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Articles 43171 - 43200 of 304371
Full-Text Articles in Physical Sciences and Mathematics
A Southwestern United States Pilot Investigation Of Triatomine–Mite Prevalence, Kyndall C. Dye-Braumuller, Hanna Waltz, Mary K. Lynn, Stephen A. Klotz, Justin O. Schmidt, Alvaro Romero, Marvin Stanley Rodriguez Aquino, Jose Ricardo Palacios Valladares, Pamela Michelle Cornejo Rivas, Melissa Nolan Ph.D., Mph
A Southwestern United States Pilot Investigation Of Triatomine–Mite Prevalence, Kyndall C. Dye-Braumuller, Hanna Waltz, Mary K. Lynn, Stephen A. Klotz, Justin O. Schmidt, Alvaro Romero, Marvin Stanley Rodriguez Aquino, Jose Ricardo Palacios Valladares, Pamela Michelle Cornejo Rivas, Melissa Nolan Ph.D., Mph
Faculty Publications
An estimated 70 million persons in the Western Hemisphere are living at risk for Chagas disease, a parasitic infection transmitted to humans by over 156 different competent triatomine insect vector species. Prior Pan American Health Organization insecticide campaigns throughout Latin America in the 1990s and 2000s demonstrated that domestic insecticide spraying had temporary effects, which resulted in the re-establishment of triatomine species within a few years. Serendipitously, our team found ectoparasitic mites parasitizing triatomines collected from the field in multiple locations in the southwestern United States, where human–triatomine interaction was high but human parasite infection remains low. Upon further investigation …
Butte Priority Soils Operable Unit (Bpsou) 2021 Monthly Progress Report. Consent Decree For The Butte Priority Soils Operable Unit. Civil Action No. Cv 89-039-Bu-Seh, Josh Bryson
Silver Bow Creek/Butte Area Superfund Site
No abstract provided.
Erratum: Searches For Continuous Gravitational Waves From Nine Young Supernova Remnants (Apj (2015) 813 (39) Doi: 10.1088/0004-637x/813/1/39), J. Aasi, B. P. Abbott, R. Abbott, T. Abbott, M. R. Abernathy, F. Acernese, K. Ackley, C. Adams, T. Adams, P. Addesso, R. X. Adhikari, V. Adya, C. Affeldt, M. Agathos, K. Agatsuma, N. Aggarwal, O. D. Aguiar, A. Ain, P. Ajith, Tiffany Z. Summerscales
Erratum: Searches For Continuous Gravitational Waves From Nine Young Supernova Remnants (Apj (2015) 813 (39) Doi: 10.1088/0004-637x/813/1/39), J. Aasi, B. P. Abbott, R. Abbott, T. Abbott, M. R. Abernathy, F. Acernese, K. Ackley, C. Adams, T. Adams, P. Addesso, R. X. Adhikari, V. Adya, C. Affeldt, M. Agathos, K. Agatsuma, N. Aggarwal, O. D. Aguiar, A. Ain, P. Ajith, Tiffany Z. Summerscales
Faculty Publications
Equation (7) of the published article (Aasi et al. 2015) is in error; it should read (Equation presented). The upper limits on ò presented in the published article are unaffected by this error. Equation (8) of the published article is in error; it should read (Equation presented) The upper limits on α presented in Figure 3 and Table 4 of the published article were computed incorrectly. The revised Figure 3 (bottom) shows the corrected upper limits on α for the G266.2-1.2 (Vela Jr.) wide search. The revised Table 4 is provided here. The correct lowest upper limit on α (quoted …
Comparison Of Nitrate Contents For Reed Canarygrass And Orchardgrass In Large Amounts Of Compound Fertilization, A. Fushimi, Y. Tamura, K. Matoba
Comparison Of Nitrate Contents For Reed Canarygrass And Orchardgrass In Large Amounts Of Compound Fertilization, A. Fushimi, Y. Tamura, K. Matoba
IGC Proceedings (1993-2023)
Reed canarygrass (Phalaris arundinacea L.) could be an ideal candidate for manure application. We compared its growth, crude protein (CP) and nitrate N (NO3-N) content to that of orchardgrass (Dactylis glomerata L.) on different levels of nitrogen fertilization (3,10,15 and 20g N m-2, applied from May 15 to September 15 after each monthly cutting. The dry weight (DW) of reed canarygrass increased significantly with increasing amounts of N nitrogen on July, August and September. However, orchardgrass only showed a significant increase in yield on September. The concentration of CP of reed canarygrass was significantly …
Modelling Nitrogen Uptake In Winter Oilseed Rape By Using Influx Kinetics Of Nitrate Transport Systems, S. Faure, P. Malagoli, P. Lainé, E. Le Deunff, F. Ledily, A. Ourry, J. Boucaud
