Physical Sciences and Mathematics Commons^™

Synthesis, Characterization, And Applications Of Nucleobase-Functionalized Conjugated Polymers, Sina Sabury

Doctoral Dissertations

Understanding the effect of the functional groups at the terminus of the side chains is important for developing conjugated polymers through side chain engineering. Nucleobases, which are known for their multi-functionality, have not been deeply studied as functionality in conjugated polymers due to synthetic challenges. The overarching goal of my dissertation is to design, synthesize, characterize conjugated polymers bearing nucleobase functionality in their side chains and demonstrate their utility in various applications. Stille cross-coupling and direct arylation polymerization are used to synthesize adenine- and thymine-containing conjugated polymers. Monomer design requirements for successful polymerization are studied and conditions that optimize polymerization …

Motor Control-Based Assessment Of Therapy Effects In Individuals Post-Stroke: Implications For Prediction Of Response And Subject-Specific Modifications, Ashley Rice

Doctoral Dissertations

Producing a coordinated motion such as walking is, at its root, the result of healthy communication pathways between the central nervous system and the musculoskeletal system. The central nervous system produces an electrical signal responsible for the excitation of a muscle, and the musculoskeletal system contains the necessary equipment for producing a movement-driving force to achieve a desired motion. Motor control refers to the ability an individual has to produce a desired motion, and the complexity of motor control is a mathematical concept stemming from how the electrical signals from the central nervous system translate to muscle activations. Exercising a …

Hazardous Weather And Human Response In The Southeastern United States, Daniel Burow

Doctoral Dissertations

Effectively mitigating the human costs of future hazardous weather events requires examining meteorological threats, their long-term patterns, and human response to these events. The southeastern United States is a region that has both a high climatological risk and a high societal vulnerability to many different meteorological hazards. In this dissertation, I study hazardous weather and human response in the Southeast through three different lenses: identifying uniquely simultaneous hazards posed by tropical cyclones, assessing precipitation and synoptic weather patterns on hazardous weather days, and examining patterns in intended response to tornado watches. I find that simultaneous and collocated tornado and flash …

Spectroscopic Properties Of Ferroic Superlattices, Shiyu Fan

Doctoral Dissertations

The interplay between charge, structure, magnetism, and orbitals leads to rich physics and exotic cross-coupling in multifunctional materials. Superlattices provide a superb platform to study the complex interactions between different degrees of freedom. In this dissertation, I present a spectroscopic investigation of natural and engineered superlattices including Fe_xTaS₂ and (LuFeO₃)_m/(LuFe₂O₄)₁ under external stimuli of temperature and magnetic field as well as chemical substitution. Studying the phase transitions, symmetry-breaking, and complex interface interactions from a microscopic viewpoint enhances fundamental understanding of coupling mechanism between different order parameters and the …

Susceptibility Of Riverine Fishes To Anthropogenically-Linked Trauma: Strikes From Hydropower Turbine Blades, Ryan K. Saylor

Doctoral Dissertations

Hydropower accounts for nearly 40% of renewable electricity generation in the US; however, dams significantly impact the surrounding aquatic ecosystems. One of the most visible impacts of hydropower―beyond the dam itself―is the direct negative impacts (injury or death) to fish populations that must pass through hydropower turbines to access desired downstream habitat. During passage, fishes face many potential stressors that can cause severe injuries and often leads to high rates of mortality. In this dissertation, I have focused on quantifying how fishes respond to impacts from turbine blades that may occur during turbine passage. Laboratory research into blade strike impact …

Characterization And Benchmarking Of Quantum Computers, Megan L. Dahlhauser

Doctoral Dissertations

Quantum computers are a promising technology expected to provide substantial speedups to important computational problems, but modern quantum devices are imperfect and prone to noise. In order to program and debug quantum computers as well as monitor progress towards more advanced devices, we must characterize their dynamics and benchmark their performance. Characterization methods vary in measured quantities and computational requirements, and their accuracy in describing arbitrary quantum devices in an arbitrary context is not guaranteed. The leading techniques for characterization are based on fine-grain physical models that are typically accurate but computationally expensive. This raises the question of how to …

