Physical Sciences and Mathematics Commons^™

Managing Risk For Power System Operations And Planning: Applications Of Conditional Value-At-Risk And Uncertainty Quantification To Optimal Power Flow And Distributed Energy Resources Investment, Thanh To

All Dissertations

Renewable energy sources are indispensable components of sustainable electrical systems that reduce human dependence on fossil fuels. However, due to their intermittent nature, there are issues that need to be addressed to ensure the security and resiliency of these power systems. This dissertation formulates several practical problems, from an optimization perspective, stemming from the increasing penetration of intermittent renewable energy to power systems. A number of Optimal Power Flow (OPF) formulations are investigated and new formulations are proposed to control both operations and planning risks by utilizing the Conditional Value–at–Risk (CVaR) measure. Our formulations provide system operators and investors analysis …

Determining The Value Of Ecosystem Services Provided By Green Stormwater Infrastructure In Coastal South Carolina, Joan U. Ureta

All Dissertations

Rapid urbanization changes the natural hydrology of a landscape, making stormwater management a crucial aspect of land development. As the fastest growing ecosystem globally, an innovative way of managing stormwater is needed to address the increase in urban run-off. In coastal South Carolina, stormwater practices have been widely adopted at the neighborhood level, yet threat of flooding is becoming more evident as the urban population and development continue to rise.

To determine the importance of stormwater practices to coastal residents, we assessed perception on stormwater practices and programs at different decision levels— 1) household, 2) neighborhood, and 3) city/county. Results …

Synthesis Of Fluorinated Monomers And Polymers For Various Applications, Cassandra J. Hager

All Dissertations

The world of industry utilizes a variety of polymers for various applications in many prominent fields. From electronics to food storage, the versatility of this class of chemistry has been widely proven. The Thrasher research group undertook a program dedicated towards the development of a library of fluorinated materials that focused on the synthesis and characterization of perfluoroalkoxy (PFA) copolymers of tetrafluoroethylene (TFE) and perfluoroalkyl trifluorovinyl ethers. One aim of the project was to improve upon the mechanical strength and wearability of commercial PFA resins by incorporating bulkier perfluoroalkoxy trifluorovinyl ether monomers into these copolymers. In addition to focusing on …

Optimization Of Modular, Long-Range, Ultra-Fast Optical Tweezers With Fluorescence Capabilities For Single-Molecule And Single-Cell Based Biophysical Measurements, Subash C. Godar

All Dissertations

An Optical tweezer is a tightly focused laser beam that applies and senses precise and localized optical force to a dielectric microsphere and offers a unique and effective tool for manipulating the single cell or cell components, including nucleotides and dynein motor proteins. Here, I used highly stabilized optomechanical components and ultra-sensitive detection modules to significantly improve the measurement capabilities over a wide range of temporal and spatial scales. I combined the optical tweezer-based force spectroscopy technique with fluorescence microscopy to develop an integrated high-resolution force-fluorescence system capable of measuring displacements at sub-nanometer, forces at sub-piconewton over a temporal range …

Exploring The Glow Of The Universe In Gamma-Rays And Hunting Distant Agn, Changam Meenakshi Rajagopal

All Dissertations

The entirety of the γ-ray radiation permeating our Universe is encoded in the extragalactic γ-ray background. This is a superposition of resolved sources, mostly powerful relativistic jets powered by supermassive black holes, i.e., blazars, and an unresolved isotropic component, aka, the diffuse isotropic gamma-ray background (IGRB). Studying the IGRB can help unveil its composition, as well as unearth multi-messenger relationships between the intensities of PeV neutrinos, ultra high energy cosmic rays (> 1018 eV), and sub-TeV γ-rays. The comparable energy budgets of these three phenomena (neutrinos, UHECR, and γ-rays) indicates a physical connection or a common source amongst them. On …

Supertertiary Structural Dynamics Modulate Function In Postsynaptic Density Protein 95, George L. Hamilton Iii

All Dissertations

Proteins, RNA, and DNA serve as the primary sub-cellular machinery that give rise to the necessary functions of life. The long-standing paradigm has been that the structures of biomolecules, or the arrangement of the subunits that make up a biomolecule, determine biological function. However, biomolecules are not static objects. Instead, they often undergo structural rearrangements that are crucial to enabling and regulating their functions. In my thesis I present several studies of the interplay between the structures, dynamics, and functions of biomolecules that combine experimental fluorescence spectroscopy and computational methods to probe these systems at the single-molecule level. In particular, …

