Physical Sciences and Mathematics Commons^™

Reed Research Reactor Neutron Beam Characterization And Analysis, Vee Bartko, Jerry Newhouse

Student Research Symposium

Using neutron activation analysis of 99% pure gold foils, the authors characterize the neutron dose and shape of the neutron beam at the Reed Research Reactor (RRR). The experimental procedure followed extensive modeling in Monte Carlo N-Particle (MCNP) and Tool for Particle Simulation (TOPAS) simulations, in which the beam was projected to be roughly collimated. The shape, defined in terms of neutron flux, was measured by placing the foils directly on top of the neutron beam cap at powers of 1, 5, and 10 kilowatts. The flux was then converted to neutron dose via the Nuclear Regulatory Commission's neutron fluence …

Textural Investigation Into Rapid Welding Transitions In The Tuff Of Leslie Gulch Along Succor Creek At The Mahogany Mountain-Three Fingers Rhyolite Field, Southeastern Oregon, Alicia J. Martinez-Garling, Martin J. Streck

Student Research Symposium

The Mahogany Mountain-Three Fingers Rhyolite Field (MM-TFrf) in southeastern Oregon, associated with mid-Miocene rhyolite activity and Columbia River flood basalts, has been the subject of geological scrutiny. Previous studies proposed separate origins for the tuff of Leslie Gulch (LGT) and Spring Creek, but Benson and Mahood (2006) suggested a single ignimbrite event at 15.8 Ma, prompting a reassessment of MM-TFrf's history. This research focuses on LGT, investigating textural disparities between welded and non-welded tuff formations. Petrographic examinations delve into the transformation stages of pyroclastic tuff deposition, revealing the dynamic influences of volcanological and magmatic processes on welded and non-welded tuff …

Competing Supramolecular Forces: Boron Coordination Vs Π-Π Stacking, Sidhaesh A. Agarwal, Gonzalo Campillo-Alvarado, Nicholas Lutz, Jesus Daniel Loya, Eric W. Reinheimer

Student Research Symposium

This study explores the impact of fluorination levels in azopyridine Lewis bases on their ability to direct the formation of B←N coordination adducts or cocrystals with phenylboronic ester. We hypothesize that the degree of fluorination can be used as a tool to control the outcome of supramolecular bonding competition, thus influencing complex self-assembly.

A series of azopyridines with varying degrees of fluorination were synthesized and reacted with phenylboronic ester. Their structures were analyzed using Hartree-Fock calculations, Hirshfeld surface analyses, and single crystal X-ray diffraction to assess the impact of fluorination on supramolecular interactions.

The study reveals that azopyridines with up …

Multiscale Variability Of Heavy Metals In A Western U.S. Snowpack, Kelsey Hefner

Student Research Symposium

Natural and anthropogenically sourced particulates are deposited from the atmosphere to landscapes via dry and wet deposition, making frozen winter snowpack a natural archive of atmospheric elemental composition. Wildfires in the Western United States are increasing in extent, duration, and severity, especially in alpine regions. Severe fires remove forest canopy and can impact how atmospheric elements are dispersed and stored across snow-dominated watersheds. We evaluated Al, V, Cr, Mn, Ni, Cu, As, Zn, Se, Mo, Cd, and Pb concentrations in 394 winter snow core samples. We collected samples in 2019 and 2020 from a chronosequence of eight forests that burned …

Neutron Time Of Flight Spectrometry As A Diagnostic Tool For Inertial Electrostatic Confinement Fusion Plasmas, Andrew H. Dempsey, Erik J. Sanchez

Student Research Symposium

Inertial electrostatic confinement (IEC) is a method for achieving fusion of light nuclei wherein ions are injected into a spherically symmetric system of concentric electrodes. When the innermost electrode is held at negative high voltage with respect to the outer electrode, ions injected into the reactor at cathode (ground) potential accelerate toward the anode where they may undergo collisions with sufficient energy to overcome Coulomb repulsion and achieve nuclear fusion. The most commonly used IEC fusion fuels are deuterium-deuterium (D-D) and deuterium-tritium (D-T). Both fuels undergo fusion reactions that result in production of fast neutrons with distinct energies. Neutron production …

Wildland Urban Interface Growth And Development Potentials In Deschutes County, Samantha Hall

