Physical Sciences and Mathematics Commons^™

Machine Learning Applied To A Modern-Pleistocene Petrographic Dataset: The Global Prediction Of Sand Mineralogy (Gloprsm) Model, Isaac Johnson

Graduate Theses and Dissertations

Petrography has long been used as a tool to decipher the sedimentary provenance of sand and sandstone from the relative proportions of framework grain types. Petrographers have also related the proportions of quartz (Q), feldspar (F), and lithic (L) grains to the processes that form and modify sediments within sediment routing systems. This past work has shown that factors including source lithology, climate, transport history, and tectonism work in concert to modify the framework mineralogy of sand. However, there is a lack of a quantitative understanding of the interactions and feedbacks between these factors and how they modify sand mineralogy. …

Design, Synthesis, And Catalytic Application Of Crystalline Porous Nanomaterials, Zainab Abdullah Almansaf

Graduate Theses and Dissertations

Chapter 1: COFs (covalent organic frameworks) are a new type of microporous crystalline polymer connected by organic units via strong covalent bonds. Due to their well-defined crystalline structures and excellent chemical and thermal stabilities, COF materials are considered promising candidates in applications such as gas adsorption, catalysis, and energy storage.Chapter 2: A new covalent organic framework (COF) based on imine bonds was assembled from 2-(4-formylphenyl)-5-formylpyridine and 1,3,6,8-tetrakis(4-aminophenyl)pyrene, which showed an interesting dual-pore structure with high crystallinity. Postmetallation of the COF with Pt occurred selectively at the N donor (imine and pyridyl) in the larger pores. The metalated COF served as …

Evapotranspiration In Mid-South Rice Production, Colby Wade Reavis

Graduate Theses and Dissertations

Rice provides much needed sustenance to a large portion of the global population, particularly in the developing world. With stress placed on food production systems under the reality of climate change and an increasing global population, rice production systems require solutions to a number of issues, including a limited water supply. As producers explore new strategies for conserving local water resources to continue to maintain yields, new irrigation strategies and technologies are being developed and validated for use at commercial production scales. Alternate wetting and drying (AWD) is an irrigation practice that provides water savings through the capture of rainfall …

Data-Driven Statin Initiation Evaluation And Optimization For Prediabetes Population, Muhenned A. Abdulsahib

Graduate Theses and Dissertations

This dissertation develops quantitative models to support medical decision making of statininitiation considering the uncertainty in disease progression for prediabetes patients. A mathematical model is built to help medical decision-makers take action of statin initiation under uncertainty in future prediabetes progressions. The association between cholesterol drug use, such as statin, and elevating glucose level attracted considerable amounts of attention in the literature. Statin effects on glucose vary with respect to different levels of glucose. The first chapter of this dissertation introduces the problem and an overview of the tools that will be used to solve it. In the second chapter …

Body Mass And Body Condition Variation Of Mallards (Anas Platyrhynchos) Within And Among Winters Within The Lower Mississippi Alluvial Valley, John Thompson Veon

Graduate Theses and Dissertations

Most North American waterfowl overwinter in southern North America before migrating back to breeding grounds in the northern US and Canada. These species face the challenge of needing to maintain or increase their body mass during an environmentally difficult winter period. Successful body mass maintenance during the winter period has major ramifications not only for their winter survival but for their fitness across the entire year. Recent research in Europe and the western United States suggests that the body mass of mallards (Anas platyrhynchos) has increased from the late 1960s to early 2000s. However, the factors responsible for increases in …

Investigating Depth Estimation To Archaeological Magnetic Source Bodies, Jeremy G. Menzer

Graduate Theses and Dissertations

Magnetometry is the most widely applied archaeo-geophysical technique. Current practice standards employ the technique to map only in a two-dimensional plan view fashion, but in deep geologic studies depth estimators are routinely applied to magnetic datasets. These estimators provide three-dimensional information to magnetic source-bodies. There are many different depth estimators employed in geologic study that all require various degrees of processing complexity. This study investigates two mathematically simple techniques, half-width rules and multi-height methods. Half-width rules are likely the oldest depth estimators within the field while multi-height techniques are but a minor footnote in the literature. The applicability of these …

