Physical Sciences and Mathematics Commons^™

Synthesis, Isolation And Structural Elucidation Of Cage-Shaped Aluminum And Gallium Phosphorous Aryloxide Complexes As Highly Reactive Lewis Acids And Carboxyboranes As Carbon Monoxide Releasing Molecules (Corms), Hussam Wannas Shinawa Alhamza

Theses and Dissertations

Group 13 Lewis acids have gained a lot of interest in over the years due to their reactivity, potency, and applications in the field of catalysis. Generally, there is a direct relationship between the catalytic activity of the organometallic Lewis acid and its acidity. However, this gives rise to a bigger challenge which is related to the stability of the catalyst. Our preliminary results from working on the catalytic reduction of CO2 have shown catalytic deactivation after one or two cycles. Utilizing bulkier substituents such as monodentate phenolates have shown promising increased stability and reactivity. The structural optimization (i.e., open-shape …

On Inter-Organizational Trust, Control And Risk In Transboundary Fisheries Governance, Gordon M. Hickey, Hunter T. Snyder, Jasper R. Devries, Owen Temby

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Inter-organizational collaboration is often considered essential to transboundary fishery governance, due, in part, to the high levels of task interdependence, the remote and often treacherous conditions, and the limited levels of information available to any policy actor on resource status. In the high seas, Regional Fisheries Management Organizations (RFMOs) are responsible for sustainably managing highly migratory and straddling fish stocks through the implementation of ecosystem-based approaches and ensuring adequate inter-jurisdictional cooperation. A central question facing RFMO governance is therefore how to structure and sustain inter-organizational transboundary collaboration under high uncertainty? This paper presents the case of the North Atlantic Salmon …

On A Class Of Critical N-Laplacian Problems, Tsz Chung Ho

Theses and Dissertations

We establish some existence results for a class of critical N-Laplacian problems in a bounded domain in R^N. In the absence of a suitable direct sum decomposition, we use an abstract linking theorem based on the Z₂-cohomological index to obtain a nontrivial critical point.

Changes In The Abundance And Distribution Of Benthic Mollusks In Polluted Sediments Of A Shallow Subtropical Estuary, Rachael Holtsberg Stark

Theses and Dissertations

The Indian River Lagoon (IRL) has been degraded by decades of eutrophication, and has accumulated an abundance of fine-grained, organic-rich sediments (muck). To quantify the impacts of organic sediments and environmental dredging, benthic mollusks were chosen to serve as bioindicators of environmental change, sediment health, and water quality. Data on species richness, biodiversity, and abundances was collected alongside sediment and water quality data before, during and after dredging. Organic sediment content was found to have an inverse logarithmic relationship benthic mollusk biodiversity, species richness, and abundance. Sediments low in percent organic content (0.7% to 6.1%) were located near the adjacent …

Development And Optimization Of A Denitrification System To Promote Biological Nutrient Removal In A Subtropical Estuary, Abigail Gering

Theses and Dissertations

Eutrophication impacts coastal ecosystems globally and triggers phytoplankton and algal blooms, leading to an increase in oxygen demand in the water column and sediments due to various biogeochemical processes. Naturally, biological nitrification, denitrification and anammox processes help to remove nitrogen predominately by nitrifying and denitrifying bacteria in the sediments. Eutrophic systems have increased nutrient and organic matter loading and are prone to the accumulation of ‘muddy’, fine-grained, organic-rich sediments (locally termed ‘muck’) that may not be able to support high enough populations of these bacteria, and therefore, may not adequately support nitrification/denitrification processes that would otherwise remove nitrogen. To decrease …

An Assessment Of Image-Cloaking Techniques Against Automated Face Recognition For Biometric Privacy, Brandon Scott Ledford

Theses and Dissertations

Over the past two decades, Americans have aggressively increased the amount of facial data uploaded to the internet primarily via social media. This data is largely unprotected due to the dire lack of existing regulations protecting users from large scale face recognition in the United States, where the value of data trade is in the tens of billions. In its current state, facial privacy in the United States depends on American corporations opting not to collect the public data, an option rarely chosen. Much research has been done in the area of suppressing recognition abilities, giving users the ability to …

Iowa Waste Reduction Center Newsletter, December 2021, University Of Northern Iowa. Iowa Waste Reduction Center.