Student Research Symposium

Policy can and has been used as a tool to reduce the risk communities experience from natural hazards by limiting development in areas most vulnerable. How and where development occurs directly influences the amount of risk a community experiences from natural hazards like hurricanes, earthquakes, flash floods, and wildfire among others. Development patterns that contribute to increased wildfire risk mostly occur within the wildland urban interface, a land use type where development is at the fringes or intercept of wildland areas and is more flammable due to surrounding vegetation, slope, local climate, and other factors. For this research, Deschutes County …

Computationally Assisted Mechanistic Analysis Of The Protonolysis Of A Pt–Me Bond, Clement Dasilva

Student Research Symposium

Mechanistic study of the protonolysis of (cod)PtMe2 could give insight into the activation of C-H bonds by platinum because it is the microscopic reverse reaction. Two possible mechanisms for the protonolysis of dimethyl platinum complexes have been proposed, with experimental and computational data supporting the single step, SE2, over the multistep, SE(ox) mechanism. New experimental work from our group supports a multi-step mechanism with multiple acid molecules. In this work, the SE2 mechanism as well as a proposed SE(ox) mechanism were computationally modeled with a single equivalent of acid, TFAH, and two equivalents using density functional theory. The modeled pathways …

Method Validation Of Metals In Environmental Soil Samples, Sofia Deangelis, Nana Nguyen

Student Research Symposium

Vehicles are a major source of metal accumulation in terrestrial environments. Green infrastructure, such as bioswales, has been implemented as a way to mitigate this damage. However, there is a limited understanding of the processes that occur in these bioswales as few go back after implementation to identify areas in the bioswale with accumulation of pollutants. Inductively coupled mass spectrometry (ICP-MS) has the potential to be used in this type of study due to the machine’s high sensitivity and selectivity. However complications can arise while using the ICP-MS to characterize complex environmental samples. This study seeks to optimize microwave assisted …

Going Down An Incline With Chatgpt, Corey R. Sissons

Student Research Symposium

In our Large Language Model (LLM) research, examining ChatGPT 4, we devised a physics problem involving an object descending an inclined plane. Through variations in terminology such as "rolling," "sliding," "solid sphere," "hollow sphere," "wooden ramp," "no-slip ramp," and more, we sought to evaluate LLM responses for different scenarios. Our analysis aimed to discern whether the LLM’s answers exhibited expertise in the field of physics. This experiment sheds light on LLM’s ability to give accurate and precise physics answers as well as variation in responses to nuanced changes in problem formulation. This provides valuable insights into its proficiency and potential …

Analyzing Intensifying Storm Events Correlation To Landslide Frequency In Portland’S West Hills, Aurora Villa Juan

Student Research Symposium

As the Pacific Northwest climate changes, extreme weather, such as intensifying storms, and a shift in the type of precipitation experienced with warmer winters causing more precipitation to fall as rain instead of snow, may lead to an increased frequency of landslides. There have been several recent landslides in Portland, noticeable to the public, particularly in areas of high elevation such as Council Crest, which stands at 1,073 feet. Additionally, residents of neighboring homes have observed changes in the landscape, including those on private properties. To better safeguard both public and private property, comprehensive research and mitigation efforts are required. …

Story Of Your Lazy Function’S Life: A Bidirectional Demand Semantics For Mechanized Cost Analysis Of Lazy Programs, Laura Israel, Nicholas Coltharp

Student Research Symposium

Lazy evaluation is a powerful tool that enables better compositionality and potentially better performance in functional programming, but it is challenging to analyze its computation cost. Existing works either require manually annotating sharing, or rely on separation logic to reason about heaps of mutable cells. In this paper, we propose a bidirectional demand semantics that allows for reasoning about the computation cost of lazy programs without relying on special program logics. To show the effectiveness of our approach, we apply the demand semantics to a variety of case studies including insertion sort, selection sort, Okasaki's banker's queue, and the push …

Systematic Comparison Of Reservoir Computing Frameworks, Nihar S. Koppolu, Christof Teuscher

Student Research Symposium

In this poster, we present a systematic evaluation and comparison of five Reservoir computing (RC) software simulation frameworks, namely reservoirpy, RcTorch, pyRCN, pytorch-esn, and ReservoirComputing.jl. RC is a specific machine learning approach that leverages fixed, nonlinear systems to map signals into higher dimensions. Its unique strength lies in training only the readout layer, which reduces the training complexity. RC excels in temporal signal processing and is also well suited for various physical implementations. The increasing interest in RC has led to the proliferation of various RC simulation frameworks. Our RC simulation framework evaluation focuses on a feature comparison, documentation quality, …