Some Improved Markov Chain Convergence Rates, Fun Choi John Chan

All Dissertations

Explicit convergence rates to equilibrium are established for non reversible Markov chains not having an atom via coupling methods. We consider two Markov chains having the same transition function but different initial conditions on the same probability space, that is, a coupling. A random time is constructed so that subsequent to the random time the two processes are identical. Exploiting a shadowing condition, we show that it is possible to bound the tail distribution of the random time using only one of the chains. This bound gives the convergence rate to equilibrium for the Markov chain. The method is then …

Light Harvesting And Electrically Conducting Metal-Organic Frameworks, Monica Gordillo Varela

All Dissertations

Composed of metal clusters nodes and organic linkers, metal-organic frameworks (MOFs) have emerged as versatile platforms with unparalleled chemical and structural tunability, synthetic facility, permanent porosity, and size-selective guest encapsulation capability. These features make them potential candidates for a variety of applications such as gas storage,drug delivery, catalysis,and sensing. In recent years, the introduction of redox- and photoactive components have yielded stimuli-responsive electronic and photonic MOFs and expanded their utility in molecular electronics and energy storage devices/technologies.

Chapter one describes the light-harvesting ability of a porphyrin-based MOF. Herein, we have demonstrated spontaneous solvothermal growth of [100]-oriented uniform pillared-porphyrin framework-11 (PPF-11) …

Groundwork For The Development Of Gpu Enabled Group Testing Regression Models, Paul Cubre

All Dissertations

In this dissertation, we develop novel techniques that allow for the regression analysis of data emerging from group testing processes and set the groundwork for graphic processing units (GPU) enabled implementations. Group testing primarily occurs in clinical laboratories, where it is used to quickly and cheaply diagnose patients. Typically, group testing tests a pooled specimen--several specimens combined into one sample--instead of testing individual specimens one-by-one. This method reduces costs by using fewer tests when the disease prevalence is low. Due to recent advances in diagnostic technology, group testing protocols were extended to incorporate multiplex assays, which are diagnostic tests that, …

Automated Parallel Optimization Of Simulation Parameters Using Modified Nelder-Mead Simplex Algorithm, Erina Mills

All Dissertations

Computational simulations used in many fields have parameters that define models that are used to evaluate simulated properties. When developing these models, the goal is to choose the parameters that best replicate a set of desired properties. Mathematical optimization methods can be used to optimize the simulation parameters by defining a function that uses simulation parameters as input and outputs a value describing how well a set of experimental properties are reproduced.

Because simulated properties are often calculated using stochastic sampling methods, this optimization involves an objective function that is noisy and expensive to evaluate. Also, optimization of the simulation …

Extractive Membranes For The Detection And Screening Of Waterborne Plutonium, James Foster

All Dissertations

The development of rapid screening tools for special nuclear materials remains a crucial focus for nonproliferation efforts. Traditional approaches for the analysis of trace-level Pu isotopes in water requires tedious and time-consuming sample preparation steps that do not lend well to expeditious screening. Therefore, a novel analytical method that combines both Pu concentration and source preparation into a single detection system would make for an invaluable tool for nuclear security applications. Extractive membranes absorbers can help to fulfill this role as they are capable of concentrating Pu to detectable limits while subsequently serving as alpha spectrometry sample sources. In Chapter …

Improved First-Order Techniques For Certain Classes Of Convex Optimization, Trevor Squires

All Dissertations

The primary concern of this thesis is to explore efficient first-order methods of computing approximate solutions to convex optimization problems. In recent years, these methods have become increasingly desirable as many problems in fields such as machine learning and imaging science have scaled tremendously. Our aim here is to acknowledge the capabilities of such methods and then propose new techniques that extend the reach or accelerate the performance of the existing state-of-the-art literature.

Our novel contributions are as follows. We first show that the popular Conditional Gradient Sliding (CGS) algorithm can be extended in application to objectives with H\"older continuous …

Cell Tracking At Low Frame Rate Using Deep Learning And Bayesian Integration, Xiang Zhang

All Dissertations

Tracking cells over time is a fundamental task in live-cell imaging, and often requires costly manual analysis if images are not acquired with high enough frame rate. Acquiring high frame rate images, however, can limit the number of conditions explored and cells analyzed, and contribute to photobleaching, which makes fluorophores dimmer and phototoxicity, which affects cell health and renders the resulting data unusable.