Iowa Waste Reduction Center Newsletter

Inside this Issue:

--- End of 2021 Director Address
--- Calendar
--- Welcome, Megan!
--- Saying Goodbye! : David Hindman - Elle Olthoff - Brandon Stenger
--- IGCB Awards New Gold-Level Breweries
--- 2022-2023 Recordkeeping Compliance Calendars for Dry Cleaners
--- 2022-2023 Compliance Calendar/Logbook for Bulk Gasoline Plants
--- Industry News

A Fine-Grained Attribute Based Data Retrieval With Proxy Re-Encryption Scheme For Data Outsourcing Systems, Hanshu Hong, Ximeng Liu, Zhixin Sun

Research Collection School Of Computing and Information Systems

Attribute based encryption is suitable for data protection in data outsourcing systems such as cloud computing. However, the leveraging of encryption technique may retrain some routine operations over the encrypted data, particularly in the field of data retrieval. This paper presents an attribute based date retrieval with proxy re-encryption (ABDR-PRE) to provide both fine-grained access control and retrieval over the ciphertexts. The proposed scheme achieves fine-grained data access management by adopting KP-ABE mechanism, a delegator can generate the re-encryption key and search indexes for the ciphertexts to be shared over the target delegatee’s attributes. Throughout the process of data sharing, …

Unveiling Migration Patterns Using Data And Network Science, Firas Aswad

Theses and Dissertations

Many real-world phenomena have recently been witnessed, motivating scientists to provide a comprehensive understanding of worldwide networks, such as the human migration phenomenon. Human migration research is multidisciplinary and has yielded work in social sciences, physics, and the new field of smart city designing and planning based on big data analytics. The importance of the research comes from the impacts on both countries, sources, and distention. Impacts occur at several levels such as economy, city planning, politics, and law enforcement, leading to changes in demographics. Thus, studies on human migration help policymakers prepare and handle crises when they occur in …

Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly

Masters Theses

Uranium processing and waste storage in unlined waste ponds leached contaminants into the groundwater at Y-12, Oak Ridge, Tennessee, from the 1950s to 1980s. Groundwater wells near the S-3 ponds have had the highest nitrate concentrations of groundwater anywhere in the world (>10,000 mg/L). For reference, the maximum contaminant level for nitrate in drinking water set by the U.S. Environmental Protection Agency is 10 mg/L. Since 2012, the ENIGMA (Ecosystems and Networks Integrated with Genes and Molecular Assemblies) group has been characterizing, monitoring, and conducting field experiments to understand the interactions between contaminants, microbes, and the subsurface. The goals …

Designing Polymer Materials For Improved Additive Manufacturing, Kaizhong Guan

Masters Theses

Currently, two of the most used additive manufacturing methods for polymers are selective laser sintering (SLS) and fused filament fabrication (FFF). Although at high market size, they both have imperfections. The materials for SLS are limited and the objects manufactured by FFF existing anisotropic behavior. Targeting on these drawbacks, this thesis has proposed a novel method to prepare polypropylene (PP) microsphere which is suitable for SLS with low cost and scalable potential; and a novel material with polycarbonate as matrix that has shown a decrease in anisotropy after FFF printing.