Community Responses To Us Regional Clean Hydrogen Hubs, Bethani Turley

Student Research Symposium

In 2023, the Bipartisan Infrastructure Law designated 7 billion dollars to fund regional hydrogen hubs across the US with the goal of kickstarting a utility scale hydrogen economy for the US electric grid. A promising technology in the renewable energy transition, hydrogen can be made from a multitude of energy sources, often designated by colors: green hydrogen is made from solar and wind, pink hydrogen from nuclear, and blue hydrogen from natural gas. This presentation examines this new hydrogen economy through the case study of the Appalachian Regional Clean Hydrogen Hub (ARCH2). ARCH2 is a blue hydrogen hub proposal by …

Development Of A Fast-Neutron Source Localization System, Abdulsalam F. Al Mutairi

Student Research Symposium

Power generation by nuclear fusion is a continuing ambition that has been the focus of nuclear fusion research for nearly a hundred years. However, small-scale fusion reactors have further propulsion and neutron imaging applications that don’t require greater than breakeven efficiencies that a fusion energy source needs. Inertial Electrostatic Confinement (IEC) fusion devices have the potential for miniaturization, making them a strong candidate for such applications. Yet the contributions of different interactions within an IEC fusion device are still not fully understood. Imaging an IEC device and investigating each interaction's Neutron Production Rate (NPR) can enhance design efficiency. Neutron imaging …

Behavioral Intention For Ai Usage In Higher Education, Isaac A. Odai, Elliot Wiley

Student Research Symposium

This study sought to further understand the cognitive factors that influence undergraduate students' behavioral intention to use generative AI. Generative AI's presence in academic spaces opens the door for ethical and pedagogical questions. This study surveyed 51 undergraduate communication students to measure their attitudes, subjective norms, self efficacy and their behavioral intention to use GenAI for school work. The results of this study showed behavioral intent had a positive relationship with attitudes and subjective norms. The implications of these findings show that personal beliefs and the perceived beliefs of others are correlated to undergraduate students’ intent to use GenAI for …

Photocathodes From Aerobic Oxidation Of Tellurorhodamines, Amelia Jellison

Student Research Symposium

Contemporary dye-sensitized solar cells are far less efficient than silicon solar panels, therefore this project seeks to develop an improved dye sensitized photocathode. Tellurorhodamine dyes, including mesityl derivatives and tellurium black, have been chosen to increase efficiency through increased light harvesting. The photophysical and electrochemical properties of tellurorhodamines with varying structures are analyzed to quantify its efficiency to serve as a dye sensitized photo cathode. Dyes undergo aerobic oxidation facilitated by light, the absorption profile is obtained before and after. Mesityl derivatives are known to experience significant red-shifting following aerobic oxidation. At its base oxidation state, tellurium black experiences an …

Exploring The Potential Of Α-Aryl Substitution Of Gddota To Address Challenges Associated With Mri Contrast Agents., Charlene I. Kupara

Student Research Symposium

Gadolinium chelates have found widespread application as contrast agents in Magnetic Resonance Imaging (MRI) a cornerstone in modern medical diagnostics. In recent years two significant challenges have emerged to the use of Gd³⁺ chelates in MRI:

• The safety of these Gd³⁺-based agents, specifically related to the possible in vivo release of Gd³⁺.
• The environmental impact of anthropogenic Gd³⁺ pollution of surface waters arising from using contrast agents.

The escalating reports of Gd³⁺ presence in environmental matrices, and its adverse effects on marine life and human health, necessitate urgent intervention to mitigate consequential environmental …

Feasibility Of Deploying Home-Based Digital Technology, Environmental Sensors, And Web-Based Surveys For Assessing Behavioral Symptoms And Identifying Their Precipitants In Older Adults: Longitudinal, Observational Study., Wan-Tai M. Au-Yeung, Yan Liu, Remonda Hanna, Sarah Gothard, Nathaniel Rodrigues, Cierra Leon Guerrero, Zachary Beattie, Jeffrey Kaye

Mathematics and Statistics Faculty Publications and Presentations

Apathy, depression, and anxiety are prevalent neuropsychiatric symptoms experienced by older adults. Early detection, prevention, and intervention may improve outcomes.

Canonical Extensions Of Quantale Enriched Categories, Alexander Kurz

MPP Research Seminar

No abstract provided.