Assuming a relatively high frame rate in image acquisition, state-of-the-art cell tracking approaches rely on either spatial proximity or morphological similarity to link cells in consecutive frames. The problem is that, at low frame rate, both approaches …

Valorization Of Biopolymers And Biomass To Produce Materials For A More Circular Economy, Moira Lauer

All Dissertations

With a globally increasing population and largely unchecked consumption of raw materials, human society is on track for devastating consequences. Two industries responsible for utilizing massive amounts of raw materials and generating equally gargantuan quantities of waste are the packaging and infrastructure sectors. In 2017 in Europe, for example, packaging reached a record 173 kg of packaging waste per capita. One of the largest packaging consumers is the food industry, in which 40% of packaging is made of petroleum-derived single-use plastic, leading to a massive carbon imbalance. “The Built Environment,” on the other hand, is responsible for about 50% of …

Length-Based Risk Analysis Of Management Options For The Southern Florida Usa Multispecies Coral Reef Fish Fishery, Jerald Ault, Steven G. Smith, Matthew W. Johnson, Laura Jay W. Grove, James A. Bohnsack, Gerard T. Dinardo, Caroline Mclaughlin, Nelson M. Ehrhardt, Vanessa Mcdonough, Michael P. Seki, Steven Miller, Jiangang Luo, Jeremiah Blondeau, Michael P. Crosby, Glenn Simpson, Mark E. Monaco, Clayton G. Pollock, Michael W. Feeley, Alejandro Acosta

Marine & Environmental Sciences Faculty Articles

Exploitation impacts and management options for 15 coral reef fish species central to the commercial and recreational fisheries of the southern Florida USA coral reef ecosystem were evaluated using a length-based risk analysis (LBRA) framework. Population abundance-at-length composition data were obtained from several regional federal-state sampling programs. These and updated life history demographic data were integrated into a length-based numerical cohort model to generate LBRA fishery sustainability metrics from a probabilistic perspective. Three of five groupers, eight of eight snappers, and two of two grunts were below the 40% spawning potential ratio (SPR) stock sustainability minimum; ten of these …

A Biological Condition Gradient For Coral Reefs In The Us Caribbean Territories: Part I. Coral Narrative Rules, Deborah Santavy, Susan K. Jackson, Benjamin Jessup, Jeroen Gerritsen, Caroline Rogers, William S. Fisher, Ernesto Weil, Alina Szmant, David Cuevas-Miranda, Brian K. Walker, Christopher Jeffrey, Patricia Bradley, David Ballantine, Loretta Roberson, Hector Ruiz-Torres, Brandi Todd, Tyler Smith, Randy Clark, Ernesto Diaz, Jorge Bauzá-Ortega, Christina Horstmann, Sandy Raimondo

Marine & Environmental Sciences Faculty Articles

As coral reef condition and sustainability continue to decline worldwide, losses of critical habitat and their ecosystem services have generated an urgency to understand and communicate reef response to management actions, environmental contamination, and natural disasters. Increasingly, coral reef protection and restoration programs emphasize the need for robust assessment tools for protecting high-quality waters and establishing conservation goals. Of equal importance is the need to communicate assessment results to stakeholders, beneficiaries, and the public so that environmental consequences of decisions are understood. The Biological Condition (BCG) model provides a structure to evaluate the condition of a coral reef in increments …

Alpha-Crystallin-Membrane Association Modulated By Phospholipid Acyl Chain Length And Degree Of Unsaturation, Geraline Trossi-Torres, Raju Timsina, Laxman Mainali

Physics Faculty Publications and Presentations

α-crystallin-membrane association increases with age and cataracts, with the primary association site of α-crystallin being phospholipids. However, it is unclear if phospholipids’ acyl chain length and degree of unsaturation influence α-crystallin association. We used the electron paramagnetic resonance approach to investigate the association of α-crystallin with phosphatidylcholine (PC) membranes of different acyl chain lengths and degrees of unsaturation and with and without cholesterol (Chol). The association constant (K_a) of α-crystallin follows the trends, i.e., K_a (14:0–14:0 PC) > K_a (18:0–18:1 PC) > K_a (18:1–18:1 PC) ≈ K_a (16:0–20:4 PC) where the presence of Chol decreases K …