The PP microsphere in this thesis was prepared via liquid-liquid …

Shipboard Lidar As A Tool For Remotely Measuring The Distribution And Bulk Characteristics Of Marine Particles, Brian Leigh Collister

OES Theses and Dissertations

Light detection and ranging (lidar) can provide remote estimates of the vertical distribution of optical properties in the ocean, potentially revolutionizing our ability to characterize the spatial structure of upper ocean ecosystems. However, challenges associated with quantifying the relationship between lidar measurements and biogeochemical properties of interest have prevented its adoption for routinely mapping the vertical structure of marine ecosystems. To address this, we developed a shipboard oceanographic lidar that measures attenuation (α) and linear depolarization (δ) at scales identical to those of in-water optical and biogeochemical measurements. The instrument’s ability to resolve the distribution of optical and biogeochemical properties …

Design, Synthesis And Characterization Of Carbohydrate Based Macrocycles, Photo Responsive Derivatives, And Glycoconjugates Based Low Molecular Weight Gelators, Surya Bahadur Adhikari

Chemistry & Biochemistry Theses & Dissertations

Functional glycoconjugates are important classes of compounds with many applications in different research fields. Our lab has been studying the synthesis and applications of different classes of glycoconjugates ranging from macrocycles to sugar heterocycle derivatives. Due to the importance of these compounds, our research is based on development of synthetic methods for various carbohydrate derivatives. This dissertation includes introduction and overview of projects, followed by the synthesis and studies of several different series of glycomacrolactones. The second project focuses on two classes of photoresponsive molecules, the coumarins and diarylethenes. The third project involves the synthesis and self-assembling properties of isoxazole-based …

Genetically Engineered Thermosynechococcus Elongatus Bp1: Assessment Of Potential Biorisks And Biofuel Production, Thu Ho Anh Nguyen-Jones

Chemistry & Biochemistry Theses & Dissertations

According to the International Energy Outlook 2019, released by the U.S. Energy Information Administration, it is projected that the energy consumption will increase up to 50% between 2018 and 2050 worldwide. As fossil fuel being a finite source of energy with the risk of depletion, many countries are now facing an energy security crisis. Therefore, it is important to develop other renewable and sustainable energy sources that will allow countries to shift away from depending on fossil fuels. Among several types of renewable energy, biofuel production using genetically engineered cyanobacteria is capturing much interest due to its many advantages. Different …

Synthesis And Characterization Of 4,6-Protected Glucosamine Derivatives And Branched Glycoconjugates, Jonathan Bietsch

Chemistry & Biochemistry Theses & Dissertations

Low molecular weight gelators (LMWGs) are small molecules that self-assemble in appropriate solvents to form three dimensional networks that immobilize the solvent, creating a supramolecular gel. The self-assembly of LMWGs occurs through non-covalent interactions such as hydrogen bonding, aromatic interactions, donor-acceptor interactions, Van der Waals interactions, hydrophobic forces, halogen bonding, etc. Due to self-assembly occurring through reversible non-covalent interactions, supramolecular gels can undergo a gel to solution transformation. Because of this, these materials can be sensitive to external stimuli such as temperature changes, pH changes, and other stimuli that effect non-covalent interactions. This makes the synthesis of LMWG’s an appealing …

Phytoplankton Community Response To Upwelling Events: Distribution And Abundance Investigated Using Genomic Methods, Sveinn V. Einarsson

OES Theses and Dissertations

Upwelling events are known to support blooms of phytoplankton, important primary producers at the base of the oceanic food web. Phytoplankton community structure changes in response to upwelling support higher trophic level growth and increased efficiency of carbon export from the euphotic zone. While these events occur globally, this study examined upwelling in coastal regions, where alongshore winds can drive Ekman transport and upwelling of deeper waters. The two upwelling regimes examined were the California Current System and the Alaskan Beaufort Sea. In the California Current System, the relative diatom community composition was examined using 18S sequencing to determine how …

Data-Driven Operational And Safety Analysis Of Emerging Shared Electric Scooter Systems, Qingyu Ma

Computational Modeling & Simulation Engineering Theses & Dissertations

The rapid rise of shared electric scooter (E-Scooter) systems offers many urban areas a new micro-mobility solution. The portable and flexible characteristics have made E-Scooters a competitive mode for short-distance trips. Compared to other modes such as bikes, E-Scooters allow riders to freely ride on different facilities such as streets, sidewalks, and bike lanes. However, sharing lanes with vehicles and other users tends to cause safety issues for riding E-Scooters. Conventional methods are often not applicable for analyzing such safety issues because well-archived historical crash records are not commonly available for emerging E-Scooters.