A Just, Sustainable Transition At Fordham University, Ethan Shepard

Student Theses 2015-Present

This paper takes a deeper look at Fordham University’s environmental impact and concludes with a strategy outline that works towards a just, sustainable future on the university campus and surrounding areas. New York City is an area already facing the adverse effects of climate change, and there are several threats that have the potential to cause grave consequences moving forward. Prior to constructing a climate action plan, it is integral to understand the past and present status of The Bronx under a socio-environmental lens. Chapter One focuses on the current status of Fordham’s Rose Hill Campus from a sustainability perspective …

Fireflies At Rpa Natural Area Final Report, Olivia H. Bush, Sydney M. Shea, Sofia J. Gordon, Nick S. Wiebke

Final Reports in ENST 411: Environmental Community Projects

Our group worked alongside community partners Shaunna Barnhart and Jim Dunn during the Spring 2024 semester to assist with their annual event Fireflies at RPA Natural Area. RPA Natural Area is a local park in South Williamsport, Pennsylvania that was recently acquired by Southside Recreational Authority. Since taking over the park, the organization has begun hosting an event each July to educate the general public about firefly biology and conservation by showing a film and guiding attendees through a firefly tour through the park. Our goals for this project included creating physical educational materials to be used at the park …

Revitalizing Turtle Creek Park, Michael Hardyway, Ethan Harm, Abbey Jacoby, Casey Stephenson

Final Reports in ENST 411: Environmental Community Projects

We current ENST 411 students, Abbey Jacoby, Michael Hardyway, Ethan Harm, and Casey Stephenson have chosen to work with Jim Knight, East Buffalo Township, the Merrill Linn Land and Waterways Conservancy, and many others in an attempt to revitalize Turtle Creek Park for a plethora of reasons. Three of us are majoring in biology, and two are majoring in environmental science, which makes much of the information and techniques relevant in Turtle Creek applicable to our courses of study. This project included heavy hands on work which allowed us students to leave a memorable and impactful influence on the Lewisburg …

Excellent Bifunctional Oxygen Evolution And Reduction Electrocatalysts (5a1/5)Co2o4 And Their Tunability, Xin Wang, Harish Singh, Manashi Nath, Kurt Lagemann, Katharine Page

Chemistry Faculty Research & Creative Works

Hastening the Progress of Rechargeable Metal-Air Batteries and Hydrogen Fuel Cells Necessitates the Advancement of Economically Feasible, Earth-Abundant, Inexpensive, and Efficient Electrocatalysts Facilitating Both the Oxygen Evolution Reaction (OER) and Oxygen Reduction Reaction (ORR). Herein, a Recently Reported Family of Nano (5A1/5) Co2O4 (A = Combinations of Transition Metals, Mg, Mn, Fe, Ni, Cu, and Zn) Compositionally Complex Oxides (CCOs) [Wang Et Al., Chemistry of Materials, 2023, 35 (17), 7283-7291.] Are Studied as Bifunctional OER and ORR Electrocatalysts. among the Different Low-Temperature Soft-Templating Samples, Those Subjected to 600 °C Post annealing Heat Treatment Exhibit Superior Performance in Alkaline Media. One …

Simulating Cross-Scale Solid-Fluid Interaction Phenomena, Jinyuan Liu

Dartmouth College Ph.D Dissertations

Solid-fluid interactions are ubiquitous in nature, and accurate simulation methods are essential for realistic animation, industrial design, and engineering analysis. Com- pared to large-scale coupling phenomena, simulating fine-scale interactions poses extra challenges due to factors such as surface tension, material wettability, and geometric complexity. In this thesis, we pursue novel methodologies to accurately model in- terfacial dynamics between surface-tension fluids and codimensional solids, involving capillary interactions, controllable wettability, and robust contact behaviors. Our ini- tial approach involves developing a novel three-way coupling method, which utilizes a thin liquid membrane, modelled as a simplicial mesh, to facilitate accurate momen- tum transfer, …

Evaluating Neuroimaging Modalities In The A/T/N Framework: Single And Combined Fdg-Pet And T1-Weighted Mri For Alzheimer’S Diagnosis, Peiwang Liu

McKelvey School of Engineering Theses & Dissertations

With the escalating prevalence of dementia, particularly Alzheimer's Disease (AD), the need for early and precise diagnostic techniques is rising. This study delves into the comparative efficacy of Fluorodeoxyglucose Positron Emission Tomography (FDG-PET) and T1-weighted Magnetic Resonance Imaging (MRI) in diagnosing AD, where the integration of multimodal models is becoming a trend. Leveraging data from the Alzheimer's Disease Neuroimaging Initiative (ADNI), we employed linear Support Vector Machines (SVM) to assess the diagnostic potential of these modalities, both individually and in combination, within the AD continuum. Our analysis, under the A/T/N framework's 'N' category, reveals that FDG-PET consistently outperforms T1w-MRI across …