Development Of A Prototype Electron Detector For Use In Ucna+, Richard Mcdonald

Undergraduate Honors Theses

The UCNA Experiment at the Los Alamos Neutron Science Center (LANSCE) uses an electron spectrometer to observe angular correlations between the neutron spin and the momenta of β particles emitted during the process of β decay. These angular correlations give rise to an asymmetry determined by the ratio of two coupling constants, gA and gV . Combined with neutron lifetime measurements, these observations probe physics beyond the standard model through unitarity tests of the Cabbibo-Kobayashi-Maskawa Matrix. UCNA’s current spectrometer uses a multi-wire proportional chamber and a plastic scintillator coupled to four photomultiplier tubes (PMTs) by 2 meters of light guides …

Code Review Practices For Refactoring Changes: An Empirical Study On Openstack, Mohamed Wiem Mkaouer, Eman Abdullah Alomar, Moatz Chouchen, Ali Ouni

Articles

Modern code review is a widely used technique employed in both industrial and open-source projects to improve software quality, share knowledge, and ensure adherence to coding standards and guidelines. During code review, developers may discuss refactoring activities before merging code changes in the code base. To date, code review has been extensively studied to explore its general challenges, best practices and outcomes, and socio-technical aspects. However, little is known about how refactoring is being reviewed and what developers care about when they review refactored code. Hence, in this work, we present a quantitative and qualitative study to understand what are …

How Blockchain Solutions Enable Better Decision Making Through Blockchain Analytics, Sammy Ter Haar

Information Systems Undergraduate Honors Theses

Since the founding of computers, data scientists have been able to engineer devices that increase individuals’ opportunities to communicate with each other. In the 1990s, the internet took over with many people not understanding its utility. Flash forward 30 years, and we cannot live without our connection to the internet. The internet of information is what we called early adopters with individuals posting blogs for others to read, this was known as Web 1.0. As we progress, platforms became social allowing individuals in different areas to communicate and engage with each other, this was known as Web 2.0. As Dr. …

Forecasting Razorback Baseball Game Outcomes, Austin Raabe

Information Systems Undergraduate Honors Theses

Despite the disappointing end to the 2021 Arkansas Razorback baseball year, the team’s success provided hog fans something to look forward to next season. While they will be without the 2021 Golden Spikes Award winner, Kevin Kopps, and four All-SEC team selections, the 2022 roster has promising new and returning talent. With fifty percent of the players who played significant time last year coming back (minimum ten hits or ten innings pitched), the arrival of several impact transfers from major conferences, and a recruiting class ranked in the top five according to Perfect Game, there is reason to believe that …

Nanotechnology-Based Approaches To Mitigate Environmental Pollutants -- Induced Neurological Disorders, Jyoti Ahlawat

Open Access Theses & Dissertations

Neurodegenerative diseases such as Parkinson's disease (PD), Alzheimerâ??s Disease (AD) and Huntingtonâ??s Disease (HD) have no cure despite intensive research efforts geared towards therapeutics development. In the USA, patients with PD and AD alone cost the nation ~ $200 billion annually in patient care and lost productivity. Therefore, there remains an urgent and unmet need to develop novel drugs and drug carriers with the potential to slow down, halt and ideally reverse the course of neurodegenerative disorders. The dissertation focuses on developing approaches towards targeting PD using multifactorial mechanisms including the targeting of protein aggregation and oxidative stress. This is …

Using A Geospatial Analysis Tool To Visualize Water Impairments And Engage Stakeholders In The San Bernardino National Forest, Jovany Estrada

Electronic Theses, Projects, and Dissertations

High quality water is an important resource that is integral to supporting environmental and human health. It is essential for economic, social and environmental purposes. Impairments to water resources can be attributed to anthropogenic sources that are associated with terrestrial activities including urban development and agricultural activities. Community-Based Participatory Research (CBPR) is an approach that can be used to include community input to improve water management strategies. In the San Bernardino National Forest (SBNF) area in southern California, there are disadvantaged communities that can benefit from a CBPR study to increase water quality in the area. A geovisualization tool will …

Advantages And Disadvantages Of Centralized Versus Decentralized Information Systems And Services From A Project Management Perspective, Garrett William Cuillier

Electronic Theses, Projects, and Dissertations

After an extensive review of the available literature, it is evident that within the Information Systems and Technology (IT) field, project managers are still debating whether to centralize or decentralize IT systems and services personnel. This decision can have a major impact on the effectiveness of the project management process with both organizational structures having advantages and disadvantages. The study examines two real-world examples of projects in the aerospace and defense technology industry that were performed from either a centralized or decentralized organizational structure. Using an industry standard project management methodology (i.e., Agile and Scrum), the study clearly identified the …

