Physical Sciences and Mathematics Commons^™

Structure Determination Of Pd2sin (N = 1 - 9) Clusters, Ryan Carlin

Honors College Theses

The geometry and relative stability of small Pd2Sin (n = 1 - 9) clusters are determined using the B3LYP hybrid density functional theory method. Candidate structures are identified by the utilization of unbiased global optimization procedures. From the lowest energy geometries, binding energy, fragmentation energy, second-order energy difference, and frontier orbital gap energy are calculated to determine cluster stability. Pd2Sin (n = 8 and 9) adapts new lowest energy geometric configurations that have previously not been considered. Pd2Si5 is determined to have a high relative stability of the clusters within this size range.

Storing Intermediate Results In Space And Time: Sql Graphs And Block Referencing, Basem Ibrahim Elazzabi

Dissertations and Theses

With the advancement of data-collection technology and with more data being available for data analysts for data-intensive decision making, many data analysts use client-based data-analysis environments to analyze that data. Client-based environments where only a personal computer or a laptop is used to perform data analysis tasks are common. In such client-based environments, multiple tools and systems are typically needed to accomplish data-analysis tasks. Stand-alone systems such as spreadsheets, R, Matlab, and Tableau are usually easy to use, and they are designed for the typical, non-technical data analyst. However, these systems are limited in their data-analysis capabilities. More complex data …

Game-Based Learning In Science: Can Video Games Simplify Organic Chemistry?, Rachel Israel

Senior Honors Theses

Organic chemistry has been taught in the same way for decades, and students still have difficulty understanding and comprehending the subject material. Perhaps it is time to change the methods by which this subject is taught. Video games have been successfully used in education to create learning environments that increase student motivation and engagement as well as challenge students and promote collaboration. It is difficult for students to maintain a growth mindset in organic chemistry within the classroom. However across different genres, video games create a unique environment where an individual is encouraged to try again when they fail. This …

Megasporogenesis, Microsporogenesis And Development Of Male And Female Gametophytes In Ceratoides Arborescens, Lina Lu, Xiao He, Jin Yi, Qingfeng Li

IGC Proceedings (1993-2023)

No abstract provided.

Effects Of Seed Size And Temperature On Seed Dormancy In An Alpine Meadow On The Eastern Tsinghai‐Tibet Plateau, Wenlong Li, Jing Xu, Guozhen Du, Zizhen Li

IGC Proceedings (1993-2023)

No abstract provided.

The Primary Study On Morphological Variations Of Elytrigria Repens Germplasm Resources, Peiying Li, Zongjiu Sun, Abulaiti

IGC Proceedings (1993-2023)

No abstract provided.

Study On Course Of Germinating, Seedling And Developing Of Ceratoides Seeds, Kurban Nizamidin, Israyil Barat

IGC Proceedings (1993-2023)

No abstract provided.

The Effect Of Chemical Scarification And Washing On The Germination Of Ferula Ovina Seeds, H. R. Keshtkar, F. Mellati

IGC Proceedings (1993-2023)

No abstract provided.

Species In Vernal Pools: Anova, Lisa Manne

Open Educational Resources

A one-way analysis of variance exercise using data on species diversities from vernal pools.Data are from vernal pools in Willowbrook Park (adjacent to College of Staten Island's campus) in spring.

The typical ANOVA gives a straightforward result (significant anova, easily-interpreted Tukey-Kramer analysis). This data set requires more nuanced interpretation, as the ANOVA is marginally significant, and Tukey-Kramer yields one significant pairwise comparison between groups. Relative lack of variation within groups explains this apparent enigma.

Disentangling The Effects Of Vapor Pressure Deficit And Soil Water Availability On Canopy Conductance In A Seasonal Tropical Forest During The 2015 El Niño Drought, Yilin Fang, L. Ruby Leung, Brett T. Wolfe, Matteo Detto, Ryan G. Knox, Bryan Powell, Charlotte Grossiord, Chonggang Xu, Bradley O. Christoffersen, Pierre Gentine

Biology Faculty Publications and Presentations

Water deficit in the atmosphere and soil are two key interactive factors that constrain transpiration and vegetation productivity. It is not clear which of these two factors is more important for the water and carbon flux response to drought stress in ecosystems. In this study, field data and numerical modeling were used to isolate their impact on evapotranspiration (ET) and gross primary productivity (GPP) at a tropical forest site in Barro Colorado Island (BCI), Panama, focusing on their response to the drought induced by the El Niño event of 2015–2016. Numerical simulations were performed using a plant hydrodynamic scheme (HYDRO) …