Perceiving the growth of such a micro-mobility …

A Copula Model Approach To Identify The Differential Gene Expression, Prasansha Liyanaarachchi

Mathematics & Statistics Theses & Dissertations

Deoxyribonucleic acid, more commonly known as DNA, is a complex double helix-shaped molecule present in all living organisms and hosts thousands of genes. However, only a few genes exhibit differential expression and play a vital role in a particular disease such as breast cancer. Microarray technology is one of the modern technologies developed to study these gene expressions. There are two major microarray technologies available for expression analysis: Spotted cDNA array and oligonucleotide array. The focus of our research is the statistical analysis of data that arises from the spotted cDNA microarray. Numerous models have been proposed in the literature …

Maine Won't Wait One-Year Progress Report, 2021, Maine Climate Council, Governor's Office Of Policy Innovation And The Future, Ivan Fernandez, Stephen Dickson, Susie Arnold, Cassaundra Rose, Troy Jackson, Russell Black, Nicole Grohski, Amanda Collamore, Linda Bacon, Brian Beal, Sean Birkel, Alix Contosta, Amanda Cross, Adam Daigneault, Phillips Demaynadier, Susan Elias, Glenn Hodgkins, Joe Kelley, Glen Koehler, Rebecca Lincoln, Pamela Lombard, Brandfield Lyon, Nicole Price, Jonathan Rubin, Joseph Salisbury, Peter Slovinsky, Alyssa Soucy, Robert Steneck, Sally Stockwell, Richard Wahle, Aaron Weiskittel, Carl Wilson

General University of Maine Publications

This document, an “Maine Climate Science Update 2021”, is an interim communication to the Maine Climate Council and the public about the ongoing work of the scientific community and recent events associated with climate change. It is divided into three sections: (1) current events that reflect the acceleration of extreme weather events in Maine and elsewhere with possible connections to climate change; (2) noteworthy scientific reports with national and international scope released in 2021; and (3) examples of recent peer-reviewed publications from the ongoing work of the scientific community to understand climate change in Maine.

Reinforcement Learning Policy Gradient Methods For Reservoir Operation Management And Control, Sadegh Sadeghi Tabas

All Theses

Changes in demand, various hydrological inputs, and environmental stressors are among issues that water managers and policymakers face on a regular basis. These concerns have sparked interest in applying different techniques to determine reservoir operation policy and improve reservoir release decisions. As the resolution of the analysis rises, it becomes more difficult to effectively represent a real-world system using traditional approaches for determining the best reservoir operation policy. One of the challenges is the “curse of dimensionality,” which occurs when the discretization of the state and action spaces becomes finer or when more state or action variables are taken into …

Studies In Consumption And Production Of South Carolina Aquaculture Products, David Cheplick

All Theses

Market demand for seafood products among South Carolina (SC) consumers has led to increased aquaculture production as a means of supporting the seafood supply chain across the state. Our objective is broken into four distinct parts; (1) understanding consumer’s preferences and perceptions of seafood, (2) calculating their willingness to pay (WTP) for seafood products available in SC using attributes of sustainability and locality; and (3) gathering production metric and anecdotal data from SC oyster growers. Previous research assessing the market channels of seafood in South Carolina is compared to survey results. Respondents indicated that taste and quality were the most …

A Parallelized And Layered Model For The Shallow-Water Equations, Alexander Stevens