Modelling Nitrogen Uptake In Winter Oilseed Rape By Using Influx Kinetics Of Nitrate Transport Systems, S. Faure, P. Malagoli, P. Lainé, E. Le Deunff, F. Ledily, A. Ourry, J. Boucaud
IGC Proceedings (1993-2023)
A mechanistic model was proposed in order to predict nitrogen uptake by a culture of oilseed rape (Brassica napus L.), using independently measured characteristics of plants growing in hydroponic or under field conditions. Uptake kinetics of the different components (Constitutive and Inducible) of the Low and High Affinity Transport Systems of nitrate (CLATS, ILATS, CHATS and IHATS, respectively) were determined by 15NO3- labelling in controlled conditions. The use of kinetic equations of transport systems and the experimental field data from the INRA-Châlons rape databank allowed to model NO3- uptake during the plant growth cycle. …
Biological Interactions In Grassland Soils And Productivity, R. Cook, R. D. Bardgett, W. R. Eason, L. Skøt, K. J. Webb
Biological Interactions In Grassland Soils And Productivity, R. Cook, R. D. Bardgett, W. R. Eason, L. Skøt, K. J. Webb
IGC Proceedings (1993-2023)
This paper describes research on interactions between grassland plant species and soil microorganisms. Both parasitic and symbiotic microorganisms modify nutrient transfers between plants and soil. Experiments are described in which nematode infection of clover increased nitrogen transfer to companion ryegrass plants. Infection of clover enhanced activity of soil bacterial and fungal communities. Legume genotypes differing only in responses to symbionts (rhizobium and arbuscular mycorrhizal fungi) and pathogens are being developed for studies of gene expression during establishing and functional symbioses. Such plants can be used in experiments as defined perturbations that will provide information on the interactions and functions of …
Nitrogen Balances In High Rainfall, Temperate Dairy Pastures Of South Eastern Australia, Richard J. Eckard, D. F. Chapman, R. E. White, A. Smith, D. Chen, P. A. Durling
Nitrogen Balances In High Rainfall, Temperate Dairy Pastures Of South Eastern Australia, Richard J. Eckard, D. F. Chapman, R. E. White, A. Smith, D. Chen, P. A. Durling
IGC Proceedings (1993-2023)
Nitrogen (N) fertilizer use on dairy pastures in south eastern Australia has increased exponentially over the past 15 years, causing increasing environmental concerns. Volatilisation, denitrification and leaching of N were measured for one year (1998-1999) in pastures receiving no N fertilizer (grass/clover), or 200 kg N/ha applied as urea (46%N) or ammonium nitrate (34.5%N). Nitrogen balances were calculated for each treatment.
Significantly more N was lost through volatilisation and denitrification when N was applied as urea compared to ammonium nitrate. Nitrate leaching losses were significantly greater with the application of N fertilizer, although the maximum loss was only 4.1 kg …
A Proposed Framework For The Development And Qualitative Evaluation Of West Nile Virus Models And Their Application To Local Public Health Decision-Making, Alexander C. Keyel, Morgan E. Gorris, Ilia Rochlin, Johnny A. Uelmen, Luis F. Chaves, Gabriel L. Hamer, Imelda K. Moise, Marta Shocket, A Marm Kilpatrick, Nicholas B. Defelice, Justin K. Davis, Eliza Little, Patrick Irwin, Andrew J. Tyre, Kelly Helm Smith, Chris L. Fredregill, Oliver Elison Timm, Karen M. Holcomb, Michael C. Wimberly, Matthew J. Ward, Christopher M. Barker, Charlotte G. Rhodes, Rebecca L. Smith
A Proposed Framework For The Development And Qualitative Evaluation Of West Nile Virus Models And Their Application To Local Public Health Decision-Making, Alexander C. Keyel, Morgan E. Gorris, Ilia Rochlin, Johnny A. Uelmen, Luis F. Chaves, Gabriel L. Hamer, Imelda K. Moise, Marta Shocket, A Marm Kilpatrick, Nicholas B. Defelice, Justin K. Davis, Eliza Little, Patrick Irwin, Andrew J. Tyre, Kelly Helm Smith, Chris L. Fredregill, Oliver Elison Timm, Karen M. Holcomb, Michael C. Wimberly, Matthew J. Ward, Christopher M. Barker, Charlotte G. Rhodes, Rebecca L. Smith
School of Natural Resources: Faculty Publications