Modernizing Legacy Business Practices And Maintaining Backwards Compatibility When Replacing Legacy Software, Thomas Hillebrandt

Honors Theses

As technology advances and hardware as well as user expectations becomes more advanced, software systems must change alongside or go obsolete. When software is no longer developed, decisions must be made regarding its future. Through various methods, legacy software may continue to see usage far past its obsolescence, however legacy software will sooner or later face replacement by new applications, built for state-of-the-art machines, to comply with modern requirements. When writing new software to replace older programs, the added challenge for developers is to help the client also modernize their workflow. When a program has been in long time use …

Investigations Involving Mononuclear And Dinuclear Transition Metal Catalysts For Photochemical Carbon Dioxide Reduction, Ansu Edwards

Honors Theses

There is currently a global energy crisis, which is in desperate need of solutions. New energy sources are required that will not pollute as much as our longstanding reliance on nonrenewable fossil fuels as an energy source. This pollution involves large amounts of greenhouse gas emissions, predominantly carbon dioxide (CO₂), that contribute to environmental problems such as climate change. In this context, a fairly recent research direction to address this problem is the development of transition metal catalysts that can convert CO₂ into reduced carbon products that can serve as chemical fuels. This work focuses on the …

Effects Of Halogen Bonding On 13c Nmr Shifts Of Various Tolan Species, Anthony Lybrand

Honors Theses

Halogen bonding is slowly becoming a more and more useful part of the world of chemistry and is beginning to be incorporated into various aspects of the chemical industry. This study’s purpose is to determine whether or not halogen bonding can cause any effect in the 13C NMR shifts. The specific purpose of this study is to determine whether these chemical shifts change when a Lewis Base is added to the dissolved sample. In order to do this, the tolan species (4-iodotolan and 4-chlorotolan) had to be synthesized. Once synthesized, the tolan species were analyzed via NMR. NMR data indicated …

Effects Of Crowding Agents On I-Motif Dna, Hayden Brines

Honors Theses

Deoxyribonucleic acid (DNA) is a well-known double stranded, helical, biological molecule. In addition to its more commonly known structure, DNA can also form more complicated structures like G-quadruplexes and i-motifs (iM). The iMs are formed by cytosine rich DNA and are a four stranded structure that is typically looped around itself. The iM formation is typically pH-dependent and is favored in more acidic conditions; the pKa value is approximately 6.5. This pKa value allows for potential in vivo formation, since the cells have a pH of approximately 7.3. Due to this, iMs are thought to be powerful, innovative molecules for …

Characterization Of Mechanical Responses Of Helical Antenna For Satellite Communications, Scott Chumley

Honors Theses

The purpose of this work was to identify and analyze the vibrational modes of a helical structure to model the vibrational characteristics of an L-band helical antenna for satellite communications. This project focused on the vibrational modes between 1 and 50 Hz. Using COMSOL Multiphysics finite element modeling of helices were performed to predict mode shapes and frequencies to compare with both continuous wave (CW) and impulsive measurements. In the initial phase of the experimental work, five helical samples were constructed and evaluated. In the second phase of the study, one sample was chosen for more detailed quantitative measurements. In …

End Group Modification Of Linear Dendritic Block Copolymers (Ldbcs), Chinwe Udemgba

Honors Theses

Linear dendritic block copolymers are amphiphilic molecules that consist of a dendritic hydrophilic portion and a linear hydrophobic portion. Its unique ability to self-assemble into spherical nanoaggregates while having the potential to uptake and transport both hydrophilic and hydrophobic drugs makes these polymers an item of interest in regard to the drug delivery field. The synthesis of polyamidoamine-polylactide linear dendritic block copolymers was designed to address the common issues in drug delivery systems, including problems in permeability, solubility, stability, specificity, and retention. Though this linear dendritic block copolymer has previously been synthesized in our lab with cationic amine surface functionalities, …

Applications Of Sodium Azide In The Synthesis Of Tetrazines And Hydrolysis Reactions, My Le

Honors Theses

The inverse electron demand Diels−Alder cycloadditions of heterocyclic azadienes have provided a robust methodology for synthesizing highly substituted and functionalized heterocycles. It is widely used in organic synthesis and the pharmaceutical industry in the divergent construction of screening libraries and bioorthogonal conjugation. Each heterocyclic azadiene was found to possess a unique reactivity toward different classes of dienophiles, display predictable modes of cycloaddition, and exhibit substantial substituent electronic effects impacting their intrinsic reactivity and cycloaddition regioselectivity. Synthesis of 1,2,4,5-tetrazine has been reported in the literature since the late 19th century, showing scientists' tremendous interest in its application.