All Theses

An energy- and enstrophy-conserving and optimally-dispersive numerical scheme for the shallow- water equations is accelerated through implementation in the GPU environment. Previous research showed the viability of the numerical scheme under standard shallow-water test cases, but was limited in applications by computation time constraints. We overcome these limitations by paral- lelizing the numerical computation in the GPU environment. We also extend the capabilities of the implementation to support not just a single shallow-water layer, but multiple. These improvements significantly expand the range of tests that can be used to exercise the model, and enable better understanding of the power of …

Efficacy Of Sediment Contaminant Remediation Of The Benthos In A Segment Of The Southern Branch Of The Elizabeth River, Colton Martin

Biological Sciences Theses & Dissertations

The bottom sediment of the Southern Branch of the Elizabeth River, a tributary of Chesapeake Bay, was historically contaminated with hydrocarbons from industrial sources especially wood treatment facilities. The Elizabeth River Project selected a section of the bottom off Money Point in the Southern Branch for a sediment contaminant remediation effort. Prior to initiation of remediation efforts, a survey occurred in summer 2010 to characterize the ecological condition of the benthic communities off Money Point compared to benthic communities of a benthic region across the channel and northwest of Money Point near Blows Creek. That study characterized the benthos of …

Connecting The Dots: The Boons And Banes Of Network Modeling, Sharlee Climer

Computer Science Faculty Works

Network modeling transforms data into a structure of nodes and edges such that edges represent relationships between pairs of objects, then extracts clusters of densely connected nodes in order to capture high-dimensional relationships hidden in the data. This efficient and flexible strategy holds potential for unveiling complex patterns concealed within massive datasets, but standard implementations overlook several key issues that can undermine research efforts. These issues range from data imputation and discretization to correlation metrics, clustering methods, and validation of results. Here, we enumerate these pitfalls and provide practical strategies for alleviating their negative effects. These guidelines increase …

Identification And Characterization Of Bisbenzimide Compounds That Inhibit Human Cytomegalovirus Replication, Nicole Falci Finardi, Hyeongjun Kim, Lee Z. Hernandez, Matthew R. G. Russell, Catherine M-K Ho, Vattipally B. Sreenu, Hannah A. Wenham, Andy Merritt, Blair L. Strang

Physics and Astronomy Faculty Publications and Presentations

The shortcomings of current anti-human cytomegalovirus (HCMV) drugs has stimulated a search for anti-HCMV compounds with novel targets. We screened collections of bioactive compounds and identified a range of compounds with the potential to inhibit HCMV replication. Of these compounds, we selected bisbenzimide compound RO-90-7501 for further study. We generated analogues of RO-90-7501 and found that one compound, MRT00210423, had increased anti-HCMV activity compared to RO-90-7501. Using a combination of compound analogues, microscopy and biochemical assays we found RO-90-7501 and MRT00210423 interacted with DNA. In single molecule microscopy experiments we found RO-90-7501, but not MRT00210423, was able to compact DNA, …

Challenges For Estimating The Global Prevalence Of Micronutrient Deficiencies And Related Disease Burden: A Case Study Of The Global Burden Of Disease Study, Sonja Y. Hess, Alexander C. Mclain Ph.D., Edward A. Frongillo Jr. Ph.D., Ashkan Afshin, Nicholas J. Kassebaum, Saskia Jm Osendarp, Reed Atkin, Rahul Rawat, Kenneth H. Brown

Faculty Publications

Information on the prevalence of micronutrient deficiencies is needed to determine related disease burden; underpin evidence-based advocacy; and design, deliver, and monitor safe, effective interventions. Assessing the global prevalence of deficiency requires a valid micronutrient status biomarker with an appropriate cutoff to define deficiency and relevant data from representative surveys across multiple locations and years. The Global Burden of Disease Study includes prevalence estimates for iodine, iron, zinc, and vitamin A deficiencies, for which recommended biomarkers and appropriate deficiency cutoffs exist. Because representative survey data are lacking, only retinol concentration is used to model vitamin A deficiency, and proxy indicators …