West Nile virus(WNV) is a globally distributed mosquito-borne virus of great public health concern. The number of WNV human cases and mosquito infection patterns vary in space and time. Many statistical models have been developed to understand and predict WNV geographic and temporal dynamics. However, these modeling efforts have been disjointed with little model comparison and inconsistent validation. In this paper, we describe a framework to unify and standardize WNV modeling efforts nationwide. WNV risk, detection, or warning models for this review were solicited from active research groups working in different regions of the United States. A total of 13 …
Ratio And Difference Of Average Hazard With Survival Weight: New Measures To Quantify Survival Benefit Of New Therapy, Hajime Uno, Miki Horiguchi
Ratio And Difference Of Average Hazard With Survival Weight: New Measures To Quantify Survival Benefit Of New Therapy, Hajime Uno, Miki Horiguchi
Harvard University Biostatistics Working Paper Series
The hazard ratio (HR) has been the most popular measure to quantify the magnitude of treatment effect on time-to-event outcomes in clinical research. However, the HR estimated by Cox's method has several drawbacks. One major issue is that there is no clear interpretation when the proportional hazards (PH) assumption does not hold, because it is affected by study-specific censoring time distribution in non-PH cases. Another major issue is that the lack of a group-specific absolute hazard value in each group obscures the clinical significance of the magnitude of the treatment effect. Given these, we propose average hazard with survival weight …
Accelerated Online Certificate In Quantum Computing, Joanna Burkhardt
Accelerated Online Certificate In Quantum Computing, Joanna Burkhardt
Library Impact Statements
No abstract provided.
Mgrre_Pureoilscouttickets_Iroquois Oil Company_2_21127008940000, Mgrre
Mgrre_Pureoilscouttickets_Iroquois Oil Company_2_21127008940000, Mgrre
Legacy Scout Tickets from Pure Oil Company
No abstract provided.
The View From Ventress - 2020-21 Academic Year, University Of Mississippi, College Of Liberal Arts
The View From Ventress - 2020-21 Academic Year, University Of Mississippi, College Of Liberal Arts
Liberal Arts Newsletters
News from the College of Liberal Arts
Geology & Geography News, Georgia Southern University
Geology & Geography News, Georgia Southern University
School of Earth, Environment, and Sustainability News (2013-2021)
- Sea Level Rise Symposium – Chatham County
10578172 Edd, Pioneer Technical Services, Inc.
10578172 Edd, Pioneer Technical Services, Inc.
Silver Bow Creek/Butte Area Superfund Site
No abstract provided.
Maternal Diet In Pregnancy And Child’S Respiratory Outcomes: An Individual Participant Data Meta-Analysis Of 18 000 Children, Sara M. Mensink-Bout, Evelien R. Van Meel, Johan C. De Jongste, Isabella Annesi-Maesano, Adrien M. Aubert, Jonathan Y. Bernard, Ling-Wei Chen, Cyrus Cooper, Sarah R. Crozier, Wojciech Hanke, Nicholas C. Harvey, James R. Hébert Scd, Barbara Heude, Joanna Jerzynska, Cecily C. Kelleher, John Mehegan, Fionnuala M. Mcauliffe, Catherine M. Phillips, Kinga Polanska, Caroline L. Relton, Nitin Shivappa Mbbs, Mph, Ph.D., Matthew Suderman, Vincent W.V. Jaddoe, Liesbeth Duijts
Maternal Diet In Pregnancy And Child’S Respiratory Outcomes: An Individual Participant Data Meta-Analysis Of 18 000 Children, Sara M. Mensink-Bout, Evelien R. Van Meel, Johan C. De Jongste, Isabella Annesi-Maesano, Adrien M. Aubert, Jonathan Y. Bernard, Ling-Wei Chen, Cyrus Cooper, Sarah R. Crozier, Wojciech Hanke, Nicholas C. Harvey, James R. Hébert Scd, Barbara Heude, Joanna Jerzynska, Cecily C. Kelleher, John Mehegan, Fionnuala M. Mcauliffe, Catherine M. Phillips, Kinga Polanska, Caroline L. Relton, Nitin Shivappa Mbbs, Mph, Ph.D., Matthew Suderman, Vincent W.V. Jaddoe, Liesbeth Duijts
Faculty Publications
Rationale Severe fetal malnutrition has been related to an increased risk of respiratory diseases later in life, but evidence for the association of a suboptimal diet during pregnancy with respiratory outcomes in childhood is conflicting. We aimed to examine whether a pro-inflammatory or low-quality maternal diet during pregnancy was associated with child's respiratory health.