Regime-Switching Jump Diffusion Processes With Countable Regimes: Feller, Strong Feller, Irreducibility And Exponential Ergodicity, Khwanchai Kunwai

Theses and Dissertations

This work is devoted to the study of regime-switching jump diffusion processes in which the switching component has countably infinite regimes. Such processes can be used to model complex hybrid systems in which both structural changes, small fluctuations as well as big spikes coexist and are intertwined. Weak sufficient conditions for Feller and strong Feller properties and irreducibility for such processes are derived; which further lead to Foster-Lyapunov drift conditions for exponential ergodicity. Our results can be applied to stochastic differential equations with non-Lipschitz coefficients. Finally, an application to feedback control problems is presented.

Two Counting Problems In Geometric Triangulations And Pseudoline Arrangements, Ritankar Mandal

Theses and Dissertations

The purpose of this dissertation is to study two problems in combinatorial geometry in regard to obtaining better bounds on the number of geometric objects of interest: (i) monotone paths in geometric triangulations and (ii) pseudoline arrangements.

\medskip(i) A directed path in a graph is monotone in direction of $\mathbf{u}$ if every edge in the path has a positive inner product with $\mathbf{u}$. A path is monotone if it is monotone in some direction. Monotone paths are studied in optimization problems, specially in classical simplex algorithm in linear programming. We prove that the (maximum) number of monotone paths in a …

University City Sustainability Plan, Fall 2020 & Spring 2021, Alex Chow, Stepha Kvokov, Carter Rholl, Mary Kimball Vereen, Julia Grandury, Michael Lee, Maddie Parise, Theo Promlikitchai, Jacob Weinstein

Sustainability Exchange

University City Sustainability Plan, Sustainability Exchange, Washington University in St. Louis, Fall 2020 & Spring 2021

Habitat Characteristics Or Protected Area Size: What Is More Important For The Composition And Diversity Of Mammals In Nonprotected Areas?, Wenbo Li, Jinhua Li, Peipei Yang, Bowen Li, Chao Liu, Lixing Sun

Biology Faculty Scholarship

The margins of protected areas are usually considered to have greater forest degradation, and given that most mammals live outside protected areas, researchers and conservation practitioners are increasingly recognizing that nonprotected areas must be incorporated into conservation strategy. However, the strategy used to manage these areas still involves increasing the size of protected areas, while not considering the habitat characteristics and requirements of the species. In this study, during a 3-year period, camera trap and habitat characteristic surveys were used to estimate composition, diversity, and habitat characteristics of mammals to determine habitat characteristics or increase the size of protected areas …

The Generalized Riemann Hypothesis And Applications To Primality Testing, Peter Hall

University Scholar Projects

The Riemann Hypothesis, posed in 1859 by Bernhard Riemann, is about zeros
of the Riemann zeta-function in the complex plane. The zeta-function can be repre-
sented as a sum over positive integers n of terms 1/ns when s is a complex number
with real part greater than 1. It may also be represented in this region as a prod-
uct over the primes called an Euler product. These definitions of the zeta-function
allow us to find other representations that are valid in more of the complex plane,
including a product representation over its zeros. The Riemann Hypothesis says that
all …

Applications Of Evidence Theory To High-Consequence Systems Safety, Christina Marie Deffenbaugh

Mathematics & Statistics ETDs

Issues linked to abnormal environments (like high-consequence systems safety, e.g., nuclear weapon components, bridges, apartment buildings, etc.) may have insufficient information to use either classical statistical methods or Bayesian approaches for calculating associated probabilistic risks, so there is often a requirement for another method that can deal with a low-information situation to obtain a risk assessment. Belief/plausibility measures of uncertainty from A. P. Dempster and G. Shafer’s Evidence Theory is one such method. This thesis has two goals. First, a brief discussion on belief/plausibility measures as an application of Evidence Theory will familiarize the audience with its history and how …

Migmatite-Like Textures In Anthracite: Further Evidence For Low-Grade Metamorphic Melting And Resolidification In High-Rank Coals, James C. Hower, Susan M. Rimmer, Maria Mastalerz, Nicola J. Wagner