Combined Amplification And Sound Therapy For Individuals With Tinnitus And Coexisting Hearing Loss: A Retrospective Cohort Study, Purushothaman Ganesan, Hansapani Rodrigo, Jason Schmiedge, Rob Reiter, Simham Swapna, Vinaya Manchaiah

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

BACKGROUND: The heterogeneity of tinnitus perception and its impact necessitates a tailor-made management approach in everyone. The current study examined the effects of residual inhibition in combined amplification and sound therapy in individuals with tinnitus and coexisting hearing loss.

METHODS: A retrospective analysis was performed on patients with tinnitus and coexisting hearing loss between 2016 and 2019. A total of 72 patients provided with combined amplification and sound therapy were divided into 3 groups based on residual inhibition: (i) complete residual inhibition, (ii) partial residual inhibition, and (iii) negative residual inhibition. Tinnitus severity was measured using the Tinnitus …

The Belle Ii Online–Offline Data Operations System, Matthew Barrett, Takanori Hara, Michel Hernández Villanueva, Kunxian Huang, Dhiraj Kalita, Petteri Kettunen, Prashant Shingade

Faculty and Student Publications

Data collection at the Belle II experiment started in the spring of 2019. During the early stages of the experiment it is important that the raw data are both copied to permanent storage and made available soon after being recorded to allow for the timely commissioning and calibration of the detector. Automated procedures have been developed to transfer the data from the detector in a timely manner; these procedures include fault management, performance monitoring, and quality checks. It is important that the systems put in place will also scale to the much higher data rates expected in the coming years …

Study Of E+E- → D (1 S,2 S)Η And E+E- → D (1s)Η′ At S =10.866 Gev With The Belle Detector, E. Kovalenko, A. Garmash, P. Krokovny, I. Adachi, H. Aihara, D. M. Asner, V. Aulchenko, T. Aushev, R. Ayad, V. Babu, S. Bahinipati, P. Behera, J. Bennett, M. Bessner, T. Bilka, J. Biswal, A. Bobrov, A. Bondar, G. Bonvicini

Faculty and Student Publications

We report the first observation of the processes e+e-→D(1S,2S)η at s=10.866 GeV, with significance exceeding 10σ for both processes. The measured Born cross sections are σ(e+e-→D(2S)η)=2.07±0.21±0.19 pb, and σ(e+e-→D(1S)η)=0.42±0.08±0.04 pb. We also set the upper limit on the cross section of the process e+e-→D(1S)η′ to be σ(e+e-→D(1S)η′)<0.037 pb at 90% C.L. The results are obtained with the data sample collected with the Belle detector at the KEKB asymmetric-energy e+e- collider in the energy range from 10.63 to 11.02 GeV.

Measurements Of Q2 Moments Of Inclusive B →Xcℓ+Νℓ Decays With Hadronic Tagging, R. Van Tonder, L. Cao, W. Sutcliffe, M. Welsch, F. U. Bernlochner, I. Adachi, H. Aihara, D. M. Asner, T. Aushev, R. Ayad, V. Babu, P. Behera, K. Belous, J. Bennett, M. Bessner, V. Bhardwaj, B. Bhuyan, T. Bilka, J. Biswal

Faculty and Student Publications

We present the measurement of the first to fourth order moments of the four-momentum transfer squared, q2, of inclusive B→Xcℓ+νℓ decays using the full Belle dataset of 711 fb-1 of integrated luminosity at the (4S) resonance where ℓ=e, μ. The determination of these moments and their systematic uncertainties open new pathways to determine the absolute value of the Cabibbo-Kobayashi-Maskawa matrix element Vcb using a reduced set of matrix elements of the heavy quark expansion. In order to identify and reconstruct the Xc system, we reconstruct one of the two B-mesons using machine learning techniques in fully hadronic decay modes. The …