Methods We performed an individual participant meta-analysis among 18 326 mother–child pairs from seven European birth cohorts. Maternal pro-inflammatory and low-quality diets were estimated by energy-adjusted Dietary Inflammatory Index (E-DII) and Dietary Approaches to Stop Hypertension (DASH) scores. Preschool wheezing and school-age asthma were measured using …
Prediction Of Biome-Specific Potential Evapotranspiration In Mongolia Under A Scarcity Of Weather Data, Khulan Batsukh, Vitaly A. Zlotnik, Andrew E. Suyker, Paolo Nasta
Prediction Of Biome-Specific Potential Evapotranspiration In Mongolia Under A Scarcity Of Weather Data, Khulan Batsukh, Vitaly A. Zlotnik, Andrew E. Suyker, Paolo Nasta
Department of Earth and Atmospheric Sciences: Faculty Publications
We propose practical guidelines to predict biome-specific potential evapotranspiration (ETp) from the knowledge of grass-reference evapotranspiration (ET0) and a crop coefficient (Kc) in Mongolia. A paucity of land-based weather data hampers use of the Penman–Monteith equation (FAO-56 PM) based on the Food and Agriculture Organization (FAO) guidelines to predict daily ET0. We found that the application of the Hargreaves equation provides ET0 estimates very similar to those from the FAO-56 PM approach. The Kc value is tabulated only for crops in the FAO-56 guidelines but is unavailable …
Mgrre_Pureoilscouttickets_Schultz_1_21127007910000, Mgrre
Mgrre_Pureoilscouttickets_Schultz_1_21127007910000, Mgrre
Legacy Scout Tickets from Pure Oil Company
No abstract provided.
Communicate Sustainability Successfully: How To Connect With Your Audience, Drew Anderson
Communicate Sustainability Successfully: How To Connect With Your Audience, Drew Anderson
Sustainability Research & Practice Seminar Presentations
Meteorologist Drew Anderson, Earth and Space Sciences - Communicate Sustainability Successfully: How to Connect with Your Audience
Hiv Infection And The Risk Of World Health Organization-Defined Sudden Cardiac Death, Matthew S. Freiberg, Meredith S. Duncan, Charles Alcorn, Chung-Chou H. Chang, Suman Kundu, Asri Mumpuni, Emily K. Smith, Sarah Loch, Annie Bedigian, Eric Vittinghoff, Kaku So-Armah, Priscilla Y. Hsue, Amy C. Justice, Zian H. Tseng
Hiv Infection And The Risk Of World Health Organization-Defined Sudden Cardiac Death, Matthew S. Freiberg, Meredith S. Duncan, Charles Alcorn, Chung-Chou H. Chang, Suman Kundu, Asri Mumpuni, Emily K. Smith, Sarah Loch, Annie Bedigian, Eric Vittinghoff, Kaku So-Armah, Priscilla Y. Hsue, Amy C. Justice, Zian H. Tseng
Biostatistics Faculty Publications
Background
People living with HIV have higher sudden cardiac death (SCD) rates compared with the general population. Whether HIV infection is an independent SCD risk factor is unclear.