Center for Applied Energy Research Faculty and Staff Publications

Previous studies demonstrated that melting, initiated by supercritical fluids in the 375–400 °C range, occurred as part of anthracite metamorphism in the Appalachian Basin. Based on the known behavior of vitrinite at high temperatures and, to a lesser extent, at high pressures, it was determined that the duration of the heating, melting, and resolidification event was about 1 h. In the current study, featureless vitrinite within banded maceral assemblages demonstrates the intimate association of melted and resolidified vitrinite with anthracite-rank macerals. By analogy with metamorphosed inorganic rocks, such associations represent diadysites and embrechites, i.e., cross-cutting and layered migmatites, respectively. Even …

Heavy Metals In Ends Liquids: A Comparative Analysis Of Products From The United States, England, Canada, And Australia, Ashleigh Coggins-Block

Forensic Science Theses

The International Tobacco Control (ITC) Policy Evaluation Project 4-Country Survey, which this thesis is a part of, aims to compare policies and electronic nicotine delivery system (ENDS) products between the United States, England, Canada, and Australia. Since they can pose many serious health risks, this thesis investigated the presence of and source of heavy metals, including lead, nickel, chromium, and cadmium, in ENDS e-liquids. The source of these metals in ENDS e-liquids has been disputed between cultivated tobacco used to derive nicotine and the metal parts of ENDS devices. ENDS purchased in 2017 from each of the four countries of …

Comparison Of Raman Spectra Of Smokeless Powders For Cartridge Differentiation, Nathan Bartlett

Chemistry

As crimes involving firearms continue to be prevalent, forensic methods processing firearms evidence must keep pace with the changes in said evidence. Scanning Electron Microscopy with Energy Dispersive Spectroscopy, or SEM-EDS, is a method that targets the inorganic portions of gunshot residue (GSR) evidence, namely lead, barium, and antimony, to characterize a cartridge used at a crime scene, and was the most often used analysis method for characterizing ammunition cartridges. The rise of lead-free ammunition has made it so that SEM-EDS alone is not sufficient for the characterization of inorganic gunshot residue (IGSR), and studies have shifted towards being able …

The Business Of Chemistry: The Effect Of Chemical Innovation On The U.S. Cosmetics Market, Tania Gonzalez

Chemistry

This study discusses the relationship between two distinct fields of study: chemistry and economics. Chemistry is a business in itself and has major effects on the US economy. Examining the U.S cosmetics market and the recent development of organic products will show the effect on market growth and the growing importance of organic cosmetics in the United States. The recent awareness and concern for eco-friendly and safer ingredients fueled by millennials is discussed. The average annual expenditure in the U.S. cosmetics market is examined and inflation is taken into account. The purpose is to show the importance of research in …

The Sdss-Rm Project: Uv/Optical Accretion Disk Measurements For Supermassive Black Holes With Hubble Space Telescope, Megan Sturm

University Scholar Projects

We report accretion-disk structure measurements for eight rapidly accreting supermassive black holes selected from the Sloan Digital Sky Survey Reverberation Mapping project sample. Reverberation mapping uses light echoes to measure disk size from the time lag between variability in the inner/hotter and outer/cooler disk emission. We use Hubble Space Telescope ultraviolet observations coordinated with optical monitoring from the Liverpool Telescope and Las Cumbres Observatory. We find ten significant UV/optical lags for five out of the eight total targets. Through these time lags, we study the accretion disk as a function of disk size, temperature profile and radiative efficiency. We find …

Isolating And Manipulating Microorganisms Using Ureolysis For Creating Extraterrestrial Microbial Biotechnology Systems, Nina M. Wendel

Honors Theses

The conversion of CO2 into valuable feedstocks, such as high energy sugars would create paradigm shifting technologies for applications on earth and for interplanetary exploration. Microbes and microbe consortia may be one way to accomplish this conversion. Approximately 70% of the Earth’s microorganisms live in the dark marine biosphere (DMB). The DMB, which covers more than two-thirds of the Earth, is known as the most isolated region of the Earth’s largest CO2 sink. Despite its role in reducing CO2 and its vast majority of microorganisms, only about 5% of the sea floor has been explored. Due to the limited knowledge …

Development Of Multi-Objective Based Spectrum-Aware Routing Protocol For Cognitive Radio Ad Hoc Networks, Rashmi Naveen Raj

Manipal Institute of Technology, Manipal Theses and Dissertations

No abstract provided.