Gaas Growth On Sapphire Substrates (C And R Plane) For Integrated Microwave Photonics (Imwp), Samir Kumar Saha

Graduate Theses and Dissertations

The microwave signal processing in the optical domain creates new opportunities for information and communication technology (ICT) and networks by increasing speed, bandwidth, and processing capability. IMWP incorporates the functions of microwave photonics components/subsystems in monolithic or hybrid photonic circuits to meet future needs. Sapphire platforms have the potential to integrate all-in-one, for instance, light source, analog signal processing, light detection, CMOS control circuit, silicon on sapphire to achieve high-performance, low-cost mixed-signal optical links etc. Molecular beam epitaxy (MBE) has been used to grow GaAs on sapphire substrates to integrate optoelectronic devices in the same platform.

The initial stage of …

Two-Dimensional Black Phosphorus For Terahertz Emission And Near-Field Radiative Heat Transfer, Mahmudul Hasan Doha

Graduate Theses and Dissertations

The main focus of this work is to investigate two potential optical and optoelectronic applications of black phosphorus (BP): the near-field radiative heat transfer in plasmonic heterostructures with graphene and terahertz emission from multi-layer BP photoconductive antennas. When the separation distance between graphene-black phosphorene is much smaller than or comparable to the thermal wavelength at different temperatures, a near-field radiation heat transfer breaks the Planck blackbody limit. The magnitude of the near-field radiation enhancement acutely depends on the gate voltage, doping, and vacuum gap of the graphene and BP pair. The strong near-field radiation heat transfer enhancement of the specific …

Parity-Time Symmetry In A Coherent Atomic Medium, Jingliang Feng

Graduate Theses and Dissertations

Parity-time (PT) symmetry has attracted considerable attention since optics was realized with the ability to provide a fertile platform for the exploration of PT symmetry. Although many of the previous researches on PT symmetry have been conducted in solid-state system and the network of fiber loops, coherent atomic medium offers another platform for the exploration of PT symmetry due to its easy reconfigurability and flexible tunability in parameters.

This dissertation mainly focuses on the investigations of the phenomena related to PT-symmetric optical lattice in a coherent atomic medium. First, a controllable photonic crystal with periodic Raman gain was constructed in …

Community Perceptions And Aesthetic Valuation Of Remediation Gardens, Rachel Bechtold

Graduate Theses and Dissertations

Creating successfully remediated landscapes may rely on both natural resources and human perception in landscape design. Urban areas present a dynamic environment wherein communities and nature compete for resources and space. This dissertation study was designed to better understand aesthetic perceptions of native plants capable of land remediation in midwestern communities. Findings from this study show the importance of aesthetic perceptions of stakeholders towards rehabilitated landscapes and the importance of organizing indicators for future design decisions in an interdisciplinary fashion. Recommendations include continued evaluation of aesthetic perceptions for plant species in urban landscapes and modeling a more consistent framework for …

Experimental And Computational Studies Of Electron Rich Alkenes, Alexa May

Graduate Theses and Dissertations

Thermal homolysis is one of the most fundamental reactions in organic chemistry. Free radical reactions are generally initiated by light or a radical initiator to generate the first radical, which can then propagate or terminate the reaction. Direct thermal homolysis requires no chemical initiators, just an increase in temperature depending on the homolysis energy.There are few studies of direct radical homolysis in complex systems or under mild conditions. The reactions involving C-N homolysis under mild conditions are reported in Chapter 1. Though the authors do not all propose a radical mechanism, we believe they can all be explained by a …

Optimization Of Nitrogen Removal Rate In One-Stage Reactor Through Partial Nitrification Anammox Process During Direct Treatment Of Poultry Litter Wastewater, Yiting Xiao

Graduate Theses and Dissertations

Anammox is an increasingly common process used for the treatment of reject water and even mainstream wastewater due to its low oxygen demand. However, anammox is not commonly utilized in the direct treatment of poultry litter because of the high organic content, which would inhibit the anammox process. Thus, this project is aimed at optimizing the nitrogen removal rate through partial nitrification anammox process (PN/A) to treat synthetic poultry litter wastewater. Nitrogen removal efficiencies will therefore be improved through optimizing the combination of three operating parameters including hydraulic retention time (HRT), dissolved oxygen (DO) concentration, and carbon to nitrogen (C/N) …