Methods and Results
This study evaluated participants from the Veterans Aging Cohort Study, an observational, longitudinal cohort of veterans with and without HIV infection matched 1:2 on age, sex, race/ethnicity, and clinical site. Baseline for this study was a participant's first clinical visit on or after April 1, 2003. Participants were followed through December 31, 2014. Using Cox proportional hazards regression, we assessed whether HIV infection, CD4 cell counts, and/or HIV viral …
Heavy Metal And Contaminant Loading In The Oder River Floodplains And Consequences For Livestock Management, G. Schalitz, A. Behrendt
Heavy Metal And Contaminant Loading In The Oder River Floodplains And Consequences For Livestock Management, G. Schalitz, A. Behrendt
IGC Proceedings (1993-2023)
The predominately pristine lower Oder floodplains have experienced sedimentation and enrichment of heavy metals and contaminants since the start of industrialization in the region. With the creation of the German-Polish National Park, which included the flooded grassland area, intensive milk production has been prohibited. The objective of this research was to estimate the impact of the floodplain heavy metal and contaminant levels on the lower Oder region. Soil and plant content were analyzed for three transects according to accepted DIN methods. High content in soil did not consistently result in high plant contents; however, higher content levels were often observed …
Extended Daylength To Increase Fall/Winter Yields Of Warm-Season Perennial Grasses, P. Mislevy, T. R. Sinclair, J. D. Ray
Extended Daylength To Increase Fall/Winter Yields Of Warm-Season Perennial Grasses, P. Mislevy, T. R. Sinclair, J. D. Ray
IGC Proceedings (1993-2023)
Low forage production in fall/winter months is a severe limitation for dairy and beef cattle producers in the southeastern U.S. It was hypothesized that shrt daylengths during these months induce a physiological dormancy in grasses. Four grasses [Pensacola bahiagrass, Paspalum notatum Flugge; Tifton 85 and Florakirk bermudagrass, Cynodon dactylon (L.); Florona stargrass, C. nlemfuensis Vanderyst var. nlemfuensis] were subjected to extended daylengths during the winter/fall months in a field test. Pensacola bahiagrass and Tifton 85 bermudagrass showed especially dramatic increases in forage yield during the fall/winter season under the extended daylength. Genetic elimination of daylength sensitivity in these grasses …
On The Uniqueness Of Solutions To Martingale Problems For Diffusion Operators With Progressively Measurable Random Coefficients, Masaaki Tsuchiya
On The Uniqueness Of Solutions To Martingale Problems For Diffusion Operators With Progressively Measurable Random Coefficients, Masaaki Tsuchiya
Journal of Stochastic Analysis
No abstract provided.
Blue Carbon In South Florida's Mangroves: The Role Of Large Roots And Necromass, Zoë I. Shribman
Blue Carbon In South Florida's Mangroves: The Role Of Large Roots And Necromass, Zoë I. Shribman
LSU Master's Theses
Blue carbon sequestration and storage in mangroves largely result from belowground biomass allocation in response to flooded anaerobic soil conditions and nutrient availability. Biomass allocation to belowground roots is a major driver of mangrove soil formation and organic matter accumulation leading to blue carbon storage potential. Belowground biomass sampling in mangroves is labor intensive, limiting data availability on biomass stocks, particularly for large roots (>20 mm diameter) and necromass (dead roots). The mangrove nutrient model (NUMAN) uses mostly literature values to parameterize a soil cohort approach to simulate depth distribution of root mass and organic carbon concentration. We evaluated …
Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato
Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato
LSU Master's Theses
The movement of water through soil is preferential and heterogeneous. Subsurface interactions between mobile flows and the soil matrix are not uniform and are therefore difficult to predict through time and space. The use of stable isotopes of hydrogen (2H) and oxygen (18O) as conservative tracers of water movement is improving understanding of soil hydrological processes, yet field-scale observations of isotopic variability remain scarce despite implications for identifying dominant hydrologic processes. We sampled two adjacent soils at a ridge-swale topography floodplain forest to determine soil water isotopic variability at a 20 cm depth resolution in soils …
Digital Forensic Readiness Framework Based On Honeypot And Honeynet For Byod, Audrey Asante, Vincent Amankona
Digital Forensic Readiness Framework Based On Honeypot And Honeynet For Byod, Audrey Asante, Vincent Amankona
Journal of Digital Forensics, Security and Law