Oriented External Electric Field (Oeef) Tuning Of Unsubstituted Azoheteroarene Photoswitching Performance., Irma Avdic

College of Arts & Sciences Senior Honors Theses

Azoheteroarenes are relatively new photoswitchable compounds, where one of the phenyl rings of an azobenzene molecule is replaced by a heteroaromatic five-membered ring. Although few studies have been performed, recent findings on methylated azoheteroarenes show that these photoswitches have great potential in various optically addressable applications. Thermal stability of molecular switches is one of the primary factors considered in the design process. For the purposes of quick information transmission in materials science, the thermal (Z – E) relaxation process should be as short as possible. On the other hand, molecular memory storage devices prefer long Z - E relaxation times. …

Software Validation And Data Quality Monitoring Of The Klm Detector At Belle Ii., Dustyn Hofer

College of Arts & Sciences Senior Honors Theses

The Belle II Experiment at the SuperKEKB collider in Tsukuba, Japan is the latest of a new generation of B-factory experiments, designed to produce B meson particles in abundance. The aim of the Belle II experiment is to "discover new physics in the decay of the bottom quark (b), charm quark (c) and tau lepton (τ) and explore the dark sector." The SuperKEKB collider aims to produce instantaneous luminosities of upwards of 8 × 1035 cm−2 s−1, nearly an order of magnitude higher than previous B- factory experiments Belle and BABAR. Software packages, such as physics modules for the popular …

Cholesterol And Cholesterol Bilayer Domains Inhibit Binding Of Alpha-Crystallin To The Membranes Made Of The Major Phospholipids Of Eye Lens Fiber Cell Plasma Membranes, Raju Timsina, Geraline Trossi-Torres, Matthew O'Dell, Nawal K. Khadka, Laxman Mainali

Physics Faculty Publications and Presentations

The concentration of α-crystallin decreases in the eye lens cytoplasm, with a corresponding increase in membrane-bound α-crystallin during cataract formation. The eye lens’s fiber cell plasma membrane consists of extremely high cholesterol (Chol) content, forming cholesterol bilayer domains (CBDs) within the membrane. The role of high Chol content in the lens membrane is unclear. Here, we applied the continuous-wave electron paramagnetic resonance spin-labeling method to probe the role of Chol and CBDs on α-crystallin binding to membranes made of four major phospholipids (PLs) of the eye lens, i.e., phosphatidylcholine (PC), sphingomyelin (SM), phosphatidylserine (PS), and phosphatidylethanolamine (PE). Small unilamellar vesicles …

The Gini Index In Algebraic Combinatorics And Representation Theory, Grant Joseph Kopitzke

Theses and Dissertations

The Gini index is a number that attempts to measure how equitably a resource is distributed throughout a population, and is commonly used in economics as a measurement of inequality of wealth or income. The Gini index is often defined as the area between the "Lorenz curve" of a distribution and the line of equality, normalized to be between zero and one. In this fashion, we will define a Gini index on the set of integer partitions and prove some combinatorial results related to it; culminating in the proof of an identity for the expected value of the Gini index. …

Online Review Analysis From Two Perspectives: Customers And Business Owners, Eunjung Lee

Theses and Dissertations

As online reviews become increasingly prevalent, both online businesses and customers face big data challenges. Individuals are now relying on reviews derived from websites where the reliability of a source depends on the reviewers. Customers spend much time and effort looking for reviews that are useful for them. Accordingly, online review platforms aim to explore various approaches to select useful reviews and present them to customers. At the same time, for business owners, marketers, and e-commerce managers, it has become an essential strategy in recent years to collect as many online reviews as possible. If marketers and managers are able …