Analysis Of Bacteriorhodopsin Suspended In A Bilayer Lipid Membrane, Moath Alhejji

Graduate Theses and Dissertations

The bacteriorhodopsin protein’s unique characteristic of proton pumping can convert light energy to electric energy. The aim of this research was to generate photocurrent using bacteriorhodopsin in a bi-layer lipid membrane. Lipid monolayer and bilayer were formed using painting and folding methods, respectively. Capacitance and resistance of the lipid membranes were measured and used to validate the best methodology. My results show that the folding method is more efficient in incorporating Bacteriorhodopsin. The photocurrent was generated by illuminating a green laser (532 nm) on the bilayer lipid membranes. The patch clamp electrophysiology technique was used to apply voltage across the …

Deep Learning Strategies For Pool Boiling Heat Flux Prediction Using Image Sequences, Connor Heo

Graduate Theses and Dissertations

The understanding of bubble dynamics during boiling is critical to the design of advanced heater surfaces to improve the boiling heat transfer. The stochastic bubble nucleation, growth, and coalescence processes have made it challenging to obtain mechanistic models that can predict boiling heat flux based on the bubble dynamics. Traditional boiling image analysis relies on the extraction of the dominant physical quantities from the images and is thus limited to the existing knowledge of these quantities. Recently, machine-learning-aided analysis has shown success in boiling crisis detection, heat flux prediction, real-time image analysis, etc., whereas most of the existing studies are …

Fair And Diverse Group Formation Based On Multidimensional Features, Mohammed Saad A Alqahtani

Graduate Theses and Dissertations

The goal of group formation is to build a team to accomplish a specific task. Algorithms are being developed to improve the team's effectiveness so formed and the efficiency of the group selection process. However, there is concern that team formation algorithms could be biased against minorities due to the algorithms themselves or the data on which they are trained. Hence, it is essential to build fair team formation systems that incorporate demographic information into the process of building the group. Although there has been extensive work on modeling individuals’ expertise for expert recommendation and/or team formation, there has been …

Catalytic Activity Of Molybdenum-Dioxo Complexes, Randy Tran

Graduate Theses and Dissertations

This dissertation details the development of rationally designed dioxomolybdenum catalyst active for deoxydehydration (DODH), the net reduction of diols and polyols into alkenes and dienes. Catalyst design involved variations on dioxomolybdenum(VI) supported by a dianionic meridional pincer ligand. Rational substrate scope was explored using aliphatic diols, aromatic diols, and biomass derived diols. Various reductants were tested for ability to catalyze the reaction. The substrate specific mechanism of DODH was explored utilizing NMR and in-situ infrared spectroscopy and important rate constants and rate determining steps were found to aid in the optimization of ideal reaction conditions. Catalytic activity was observed to …

Investigation Of N-Sulfonyliminium Ion Triggered Cyclizations For The Synthesis Of Piperidine Scaffolds, Kaitlyn Birkhoff

Honors Theses

In consideration of the on-going global pandemic, immediate access to Food and Drug Administration approved pharmaceutical medications and vaccines is a matter of utmost priority to our national healthcare system. One significant modality in managed care is the dispensation of prescription drugs for the prevention or treatment of illnesses and diseases. According to the Centers for Disease Control and Prevention, physicians order and provide over 2.9 billion prescriptions each year with analgesics, antihyperlipidemics, and dermatological agents being the most prescribed therapeutic classes. Within those classes exists a disparate variety of chemical structures that must be prepared on a metric ton …

Techniques For The Enantioselective Asymmetric Synthesis Of Benzyl Substituted Malonic Acid Esters, Madison Hansen

Honors Theses

A popular method for the enantioselective synthesis of substituted malonic half esters is hydrolysis via Pig Liver Esterase (PLE), however some substrates produce low enantiomeric excess, namely benzyl-substituted malonic esters. Presented here are alternative methods explored for this synthesis, the first being phase-transfer catalyzed hydrolysis via N-benzyl quaternary ammonium salts derived from cinchona alkaloids. The second method utilized chiral auxiliary directed benzylation with auxiliaries including menthol and oxazolidinones. Though unsuccessful, this research provided valuable groundwork in the investigation for the enantioselective asymmetric synthesis of benzyl-substituted malonic acid esters.