Testing The Hypothesis That Tennis Points Are Independent And Identically Distributed Using Statistical Methods, Ernesto Ugona Santana

Senior Honors Theses

Most research on the probability of winning a tennis match is based on the assumption that the points are independent and identically distributed, treating each point as a Bernoulli trial with fixed probability of success. This assumption, however, seems to contradict experience. Players' performance appears to fluctuate as the match progresses due to the psychological effect of past performance. To test this counterintuitive yet central assumption, previous research has attempted to test the independence hypothesis. However, there exists a research gap in evaluating the identicality-of-distribution hypothesis, a question of broader scope than that of independence. Hence, the purpose of this …

A Constrained Maximum Likelihood Approach To Developing Well-Calibrated Models For Predicting Binary Outcomes., Yaqi Cao, Weidong Ma, Ge Zhao, Anne Marie Mccarthy, Jinbo Chen

Mathematics and Statistics Faculty Publications and Presentations

The added value of candidate predictors for risk modeling is routinely evaluated by comparing the performance of models with or without including candidate predictors. Such comparison is most meaningful when the estimated risk by the two models are both unbiased in the target population. Very often data for candidate predictors are sourced from nonrepresentative convenience samples. Updating the base model using the study data without acknowledging the discrepancy between the underlying distribution of the study data and that in the target population can lead to biased risk estimates and therefore an unfair evaluation of candidate predictors. To address this issue …

Controls On Soft Tissue And Cellular Preservation In Late Eocene And Oligocene Vertebrate Fossils From The White River And Arikaree Groups Of Nebraska, South Dakota, And Wyoming, John E. Gallucci, Grace Woolslayer, Kelsey Barker, Brian Kibelstis, Allison R Tumarkin-Deratzian, Paul V. Ullmann, David E. Grandstaff, Dennis O. Terry

School of Earth & Environment Departmental Research

Previous studies on microtaphonomy have identified multiple types of organic microstructures in fossil vertebrates from a variety of time periods and past environmental settings. This study investigates potential taphonomic, paleoenvironmental, and paleoclimatic controls on soft tissue and cellular preservation in fossil bone. To this end, fifteen vertebrate fossils were studied: eight fossils collected from the Oligocene Sharps Formation of the Arikaree Group in Badlands National Park, South Dakota, and seven fossils from formations in the underlying White River Group, including the Oligocene Brule Formation of Badlands National Park, and the Eocene Chadron Formation of Flagstaff Rim, Wyoming; Toadstool Geologic Park, …

Heavy Steers And Heifers Run At Low Stocking Rates Enhance Drought Resilience In A Pastoral Region Of Australia, Christophe D'Abbadie, Ross Kingwell, Philip E. Vercoe, Bradley Plunkett, Alan Peggs

Animal Production and Livestock Research Articles

CONTEXT

The semi-arid mulga lands of the Southern Rangelands of Western Australia experience frequent droughts. Maintaining a profitable animal grazing enterprise whilst preserving rangeland condition requires selecting an appropriate stocking rate and herd structure.

OBJECTIVE

We construct and apply bioeconomic models of beef enterprises for the semi-arid Southern Rangelands of Western Australia, to assess the profitability and relative riskiness of three different livestock production systems and three different stocking rates when exposed to different frequencies of drought.

METHODS

We construct bio-economic models of herd structures that separately focus on producing either: (i) 200 kg heifers and 210 kg steers (ii) …

A Bilevel Approach To Resource Allocation For Utility-Based Request-Response Systems, Tanner Jack Sundwall

Theses and Dissertations

We present a novel bilevel programming formulation that aims to solve a resource allocation problem for request-response systems. Our formulation is motivated by potential inefficiencies in the allocation of computational resources to incoming user requests in such systems. In our experience, systems often operate with a surplus of resources despite potentially incurring unjustifiable cost. Our work attempts to optimize the tradeoff between the financial cost of resources and the opportunity cost of unfulfilled user demand. Our bilevel formulation consists of an \textit{upper} problem which has a constraint value appearing in the \textit{lower} problem. We derive efficient methods for finding global …