The Development Of Photoinduced Initiation Of Olefin Polymerization And Its Applications, Justin M. Burroughs

Doctoral Dissertations

Polyolefin synthesis is an ever-growing field due to the low cost of monomer feed stocks and the wide range of applications of the resulting polymeric material. Polyolefins are most commonly polymerized through coordination-insertion polymerization. One area this field of research has progressed is the development of complex ligand scaffolds to achieve various levels of control over polymerization. For example, researchers have been able to control molecular weight, branching density, and tacticity of various olefin polymerizations. As a result of complex ligand scaffolds, the catalytic systems become more expensive and less industrially applicable. On the other hand, little research efforts have …

Chiral Mesogen-Free Liquid Crystalline Polyethers With Sulfonylated Side Chains And Patchy Brush Nanoparticles, Caleb A. Bohannon

Doctoral Dissertations

Ferroelectric liquid crystalline polymers (LCPs) hold promise for various applications driven by low electric fields, e.g., electrocaloric materials, because of the higher molecular motion in the liquid crystalline (LC) state. However, traditional chiral smectic C (SmC*) LCPs exhibit small spontaneous polarizations due to the bulky aromatic mesogens and weak polar groups. This dissertation research is focused on the design of mesogen-free sulfonylated LCPs with a goal of seeking the ferroelectric SmC* phase. Such LCPs are expected to exhibit high polarizations owing to the sulfonyl’s large dipole moment. A series of poly(oxypropylene)s (POPs), with chirality being introduced into either the backbone …

Study Of One-Nucleon Transfer Reactions, Jerome Mathew Kovoor

Doctoral Dissertations

The structure of nuclei away from the line of stability and near the driplines in the nuclear chart has been of huge interest since the arrival of radioactive ion beam facilities. The properties of nuclei evolve as a function of proton and neutron numbers and understanding the mechanisms behind this is one of the keys to explaining the strong nuclear force. Single-nucleon transfer reactions using deuteron targets are powerful probes of nuclear structure when the emitted proton or neutron is measured with high fidelity.

A variety of structure phenomena are observed in the beryllium isotopes marking them particularly attractive for …

A High Rate Pixelated Neutron Detector For Neutron Reflectometry At The Spallation Neutron Source, Su-Ann Chong

Doctoral Dissertations

This work presents the development of a high-rate 6Li-based pixelated neutron detector for neutron reflectometry instruments at the Spallation Neutron Source (SNS), Oak Ridge National Laboratory. The current detector technology falls short on the instrument requirements, particularly on the counting rate capability. This detector was designed specifically to overcome the limitation in counting rate by having a fully pixelated design from neutron conversion layer to photodetector and readout system. For the neutron converting layer, a 6Li-based neutron scintillator was used. Each scintillator element was coupled to a photodetector, in this case, a silicon photomultiplier (SiPM). The output of each SiPM …

Alkali Linewidths Under High Temperatures And Pressures Of 3he, Michael Parker

Undergraduate Honors Theses

Current research at Thomas Jefferson National Accelerator Facility is being conducted to study the spin structure of the neutron through collisions with polarized 3He nuclei. The helium is contained in high pressure glass vessels (called cells) along with nitrogen, rubidium, and potassium. To deduce the spin structure from collisions, we need to know the precise number density of 3He in the cell. The process of polarizing 3He through spin-exchange optical pumping requires nitrogen and alkali metal. We can use the absorption linewidths of rubidium and potassium to more accurately determine the density of helium. Throughout my research, I collected absorption …

Spectroscopic Measurements Of Meibum Compositional, Structural, And Functional Relationships To Elucidate The Role Of Meibum In Dry Eye., Anthony Chigozie Ewurum

Electronic Theses and Dissertations

The major aim of my dissertation was to investigate the etiology of dry eye disease which affects about 7 million people in the United States, causing symptoms that can lead to visual disturbance. Correlation between dry eye and an abnormal lipid layer of the tear film has been found. Tear film lipids originate mostly from the meibomian glands. Cholesteryl ester (CE) and Wax ester (WE) lipids make up most of the human meibum lipidome and the CE/WE ratio has been shown to decrease in patients with meibomian gland dysfunction. Model studies using synthetic CE and WE, although providing some insight, …