Keywords: Pig Liver Esterase, Enantioselectivity, Phase-Transfer Catalysis, Cinchona Alkaloids, Quaternary Ammonium …

Quantifying Surface Water Capture By Municipal Pumping Wells In An Urban Watershed Impacted By Road Salt, Austen York

Masters Theses

The Spring Valley sub-watershed is located within the Kalamazoo Township contains Spring Valley Lake, a man-made impoundment that ultimately discharges into the Kalamazoo River. Elevated chloride levels in pumped water from the Kalamazoo Station 14 municipal wellfield, located along the shoreline of Spring Valley Lake, has resulted in less than ideal corrosivity values for the water distribution system. Specific project objectives include: (1) identifying the cause of elevated chloride, (2) assessing surface water capture by the Station 14 wellfield, and (3) characterizing of water quality in Spring Valley Lake. Monitoring along a series of sampling transects spanning the sub-watershed, focused …

Functional Signatures: New Definition And Constructions, Qingwen Guo, Qiong Huang, Sha Ma, Meiyan Xiao, Guomin Yang, Willy Susilo

Research Collection School Of Computing and Information Systems

Functional signatures (FS) enable a master authority to delegate its signing privilege to an assistant. Concretely, the master authority uses its secret key sk(F) to issue a signing key sk(f) for a designated function f is an element of F-FS and sends both f and sk(f) to the assistant E, which is then able to compute a signature sigma(f) with respect to pk(F) for a message y in the range of f. In this paper, we modify the syntax of FS slightly to support the application scenario where a certificate of authorization is necessary. Compared with the original FS, our …

Adadeep: A Usage-Driven, Automated Deep Model Compression Framework For Enabling Ubiquitous Intelligent Mobiles, Sicong Liu, Junzhao Du, Kaiming Nan, Zimu Zhou, Hui Liu, Zhangyang Wang, Yingyan Lin

Research Collection School Of Computing and Information Systems

Recent breakthroughs in deep neural networks (DNNs) have fueled a tremendously growing demand for bringing DNN-powered intelligence into mobile platforms. While the potential of deploying DNNs on resource-constrained platforms has been demonstrated by DNN compression techniques, the current practice suffers from two limitations: 1) merely stand-alone compression schemes are investigated even though each compression technique only suit for certain types of DNN layers; and 2) mostly compression techniques are optimized for DNNs’ inference accuracy, without explicitly considering other application-driven system performance (e.g., latency and energy cost) and the varying resource availability across platforms (e.g., storage and processing capability). To this …

Towards Non-Intrusive Camera-Based Heart Rate Variability Estimation In The Car Under Naturalistic Condition, Shu Liu, Kevin Koch, Zimu Zhou, Martin Maritsch, Xiaoxi He, Elgar Fleisch, Felix Wortmann

Research Collection School Of Computing and Information Systems

Driver status monitoring systems are a vital component of smart cars in the future, especially in the era when an increasing amount of time is spent in the vehicle. The heart rate (HR) is one of the most important physiological signals of driver status. To infer HR of drivers, the mainstream of existing research focused on capturing subtle heartbeat-induced vibration of the torso or leveraged photoplethysmography (PPG) that detects cardiac cycle-related blood volume changes in the microvascular. However, existing approaches rely on dedicated sensors that are expensive and cumbersome to be integrated or are vulnerable to ambient noise. Moreover, their …

Verification Assisted Gas Reduction For Smart Contracts, Bo Gao, Siyuan Shen, Ling Shi, Jiaying Li, Jun Sun, Lei Bu

Research Collection School Of Computing and Information Systems

Smart contracts are computerized transaction protocols built on top of blockchain networks. Users are charged with fees, a.k.a. gas in Ethereum, when they create, deploy or execute smart contracts. Since smart contracts may contain vulnerabilities which may result in huge financial loss, developers and smart contract compilers often insert codes for security checks. The trouble is that those codes consume gas every time they are executed. Many of the inserted codes are however redundant. In this work, we present sOptimize, a tool that optimizes smart contract gas consumption automatically without compromising functionality or security. sOptimize works on smart contract bytecode, …

Book Review: Is Law Computable?: Critical Perspectives On Law And Artificial Intelligence, F. Tim Knight

Librarian Publications & Presentations

No abstract provided.