The utilization of the internet within organizations has surged over the past decade. Though, it has numerous benefits, the internet also comes with its own challenges such as intrusions and threats. Bring Your Own Device (BYOD) as a growing trend among organizations allow employees to connect their portable devices such as smart phones, tablets, laptops, to the organization’s network to perform organizational duties. It has gained popularity over the years because of its flexibility and cost effectiveness. This adoption of BYOD has exposed organizations to security risks and demands proactive measures to mitigate such incidents. In this study, we propose …
Nitrogen Or Water Limitation To Grassland Growth During A Moderate Dry Season In The Humid Tropics, P. Cruz, M. Boval
Nitrogen Or Water Limitation To Grassland Growth During A Moderate Dry Season In The Humid Tropics, P. Cruz, M. Boval
IGC Proceedings (1993-2023)
The aim of this work was to compare the effects of nitrogen and water shortage on grassland production during a moderate dry season in a tropical humid environment. The results of two experiments carried out in Guadeloupe (FWI) have shown that during dry spells, the reduction in growth of natural grasslands based on Angleton grass (Dichantium aristatum) is more easily corrected by nitrogen fertiliser application than by irrigation. This shows that it is not the availability of water, but that of nitrogen, which is limiting the primary production of Angleton grass, stands. This result is less clear for …
Screening Brachiaria Introductions For Resistance To Spittlebugs (Homoptera: Cercopidae), José R. Valério, Cacilda Borges Do Valle, A. P. De Souza, M. C. M. Oliveira
Screening Brachiaria Introductions For Resistance To Spittlebugs (Homoptera: Cercopidae), José R. Valério, Cacilda Borges Do Valle, A. P. De Souza, M. C. M. Oliveira
IGC Proceedings (1993-2023)
Spittlebugs are the most evident and damaging pests of Signal grasses (Brachiaria) in tropical America. Damage caused by these insects can result in the complete loss of available forage, thereby reducing the carrying capacity of infested pastures. Host plant resistance is a low-cost method of controlling insects. High level of spittlebug resistance is found in the cultivar Marandu (B. brizantha), but it requires more fertile soils. Brachiaria germplasm provided by the International Center for Tropical Agriculture (CIAT) is available at National Beef Cattle Research Center of the Brazilian Agricultural Research Corporation (Embrapa Beef Cattle) and it …
Mgrre_Pureoilscouttickets_Ranch, Stewart_1_21127007280000, Mgrre
Mgrre_Pureoilscouttickets_Ranch, Stewart_1_21127007280000, Mgrre
Legacy Scout Tickets from Pure Oil Company
No abstract provided.
Associations Of Circulating Dimethylarginines With The Metabolic Syndrome In The Framingham Offspring Study, Ibrahim Musa Yola, Carlee Moser, Meredith S. Duncan, Edzard Schwedhelm, Dorothee Atzler, Renke Maas, Juliane Hannemann, Rainer H. Böger, Ramachandran S. Vasan, Vanessa Xanthakis
Associations Of Circulating Dimethylarginines With The Metabolic Syndrome In The Framingham Offspring Study, Ibrahim Musa Yola, Carlee Moser, Meredith S. Duncan, Edzard Schwedhelm, Dorothee Atzler, Renke Maas, Juliane Hannemann, Rainer H. Böger, Ramachandran S. Vasan, Vanessa Xanthakis
Biostatistics Faculty Publications
BACKGROUND: Circulating levels of the endogenous inhibitor of nitric oxide synthase, asymmetric dimethylarginine (ADMA), are positively associated with the prevalence of metabolic syndrome (MetS) in cross-sectional investigations. It is unclear if circulating ADMA and other methylarginines are associated with incident MetS prospectively.
METHODS: We related circulating ADMA, symmetric dimethylarginine (SDMA), L-arginine (ARG) concentrations (measured with a validated tandem mass spectrometry assay) and the ARG/ADMA ratio to MetS and its components in 2914 (cross-sectional analysis, logistic regression; mean age 58 years, 55% women) and 1656 (prospective analysis, Cox regression; mean age 56 years, 59% women) individuals from the Framingham Offspring Study …
Emergence Of Non-Hexagonal Crystal Packing Of Deswollen And Deformed Ultra-Soft Microgels Under Osmotic Pressure Control, Molla R. Islam, Rachel Nguyen, L. Andrew Lyon
Emergence Of Non-Hexagonal Crystal Packing Of Deswollen And Deformed Ultra-Soft Microgels Under Osmotic Pressure Control, Molla R. Islam, Rachel Nguyen, L. Andrew Lyon
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Highly solvent swollen poly(N-isopropylacrylamide-co-acrylic acid) microgels are synthesized without exogenous crosslinker, making them extremely soft and deformable. These ultralow crosslinked microgels (ULC) are incubated under controlled osmotic pressure to provide a slow (and presumably thermodynamically controlled) approach to higher packing densities. It is found that ULC microgels show stable colloidal packing over a very wide range of osmotic pressures and thus packing densities. Surprising observation of co-existence between hexagonal and square lattices is also made over the lower range of studied osmotic pressures, with microgels apparently changing shape from spheres to cubes in defects or grain boundaries. It is proposed …