precision filing test involving the reduction of a steel cylinder to a perfect cube with the use of a hand file and bench vise was devised as a diagnostic tool for the early detection of freshman students having technic difficulties. The test was administered to 188 freshman dental students in three classes at Loma Linda University, School of Dentistry. Subjective and objective scores were then statistically compared with subsequent technic and clinic grades of the students. The simple linear correlations between the predictor test variable and criterion grades were statistically significant for one class and for the combined classes …

The Effect Of Pre-Admission Crisis Nursing Intervention On The Anxiety Level Of Elderly Persons On Admission To A Nursing Home, Doreen C. K. Lee

Loma Linda University Electronic Theses, Dissertations & Projects

The experimental study attempted to determine whether pre-admission crisis nursing intervention had any effect on the level of anxiety of elderly people when they were transferred from an acute hospital to a nursing home.

The literature review related to trends in numbers of nursing homes and in the increase in longevity. Several articles indicated that the aged, as a group, lacked power to alter their situations. The need for patients to express their feelings and participate in their own decisions was stressed in various studies. Other theories discussed theoretical aspects and goals of crisis intervention. Several articles suggested that crisis …

The Effect Of Planned Physical Activities On Deficient Motor Skills In Head Start Preschool Children, Darlene L. Robinson

Loma Linda University Electronic Theses, Dissertations & Projects

During the past few years many physicians, nurses, psychologists, teachers, and physical educators have begun to place more emphasis upon the developmental problems of children. As an outgrowth of this, more attention has been given the child showing mild to moderate motor problems. As a result of these more subtle difficulties going unrecognized and untreated, children may suffer from learning disorders, lack of acceptance by teachers and peers, maladaptive behavior and feelings of low self-esteem (Cratty, 1970; Kiphard, -1970; and Ferinden, 1972).

The purpose of this study was to ascertain whether planned physical activities would aid in remediation and/or modification …

Photochemistry Of Beta-Methyl-Beta-Nitrostyrene And Its Derivatives, Mohammad Z. Kassaee

Masters Theses & Specialist Projects

o-CH₃, o-CH₃O, m-CH₃O and p-CF₃-β-methyl- β-nitrostyrene (compounds not previously reported) were synthesized using the method of Lappin¹³ and Robertson.¹⁴ These styrenes were irradiated in the U.V. region. The yield of corresponding oximes varied from 85 to 100% in aqueous ethanol. This variation in yield of the oximes was attributed to the effect of the substituent on the phenyl rings of the corresponding styrenes. Electron donating substituents promoted the nitro-nitrite rearrangement and electron-withdrawing groups inhibited this rearrangement. A mechanism is proposed for this reaction which unifies and includes ideas proposed by …

Development Of A Water Quality Simulation Model Applicable To Great Salt Lake, Utah, Craig T. Jones, Calvin G. Clyde, William J. Grenney, J. Paul Riley

Reports

The development of a model capable of predicting the long term (seasonal) . distribution of water quality constituents within Great Salt Lake was undertaken as a portion of the ongoing Great Salt Lake project at Utah State University. The overall goal of the project is the development of a modeling framework to assist relevant decision making bodies in the comprehensive management of the Great Salt Lake system. Phase I of the project provided the overall structural framework for management of the Great Salt Lake system, identified data needs, and established priorities for the development of submodels for incorporation into the …

Lattice Vibrations Of A Planar Hexagonal Structure, Hani Henry Ibrahim Abou-Seif

Archived Theses and Dissertations

No abstract provided.

The Lower Reaches Of Long Creek, Kentucky: A Karst Anomaly In Allen County, Doral Conner

Masters Theses & Specialist Projects

A field study of the lower reaches of the Long Creek drainage area in southeastern Allen County, Kentucky, established the karst character of that area. The area heretofore had been described as a non-karst area. Four swallow holes, which individually or collectively totally pirate Long Creek, were identified. Two major resurgences of the pirated flow were located and described. A detailed study of a portion of the Long Creek drainage area revealed thirty-four springs, all of which were pirated at least once, and no flow from these springs reached Long Creek by surficial routes. The field survey also revealed dolines …

Some New Metallocenes, Larry Warfield

Masters Theses & Specialist Projects

The synthesis and characterization of some new metallocenes is discussed. These organometallic compounds contain some of the first reported pi-complexes between an aromatic ylid, triphenylphosphoniumcyclopentadienvlide. and some transition metals.

Also reported is the synthesis of some new mercury halide metallocenes involving dimethylsulfoniumcyclopentadienylide as the sigma bonded organic substrate.

An Energy Accounting Evaluation Of Several Alternatives For Hydropower And Geothermal Development, J. Clair Batty, J. Paul Riley, William J. Grenney, David A. Bell

Reports

Alternative management strategies for hydropower and geothermal development are myriad. This study does not attempt to evaluate or even summarize the many schemes which are possible. In an era of plentiful natural resources, economic analysis procedures for selecting a particular alternative have been developed which traditionally have tended to optimize on the basis of capital and labor. The approach taken in this study is based on the notion of optimum deployment of finite resources. A legitimate question which this study has attempted to address is: Does the construction of large water management facilities, such as hydropower dams, which involve huge …

The Effects On Agriculture In Utah Of Water Transfers To Oil Shale Development, B. Delworth Gardner, Kenneth S. Lyon, Roger O. Tew

Reports

In Part I the institutional factors affecting water distribution in the Upper Colorado River Basin in general and specifically the Uintah Basin are presented. The historical development of the appropriation doctrine of water allocation is outlined and Utah water policy is examined. These institutional factors are analyzed in light of the prototype oil shale development in the Uintah Basin and potential impact on the area's agricultural sector. Oil shale water estimates are compared with Uintah Basin water availability and examined with regard to population projections and municipal water use. Lastly, Utah water policy and the appropriation doctrine are viewed as …

Scs 6: More Notes On Chains In Cl-Objects, James H. Carruth, Charles E. Clark, J. Winston Crawley, E. L. Evans, R. L. Wilson

Seminar on Continuity in Semilattices

No abstract provided.