A Practical Extension To The Ab/Ba Design, My T.A Nguyen

Electronic Theses and Dissertations

In this work, we take a close look at a general extension to the traditional AB/BA
crossover design that is commonly used in clinical trials to determine the effectiveness
of new candidate drugs. While the traditional crossover design requires each patient
in the study to be measured on both treatment A and treatment B, we consider the
possibility of additional measurements being available on each patient. This produces
designs such as the AABB/BBAA design which has been used in previous studies.
A general test statistic will be derived to test for treatment effects as well as its
corresponding power function …

Confidence Interval For The Mean Of A Beta Distribution, Sean Rangel

Electronic Theses and Dissertations

Statistical inference for the mean of a beta distribution has become increasingly popular in various fields of academic research. In this study, we developed a novel statistical model from likelihood-based techniques to evaluate various confidence interval techniques for the mean of a beta distribution. Simulation studies will be implemented to compare the performance of the confidence intervals. In addition to the development and study involving confidence intervals, we will also apply the confidence intervals to real biological data that was gathered by the Department of Biology at Stephen F. Austin State University and provide recommendations on the best practice.

Explainable Transfer-Learning And Knowledge Distillation For Fast And Accurate Head-Pose Estimation, Nima Aghli

Theses and Dissertations

Head-pose estimation from facial images is an important research topic in computer-vision. It has many applications in detecting the focus of attention, monitoring driver behavior, and human-computer interaction. As with other computer-vision topics, recent research on head-pose estimation has been focused on using deep convolutional neural networks (CNNs). Although deeper networks improve prediction accuracy, they suffer from dependency on expensive hardware such as GPUs to perform real-time inference. As a result, CNN model compression becomes an important concept. In this work, we propose a novel CNN compression method by combing weight pruning and knowledge distillation. Additionally, we improve the state-of-the-art …

Design, Assembly, And Testing Of A Small 3d-Printed Thick-Gem, Jerry Lamar Collins Ii

Theses and Dissertations

Thick GEMs are a type of gas electron multiplier, a micropattern gaseous detector, with many applications in research. The subject of this study is whether or not a small 3D printed thick GEM board can be used to form a well-functioning detector. A Thick GEM having three separate board sectors, each having different sized clearance rim annuli around their holes, was designed, printed, and assembled. Several studies to quantify its behavior over both short and long time intervals were conducted, and the results calculated. The THGEM sector with 0.1 mm annulus rims was able to achieve primarily 102 gain, whereas …

Arion 33: A Prospective Mission To Near-Earth Asteroids, Alita Regi

Theses and Dissertations

Near-Earth asteroids will become primary targets for space industrialization in the future as humanity becomes a multi-planetary species. But before such missions, it is necessary to survey these asteroids for their intrinsic scientific value. Exploring asteroids via orbiter missions can help us understand the asteroid's surface composition while providing us a cost and power model required for future missions. Therefore, it is beneficial to study asteroids to pave the way for future mining operations or more comprehensive scientific explorations. Hence, in this thesis, the target asteroids 2011 UW158 and 65803 Didymos are selected as case studies for the hypothetical mission …

Intermittency Scaling Laws In Magnetohydrodynamic Turbulence: Theory, Simulations And Observations, Juan Carlos Palacios Caicedo

Theses and Dissertations

The main objective of this dissertation is to investigate intermittency of Magnetohydrodynamic (MHD) plasmas by means of high-resolution numerical simulations and large sets of solar wind data. Understanding intermittency scaling laws is a significant step forward towards understanding the fundamental properties of plasma turbulence and how spatial structures influence dissipation, heating, transport and acceleration of charged particles, which is important in a wide range of laboratory, space and astrophysical plasmas. The current stateof- the art in the theoretical understanding of intermittency in MHD turbulence is based on phenomenological (non-exact) models, numerical simulations and solar wind observations of structure functions of …