The Flow Less Traveled: Documenting Independent Original Research On Fluid Flow Interactions In The Laurentian Great Lakes And Immediate Surroundings, Thomas F. Hansen

Theses and Dissertations

This work is a compilation of several research projects undertaken by the author. Each research effort identifies a problem that has been addressed traditionally using methods that are significantly costly, to such an extent that, in general, funding, convenience, and practicality are primary limiting factors to their effective implementation. In each case, the author has been able to either build upon existing, less expensive alternatives, or even invent novel approaches. The fundamental recurring research question is, can creative, even novel, computational approaches make more efficient use of resources to interpret or present data in such a way as to make …

Molecular Weight Distributions And Size-Dependent Composition Of Dissolved Organic Matter In The Aquatic Continuum, Hui Lin

Theses and Dissertations

Dissolved organic matter (DOM) in aquatic environments is one of the most important carbon reservoirs in global carbon cycling. The molecular weight of DOM is strongly related to a great number of biogeochemical reactions, influencing ecological functions and the fate of bioactive elements in aquatic ecosystems. A new technique coupling flow field-flow fractionation with fluorescence excitation-emission matrix (EEM) and parallel factor (PARAFAC) analysis was developed to elucidate the variations in DOM composition and optical properties with molecular weight in the individual samples and their changes along the aquatic continuum. Based on the novel coupling technique, variations in DOM characteristics were …

Health Goals For Perfluorinated Alkyl Substances (Pfas): A Review Of Branched Isomers, The Role Of Industrial Sources, And The Implications Of Pfas In Biosolids On End-Of-Life Disposal Methods, Katarina Schulz

Theses and Dissertations

Per- and polyfluorinated alkyl substances, or PFAS, have been used for over half a century, but have become an emerging contaminant of significant concern due to their newly found widespread occurrence and recalcitrance in the environment, their tendency to bioaccumulate, and the health effects now associated with a very low level of exposure. Many gaps in knowledge remain about the fate of these chemicals in the environment and the extent of their impacts on biota. This thesis aims to fill some of the recognized gaps in knowledge: differences between linear and branched isomers of PFAS, predicting the presence of PFAS …

The Fermi-Gbm Gamma-Ray Burst Spectral Catalog: 10 Yr Of Data, S. Poolakkil, R. Preece, C. Fletcher, A. Goldstein, P. N. Bhat, E. Bissaldi, M. S. Briggs, E. Burns, W. H. Cleveland, M. M. Giles, C. M. Hui, D. Kocevski, S. Lesage, B. Mailyan, C. Malacaria, W. S. Paciesas, O. J. Roberts, P. Veres, A. Von Kienlin, C. A. Wilson-Hodge

Faculty Publications

We present the systematic spectral analyses of gamma-ray bursts (GRBs) detected by the Fermi Gamma-Ray Burst Monitor during its first ten years of operation. This catalog contains two types of spectra: time-integrated spectral fits and spectral fits at the brightest time bin, from 2297 GRBs, resulting in a compendium of over 18,000 spectra. The four different spectral models used for fitting the spectra were selected based on their empirical importance to the shape of many GRBs. We describe in detail our procedure and criteria for the analyses, and present the bulk results in the form of parameter distributions both in …

Assessment And Improvement Of Performance Of Septic Systems In Cold Climates (Year 1), Stu Geza, Todd Menkhaus, Lianping Li, Galen Hoogestraat

SDWRI Publications and Reports

Onsite septic systems are used for wastewater treatment for households not connected to sewers. There is a concern about surface and groundwater pollution when effectiveness becomes limited due to soil texture, soil temperature, neighborhood density, and distance to water resources. The goal of this study was to assess treatment performance of local soils and selected treatment media. Lab-scale column experiments were conducted using wastewater from Wastewater Reclamation Facility in Rapid City. The experiments were conducted inside and outside the lab to evaluate the effect of temperature. The columns outside the lab were subject to seasonal variation in temperature. Moisture content, …

Benefits Of The Snakemake Workflow Management Software In Comparision To Traditional Programming (Presentation), Josh Loecker

Honors Capstone Projects

No abstract provided.