Note On The Software Design For An Elliptic Pde Solver, John R. Rice

Department of Computer Science Technical Reports

No abstract provided.

Reply To “Comments On ‘Theoretical Study Of Impurity-Induced First-Order Raman Spectra For The Alkali Halides’”, John R. Hardy, Arnold Karo

John R. Hardy Papers

This is a reply to the preceding comment by Page on the relative merits of the breathing-shell and deformation-dipole models for predicting defect-activated first-order Raman spectra. We show that when both models are parametrized in the same fashion the agreement between theory and experiment is comparable.

Effect Of Angular Momentum On The Relaxation Time In A Multicomponent Gas Mixture, Louis Biolsi Jr.

Chemistry Faculty Research & Creative Works

The effects of molecular angular momentum (spin polarization) on the bulk viscosity and relaxation time in a multicomponent gas mixture are considered. Formal theoretical results are obtained, using the Wang Chang-Uhlenbeck approach to the kinetic theory of gases with internal states. The results are given in terms of integrals over the weighted quantum mechanical degeneracy averaged cross section.

Test 1211: Case M-B 4/94 Diesel (Unimog), Nebraska Tractor Test Lab

Nebraska Tractor Tests

EXPLANATION OF TEST REPORT GENERAL CONDITIONS Each tractor is a production model equipped for common usage. Power consuming accessories may be disconnected only when the means for disconnecting can be reached from the operator station. Additional weight can be added as ballast if the manufacturer regularly supplies it for sale. The static tire loads and the inflation pressures must conform to recommendations in the Tire Standards published by the Society of Automotive Engineers. PREPARATION FOR PERFORMANCE RUNS The engine crankcase is drained and refilled with a measured amount of new oil conforming to specifications in the operator’s manual. The fuel …

Federal/State Coordination In Coastal Permitting Procedures, James H. Asthalter

Marine Affairs Theses and Major Papers

In 1972 Congress passed the Coastal Zone Management Act. Under Section 302 of the act Congress found that "there is a national interest in effective management, beneficial use, protection and development of the coastal zone." To this end, Congress in Section 303 declared that there is a national policy (a) to preserve, protect, develop and, where possible, to restore or enhance the resources of the nation's coastal zone for this and succeeding generations, (b) to encourage and assist the states to exercise effectively their responsibilities in the coastal zone through development and implementation of management programs to achieve wise use …

Water Current, Volume 8, No. 3, May/June 1976

Water Current Newsletter

From the Desk of the Director
Summer Institute Planned
Research Technologist Hired
Water Research in Nebraska
Bill Introduced to Amend Water Resources Planning Act
OMB Wants "Section 80" Reviewed Again
National Commission on Water Quality Sends Recommendations to Congress
Water Assessment and Appraisal Given Top WRC Priority
Rio Grande Region: More Water Stored Underground than Above
Research Review: Physiological Aspects of Plant Water Use Efficiency

Metamagnetism In Single Crystal Γ-Co(Pyridine)2Cl2, S. Foner, Richard B. Frankel, W. M. Reiff, H. Wong, Gary J. Long

Physics

Small (≤1 mg) single crystals of γ-Co(pyr)₂Cl₂ have been grown and measurements of magnetic moment vs applied field H and temperature have been made for 0≤H≤54 kG and 1.25 K≤T≤4.2 K. At 1.25 K, metamagnetic transitions are observed along the a-axis at ~700 G; along the b-axis at both ~800 and ~1500 G; and along the c-axis at ~4 kG. The low field susceptibilities show a maximum at T≃3.4 K for each orientation. Magnetic saturation is not achieved at 54 kG; about 2.5 µ_B is achieved along the a*- or b-axes, whereas a lower moment is …

Hyperfine Interactions In Antiferromagnetic Eute Using The Te-125 Mossbauer Resonance, N. A. Blum, Richard B. Frankel

Physics

Europium telluride crystallizes in the NaCl structure and is antiferromagnetic with a Néel temperature TN of 9.6 K. We have used the 35.5 keV Møssbauer transition in Te-125 to examine the nature of the spontaneous magnetic moment which has been observed in conducting samples below TN. At 80 K the Mössbauer resonance spectrum consisted of a single absorption line comparable in width with the spectrum of nonmagnetic cubic ZnTe, indicating the absence of a significant quadrupole splitting at this temperature. At 4.2 K the line-width increased by a factor of 1.5, which is equivalent to a single magnetic hyperfine field …

The Succession Of Late Cenozoic Volcanic Ashes In The Great Plains: A Progress Report, John Boellstorff

School of Natural Resources: Faculty Publications

No abstract provided.