Herein we attempt to …

Determination Of Metals And Microplastics In Sediment From Oyster Reefs In The Mississippi Sound, Shelby Goza

Honors Theses

This research centers on the determination of metals (Cd, Pb, V, Cr, Mn, Fe, Co, Ni, Cu) and microplastics (MPs) in marine sediment from oyster reefs in the Mississippi Sound Estuary. Oysters (Crassostrea virginica) are a vital part of the Gulf Coast economy, but their population has dramatically declined in recent years due to multiple stressors, including oil spills and fluctuations in salinity from flooding. Increasingly frequent flooding events also introduce high loads of MPs and sediments containing heavy metals from the Mississippi River. These pollutants can have deleterious effects on oyster biology; however, they have not been adequately …

Computational Investigation Of Stellar Cooling, Noble Gas Nucleation, And Organic Molecular Spectra, Jax Dallas

Honors Theses

Since the advent and optimization of the Hartree-Fock method, quantum chemistry has been utilized to investigate systems operating on timeframes and environments traditionally unavailable to bench-top chemistry. As computational methods have grown more robust and less time consuming, quantum chemistry has been utilized to investigate a range of fields, including the steadily growing discipline of computational astrochemistry. Through the lens of computational astrochemistry, chemistry that occurred billions of years ago can be explored with equal clarity to that which is currently happening in the cosmos. The work presented throughout this thesis is a series of investigations into different timeframes of …

Lesson Plan: Sounds Of Your Study Site, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

In this lesson, students will conduct a survey of noise in the study site. They will begin to explore the idea that noise has an impact on the ecosystem and its inhabitants. In small groups, they will use a decibel meter, data sheet and aerial photograph of the study site to collect data on a section of the site. Students will then share this information with classmates to create a map of the noise of your schoolyard. Then students will listen to prerecorded bird songs against urban noise. They will compare the bird songs and the characteristics that make them …

Student Pages - Sounds Around Your Study Site: Conducting A Noise Survey, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

The goal of this lesson is to conduct a survey of noise at your study site. In small groups, you will use a decibel meter, data sheet and an aerial photograph of your site to collect data on a particular section. You will then share this information with your classmates to create a map of the noise of your schoolyard.

Student Pages - Answer Key - Sounds Around Your Study Site: Conducting A Noise Survey, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

No abstract provided.

Lesson Plan: Behavioral Plasticity, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

In the previous lessons, students learned about the importance of noise in the urban environment. In response to urban noise as well as other characteristics of urban ecosystems, organisms modify their existing behaviors to maximize their fitness and likelihood of survival. This lesson focuses on behavioral plasticity, which is the idea that organisms’ behaviors are flexible and can be modified in response to their environment. Students complete an activity in which they investigate the plasticity of their own behaviors. The class then discusses how this analogy is similar and different compared to urban species as well as how the plasticity …

Structure Cards, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

No abstract provided.

Student Pages - How Do Behaviors Impact Survival?, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

Species constantly engage in a variety of behaviors or activities that help increase their chance of survival. For example, a bird may build a nest or a coyote might communicate to other coyotes through howling. In this activity, you are going to explore the plasticity of behaviors – the ability of an organism to change or modify its behaviors based on the external conditions. Specifically, you will examine your own behaviors, but then consider how your behaviors would be similar or different from other species. You will then consider how the plasticity of an organism’s behaviors impacts its chance of …

Student Pages - Answer Key - How Do Behaviors Impact Survival?, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

No abstract provided.

Lesson Plan: Developing A Persuasive Scientific Argument, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

In this lesson, students examine their data and construct an argument that answers their original research question. Students apply what they have been learning about behavioral adaptations to make sense of their bioacoustics data. After analyzing their data in groups and writing up their arguments, they present their research studies to the class, including their research question, methodology, and conclusions from their data. As part of these presentations, the class will discuss the validity of the different groups’ claims and whether they are supported by the data collected from the field as well as the various science concepts they have …

Presentation Template, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

No abstract provided.

Student Pages - Developing A Persuasive Scientific Argument, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

No abstract provided.

Lesson Plan: Comparing Our Results, Center For Urban Resilience

Module 07: Animal Adaptation & Behavior

The purpose of this lesson is for students to compare their findings to that of other similar studies. The goal of the lesson is two-fold. First, students should understand the big idea that organisms living in urban ecosystems have modified their behavior in response to the impacts of the humans that live there. Second, this lesson should reinforce the concept of sample size as well as help students understand that we still have many gaps in our understanding of animals in cities.